06-07-2025
1001CMD303001250026 MD
CHEMISTRY
1) If sample of Al2(SO4)3 and H2SO4 contain same number of sulphur atom then the ratio of oxygen
atoms in these sample respectively is :-
(1) 3
(2) 1/3
(3) 1
(4) None
2) Density of ozone relative to oxygen is under the same temperature and pressure
(1) 1
(2) 2
(3) 1.5
(4) 2.5
3) Atomic weight of elements A and B are 30 and 60 respectively. If there are 'y' atoms in the x gm of
A. How many atoms would be there in 2x gm of element B :-
(1) y
(2) 2y
(3) 0.5y
(4) 1.5y
4) NH3 is produced according to the following reaction:
N2(g) + 3H2(g) → 2NH3(g)
In an experiment 0.25 mol of NH3 is formed when 0.5 mol of N2 is reacted with 0.5 mol of H2. What is
% yield?
(1) 75%
(2) 50%
(3) 33%
(4) 25%
5) At NTP, 5.6 L of a gas weight 8g. The molecular weight of gas is :-
(1) 32
(2) 40
(3) 16
(4) 8
6) What will be the molality of a solution having 18 g glucose dissolved in 500 g of water :-
(1) 1 m
(2) 0.5 m
(3) 2 m
(4) 0.2 m
7) Calculate the weight of carbon in 171 gm of sucrose (C12H22O11) :-
(1) 36 g
(2) 72 g
(3) 84 g
(4) 96 g
8) Elements A and B form two compounds B2A3 and B2A. 0.05 mole of B2A3 has mass 9 g and 0.1 mole
B2A has mass 10 g. Find atomic weight of A & B respectively.
(1) 20 and 30
(2) 30 and 40
(3) 40 and 30
(4) 30 and 20
9) 10 mol SO2 and 15 mol O2 were allowed to react, the remaining mole of O2 is:
2SO2 (g) + O2 (g) → 2SO3 (g)
(1) 10 mol
(2) 2 mol
(3) 4 mol
(4) 8 mol
10) 3O2 + 2N2 → 2N2O3
9 mol O2 and 14 mol N2 are allowed to react. When 3 mol O2 remains unreacted, then how many
moles of N2O3 would have been produced?
(1) 6
(2) 3
(3) 4
(4) 12
11) Determine the empirical formula of a compound which contains 70.6% of C, 4.2%.H, 11.8% N
and 13.4% O:-
(1) C7H5NO2
(2) C7H5N2O
(3) C7H9NO
(4) C7H5NO
12) The vapour of a compound A2B is 40 times denser than H2 gas and the atomic mass of B is 40
amu then atomic mass of A is :-
(1) 20 amu
(2) 10 amu
(3) 40 amu
(4) 50 amu
13) If 1020 molecules are removed from 50 mg N2O then number of moles of N2O left approximately
(1) 10–2
(2) 10–3
(3) 10–4
(4) 0.5
14)
There is a mixture of H2(g) & O2(g). According to reaction to produce maximum mass of H2O, what
should be the ratio of masses of H2 & O2 present in mixture.
2H2(g) + O2(g) → 2H2O(g)
(1) 2 : 1
(2) 3 : 4
(3) 1 : 8
(4) 1 : 16
15) An organic compound contains mass of carbon which is 14 times as that of hydrogen and
times as that of oxygen. The empirical formula of the compound is :-
(1) C8H14O3
(2) C7H6O2
(3) C5H8O2
(4) C3H8O2
16) How many grams of CO2 will be produced on the complete decomposition of 40g of 10% pure
CaCO3 ?
(1) 176 g
(2) 17.6 g
(3) 1.76 g
(4) 0.176 g
17) Which and what amount will remain unreacted after the reaction between 3g carbon and 2g
oxygen to produce CO.
(1) 1.5 g C
(2) 0.5 g O2
(3) 1 g O2
(4) 0.5 g C
18) How many litres of air are required to burn 4 L CH4, if air contains 20% oxygen by volume ?
