Atomic Physics o Level
Atomic Physics o Level
Outcome
INTRODUCTION:
John Dalton (1766-1844) is considered as the father of atomic theory. He considered an atom of being the
simplest component of matter.
The discovery of Radioactivity by Henry Becquerel (1891) showed that atoms are complex rather than “
indivisible” but can break down ( or disintegrate ) forming atoms of different elements
Ernest Rutherford’s (1911) suggested that an atom consists of positively heavy core called nucleus where
most of the mass is concentrated and around the nucleus negatively charged electrons circle the orbit
In 1913 Neils Bohr who had studied in Rutherford’s laboratory suggested a model of hydrogen atom in
which the electrons move around the nucleus in specific circular orbits
According to Dalton an atom is the smallest indivisible particle of an element that takes part in a chemical
reaction
An atom is made up of protons, electrons and neutrons. This can be clearly demonstrated by using the diagram
below
electron
Nucleus
Shell or orbit
Structure of an atom
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Properties of these Sub-atomic particles
Atomic (or Proton) Number: This is the number of protons in an atom. It is denoted as z .
Mass (or Nucleon) Number: this is the sum total of the number of protons and neutrons in an atom. It is denoted
as A . Mathematically it is written as A=Z + N where N=¿ the number of neutrons in the nucleus of the atom.
Recall:
Activity
37 A
1. Consider the atom17Cl. By comparing it with the general expression Z X ,
i. Identify X, A and Z
ii. By using the values obtained in (i) above, calculate N
SOLUTION
2
Activity
The following are the symbols ( not their usual symbols) used to represent some elements in the periodic table
56 56 56 57
24 A 26B 25C 26 D
a. Identify a pair of isotopes
b. In each of the pair, calculate the proton number and neutron number
c. From your answer in (b) above which particle is responsible for the formation of isotopes?
SOLUTION
56 57
a. 26 B ∧26 D are isotopes
56 57
b. for 26B . Z =26 , N =30∧for 26 D . Z=26∧N=31
c. The neutron number
Conclusion: we can also define isotopes as “atoms of the same element having the same atomic ( or
proton) number but different neutron number”
QUESTIONS
LESSON 2: RADIOACTIVITY
Define Radioactivity
Write down the types of radiations released during a radioactive decay
Give properties of alpha, beta and gamma radiations
State the uses of G.M – tube and Cloud chambers
Demonstrate the behaviour of alpha, beta and gamma radiations in Electric and Magnetic fields
Write down balanced nuclear Equations
Define half-life and state its uses
2.1 Introduction:
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Some materials contain atoms with unstable nuclei. In time, each unstable nucleus disintegrate (break
up). As it does so, it shoots out tiny particles and in some cases, a burst of wave energy as well. The
particles and waves “radiate” from the nucleus and are called nuclear radiation. Materials which emit
nuclear radiation are known as radioactive materials. When an unstable nucleus breaks up to release this
nuclear radiation, the essence is to become stable
2.2 Definitions
Radioactive Decay: The disintegration of a nucleus is called radioactive decay
Radioactivity: This is the spontaneous emission of radiation by an unstable nucleus to gain
stability with the release of energy. These radiations emitted during radioactivity are alpha (α ),
beta ( β ) and gamma (γ )
Note: A radioactive process is a;
Spontaneous: i.e. it occurs on its own and are not affected by external factors like temperature,
pressure etc
Random i.e. In a given sample of radioactive nuclei, one cannot tell which nucleus is going to
decay and when.
Examples of radioactive materials include:Uranium, Radium, Polonium, Carbon etc
2.3 Properties of alpha, beta and gamma radiations
- alpha is a Helium nucleus
- beta resembles an electron
- gamma is an electromagnetic wave
α − particle
× × × × × × × ×
× × × × × × × ×
γ − particle
source × × × × × × × ×
× × × × × × ×
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β− particle
Deflection of alpha, beta and gamma particles in a magnetic field
γ
Negative plate −¿ α
+¿
Positive plate
−¿ +¿
β
−¿ +¿
−¿ +¿
source
Deflection of alpha, beta and gamma particles in an Electric field
Note:
- alpha and beta radiations are deflected because they are charged while gamma is not deflected because it
is not charged
- beta is more deflected because it is lighter than alpha
- in electric fields beta particle is deflected towards the positive plate because it has a negative charge while
alpha particle is deflected towards the negative plate because it has a positive charge.
2.4 Uses of Geiger-Müller tube and Cloud Chamber
The G.M-tube and cloud chamber are used to detect alpha, beta and gamma radiations. Another
instruments is solid state detector
2.4.1. The G.M-tube: When radiations enter the tube, it ionizes the gas inside. This set up a high-voltage
spark across the gas and a pulse of current in the circuit.
