Chapter 7 - Structural Properties of Matter
Chapter 7 - Structural Properties of Matter
Every atom is electrically neutral, the number of electrons (negative charge) orbiting around the
nucleus is equal to the number of proton (positive charge) in the nucleus. So if two atoms are placed at a
very large distance from each other then there will be a very small (negligible) interatomic force
working between them.
When these two atoms are brought close to each other to a distance of the order of 10–10 m, the
distances between their positive nuclei and negative electron clouds get disturbed, and due to this,
attractive interatomic force is produced between two atoms.
This attractive force increases continuously with decrease in r and becomes maximum for one value of r
called critical distance, represented by x (as shown in the figure). Beyond this the attractive force starts
decreasing rapidly with further decrease in the value of r.
When the distance between the two atoms becomes r0, the interatomic force will be zero. This distance r 0
is called normal or equilibrium distance.
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r0 = 0.74 Å for hydrogen
When the distance between the two atoms further decreased, the interatomic force becomes
repulsive in nature and increases very rapidly with decrease in distance between two atoms.
3. The intermolecular force is the reason for the elasticity of solid objects Explain.[R.B., C.B., Ctg.B., B.B-18]
Ans. Elasticity is the property of matter by which object regains original shape and size after removing the
deforming force. Intermolecular force is the force of attraction between two molecules. Distance between
the molecules. In solid object increases when it is deformed by applying force.
Again distance between the molecules in the solid decreases and object regains original shape when the
deforming force is removed.
Therefore intermolecular force in solid object is cause of elasticity.
4. What is stress?
Ans. For any deformation, the Force applied per unit area is known as stress. If the applied force is F acts
over an area A to deform material, then
𝐹
Stress =
𝐴
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Ans. The minimum amount of stress up to which an object shows elasticity is known as elastic limit.
11. Define breaking load and breaking stress.
Ans. The minimum load for which a material may become torn is called breaking load and the stress
caused by this heavy load is called breaking stress. Thus, the smallest force applied per unit area for which
any material tears or breaks is called the breaking stress of that material.
12. What is Elastic fatigue?
Ans. When stress is varied or applied constantly on a wire over a long period of time its elasticity
decreases, therefore, after the applied stress is removed it does not return to its original form at all. This
phenomena is called elastic fatigue.
13. What is the difference between Elastic limit and Elastic fatigue?
Ans. Elastic limit refers to the maximum value of stress or force for which a material shows elastic
behaviors. And elastic fatigue is the temporary loss of elastic properties because of the action of repeated
alternating deforming force. Then a wire may break even when a force less than the elastic limit is
applied. The key difference between these two is that if elastic limit is crossed the material loses its
elasticity and doesn't regain its original shape or size but in case of elastic fatigue, a material loses its
elasticity temporarily and regains elasticity again after a while.
14. Explain the causes of creasing elastic fatigue of a body. [D.B.; Dj.B.; S.; .J.B. 18]
Ans. Within elastic limit, if an object is continuously or regularly strained means the stress is increased and
decreased continuously then strain will not occur with stress strain occurs slowly and elasticity of the object
reduces. In this condition, the object might snap or break below the breaking weight. This is the cause of elastic
fatigue.
15. Explain longitudinal strain and longitudinal stress.
Ans. Longitudinal strain: If the applied force acting along a body causes a change in length then each unit
change per unit length is called longitudinal strain. If a body of length L subjected to an applied force along
its length deforms by a length l, then –
𝑙
Longitudinal Strain =
𝐿
Longitudinal stress: The restoring force created per unit cross section area on a body because of its
elasticity for any change in length is known as its longitudinal stress. That is –
𝑟𝑒𝑠𝑡𝑜𝑟𝑖𝑛𝑔 𝑓𝑜𝑟𝑐𝑒 𝐹
Longitudinal stress = =
𝑐𝑟𝑜𝑠𝑠−𝑠𝑒𝑐𝑡𝑖𝑜𝑛𝑎𝑙 𝑎𝑟𝑒𝑎 𝐴
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Ans. Volumetric or Bulk strain: If the applied force acting along a body causes a change in volume, then
each unit change per unit volume is called volumetric or bulk strain. If a body of volume V subjected to an
applied force reduces by a volume v, then –
𝑣
Volumetric or bulk Strain =
𝑉
Volumetric or Bulk stress: The restoring force created per unit cross section area on a body because of its
elasticity for any change in length is known as its longitudinal stress. That is –
𝑟𝑒𝑠𝑡𝑜𝑟𝑖𝑛𝑔 𝑓𝑜𝑟𝑐𝑒 𝐹
Volumetric or Bulk stress = =
𝑠𝑢𝑟𝑓𝑎𝑐𝑒 𝑎𝑟𝑒𝑎 𝐴
Shearing stress: If a shearing deformation is produced on the surface of a body due to an applied
tangential force, the restoring force created per unit area on the at surface in known as shearing stress.
