www.sakshieducation.

com

Atomic & Molecular Weights, Mole Concept and Equivalent

Weights

1. Molecular mass of Silver (Z=47) is

1) 47amu 2) 47gm 3)108amu 4)108gm

m
2. Molar mass of Sulphur is

co
1) 32amu 2) 32gm 3) 256amu 4) 256gm

3. The number of water molecules in a drop of water weighing 5mg is

n.
1) 6.023×1022 2) 3.0125×1021

io
3) 1.67×1020 4) 1.67×1021

at
4. The mass of 1.5×1019 molecules of a substance is 2mg. The molar mass of the
uc
substance is
ed

1) 20g 2) 40g 3) 80g 4) 80 a.m.u.

hi

5. The number of nitrogen molecules present in 1c.c of gas at NTP is

1) 2.67×1022 2) 2.67×1021 3) 2.67×1020 4) 2.67×1019

ks

6. The density of water is 1g/mL. Assuming that there are no interspaces between
a

water molecules in liquid water, the volume of a water molecule is

.s

1) 1.5×10–23ml 2) 6×10–23ml
w

3) 3×10–23ml 4) 3×10–22ml
w
w

7. The equivalent weight of glucose in the reaction

C6H12O6 + 6O2  6CO
2 + 6H2O is [M=mol. wt]

1) M 2) M/6 3) M/12 4) M/24

www.sakshieducation.com
 www.sakshieducation.com
8. A gaseous mixture contains oxygen and nitrogen in the ratio 1:4 by weight. The
ratio of their number of molecules is

1) 1:4 2) 4:1 3) 7:32 4) 3:16

9. The number of oxygen atoms present in 50g of calcium carbonate is

1) 6.023×1023 2) 30.1×1023 3) 9.035×1023 4) 1.206×1024

m
10. The mixture containing the same number of molecules as that of 14 g of CO is

co
1) 14g of nitrogen + 16g of oxygen 2) 7g of nitrogen + 16g of oxygen

n.
3) 14g of nitrogen + 8g of oxygen 4) 7g of nitrogen + 8g of oxygen

io
11. 3gm of carbon is completely burnt to get carbon dioxide. The number of
molecules of CO2 obtained is

1) 6×1023 2) 3×1023
at3) 1.5×1023 4) 7.5×1022
uc
12. Which of the following contains the maximum number of atoms?
ed

1) 10g of CaCO3 2) 4g of hydrogen 3) 9g of NH4NO3 4) 1.8g of C6H12O6

hi

13. Which contains more number of molecules?

ks

1) 1g of carbon dioxide 2) 4g of hydrogen 3) 8g of oxygen 4) 6g of Urea

a

14. Which of the following gases has the highest density under standard conditions?
.s

1) CO 2) N2O 3) C3H8 4) SO2

w

15. Which of the following is heaviest?

w

1) 50g of iron 2) 5 moles of nitrogen

w

3) 0.1 gram atom of silver 4) 1023 atoms of carbon

16. The molar volume of any gas at STP is

1) 1 liter 2) 22.414 lit 3) 6.02×1023 lit 4) 22.414 ml

www.sakshieducation.com
 www.sakshieducation.com
17. 1 gram - atom of oxygen is

1) 1 g of oxygen 2) 16g of oxygen 3) 22.4 g of oxygen 4) 8g of oxygen

18. One gram molecule of oxygen is

1) 16 g of oxygen 2) 32 g of oxygen 3) 8g of oxygen 4) 1g of oxygen

19. Avogadro number is

m
1) The number of atoms in one gram-atomic-weight

co
2) The number of molecules in one gram-molecular-weight

n.
3) The number of atoms in 0.012 kg of C–12

io
4) All of these

at
20. A mole is uc
1) The amount of substance containing the same number of chemical units as the
number of atoms in exactly 12g of C12.
ed

2) The amount of substance containing Avogadro number of chemical units.

