01/06/2025 A

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MM : 0 Mole Concept for RM and TYM Time : 60 Min.

Mole Concept for RM and TYM

1. Match List-I with List-II. 5. Match the following.

List-I List-II List-I List -II
P. 5.4 g of Al 1. 0.5 NA electrons Law of CH4 has carbon and hydrogen in
(P) conservation (1)
Q. 1.2 g of Mg++ 2. 15.9999 amu 3 : 1 mass ratio.
of mass
Exact atomic weight of
Law of S and O2 combine to form SO2
oxygen present in a
R. 3. 0.2 mol atoms (Q) multiple (2)
Mixture of isotopes, O16 proportion
and SO3

and O17 In H2S and SO2 mass ratio of H

S. 0.9 ml of H2O [at 4°C] 4. 0.05 moles Law of
and O w.r.t. sulphur is 1 : 16,
(R) definite (3) hence in H O, mass ratio of H
proportion 2
(A) P → 3; Q → 2, 4; R → 1, 2; S → 3, 4 and O is 1 : 8.
(B) P → 3; Q →1, 4; R → 2; S → 1, 4
Law of 4. 2 g MgCO3 gives 2.0 g residue
(C) P → 2; Q → 3; R → 2, 4; S → 1, 4 (S) reciprocal (4) on heating and 2.2g CO2 gas
proportion evolved.
(D) P → 3, 4; Q → 1; R → 3, 4; S → 1, 3

2. Which has the maximum number of molecules among the (A) P(4), Q(2), R(1), S(3)
following?
(B) P(3), Q(1), R(4), S(2)
(A) 22 g of CO2 (C) P(1), Q(3), R(4), S(2)
(B) 24 g of O2 (D) P(4), Q(2), R(3), S(4)

(C) 64 g of SO2 6. Statement-1 : One amu is 1.66 × 10–24 g.

and
(D) 10 g of H2
Statement-2 : It is th part of mass of one molecule of
1

44
3. On heating Ag2CO3 decomposes as : 12CO .
Δ
2
1
Ag CO (s) → 2Ag(s) + CO2 ( g ) + O (g)
2 3 2 2 Statement-1 is True, Statement-2 is True; Statement-2
(A)
If 5.52 g of pure Ag2CO3(s) on heating left a residue of is a correct explanation for Statement-1
4.92 g, then % yield of the reaction is (Atomic mass : Ag =
Statement-1 is True, Statement-2 is True; Statement-2
108) (B)
is NOT a correct explanation for Statement-1
(A) 89%
(C) Statement-1 is True, Statement-2 is False
(B) 60%
(D) Statement-1 is False, Statement-2 is True
(C) 50%
(D) 44.5%

4. For the reaction,

3Na2SO4 + 2FeCl3 → 6NaCl + Fe2(SO4)3
6.12 moles of NaCl is formed when 2.5 moles of FeCl3
and 3.6 moles of Na2SO4 is taken. The percent yield of
the reaction is
(A) 80
(B) 75
(C) 85
(D) 100
7. Match List-I with List-II. 10. Statement 1 : 18 g of water vapour and 18 g of ice will
not contain the same number of molecules.
List-II
Statement 2: Number of molecules are independent of
(Properties of solute or
List-I temperature and pressure, for a given mass in a
the remaining acid/base
compound.
after neutralisation)
Statement-1 is True, Statement-2 is True; Statement-2
6 gm NaOH + (A)
(P) 250 ml H O (1) Molarity = 0.6 M is a correct explanation for statement-1
2
Statement-1 is True, Statement-2 is True; Statement-2
(B)
54 gm glucose + is NOT a correct explanation for statement-1
(Q) 500 ml H O (2) Molality = 0.6 m
2
(C) Statement-1 is True, Statement-2 is False
50 ml of 1.4 M (D) Statement-1 is False, Statement-2 is True
(R) NaOH + 50 ml of (3) Mole fraction = 0.01
0.2 M HCl 11. Number of electrons present in 3.4 g of ammonia is (NA =
Avogadro number)
31.2 gm
(S) benzene + 55.2 (4) Mole fraction = 0.4 (A) 0.2 NA
gm toluene
(B) 0.1 NA
(5) Molarity = 6.3 M
[Use : d = 1 gm/cc; dtoluene = 0.87 gm/cc; M (NaOH) (C) 2 NA
H2 O

