REVISION JEE (Main + Advanced) 2023
LEADER + ENTHUSIAST COURSE
CLASS TEST # 04
INORGANIC CHEMISTRY TIME : 30 MIN.
Single Correct
1. Which of the following pair of complex/complex-ion is CORRECT against to their indicated
properties?
(A) [Ni(CN)4]2! > [NiF6]4! ; C.F.S.E.
(B) [Ni(CO)4] < [Fe(CO)5] ; Valence shell electrons on central metal ion
(C) [Fe(CN)6]3! > [FeF6]3! ; Number of unpaired electrons of central metal ion
(D) [Co(ox)3] 3! > [Co(CN)6]3! ; Stability
2. Complex which does not follow sidwick EAN rule :-
(A) Ferrocene (B) Brown ring complex
(C) K2[PtCl6] (D) [Fe(CO)2(NO)2]
3. Which wavelength of visible light can be absorbed by [Cu(H 2 O) 4 ]SO 4 .H 2 O and
[Fe(H2O)6]SO4.H2O complex respectively.
(A) Yellow and Voilet (B) Orange and Red
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(C) Blue and Green (D) Green and Orange
4. Calculate CFSE value and spin only magnetic moment for [RhF6]3–
(A) –2.4 D0 + 2P, 0 B.M. (B) –2.4 D0 + 3P, 24 B.M.
(C) –0.4 D0 + 2P, 24 B.M. (D) –0.4 D0 + 3P, 24 B.M.
5. Which of the following complex is diamagnetic as well as inner orbital complex?
(A) [Co(OH2)6]SO4 (B) K4[Fe(CN)5(O2)]
–4
(C) [Mn(NCS)6] (D) [Co(NH3)6]Cl3
6. Which of the following statements is/are CORRECT?
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(A) [CoF6 ]
31
ion is low spin complex due to pairing energy > D0
(B) In Zeise's salt, back donation weakens the double bond of alkene.
(C) Among Ar, NaCl and HCl, the NaCl shows weakest inter ionic interaction.
(D) O221 and NOÅ have same bond order.
(X) Å
7. basic solution
Salt + Na2[Fe(CN)5 NO] ¾¾¾¾¾ ® Purple Colour
Which of the following statement is CORRECT for purple colour complex?
(A) Denticity of new ligand formed is 3 (B) It's magnetic nature is paramagnetic
(C) It is low spin complex (D) Hybridisation of Fe is sp 3d2
Multiple Correct
8. Which of the following statement is CORRECT against to the indicated properties?
(A) [Pt(NH3)4]Cl2 > K2[PtCl4]; Crystal field splitting energy
(B) [Co(NH3)3ClBr(NO3)] > [Co(NH3)3Cl3] ; Number of geometrical isomers
(C) K4[Fe(CN)6] > K3[Fe(CN)6]; Valence shell's electrons of central metal ion
(D) [Fe(CO)2(NO)2] > [Fe(edta)]1 ; Number of Fe–N linkages.
9. Which of following species is/are paramagnetic?
(A) NO 1 (B) [NiCl4] 21 (C) [CuCl4] 31 (D) O2[AsF6]
10. Which of the following order is/are CORRECT for stability?
(A) [CoF 6]–3 < [Co(C2O4)3]–3 < [Co(CN)6]–3
(B) [Os(H2O)6]+2 < [Ru(H2O)6]+2 < [Fe(H2O)6]+2
(C) [Co(H2O)6]+3 < [Co(CN)6]–3 < [Ir(CN)6]–3
(D) [NiCl4]–2 < [Ni(NH3)6]+2 < [Ni(CN)4]–2
Inorganic / Revision Class Test # 04 E-1 / 2
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JEE (Main + Advanced) 2023
LEADER + ENTHUSIAST COURSE
Paragraph
Paragraph for Q. No. 11 to 12
Addition compound those which retain their identity in solution are termed as co-ordination
compound. The bonding in co-ordination compound is explained by VBT & CFT. Co-ordination
compound also show both structure and stereoisomerism.
11. Which of the following complex having maximum number of optically active isomer.
(A) [Ma2bcde]n± (B) [M(AB)c2d2]n± (C) [Ma2b2c2]n± (D) [M(AB)2(CC)]n±
12. Identify the INCORRECT matching in the following.
Complex Isomerism Complex type
(A) [Co(H2O) 6]Cl 2 Show structural isomersim low spin
(B) K3[Co(ox)3] Show optical isomerism low spin
(C) [Pt(NH3)2Cl2Br2] Form 6 stereo isomers low spin
(D) [Cu(NO2)4]2– Show structural isomerism square planar
Matching List
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13. Match list I with list II and select the CORRECT answer?
List-I List-II
(Complex compound) (Characteristics)
(P) [CoF 3(H 2O) 3] (A) Hybridisation of central metal ion is sp3d2
(Q) [Co(NO 2)6] –4
(B) Paramagnetic
(R) [Cr(CN)3(H 2O) 3] (C) Inner orbital complex
(S) [Zn(NO 2)4] –2
(D) µm= 0 B.M.
The correct option is
(A) P ®1, 3 ; Q ® 3, 4 ; R ® 2, 3; S ® 2, 4
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(B) P ®1, 2 ; Q ® 2 ; R ® 2,
(C) P ®1, 2 ; Q ® 2, 3 ; R ® 2,
4;
3;
S
S
®
® 4
4
(D) P ®1, 4 ; Q ® 2, 3 ; R ® 2, 3; S ® 4
Integer
1. Find the number of species which are diamagnetic and square planar geometry.
[IrCl(PPh 3) 3], [RhCl(PPh 3) 3], trans-platin, [Co(edta)] !, [NiCl 4] 2!, [Cu(CN) 4]3!, [Ni(CO)4],
[AuCl4]! [Z of Ir = 77, Rh = 45, Pt = 78, Co = 27, Ni = 28, Cu = 29, Au = 79]
2. Find the number of the paramagnetic and inner orbital complex in the following :-
[Ni(CO)4], [Ni(CN)4]2–, [Co(H2O)6]3+, [Cu(NH3)4]2+, [Cr(NH3)6]3+, [Fe(CN)6]3–
3. The total number of electrons in t2g orbital of Sodium nitropruside i.e. Na2[Fe(CN)5NO] = X
and the total number of electrons in t2g orbital of brown ring complex i.e. [Fe(H2O)5NO]+2 = Y
X+Y
then find value of
2
3+ !
4. [Fe(H2O)6](aq.) + SCN(aq.) [Fe(H 2O)3(SCN) 3]
(excess) (Blood red colour solution)
!
+ F(aq.)
(excess)
Colourless complex [Y]
The spin magnetic moment of hexa fluoro complex (Y) is :
5. "Crystal field splitting energy" (CFSE = "DO") for [Ti(H2O)6]3+ is 242 KJ/mol.
Then the "Crystal field stabilisation energy" (CFSE) in KJ/mol will be
E-2 / 2 Inorganic / Revision Class Test # 04
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