hi

3) The unit for expressing amount of a substance

ks

4) All the above

21. The mass of a mole of hydrogen atoms is

a
.s

1) 1.008 g 2) 2.016g 3) 6.02×1023g 4) 1.008 amu

w

22. The molar mass of hydrogen is

w

1) 1.008 g 2) 2.016 g 3) 6.02×1023 g 4) 2.016 amu

w

23. One mole of atoms of nitrogen represents

1) 6.02×1023 atoms of nitrogen 2) 28 g of nitrogen

3) 22.4L of N2 at STP 4) 7g of nitrogen

www.sakshieducation.com
 www.sakshieducation.com
24. One mole of molecules of nitrogen represents

1) 6.02×1023 molecules of nitrogen 2) 7 g of nitrogen

3) 14g of N2 4) 11.2L of N2 at STP

25. One mole of sodium represents

m
1) 6.02×1023 atoms of sodium 2) 46 g of sodium

co
3) 11g of sodium 4) 34.5g of sodium

26. The charge present on 1 mole electrons is

n.
1) 96500 Coulombs 2) 1Coulomb

io
3) 1.60×10-19 Coulombs 4) 0.1 Faraday

at
27. The weight of 0.1 mole of Na2CO3 is
uc
1) 106 g 2) 10.6 g 3) 5.3 g 4) 6.02×1022g
ed

28. The molar mass of a substance is 20g. The molecular mass of the substance is

1) 20g 2) 20 a.m.u 3) 10g 4) 10 a.m.u

hi

29. Avogadro number of helium atoms have a mass of

ks

1) 2g 2) 4g 3) 8g 4) 4×6.02×1023g
a
.s

30. The volume of two moles of SO3 at STP is

1) 22.4 L 2) 11.2 L 3) 40 L 4) 44.8 L

w
w

31. The following property of a gas does not vary with pressure and temperature
w

1) Density 2) Volume of a mole 3) Volume 4) Vapour density

32. The ratio between the number of molecules in equal masses of Oxygen and
ozone is

1) 3:2 2) 2:3 3) 1:1 4) 1:3

www.sakshieducation.com
 www.sakshieducation.com
33. The gas which is twice as dense as oxygen under the same conditions is

1) Ozone 2) Sulphur trioxide 3) Sulphur dioxide 4) Carbon dioxide

34. 1 mole of water vapour is condensed to liquid at 25°C. Now this water contains

i) 3 moles of atoms ii) 1 mole of H2

iii) 10 moles of electrons iv) 16 g of oxygen

m
The correct combination is

co
1) (i) & (ii) are correct

n.
2) (i) & (iii) are correct

io
3) (i) & (iv) are correct

at
4) All are correct uc
35. A chemical equation is always balanced with respect which one of the following

i) Number of atoms ii) Number of molecules

ed

iii) Number of moles iv) Mass

hi

1) Only i is correct 2) Only iii correct

ks

3) Only iv Correct 4) Both i & iv correct

Assertion & reason type questions

a
.s

Note: 1) Both (A) and (R) are true and (R) is the correct explanation of (A).
w

2) Both (A) and (R) are true and (R) is not the correct explanation of (A).
w

3) (A) is true but (R) is false.

w

4) Both (A) and (R) are false.

36. (A): 2 g of hydrogen contains Avogadro number of molecules

(R): One mole of an ideal gas at STP occupies 22.4 lt.

www.sakshieducation.com
 www.sakshieducation.com
37. (A): One liter of water at 4°C contains 55.5 N molecules.

(R): Density of water at 4°C is 1 g/ml and 18g. Of water represents one mole.

38. (A): 2 g of Hydrogen contains Avogadro number of atoms.

(R): One mole of any gas contains Avogadro number of atoms.

39. (A): 1 c.c. of Nitrogen at STP contains 2.67 × 1019 molecules.

m
(R): Molar volume of an ideal gas at STP contains Avogadro number of

co
molecules.

n.
40. (A): 28 g of nitrogen occupies 22.4 lt. at STP.

io
(R): Vapour density of nitrogen is 14 at all temperatures and pressures.

at
41. (A): 8 g CH4 and 14 gr. nitrogen together occupy 11.2 lt. of volume at STP.
uc
(R): Equal weights of all gases under the same conditions contain equal number
of molecules.
ed

42. (A): 58.5 g of solid NaCl contains Avogadro number of Cl– ions.
hi

(R): Chloride ion has Inert gas configuration.

ks

43. Which of the following has highest mass?

1) One gram atom of Iron 2) 5 moles of N2

a
.s

3) 1024 carbon atoms 4) 44.8 lit of Heat STP

w

44. Elements are always combine in the ratio of their

w

1) Atomic weights 2) Molecular weights

w

3) Equivalent weights 4) Mass numbers

45. Molecular weight of orthophosphoric acid is M. Its equivalent weight is

1) 3M 2) M 3) M/3 4) 3/M

www.sakshieducation.com
 www.sakshieducation.com
46. Which of the following acid has the same molecular weight and equivalent
weight?