= 40; M (glucose) = 180] (D) 0.8 NA

(Assume no volume change due to mixing)
12. Read the assertion and reason carefully to mark the
(A) (P) → (1, 4); (Q) → (2, 4, 5); (R) → (5); (S) → (1, 3) correct option out of the options given below
(P) → (1, 2, 3); (Q) → (1, 2, 3); (R) → (1, 2, 3); (S) → Assertion : Pure water obtained from different
(B) sources such as, river, well, spring, sea etc. always
(4, 5)
contains hydrogen and oxygen combined in the ratio 1 : 8
(C) (P) → (4, 5); (Q) → (1, 3); (R) → (5); (S) → (2, 3) by mass.
(D) (P) → (1, 2, 3); (Q) → (2, 4, 5); (R) → (1); (S) → (1, 4) Reason : A chemical compound always contains
elements combined together in same proportion by mass,
8. Statement-1 : 2 mol N2 reacts with 3 mole H2 to form 2 it was discovered by French chemist, Joseph Proust
mole NH3. (1799).
and If both assertion and reason are true and the reason
Statement-2 : N2 is in excess and H2 is limiting reagent. (A)
is the correct explanation of the assertion.
Statement-1 is True, Statement-2 is True; Statement-2 If both assertion and reason are true but reason is not
(A) (B)
is a correct explanation for Statement-1 the correct explanation of the assertion.
Statement-1 is True, Statement-2 is True; Statement-2 (C) If assertion is true but reason is false.
(B)
is NOT a correct explanation for Statement-1
(D) If assertion is false but reason is true.
(C) Statement-1 is True, Statement-2 is False
13. 13.4 gm of a sample of unstable hydrated salt
(D) Statement-1 is False, Statement-2 is True Na2SO4.xH2O was found to contain 6.3 gm of water. Find
9. Choose the correct statements : the value of x
(A) Weight of a substance is the amount of matter present (A) 5
in it.
(B) Mass is the force exerted by gravity on an object. (B) 10
(C) Volume is the amount of space occupied by a (C) 7
substance.
(D) Temperatures below 0°C are possible in Celsius (D) 3
scale, but in Kelvin scale negative temperature is not
possible. 14. The mass of chlorine gas that contains twice the number
(E) Precision refers to the closeness of various of molecules as present in 2.5 moles of oxygen gas is
measurements for the same quantity. (A) 177.5 g
Choose the correct answer from the options given below.
(B) 158 g
(A) (A), (B) and (C) only
(C) 355 g
(B) (A), (D) and (E) only
(D) 410 g
(C) (C), (D) and (E) only
(D) (B), (C) and (D) only
15. Consider the reaction sequence. 21. How much quick lime is obtained on heating 200 kg of
I. CaCO3(s) ⟶ CaO(s) + CO2(g) 95% pure lime stone?
II. CO (g) + C(s) ⟶ 2CO(g)
2 (A) 106.4 g
(Excess)
(B) 106.4 kg
III. 5CO(g) + I 2 O5 ⟶ 5CO2 (g) + I2

Excess )
( (C) 10.64 g
[Molar mass of I2 = 254 g/mol] (D) 10.64 kg
Minimum mass of CaCO3 sample required if 12.7 g of I2
22. B3+ does not exist in aqueous solution because of its :
is produced in final step [CaCO3 sample is 80% pure]