CH4 + 2O2 → CO2 + 2H2O
(1) 20 L
(2) 10 L
(3) 40 L
(4) 80 L
19) In the reaction 4A + 2B + 3C → A4B2C3
What will be the number of moles of product formed starting from 1 mole of A, 0.6 mole of B and
0.72 moles of C :-
(1) 0.25
(2) 0.3
(3) 0.24
(4) 2.32
20) 1.61 g of Na2SO4.10H2O contains same number of oxygen atoms as present in
(1) 0.98 g H2SO4
(2) 0.08 g SO3
(3) 1.78 g H2S2O7
(4) 0.05 g CaCO3
21) The density of a liquid is 1.2 g/mL. There are 35 drops in 2 mL. The number of molecules in 1
drop is (molecular weight of liquid = 70)
(1)
(2) 1.2 NA
(3)
(4)
22) Equal masses of O2, H2 and CH4 are taken in a container. The respective mole ratio of these
gases in container is :-
(1) 1 : 16 : 2
(2) 16 : 1 : 2
(3) 1 : 2 : 16
(4) 16 : 2 : 1
23) The mole fraction of a solvent in aqueous solution of a solute is 0.8. The molality of the aqueous
solution is :-
(1) 55.55
(2) 27.77
(3) 6.94
(4) 13.88
24) Match List-I with List-II for the reaction
C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(g)
List-I List-II
8 moles H2O produced
(a) (i) 72g
from ____ C3H8(g) at NTP
(b) 88g C3H8(g) reacts with ____ O2 (ii) 3 mole
(c) 44g C3H8 produces ____ CO2 (iii) 44.8L
1 mole C3H8 on reaction with
(d) (iv) 320 g
10 moles O2 produces _____ H2O
(1) (a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
(2) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
(3) (a)-(ii), (b)-(i), (c)-(iii), (d)-(iv)
(4) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)
25) 3 L of mixture of propane (C3H8) & butane (C4H10) on complete combustion gives 10 L CO2. Find
the composition of mixture.
(1) C3H8, 2L and C4H10, 1L
(2) C3H8, 3L and C4H10, 0L
(3) C3H8, 1.5L and C4H10, 1.5L
(4) C3H8, 0L and C4H10, 3L
26) Chlorine is prepared in the laboratory by treating manganese dioxide (MnO2) with aqueous
hydrochloric acid according to the reaction
4HCl(aq) + MnO2(s) → 2H2O(l) + MnCl2(aq)
+ Cl2(g) How many gram of HCl react with 5.0 g of manganese dioxide ?
(At. wt. of Mn = 55)
(1) 2.12 g
(2) 44.24 g
(3) 8.4 g
(4) 3.65 g
27) An unknown amino acid has 0.032% sulphur by mass. If each molecule has one sulphur atom
only, 1 g of amino acid has ......... molecules :-
(1) 6.02 × 1018
(2) 6.02 × 1019
(3) 6.02 × 1024
(4) 6.02 × 1023
28) At STP, 5L N2 and 5L H2 are allowed to react. The substance and its number of moles remains
unreacted is :
N2(g) + 3H2(g) → 2NH3(g)
(1) N2, 0.149 mol
(2) H2, 0.149 mol
(3) H2, 0.074 mol
(4) N2, 0.669 mol
29) Four one litre flasks are separately filled with the gases CO2, F2, NH3 and He at same room
temperature and pressure. The ratio of total number of atoms of these gases present in the different
flasks would be-
(1) 1 : 1 : 1 : 1
(2) 1 : 2 : 2 : 3
(3) 3 : 2 : 4 : 1
(4) 2 : 1 : 3 : 2
30) 20.0 g of a magnesium carbonate sample decomposes on heating to given carbon dioxide and 8.0
g magnesium oxide. What will be the percentage purity of magnesium carbonate in the sample ?