1) H3PO2 2) H3PO3 3) H3PO4 4) H2SO4

47. The equivalent weight of Na2CO3 is

1) 106 2) 53 3) 26.5 4) 35.33

m
48. The following is not a fixed quantity

co
1) Atomic weight of an element 2) Equivalent weight of an element (or) compound

n.
3) Molecular weight of a compound 4) Formula Weight of a substance

io
49. Equivalent weight of K2Cr2O7 in acidic medium is

at
1) 24.5 2) 49 uc 3) 147 4) 296

50. The equivalent weight of Bayer’s reagent is

1) 31.6 2) 52.6 3) 79 4) 158

ed

51. Molecular weight of KMnO4 is "M". In a reaction KMnO 4 is reduced to

hi

K2MnO4. The equivalent weight of KMnO4 is

ks

1) M 2) M/5 3) M/3 4) 2M
a

52. When Ferrous sulphate acts as reductant, its equivalent weight is

.s

1) Twice that of its molecular weight

w

2) Equal to its molecular weight

w

3) One-half of its molecular weight

w

4) One-third of its molecular weight

53. 2H2O → 4e– + O2 + 4H+. The equivalent weight of molecular oxygen is

1) 32 2) 16 3) 8 4) 4

www.sakshieducation.com
 www.sakshieducation.com
54. (A): The equivalent weights of nitric acid and crystalline oxalic acid are same.

(R): The basicity is same for both the acids.

55. (A): The basicity of H3PO3 is 2.

(R): Two hydrogen atoms are attached to phosphorus through oxygen atoms.

56. In acidic medium Dichromate ion oxidizes ferrous ion to Ferric ion. If the

m
gram-molecular weight of potassium dichromate is 294 gm, its equivalent weight

co
is

n.
1) 294 2) 147 3) 49 4) 24.5

57. The equivalent weight of Iodine in the reaction

io
2Na2S2O3 + I2  2NaI + Na2S4O6 is [M=mol. wt]

1) M 2) M/2
at 3) M/4 4) 2M
uc
58. Medium Equivalent weight of KMnO4
ed

A) Acidic a) 158
hi

B) Neutral b) 79
ks

C) Strongly basic c) 52.6

D) Weakly basic d) 31.6

a

The correct match is

.s

1) A - d, B - c, C - a, D – c 2) A - d, B - c, C - a, D - b
w
w

3) A - d, B - b, C - a, D – c 4) A - d, B - c, C - a, D – a
w

59. Molecular mass of white phosphorous is

1) 31 amu 2) 31 g 3) 124 amu 4) 124 g

60. Basicity of sulphuric acid is

1) 0 2) 1 3) 2 4) 3

www.sakshieducation.com
 www.sakshieducation.com

KEY

1)3 2)4 3)3 4) 3 5) 4 6) 3 7) 4 8) 3 9) 3 10) 4

11) 3 12) 2 13) 2 14) 4 15) 2 16)2 17) 2 18) 2 19) 4 20) 4

m
21)1 22) 2 23) 1 24) 1 25) 1 26) 1 27) 2 28) 2 29) 2 30) 4
31) 4 32) 1 33) 3 34) 4 35) 4 36) 2 37) 1 38)4 39) 1 40) 2

co
41) 4 42) 2 43)2 44)3 45) 3 46)1 47)2 48) 2 49) 2 50) 2
51) 1 52) 2 53)3 54)3 55)1 56)3 572 58) 1 59) 3 60) 3

n.
io
Solutions

at
2). Sulphur molecule is S8. Its molar mass= 8X32=256gm
uc
3) Weight of water=5mg=5X10-3g
ed