(A) 7.234 g (A) Strong reducing ability

(B) 15.625 g (B) Strong oxidizing ability

(C) 19.137 g (C) Small size and high charge

(D) 31.218 g (D) Large size and small charge

16. Mass (in g) of conc. HNO3 solution (% w/w = 70) required 23. Mole fraction of ethanol water mixture is 0.25. So, the %
concentration of ethanol by weight of mixture is,
to neutralise 0.2 M 100 mL NaOH is
(A) 54%
(A) 18 g
(B) 64%
(B) 1.8 g
(C) 46%
(C) 1.2 g
(D) 25%
(D) 0.9 g
24. A solution was prepared by adding 34.2 g of sucrose
17. 400 g mixture of AB and AC2 contains 26.25% of A by
(C12H22O11) to 3.6 g of water. Calculate mole fraction of
mass. Select the incorrect statement (Atomic masses of A
water in solution.
= 15, B = 25, C = 22.5)
(A) 0.33
(A) Number of moles of C atom in the mixture is 12
(B) 0.66
(B) Number of moles of AC2 in the mixture is 4
(C) 0.25
(C) Number of moles of AB in the mixture is 1
(D) 0.82
(D) Total moles of A atoms in the mixture is 7
25. The number of oxygen atoms in 4.4 g of CO2 is
18. The value of ‘x’ if hydrated salt Na2CO3·xH2O undergo
63% loss in mass on heating and become anhydrous is (A) 1.2 × 1023
(A) 8 (B) 6 × 1022
(B) 9
(C) 6 × 1023
(C) 10
(D) 12 × 1023
(D) 12

19. What volume of 5.0 M H2SO4 should be mixed with 10 26. Arrange following aqueous solutions in increasing order
of molarity
litre of 1.0 M H2SO4 to make 20.0 L of 3.0 M H2SO4 (P) 224 g/L KOH
solution? (Q) 11.2% w/v KOH
(A) 1.7 L (R) 5m KOH (d = 0.64 g/mL)

(B) 5 L (A) (Q) < (R) < (P)

(C) 8.3 L (B) (R) < (Q) < (P)

(D) 10.0 L (C) (R) < (P) < (Q)

(D) (P) < (Q) < (R)
20. At the sea level, the dry air mass percentage composition
is given as nitrogen gas: 70.0, oxygen gas: 27.0 and 27. Mole of oxygen present in 31 g calcium phosphate are
argon gas: 3.0. If total pressure is 1.15 atm, then calculate
the ratio of following respectively: (A) 0.4 mol
(i) partial pressure of nitrogen gas to partial pressure of (B) 0.2 mol
oxygen gas
(ii) partial pressure of oxygen gas to partial pressure of (C) 0.1 mol
argon gas
(D) 0.8 mol
(Given: Molar mass of N, O and Ar are 14, 16 and 40 g
mol–1 respectively.)
(A) 2.59, 11.85
(B) 5.46, 17.8
(C) 2.96, 11.2
(D) 4.26, 19.3
28. Following reaction is used to prepare H2 gas in the 33. The number of mol of Ca2+ ion in 200 ml of 0.3 M of
laboratory : Ca3(PO4)2 is
Zn + 2HCl → ZnCl2 + H2
What is the volume of H2 gas evolved at STP when 16.35 (A) 0.12 NA
g of zinc (atomic mass = 65.4 U) is treated with 500 mL of (B) 0.18 NA
0.8 M HCl solution?
(A) 2.24 L (C) 2.4 NA

(B) 5.6 L (D) NA

(C) 4.48 L 34. 20.45 g sample of a mixture of potassium chloride and

calcium chloride was treated with ammonium oxalate to
(D) 2.8 L
precipitate the entire calcium only as calcium oxalate.
29. Which of the following is not aromatic? The precipitate was filtered, washed and heated strong to
get a constant weight of 2.8 g residue. What is the
percentage of KCl in the mixture?
(A) 78.55%
(A)
(B) 72.86 %
(C) 67.90 %
(D) 62.78 %
(B)
35. Functional isomer of pent-1-yne is
(A) Pent-2-yne
(B) Pent-1-yne
(C)
(C) Pent-2-ene
(D) Penta-1, 3-diene

36. Which graph correctly represents molarity versus V for a

(D) given moles of solute?

30. The term formula mass is applicable to which of the

following compounds?