MgCO3 → MgO + CO2
(1) 84
(2) 75
(3) 96
(4) 60
31) If 224 mL of a triatomic elemental gas has a mass of 1 g at 273 K and 1 atm pressure, then the
mass of 1 atom is :
(1) 8.3 × 10–23 g
(2) 2.08 × 10–23 g
(3) 5.53 × 10–23 g
(4) 6.24 × 10–23 g
32) 12 moles of each A and B allowed to react as given 3A + 2B → C + D. If 60 gm of D is produced
then calculate the molar mass of D :-
(1) 30
(2) 45
(3) 60
(4) 15
33) Mole fraction of ethanol in ethanol-water mixture is 0.25. Hence, percentage concentration of
ethanol (C2H6O) by weight of mixture is :-
(1) 25
(2) 75
(3) 46
(4) 54
34) 100 mL of PH3(g) when completely decomposed produces phosphorus and hydrogen. The change
in volume of the gas is -
2PH3(g) —→ 2P(s) + 3H2(g)
(1) 50 mL increase
(2) 500 mL decrease
(3) 900 mL decrease
(4) No change
35) What mass of 95% pure CaCO3 will be required to neutralise 50 mL of 0.5 M HCl solution
according to the following reaction ? CaCO3(s)+2HCl(aq) → CaCl2(aq)+CO2(g)+2H2O(l)
[Calculate upto second place of decimal point]
(1) 1.32 g
(2) 3.65 g
(3) 9.50 g
(4) 1.25 g
36) A 1 mol sample of an unknown hydrocarbon was burnt in excess O2 to form 88 g of CO2 and 54g
of H2O. What is possible molecular formula of hydrocarbon :-
(1) CH4
(2) C2H2
(3) C4H3
(4) C2H6
37)
Assuming ideal behaviour of gas find ratio of molar mass of A & B
(1) 2 : 3
(2) 3 : 2
(3) 1 : 3
(4) 3 : 4
38) Match List-I with List-II :
List-I List-II
(a) 4.48 litres of O2 at NTP (i) 0.2 moles
12.022 × 1022 12.044 × 1023
(b) (ii)
molecules of H2O molecules
(c) 96 g of O2 (iii) 6.4 g
(d) 88 g of CO2 (iv) 67.2 litres at NTP
Choose the correct answer from the options given below :
(1) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
(2) (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
(3) (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
(4) (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii)
39) 2.76 g of silver carbonate on being strongly heated yields a residue weighing :
Ag2CO3 → 2Ag + CO2 + ½ O2
(1) 2.16 g
(2) 2.48 g
(3) 2.32 g
(4) 2.64 g
40) Consider the combustion of methane
CH4(g) + 2O2(g) → CO2(g) + 2H2O(ℓ)
(A) One mole of CH4(g) reacts with two moles of O2(g) to give one mol of CO2(g) and two moles of
H2O(ℓ)
(B) One molecule of CH4(g) reacts with 2 molecules of O2(g) to give one molecule of CO2(g) and 2
molecules of H2O(ℓ)
(C) At STP 22.7 L of CH4(g) reacts with 45.4 L of O2 (g) to give 22.7 L of CO2(g) and 45.4 L of H2O(ℓ)
(D) 16 g of CH4 reacts with 2 × 32 g of O2(g) to give 44g of CO2(g) and 2 × 18 g of H2O(ℓ)
Which statements are correct :
(1) A, B and C only
(2) A and B only
(3) A, B, C and D
(4) A, B and D only
41) Statement-I : At STP 10 mL CO2(g) and 10 mL CH4(g) contain equal number of molecules.
Statement-II : Equal volumes of all gases at the same temperature and pressure contain equal
number of molecules.
Both statement-I and statement-II are true and statement-II is the correct explanation of
(1)
statement-I.
Both statement-I and statement-II are true but statement-II is not the correct explanation of
(2)
statement-I.
(3) Statement-I is true but statement-II is false.
(4) Statement-I is false but statement-II is true.
42) Statement-I :- Actual mass of one molecule of CH4 is .
Statement-II :- Mass percentage of carbon in CH4 is 80%.
(1) Both statements are correct
(2) Statement-I is correct but statement-II is incorrect
(3) Statement-II is correct but statement-I is incorrect
(4) Both statement are wrong
43) Statement-I : The empirical mass of ethene is half of its molecular mass.
Statement-II : The empirical formula represents the simplest whole number ratio of number of
various atoms present in a compound.
(1) Both Statement I and Statement II are correct.
(2) Both Statement I and Statement II are incorrect.
(3) Statement I is correct but Statement II is incorrect.
(4) Statement I is incorrect but Statement II is correct.