No. of water molecules= (weight/GMW) X6.023X1023= (5X10-3g/18)

hi

X6.023X1023=1.67X1020
ks

4). Mass of 1.5X1019 molecules=2mg=2X10-3g

a

23 23 19 -3
 Mass of 6X10 molecules (i.e. GMW) = ( 6X10 /1.5X10 )X2X10 g=80gm
.s

5) Refer Point 12
w

6) d=1g/ml i.e. mass of 1ml water=1gm

w

No. of molecules in 1gm water= 1 X6.023X1023/18

w

Volume of (6.023X1023/18) molecules=1ml

Volume of one molecule= 1/ (6.023X1023/18) =3X10-23ml

7) Change in oxidation state per molecule= +24-0=24

www.sakshieducation.com
 www.sakshieducation.com
 GEW=M/24

8) Molecules are I the ratio of their moles. Moles of O2: moles of N2= (1/32) :( 4/28)
=7:32

9)1mole i.e. 100g CaCO3 contains 3gram atoms i.e. 3X6.023X1023atoms of Oxygen

No, of atoms of Oxygen in 50g CaCO3= (50/100)X3X6.023X1023=9.035X1023

m
co
10. No. of moles in 14gm CO=14/28=0.5

Moles in 7gm N2+8gm O2= (7/28) + (8/32) =0.5

n.
11) 12gm carbon gives 6.023X1023 molecules of CO2

io
at
3gm carbon gives (3/12)6.023X1023=1.506X1023 molecules of CO2
uc
12. No. of atoms = (weight/molar mass) X6.023X1023Xno, of atoms per molecule

13. No. of molecules = (weight/molar mass) X6.023X1023

ed

14. At STP density=GMW/22.4g/lit. Higher the Gmw, higher will be the density.
hi

15. Mass of 5moles Nitrogen=5X28=140gm

ks

Mass of 0.1 gram atoms Ag=0.1X108=10.8gm

a

Mass of 1023 atoms of carbon= (1023 /6X1023) X12=2gm

.s

26. Charge on electron=1.602X10 -19coulmbs

w

Charge o 1mole i.e. 6X1023electrons=1.602X10-19coulmbsX6X1023=96500coulmbs=1

w

Faraday
w

27. Mass of 0.1molesNa2CO3=moles XGMW=0.1X106=10.6g

28. Molar mass is in gm while molecular mass in a,m.u.

29. Mass of Avogadro number of atoms=GAW=4gm

30. Volume at STP= moles X 22.4=2X22.4=44.8lit

www.sakshieducation.com
 www.sakshieducation.com
31. V.D is the ratio of density of a gas to density of H2. It is always constant.

32. Molecules are In the ratio of their moles. Moles of O2: moles of O3= (1/32) :( 1/48)
=3:2

33 d ∞ GMW or (d1/M1) = (d2/M2)

34,1mole water contains 2moles of H atoms+1mole of O atoms=3moles of atoms

m
i.e. 1mole of H2, 16gm O and (2X1+8) =10 moles of electrons.

co
37. Mass of 1lit=1kg=1000gm water

n.
No. of molecules = (wt/GMW) XN= (1000/18) XN=55.5N

io
43. Mass of One gram atom of Iron=56gm

at
Mass of 5 moles of N2 =5X28=140gm uc
Mass of 1024 carbon atoms= (12X 1024 )/6X1023=20gm

Mass of 44.8 lit of Heat STP= (4X44.8/22.4)=8gm

ed

45. Ortho phosphoric acid is a tri basic acid.

hi

46. H3PO2 is a mono basic acid. Thus GMW=GEW

ks

47. The equivalent weight of Na2CO3 =GMW/2 =106/2 =53gm

a

50. Bayer’s reagent is cold and alkaline KMnO4. In alkaline medium, oxidation number
.s

of Mn changes from +7 to +4. Thus GEW= M/3 =158/3 =52.6

w

51. Oxidation number of Mn changes from +7 to+6. Thus GEW= M/1

w

52. Oxidation number of Fe changes from +2 to+3. Thus GEW= M/1

w

54. Nitric acid is monobasic while oxalic acid is dibasic.

56. In acid medium oxidation state of Cr changes from +6to+3.Thus change in oxidation
state per molecule =2X+3=+6

GEW of K2CrO7=GMW/6 =294/6 =49

www.sakshieducation.com