(A) Na2SO4 (A)

(B) NH2CONH2

(C) C6H12O6

(D) C2H6

31. 3.42 g of sugar (MW = 342) is dissolved in 100 g of water.

The molality of solution is (B)
(A) 0.1 m
(B) 1 m
(C) 0.8 m
(D) 0.01 m

32. If excess of water is added to 100 g oleum sample

labelled as 112% H2SO4 and is reacted with 5.3 g (C)
Na2CO3, then find the volume of CO2 evolved at 1 atm
pressure and 273 K temperature after the reaction is
complete
(A) 11.2 L
(B) 5.6 L
(C) 1.12 L
(D)
(D) 2.24 L
37. In an experiment, the yield for the reaction of zinc with 43. The incorrect postulates of the Dalton’s atomic theory are
hydrochloric acid was found to be 40%. What minimum (A) Atoms of different elements differ in mass.
amount of zinc (in grams) should be added to 2500 mL of (B) Matter consists of divisible atoms.
0.5 M HCl to liberate 3.36 L of H2 at STP ? (MZn = 65.4 (C) Compounds are formed when atoms of different
g/mol) element combine in a fixed ratio.
(D) All the atoms of given element have different
(A) 24.53 properties including mass.
(B) 20.61 (E) Chemical reactions involve reorganisation of atoms.
Choose the correct answer from the options given below.
(C) 32.75
(A) (C), (D), (E) only
(D) 19.62
(B) (B), (D) only
38. How many water molecules are present in 2 mL of water
(C) (A), (B), (D) only
(d = 1 g/mL)?
(D) (B), (D), (E) only
(A) 11.1 × 1021
44. Which of the following multiple is used for prefix zepto in
(B) 6.023 × 1023 the SI system?

(C) 3.333 × 1023 (A) 10–24

(D) 6.69 × 1022 (B) 10–21

39. One litre of 22.4 volume solution of H2O2, reacted with 71 (C) 10–18
g of chlorine gas. Then solution obtained is diluted to
double the volume. Calculate the new volume strength of (D) 1024
H2O2, if reaction is
45. CaCO3 (s) + 2 HCl(aq) → CaCl2 (aq) + CO2 (g)
H2O2 + Cl2 ⟶ 2HCl + O2
+ H2 O(l)

(A) 5.6 L Consider the above reaction, what mass of CaCl will be
2

(B) 11.2 L formed if 250 mL of 0.76 M HCl reacts with 1000 g of

CaCO3?
(C) 16.8 L (Given: Molar mass of Ca, C, O, H and Cl are 40, 12, 16, 1
(D) 8.4 L and 35.5 g mol–1, respectively)
40. In the reaction, 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(l), (A) 3.908 g
when 1 mole of ammonia and 1 mole of O2 are made to (B) 2.636 g
react to completion, then
(C) 10.545 g
(A) 1.0 mole of H2O will be produced
(D) 5.272 g
(B) 1.0 mole of NO will be produced
46. From 320 mg of O , 6.023 × 1021 molecules are
(C) All the oxygen will be consumed 2
removed, the number of moles remained is
(D) All the ammonia will be consumed
(A) 9 × 10–3 moles
41. 200 mL of M
NaOH solution completely neutralizes 4 g of
(B) 9 × 10–2 moles
12

polybasic organic acid (molar mass g/mol = 1200). Find

basicity of acid. (C) Zero
(A) 5
(D) 3 × 10–3 moles
(B) 4
47. 12 g graphite is burnt in 24 g O2 such that none of the
(C) 3 reactants are left. If CO and CO2 both are formed, the
(D) 1 percentage of CO(by mass) in the product mixture is
42. What will be the molality of the solution containing 49 g of (A) 50%
H2SO4 in 250 g of water?
(B) 14.3%
(A) 0.2 m (C) 25%
(B) 0.5 m (D) 38.9%
(C) 2 m
48. If 28 g of N2(g) reacts with 10 g of H2(g), to form NH3(g)
(D) 1.5 m then identify the incorrect statement?