2.4.2 The Cloud Chamber: This is useful for studying these radiations because it makes their tracks visible
Gamma
Alpha Beta
Cloud chamber tracks for alpha, beta and gamma radiations
Recall: A radioactive process is a decay process which requires the breakdown of unstable nucleus to produce a stable
one. For this to occur, the nucleus must emit radiation and this emission may alter (or change) the number of protons and
neutrons in the nucleus. It might become the nucleus of another element.
Note: The change of the nucleus of an element to the nucleus of another element because of emission of radiation is called
Transmutation
Since an alpha particle has symbol 42He ∨42 α , it therefore means during an alpha decay;
Examples: 10n 1
P +¿−1 β
0
and 131
I 131 0
1 53
54 X e+ ¿ −1 β
2.5.3. Gamma decay
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During gamma radiation, proton=s and neutrons themselves to make the nucleus more stable and during this
rearrangement, energy is lost in the form of gamma ray. Therefore gamma decay does not exhibit transmutation
A A
That is z X Z X +γ
In a nucleus, some proportions of neutrons to protons are more stable than others. Therefore to compare the stability of
two or more nuclei, we use the neutron-proton (N/Z) ratio
activity N
T 1of a sample
T 1 is ON T 1 No
2 No 2 o 2
No 4 8
2
Example: The activity of a radioactive sample is 100 Bq (Becquerel) and the half-life of this sample is 10
minutes. This activity disintegrate from100Bq to 12.5 Bq
In conclusion 3 T 1 =30 minutes. If n = number of half-lives and t = total time for a decay, then
2
t
n T 1 =t i .e T 1 =
2 2
n
Uses of Half-life
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QUESTIONS
There is a small amount of radiation around us all the time because of radioactive materials in the environment.
This is called background radiation
Background radiations are radiations coming from the environment that can be detected by instruments in the
absence of an obvious radioactive source
Sources: soil, rocks, air, building materials, food and drinks, cosmic rays from outer space, industrial wastes,
radioactive carbon in plants
3.2.1. Definitions
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Ratemete. This gives the reading in counts per second e,g if 50 alpha particles were detected by G.M tube every
second, then the ratemeter would read 50 counts per second ( 50 counts/second is called the activity of the
sample). Activity is the disintegration per second. 100Bq or counts per second means 100 disintegration is one
second
A scaler. This counts the total number of particles detected by the tube
An amplifier or loudspeaker. The loud speakers makes a “click” when each particle is detected
When the radiation from radioactive source is measured, the readings always include any background radiation
present. So an average reading for background radiation alone must be found and subtracted from the total.
Example: An experiment was carried out to measure the activity of radon-222, a radioactive isotope of radium.
When the instrument was switched on in the absence of radon-222 source and left unaltered the following
readings were obtained from the intervals of one minute
Counts/minutes: 26 25 30 17 27
Table I
When radon-222 was then placed into the instrument and switched on the readings were as follows:
Time/days 0 1 2 3 4 5 6
Counts/ 225 197 171 146 126 115 90
minutes
From this information
Table II
i. What is the name given to Table I?
ii. Name four ( 4 ) sources from where they could be obtained
iii. Calculate the average value
iv. By using Table II obtain the corrected count rate
3.2.2. Using Radioactive decay curve to determine the half-life of a radioactive sampleA decay curve is a plot of the
activity of a radioactive sample against time. A typical decay curve for a radioactive sample is as shown on the graphs
below
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At the start ( or beginning) the count rate is A o but as time goes by, the count rate drops as the number of
undecayed nuclei decreases.
Ao
The time for A o to drop to is called the half-life and can be calculated as will be demonstrated below
2
Example: In the absence of a known radioactive source, a ratemeter indicated an average reading of 25
counts/minute. The table below shows how the reading of the ratemeter varies with time in the presence of a
known radioactive substance.
40
LESSON 4: RADIOISOTPES 20
4.1. Definition 0 1 2 3 4 5 6 7
Time / hours
Radioisotopes are the unstable forms of an element that emit radiations to become stable
Radioisotopes ( or radionuclides) is also called radioactive isotopes.
Examples are carbon-14, cobalt-60 etc.
4.2.1. In medicine
Killing of cancerous cells (radiotherapy ). Here gamma radiation is used. The radioisotopes appropriate here are
cobalt-60 and caesium -137 ( very good gamma emitters)
One other advantage of gamma used in this purpose is that it causes no significant ionisation which can
lead to damage of cells.
Gamma is highly penetrating and can penetrate cells or can provide energy which can ionize cancerous
cells
Checking the functioning of the thyroid glands
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Here a patient drinks liquid containing iodine -123, a gamma emitter. Iodine is suitable in providing gamma in this case
because it has a very short half-life ( of about 8 days). The amount of radiation emitted gives an idea of the nature of the
thyroid
Sterilizers: High-energy gamma radiation can kill bacteria and other microbes and so used to destroy germs in
medical equipments.The radioisotope suitable is cobalt -60
NB: Gamma sterilization is preferred to boiling because it does not expose delicate instruments to high temperatures.
4.2.2. In Industries
Testing for cracks (or locate leakages in pipes)
Gamma radiation is suitable here because it has a short wavelength.