That is –
𝑟𝑒𝑠𝑖𝑠𝑡𝑎𝑛𝑐𝑒 𝑡𝑎𝑛𝑔𝑒𝑛𝑡𝑖𝑎𝑙 𝑓𝑜𝑟𝑐𝑒 𝐹
Shearing stress = =
𝑠𝑢𝑟𝑓𝑎𝑐𝑒 𝑎𝑟𝑒𝑎 𝐴
The magnitude of this constant depends entirely upon the material the body is made of. This is known as
elastic modulus or modulus of elasticity.
Its unit is Nm-2 and dimension is ML-1T-2
19. State Young’s modulus.
Ans. Within elastic limit the ratio of the longitudinal stress to the longitudinal strain produced on a body is
called Young’s modulus. It is denoted by Y and
𝐹
𝑙𝑜𝑛𝑔𝑖𝑡𝑢𝑛𝑎𝑙 𝑠𝑡𝑟𝑒𝑠𝑠 𝐴 𝐹𝐿
Young’s modulus: Y = = 𝑙 =
𝑙𝑜𝑛𝑔𝑖𝑡𝑢𝑑𝑖𝑛𝑎𝑙 𝑠𝑡𝑟𝑎𝑖𝑛 𝐴𝑙
𝐿
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Ans. Within elastic limit the ratio of the volumetric stress to the volumetric strain produced on a body is
called bulk modulus. It is denoted by Y and
𝐹
𝑣𝑜𝑙𝑢𝑚𝑒𝑡𝑟𝑖𝑐 𝑠𝑡𝑟𝑒𝑠𝑠 𝐹𝑉
Bulk modulus: 𝛽 = = 𝐴
𝑣 =
𝑣𝑜𝑙𝑢𝑚𝑒𝑡𝑟𝑖𝑐 𝑠𝑡𝑟𝑎𝑖𝑛 𝑉
𝐴𝑣
Ans. Young's modulus of a material, Y = 2 1011 Nm2 means applying a force of 2 1011 along length of a wire
having cross sectional area of 1 m2 will increase its length so that change of length will be equal to its initial
length.
23. What is compressibility?
Ans. Within elastic limit the ratio of bulk strain to bulk stress is known as compressibility. That is –
𝑏𝑢𝑙𝑘 𝑠𝑡𝑟𝑒𝑠𝑠 1 1
Compressibility = = 𝑏𝑢𝑙𝑘𝑠𝑡𝑟𝑒𝑠𝑠 =
𝑏𝑢𝑙𝑘 𝑠𝑡𝑟𝑎𝑖𝑛 𝛽
𝑏𝑢𝑙𝑘 𝑠𝑡𝑟𝑎𝑖𝑛
So, the compressibility is opposite to the bulk modulus. That is why, bulk modulus is also called
incompressibility.
24. What is rigidity modulus?
Ans. Within elastic limit the ratio of the shearing stress to the shearing strain produced on a body is called
rigidity modulus. It is denoted by Y and
𝐹
𝑠ℎ𝑒𝑎𝑟𝑖𝑛𝑔 𝑠𝑡𝑟𝑒𝑠𝑠 𝐹
rigidity modulus: 𝜇 = = 𝐴
=
𝑠ℎ𝑒𝑎𝑟𝑖𝑛𝑔 𝑠𝑡𝑟𝑎𝑖𝑛 𝜃 𝐴𝜃
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Ans. Poisson's ratio of copper being 0.33 implies that the ratio of lateral strain to longitudinal strain of a
copper within its elastic limit is 0.33.