(A) N2(g) is the limiting reagent

(B) 2 mole of H2(g) is left in excess

(C) 2 mole of NH3(g) is formed

(D) 0.5 mol of N2(g) is left in excess

49. Number of electrons in 3.6 grams of H2O are 55. Assertion (A) : Dalton’s theory could explain the laws of
chemical combination.
(A) 12.04 × 1023 Reason (R) : Dalton’s theory could not explain the laws
of gaseous volume.
(B) 6.02 × 1023
Both (A) and (R) are true and (R) is the correct
(A)
(C) 1.204 × 1023 explanation of (A).
Both (A) and (R) are true but (R) is not the correct
(D) 120.44 × 10–23 (B)
explanation of (A).
50. The mass of P4O10 that will be obtained from reaction of (C) (A) is true but (R) is false.
1.33 g of P4 and 5.07 g of oxygen is (D) (A) is false but (R) is true.
(A) 2.05 g 56. STATEMENT 1 : Combustion of 16 g of methane gives 18
(B) 3.05 g g of water.
STATEMENT 2 : In the combustion of methane, water is
(C) 4.05 g one of the products.
(D) 5.05 g Statement-1 is True, Statement-2 is True; Statement-2
(A)
is a correct explanation for Statement-1
51. 40 gm of CaCO3 is heated to form a residue and a gas. If
% yield of the reaction is 40%. Find mass of the gas Statement-1 is True, Statement-2 is True; Statement-2
(B)
evolved is NOT a correct explanation for Statement-1

(A) 7.04 gm (C) Statement-1 is True, Statement-2 is False

(B) 17.6 gm (D) Statement-1 is False, Statement-2 is True

(C) 8.8 gm 57. Each of these questions contains, Statement-I (assertion)

and Statement-II (reason).
(D) 14.08 gm Statement-I : The balancing of chemical equations is
52. Two pure substances of equal molar mass are AHCO3 based on law of conservation of mass.
Because
and BCO3. They decompose as shown
Statement-II : Total mass of reactants is equal to total
Δ
2 AHC O3 → H2 O + CO2 + A2 CO3
mass of products formed.
Δ Statement-I is true, Statement-II is true; Statement-II is
BC O3 → BO + CO2 (A)
correct explanation for Statement-I.
6.2 g mixture of H2O and CO2 is obtained by 16.8 g of
Statement-I is true, Statement-II is true; Statement-II is
AHCO3. Find out molar mass (in g mol–1) of AHCO3 and (B)
NOT a correct explanation for statement-I
2
x+y
BCO3 and value of (
2
) where x and y are molar (C) Statement-I is true, Statement-II is false
mass of AHCO3 and BCO3 respectively (D) Statement-I is false, Statement-II is true
(A) 84 each, 168.0 58. What are two?
(B) 57.9 each, 3360 59. Each of these questions contains, Statement-I (assertion)
(C) 59.39 each, 3528 and Statement-II (reason).
Statement-I : Law of conservation of mass hold good for
(D) 84 each, 7056 a nuclear reaction.
Because
53. One atom of an element x weigh 6.643 × 10–23 g. Statement-II : The law states that mass can neither be
Number of moles of atom in 10 kg is created nor destroyed in a chemical reaction.
(A) 50 (A) Statement-I is true, Statement-II is true; Statement-
(A)
II is correct explanation for Statement-I.
(B) 100
(B) Statement-I is true, Statement-II is true; Statement-
(C) 250 (B)
II is NOT a correct explanation for statement-I
(D) 500 (C) (C) Statement-I is true, Statement-II is false
54. A given solution of NaOH contains 8.00 g of NaOH per (D) (D) Statement-I is false, Statement-II is true
litre of solution. Calculate the molarity of this solution
60. What should be the density of an aqueous solution of
(A) 0.2 urea (molar mass = 60 g/mol) such that the molality as
(B) 0.4 well as molarity of the solution becomes equal to 1.0
unit?
(C) 0.6
(A) 1.0 g/ml
(D) 0.8
(B) 1.6 g/ml
(C) 1.06 g/ml
(D) 1.16 g/ml