Cobalt-60 acts as a gamma source here
Gamma emitting isotopes (tracers) are added to oil which moves with the tracers along the pipeline. If
there is a leak, there will be an unusual count rate closed to the crack.
Gamma radiation is very penetrating and straight ( not deflected)
Thickness monitoring
In some production processes a steady thickness of material has to be maintained.
If a cord or paper is too thin, more beta radiation reaches the detector. A beta radiation is most
appropriate because alpha radiation will not pass through the paper while paper has little intensity of
gamma radiation.
A source with a long half-life like carbon-14 (half-life of 5730 years) is required so that it does not need
to be replaced very often.
4.2.3. In Agriculture
When rocks are formed, some radioisotopes become trapped in them e.g potassium-40 is trapped when
molten materials cools to form igneous rocks. As potassium -40 decays, more and more stable of its
components like argon-40 is created.
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Provided none of the argon gas escaped, the age of the rock can be estimated from the proportion of
potassium-40 to argon-40.
Igneous rocks can also be dated by the proportion of Uranium to lead isotope. Lead being the final stable
product of a series of decays that start with Uranium.
Ionizing radiation is a type of energy released by atoms that travels in the form of electromagnetic waves
( gamma or X-rays) or particles ( neutrons, beta or alpha)
Exposure to ionizing radiation maybe external or internal
Internally, could be through inhaling, ingested or enters in blood streams ( e.g by injection or
through wounds)
Externally through airborne radioactive materials ( such as dust, liquids or aerosols) is deposited
on skin or cloths. This can be removed from skin by simply washing
This can be eliminated from the body either spontaneously ( such as through excreta) or as a
result of treatment
People can be exposed to ionizing radiation under different circumstances: at home or public places
( public exposure, their work places, in medical settings ( as patients, caregivers and volunteers) )
These effects could include:
Damage of body tissues which can lead to sterility or birth defects
Gene mutation
Blood cancer or leukemia
Skin burns
Growth of tumours
Cataract or blurred vision due to the destruction of the eye lens
QUESTIONS
1.
a) What are radioisotopes?
b) How are artificial radioisotopes produced?
c) Give two medical uses of radioisotopes.
2. Give two uses of gamma radiation
3. In a thickness monitoring system of a tyre
a) Why is beta source used, rather than an alpha or gamma source?
b) What is the effect on the detector if the thickness of the tyre cord increases
4.
a) Give two uses of radioactive tracers
b) Why is it important to use radioactive tracers with short hslf-lives?
5. Carbon-14 is a radioactive isotope of carbon.
a) What happens to the proportion of csrbon-14 in the body of a plant or animal while it is alive?
b) Why does the proportion of carbon-14 in the remains of dead plants and animals give clues about their age?
In this process, an enormous amount of energy is released. If the neutron penetrates other Uranium-235
nuclide in the sample, a chain reaction can be generated.
Example of nuclear fusion include
2 2 3 1
1 H + 1 H → 1 H + 0n
Fusion Fission
- More energy is produced - Less energy produced 5.3. The
- High temperature required - Less temperature required
- Deals with joining smaller nuclei to - Splitting of larger nuclei to form
form larger ones smaller ones
- Used to produce power since the - Use in power reactors since it can be
reaction is not easily controlled controlled
- More expensive - Less expensive to create
- Require high pressure - Less pressure
- Not a chain reaction - A chain reaction
origin of energy released during nuclear decay.
When α ∨β particles are emitted by a radioactive isotope they collide with surrounding atom and make them
move faster i.e. temperature rises as nuclear energy is transformed to thermal energy ( heat).
In radioactive decay, the energy released per atom is around a million times greater than from chemical changes
such as burning
Protons and neutrons in the nucleus of an atom possess nuclear potential energy which is often referred to as nuclear
energy. During radioactivity, the protons and neutrons place themselves in a more stable arrangement thereby losing
nuclear energy to emitted particles.
According to Albert Einstein (1905),energy itself has mass. If an object gains energy, its mass increases. If it loses
energy, its mass decreases. The mass change ( in kg ) is linked to the energy change E ( in joules ) by his equation
2
E=m c
Where c is the speed of light (3.0 x 108 m/s). The equation is called the equation of mass defect
However, in nuclear reactions the energy changes per atom are much and produce detectable mass changes
The mass of parent nucleus is always more than the total mass of decay products. This loss is converted into energy
using the equation above.
QUESTIONS
1. What is meant by
a) Fission b) fusion
2. Given the data below
−27
Mass of neutron 1.675 x 10 kg
−27
Uranium-235 nucleus 390.250 x 10 kg
14
−27
Barium -141 nucleus 233.964 x 10 kg
−27
Krypton – 92 nucleus 152.628 x 10 kg
a) Using the data above, calculate the total mass of Uranium and neutron.
b) Calculate the total mass of the barium and krypton nuclei and three neutrons
c) Use E=m c2 to calculate the energy released per decay by fission process.
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