44) Match column-I with column-II :-
Column-I Column-II
Mass of 2 gram-atom
(i) (p) 32 g
of carbon
Number of H-atom
(ii) in 2 gm-molecules (q) 2 NA
of H2O
Mass of
(iii) 2 gm-molecules (r) 24 g
of CH4
Number of oxygen
(iv) atoms in 0.25 mol (s) 4 NA
Ca3(PO4)2
(1) (i) → p, (ii) → q, (iii) → r, (iv) → s
(2) (i) → r, (ii) → p, (iii) → q, (iv) → s
(3) (i) → r, (ii) → s, (iii) → p, (iv) → q
(4) (i) → q, (ii) → r, (iii) → p, (iv) → s
45) In a compound C, H, N atoms are present in 9 : 1 : 3.5 ratio by mass. Molecular mass of
compound is 108. Its molecular formula is :-
(1) C2H6N2
(2) C3H4N
(3) C6H8N2
(4) C8H12N2
ANSWER KEYS
CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 3 3 1 1 1 4 2 3 1 3 4 1 2 3 2 3 1 3 3 3
Q. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A. 1 1 4 4 1 3 1 1 3 1 3 1 3 1 1 4 3 1 1 4
Q. 41 42 43 44 45
A. 1 2 1 3 3
SOLUTIONS
CHEMISTRY
1) Let number of moles of Al2(SO4)3 and H2SO4 are x and y respectively
= = × =
2) = 1.5
3)
4) N2 + 3H2 → 2NH3
0.5 mol 0.5 mol
LR
3 mol H2 → 2 mol NH3
0.5 mol H2 → =
% yield =
5)
Moles of gas =
∴ 0.25 mol of gas has the weight = 8g and gram molar mass = 8 × 4 = 32
6)
7) mol
no. of carbon = 0.5 × 12 = 6
wt. of carbon = 72 g
8)
2MB + 3MA = .....(1)
2MB + MA = .....(2)
9)
2SO2 + O2 → 2SO3
10 mol 15 mol
(L.R.)
After reaction mole of O2 = 15 –
= 10 mole
10)
3O2 + 2N2 → 2N2O3
9 mol 14 mol
after reaction
(9 – 6) (14 – 4) 4 mol
= 3 mol = 10 mol
11)
C= = = 5.88
H= = = 4.2
N= = = 0.84
O= = = 0.84
12)
M. mass = 2 × V.D = 2 × 40 = 80
2A + B = 80 ⇒ A = = 20
13)
Removed moles of N2O =
= 0.17 × 10–3
initial moles of N2O =
left moles of N2O = 1.14 × 10–3 – 0.17 × 10–3
= 0.97 × 10–3 ≃ 10–3
14)
For maximum mass of product reactant must have their molar ratio according to
stoichiometry.
2 : 1
2×2 : 1 × 32
1 : 8
15)
C H O
Mass 14 1
Mole 1.16 1
Simple ratio 3.5 3 1
7 6 2
E.F. = C7H6O2
16)
CaCO3 → CaO + CO2
Mass of pure CaCO3 = 4g
M.M of CaCO3 = 100 ; mole of CaCO3 = 0.04 mole
mole of CO2 produced = 0.04 mole
mass of CO2 produced = 1.76 g
17)
3g 2g
mole Limiting reagent
∵ 16 g O2 react with 12g C
∵ 2 g O2 react with × 2g C
Creacted =
Cremain = 3 – 1.5 = 1.5 g
18)
= 8 × 5 = 40 L
19) 4A + 2B + 3C → A4B2C3
1 0.6 0.72
limiting reagent = C
3 moles of C gives = 1 mole product
∴ 0.72 -------------- = × 0.72 = 0.24
20)
Oxygen atoms in
Na2SO4 . 10H2O = =
H2SO4 = =
SO3 =
H2S2O7 = =
CaCO3 = NA × 3 =
21) Number of molecules in a drop
22)
Let mass of all gases = x
1 : 16 : 2
23)
= = 13.88
24)
C3H8+5O2→3CO2+4H2O
8 mole H2O produced from C3H8 =
88g C3H8 reacts with O2
44g C3H8 produces 3 mole CO2
1 mole C3H8 produces 4 mole H2O = 4 × 18 = 72 g
25) Volume of C3H8 = xL & volume of C4H10
= (3 – x) L
C3H8 + 5O2 —→ 3CO2 + 4H2O
1L ———— 3L
xL ———— 3xL
C4H10 + —→ 4CO2 + 5H2O
1L ———— 4L
(3 – x)L ———— 4 × (3 – x)L
Volume of CO2 = 3x + 4(3 – x) = 10
3x – 4x + 12 = 10
x=2
26)
4HCl(aq)+MnO2(s) —→ 2H2O(l) + MnCl2(aq)+Cl2(g)
1 mol MnO2 ———— 4 mol HCl
MnO2 ———— HCl
wt. of
27)
M = 105 ⇒
no. of molecules = n × NA
= 10–5 × 6.02 × 1023 = 6.02 × 1018
28) N2 + 3H2 → 2NH3
5L 5L
mole
LR ; H2 is Limiting reagent
So, N2 remains unreacted
remaining mole (N2) =
= 0.149 mol
29)
At same temperature and pressure, equal volume of all gases contain same no. of molecules.