27. Why does not the Poisson's Ratio depend on the stress applied, within the elastic limit? [R.B., C.B.,Ctg.B., B.B.-18]
Ans. Poisson's ratio is the ratio of relative lateral strain normal to the applied force to the relative axial strain
in the direction of applied force. The applied most be within elastic limit. So, Poisson’s ration depends on
whether volume of material increases or decreases or remains same when force applied on it. This on the
other hand depends on the property of the material. That's why Poisson’s ratio depends on material only, hot
on applied force.
28. What is elastic potential energy? Or,
𝟏
Show that the potential energy stored per unit volume = 𝐗 𝐒𝐭𝐫𝐞𝐬𝐬 𝐗 𝐒𝐭𝐫𝐚𝐢𝐧 .
𝟐
Ans. We know, work done in order to change the shape of any body,
dW = Fdl
𝑙
𝑙 𝑙 𝑌𝐴𝑙𝑑𝑙 𝑌𝐴 𝑙2 1 𝑌𝐴𝑙2 1
W = ∫0 𝐹𝑑𝑙 = ∫0 = [ ] = = 𝐹𝑙
𝐿 𝐿 2 0 2 𝐿 2
1
Thus, elastic potential energy = X applied force X extension
2
1 F l 1
= X X = X Stress X Strain
2 A L 2
𝐹𝐿
And Young’s modulus for the rubber wire, Yr =
𝐴𝑙𝑟
𝐹𝐿
𝑌𝑠 𝐴𝑙𝑠 𝑙𝑟
From the above two equation, = 𝐹𝐿 =
𝑌𝑟 𝑙𝑠
𝐴𝑙𝑟
As ls < lr then we can conclude that Ys > Yr that is steel is more elastic than rubber.
30. What is flow of fluid?
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Ans. The state of motion of liquid or gas is known as its flow of fluid.
31. How many types of flow of fluids are there?
Ans. There are two types of flow:
i) Streamline flow: In fluid dynamics, when a fluid in practical layers with no disruption between them.
ii) Turbulent flow: When the molecules of a fluid do not flow parallel to the direction of motion or parallel
to each other.
If a relative velocity exists between two layers, then viscous force will act to oppose their motion.
Newton proved that at a particular temperature the force,
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F α A and
𝑑𝑣
Fα
𝑑𝑦
𝑑𝑣
Therefore, F = -ηA where 𝜂 is constant of proportionality. It’s value depends on the temperature and
𝑑𝑦
That is, if the velocity gradient is unity, the viscous force acting over unit surface area between the
adjacent layers of the fluid is defined as the coefficient of viscosity.
The coefficient of viscosity is a measure of the viscosity of the fluid. i.e., coefficient of viscosity measures
how viscous the fluid is. .
It’s unit is Nsm-2 and dimension is ML-1T-1
35. What is 1 poise?
Ans. 1 poise is the unit of co-efficient of viscosity. It is the viscosity of a fluid that requires a shearing force
of 1 dyne to move a square centimeter area of either of two parallel layers of fluid 1 centimeter apart with
a velocity of 1 centimeter per second relative to the other layer, the space between the layers being filled
with the fluid. 1 poise = 0.1 Pa-s.
36. Compare frictional and viscous force.
Ans.
i. Viscous force prevents the relative flow between two layers of a fluid and frictional force prevents
the relative movement of the particles between two layers of solids in contact with each other. So
viscosity is called internal friction.
ii. A viscous force is not observed in stationary fluid but friction is always present in stationary body.
iii. Magnitude of frictional force does not depend on the surface area of contact or the relative speed
where viscous force depends on the relative surface area in contact and relative speed of the fluid.
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According to this theorem, if a sphere of radius r is moving with a velocity v inside a fluid whose
coefficient of viscosity is 𝜂, then
Fαr
Fαv
Fαη
So, F = krvη
Experimentally proved that k = 6π
F = 6πrvη
This expression can be proven using dimension analysis
F = kra vbηc
Therefore, [F] = k[ra] [vb] [ηc]
[MLT-2] = [L]a [LT-1]b [ML-1T-1]c
Equating the indices of ML and T on both sides we get, c = 1,
-b – c = -2, ∴ b = 1
a+b–c=1
a=1
Using mathematical derivations Stokes proved that k = 6 π
F = krvη = 6πrvη
38. What's terminal velocity?
Ans. Terminal velocity is the limiting uniform velocity attained by a falling body when resistance of the air
has become equal to the force of gravity.