CO2 : F2 : NH3 : He
No. of Molecules 1 : 1 : 1 : 1
No. of atoms 3 : 2 : 4 : 1
30)
MgCO3 → MgO + CO2
1 mol 1 mol
8g MgO ⇒ 0.2 mol MgO is obtained from 0.2 mol Mg CO3
Mass of pure MgCO3 = 0.2 × 84
% purity =
= = 84 %
31) PV =
=1×
= Mw = 100 amu
Wt. of 1 atom =
32) 3A + 2B → C +
12 mol 12 mol
(L.R)
∵3 moles of A produces D = mol
∴12 moles of A will produce D = = 2mol.
given amount of D = 60 g = 2 mol
∴ molar mass of D = 30
33)
=
= 46%
34)
PH3(g) → 2P(s) +
1mL PH3 →
100 mL PH3 →
vi = 100 mL
vf = 150 mL
⇒ Δv = vf – vi = 150 – 100 = 50 mL
35) CaCO3(s) + 2HCl(aq.) → CaCl2(aq.) + CO2(g) + H2O(ℓ) no. of moles of CaCO3 (pure) = × mole of
HCl
[Mole = molarity × volume(in ltr.)]
=
weight of CaCO3 (pure) = mole × mol. wt
= 0.0125 × 100 = 1.25 g
% purity =
wt. of impure sample =
36) → x CO2 + H2O
∴ x = 2 and y = 6
and molecular formula of the hydrocarbon = C2H6
37)
38)
(a) 4.48 ℓ of O2
mol = mol.
w = 0.2×32 = 6.4 gm
molecules = 0.2×6.02×1023 = 1.2 × 1023 molecules
(b) 12.022×1022 molecules of H2O
mol.
w = 0.2 × 10 = 3.6 gm
(c) 96 gm of O2 ⇒ mol = = 3 mol.
w = mol × mm = 3 × 32 = 96 gm
V = 3×22.4 L = 67.2 L at STP
molecules = 3 × 6.022 × 1023 = 18.066×1023
(d) 88 gm of CO2
= 2 mol CO2
v = mol × 22.4 L
= 2 × 22.4 L = 44.8 L
molecules = 2 × 6.022 × 1023
= 12.044 × 1023
39)
1 mol Ag2CO3 = 2 mol at Ag
mol.
w in gm of Ag = gm = 2.16 gm
40) Concept of stoichiometry
NCERT(2017)-XI, Part-1, Pg # 18
41) NCERT : Avogadro's Law
42)
Actual mass of a molecule of CH4 is
& % carbon is CH4 is 75%
43)
Ethene is C2H4
44)
(i) 2g- atom C = 2 mole C
(ii) 2g- molecule H2O = 2 mole H2O ⇒ (2 × 2) mole H atom
(iii) 2g-molecule CH4 = 2 mole CH4
(iv) 0.25 mole molecule = 0.25 × 8 mole'O' atom.
45) ⇒
E.M. = 54 E.F. = 3 : 4 : 1
C3H4N
M.F. = 2 × E.M.