39. State the equation for Coefficient of viscosity.
Ans. When a particle falls under the influence of gravity through any fluid, 3 forces acts upon it –
i) weight (W) – downward
ii) upthurst (U) – upward
iii) viscous drag (F) – opposite to the direction of particles
Thus the net force on the particle = W – (U + F)
Thus the net force on the particle = W – (U + F)
Viscous force F depends on the velocity of the particle, v.
Initially, when v = 0, F = 0 and net force = W – U
As the particle’s speed increases, the viscous drag F increases and the net force decreases proportionately.
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At one point net force becomes zero and object comes down at uniform velocity named as terminal
velocity denoted by vt
If the particles is a sphere of radius r, then –
𝟒
The weight of the sphere, (W) = 𝝅𝒓𝟑 𝝆𝒔 𝒈
𝟑
𝟒
Upthurst (U) = weight of the volume of displaced fluid = 𝝅𝒓𝟑 𝝆𝒇 𝒈
𝟑
When the sphere reaches to its terminal velocity, v = v t and the net force becomes zero. So,
4
𝜋𝑟 3 (𝜌𝑠 − 𝜌𝑓 ) − 6πrvη = 0
3
4
6πrvη = 𝜋𝑟 3 (𝜌𝑠 − 𝜌𝑓 )
3
2𝑟 2 (𝜌𝑠 −𝜌𝑓)𝑔
Or, 𝜂 =
9𝑣𝑡
In case of gas:
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The viscosity of gases increases with the increase of temperature. Experimentally proven that,
𝜂 ∝ √𝑇
42. Explain the change of surface tension with the increase of temperature of liquid.
Ans. Surface tension of a liquid changes with temperature according to this equation T = T (1 α). Here, T
& T0 are respectively surface tension at & 0C, is a constant. According to this equation, surface tension
decrease as temperature increases. And according to molecular theory of surface tension, it evolves from
intermolecular force which decreases with temperature increase because of increasing temperature. Hence,
surface tension decreases with increase of temperature.
43. What is the effect of pressure on viscosity?
Ans. In case of liquids:
The viscosity of liquid materials increases with the increase of pressure.
In case of gases:
Based on kinetic theory of gases Maxwell observed that there is no effect of pressure on the viscosity of a
gas, however, there are some exception in case of low pressure.
44. What's surface tension?
Ans. If a line is imagined on the surface of a liquid. Then a force is acting on the line perpendicularly but
tangential to the liquid surface. The force per unit length of the imaginary line is known as surface tension.
𝑓𝑜𝑟𝑐𝑒
Surface tension, T =
𝑙𝑒𝑛𝑔𝑡ℎ
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Ans. If a large drop is divided into several smaller droplets then its surface area INCREASES.
If the radius of small drop r and big drop R then
4 4
𝜋𝑅 3 = 𝑁 𝜋𝑟 3
3 3
𝑅
r= 1
𝑁3
53. Explain the change of surface tension with the increase of temperature of liquid.
Ans. Surface tension of a liquid changes with temperature according to this equation T = T (1 α). Here,
T& T0 are respectively surface tension at & 0C, is a constant. According to this equation, surface tension
decrease as temperature increases. And according to molecular theory of surface tension, it evolves from
intermolecular force which decreases with temperature increase because of increasing temperature. Hence,
surface tension decreases with increase of temperature.
54. What is a capillary tube?
Ans. In Latin, the word 'capillus' means hair or a lock of hair. A capillary tube is a tube that hasan internal
diameter of hair like thinness.
55. What is angle of contact?
Ans. It is defined as the angle made by the tangent at the point of contact with the tangent plane to the
solid surface inside the liquid. It is denoted by .
56. Why water sticks to glass while doesn't stick to taro leaves? Explain.
Ans. Cohesive force between molecules of water is greater than the adhesive force between water of
leaves of taro. So, water doesn't stick with taro leaves. On the other hand, adhesive force between water &
glass is greater than the cohesive force between water molecules. So, water sticks with glass.
57. Explain why hot soup is more tasteful than cold one.
Ans. Soup is a viscous liquid. Its viscosity decreases with temperature. It soup becomes it tends not to flow
over the tongue & doesn't come to the contact of taste buds well. But viscosity of hot soup is less & it
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diffuses all over the tongue & comes to well contact of the taste buds. That's why hot soup tastes better
than the cold one.
58. Why is drop of rain spherical? [D.B,.Dj.B., S.B., J.B., 18]
Ans. There is potential energy stored on liquid surface which depends on the surface. This potential energy
decreases with the decrease of surface area. In nature everything becomes stable when its potential energy is
the lowest. So, for lowest potential energy in this case the surface area has to be minimum. For a certain
volume, an object has minimum surface area when it's spherical in shape. That's why rain drops shape is
spherical.
59. Explain the reason behind the water rise in Capillary tube made of glass.
Ans. Adhesive force between molecules of water and glass is greater than the cohesive force between
molecules of water. That's why water wets glass. Hence contact angle between water and glass is an acute
one. As a result when a capillary tube is inserted into water, upper surface of water inside the tube
become concave & surface area increases. But due to surface tension of water, the surface tends to reduce
its area which in turn produces an upward force that moves up the water inside the capillary tube.
60. Explain the absorption of water by a tissue paper.[J.B. 17]
Ans. The adhesive force between tissue paper & water is greater than the cohesive between water
molecules. Apart from that the fine pores in tissue paper behave as capillary tubes which absorb water.
That's how tissue paper absorbs water.
61. Water speed is more in hot water than cold water – why?
Ans. Flow of liquid depends on its viscosity. The less the viscosity of fluid the more the flow. When
temperature increases then the coefficient of viscosity of water decreases. So hot water speed becomes
more than the cold water.
62. Draw a terminal velocity vs time graph if a metallic ball is dropped in a viscous liquid.
Ans. When a metallic ball is dropped in a viscous liquid then initially due to gravity it’s velocity go on
increasing. But after some time due to increase of frictional force force of gravity and frictional force
becomes same and as a result the ball will start flowing at constant velocity. Which is called terminal
velocity. The graph between terminal velocity and the time graph is as follows:
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63. Explain the relation between liquid density and contact angle.
Ans. The liquids which density is less than the solid those liquids wet the solid surface and in this case
contact angle become acute angle.
64. In a glass surface if equal amount of oil and glycerin are kept then which will take more space? Explain.
Ans. We know, the less the density of material the more spread the substance. Here, density of oil is less
than the glycerin. So, when these two are brought in contact of same material then oil will spread more
that is will take more space.
65. Explain the relation between intermolecular force and intermolecular space.
Ans. We know that the special type of force by which the molecules are attached with each other is called
intermolecular force. And the molecules attract each other from almost 10-9 to 10-10 m distance. When the
distance changes then the force also changes. If the distance increases then the intermolecular force
decreases.
66. In capillary tube why mercury depression is visible?
Ans. We know that the liquids which density is more than the solid those liquids do not wet the solid
surface and in this case contact angle become obtuse angle. As the density of mercury is more than the
solid so mercury does not wet the glass surface. Rather than produces obtuse angle. So, mercury
depression is visible in capillary tube.
67. What do you mean by positive Poisson’s ratio?
Ans. Positive Poisson’s ratio means for positive length deformation lateral strain also remains positive. i.e.,
when force is applied for expanding the length it increases laterally also.
68. Rain water does not go through the umbrella in spite of the pores in the umbrella – explain.
Ans. When the rain drop falls on umbrella then due to surface tension of water it takes the round shape
and rolls down in spite of pores on umbrella fabric.
69. If a large rain drop splits into small drops then will there be any change in heat? Explain.
Ans. When a large water drop splits into small drops then energy is absorbed. As a result heat is produced.
Because, work is done to change the surface area.
Try
o What is matter?
o Explain different states of matter and the reason for different states
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o What do you understand by the spring constant of a spring is 5 N/m?
Ans. Spring constant is the restoring force that's exerted by the spring when its free end is displaced by unit
amount. So, if spring constant of a spring is 5N/M, that means a force of 5N has to be applied on the spring
to cause l m displacement of its free end.
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