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Research of The Effect of Filament Humidity On The Quality of 3D Printing

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COMPUTER DESIGN SYSTEMS.

THEORY AND PRACTICE


Vol. 6, No. 3, 2024

Bohdan Oliinyk1, Andriy Zdobytskyi2, Ostap Marunchyn3


1
Computer Aided Design Department, Lviv Polytechnic National University, 12, S. Bandery str., Lviv, Ukraine,
E-mail: [email protected], ORCID 0009-0001-3725-7446
2
Computer Aided Design Department, Lviv Polytechnic National University, 12, S. Bandery str., Lviv, Ukraine,
E-mail: [email protected], ORCID 0000-0001-8044-9593
3
Computer Aided Design Department, Lviv Polytechnic National University, 12, S. Bandery str., Lviv, Ukraine,
E-mail: [email protected]

RESEARCH OF THE EFFECT OF FILAMENT HUMIDITY


ON THE QUALITY OF 3D PRINTING
Received: November 15, 2024 / Revised: November 20, 2024 / Accepted: November 25, 2024
© Oliinyk B., Zdobytskyi A., Marunchyn O., 2024
https://doi.org/10.23939/cds2024.03.160
Abstract. This study investigates the process of 3D printing a model with several types of
filament at different percentages of material moisture. Due to the unique characteristics of individual
plastics, each print requires preliminary setup of both the printer and the printing process, it is also
important to prepare the appropriate material. Neglecting at least one of these nuances will lead to an
incorrect printing process and, as a result, a deterioration in the quality of the part. The purpose of
the study is to determine the value of the percentage of moisture content in the most common types
of filament under the condition of high-quality printing, by comparing physical objects printed under
different conditions and at different material moisture. An exoskeleton vertebra model was chosen as
a test object. The result shows a significant improvement in quality when observing the correct
filament moisture requirements and adjusting the printing process accordingly for each plastic.
Keywords: 3D printing, filament, humidity, part quality, 3D printer, exoskeleton vertebra
Introduction
Varieties of 3D printing technologies have been developed with the different function. According to
ASTM Standard F2792 [1], ASTM catalogued 3D printing technologies into seven groups, including the
binding jetting, directed energy deposition, material extrusion, material jetting, powder bed fusion, sheet
lamination and vat photopolymerization. There are no debates about which machine or technology function
better because each of them has its targeted applications. Nowadays, 3D printing technologies are no
longer limited to prototyping usage but are increasingly also being used for making variety of products [2].
Material extrusion-based 3D printing technology can be used to print multi-materials and multi-
colour printing of plastics, food or living cells [3]. This process has been widely used and the costs are very
low. Moreover, this process can build fully functional parts of product [4]. Fused deposition modelling
(FDM) is the first example of a material extrusion system. FDM was developed in early 1990 and this
method uses polymer as the main material [5]. FDM builds parts layer-by-layer from the bottom to the top
by heating and extruding thermoplastic filament.
The operations of FDM are as follows:
I. Thermoplastic heated to a semi-liquid state and deposits it in ultra-fine beads along the extrusion.
II. Where support or buffering needed, the 3D printer deposits a removable material that acts as
scaffolding. For example, FDM uses hard plastic material during the process to produce 3D bone model
[6].
3D printing technologies are widely used for the production of polymer components from prototypes
to functional structures with difficult geometries. By using fused deposition modelling (FDM), it can form
a 3D printed through the deposition of successive layers of extruded thermoplastic filament, such as

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Research of the Effect of Filament Humidity on the Quality of 3D Printing

polylactic acid (PLA), acrylonitrile butadiene styrene (ABS), polypropylene (PP) or polyethylene (PE) [7].
Lately, thermoplastics filaments with higher melting temperatures such as PEEK and PMMA can already
be used as materials for 3D printing technology [8]. 3D printing polymer materials in liquid state or with
low melting point are widely used in 3D printing industry due to their low cost, low weight and processing
flexibility [9]. Mostly, the materials of polymers played important role in biomaterials and medical device
products often as inert materials, by contributing to the efficient functioning of the devices as well as
providing mechanical support in many orthopaedic implants [10].
There are many types of filament with different properties. Below are examples of plastics and their
main characteristics that were used for the study:
• PLA – easy to print, biodegradable, variety of colors.
• coPET – more flexible than PLA, not stronger than ABS but devoid of the problem of harmful
fumes.
Plastics used in 3D printing have one common and main enemy – humidity. You can easily find
countless stories on the net about the filament deteriorating when stored in air. Or examples of unsu-
ccessful products printed from such filaments.
It is important to note that some filaments are more susceptible to humidity than others. For
example, PLA plastic, PVA support material, nylon and ABS are particularly sensitive to humidity.
Plastics are sensitive to humidity because they are made of materials that easily absorb water or have
a high level of hygroscopicity, to put it correctly. For example, PLA plastic is biodegradable and is made
from natural resources such as corn or rice. While this is much better for the environment than other
plastics, it also means that under certain conditions it will break down into carbon dioxide, water and
methane. Humid conditions and UV light accelerate the breakdown of this material. It won’t crumble, of
course, but it will become unusable. When moisture is absorbed by the filament and then this material is
heated by a 3D printer for extrusion, the water combines with the heat to form steam. Naturally, this leads
to the formation of bubbles as the filament exits the nozzle and leaves a porous and uneven surface.
Objectives and Problems of Research
Oven. The most common option at home, where you can dry the thread. But you should only use
ovens that have controlled heating and temperature regulation, since too high a temperature leads to partial
softening of the monofilament and its sticking together. It is also worth turning on the convection function
and leaving a gap, without closing the oven completely, for the intake of dry air and the exit of moist air.
The biggest advantage is accessibility. Disadvantages: inaccuracy – difficult to achieve precise temperature
control; high risk of filament damage due to overheating; need to constantly monitor the drying process.
Vegetable dryer. Food dehydrators are designed to slowly remove excess moisture by providing low
heat. The advantage of using a dehydrator is that all you have to do is set the temperature and leave the coil
inside to dry. The disadvantage of this drying option is the fact that this equipment is designed to dry
materials that have a high moisture content (50–70 %), and in the case of plastics, this figure is lower.
The advantage is that it provides fairly precise control of temperature and humidity. The main
disadvantage is the limited capacity, and the dehydrator also needs modernization and is not very common.
A monofilament dryer is a piece of equipment specifically designed to remove excess moisture from
filament. The principle behind it is quite simple: they hold a spool of monofilament in a heated housing,
which causes the water molecules to evaporate. The simplest monofilament dryers consist of a heated
container that fits at least one spool of monofilament. More sophisticated machines are equipped with
additional features such as rotation and directional airflow to evenly distribute the heat. In addition, some
monofilament dryers are designed to dry the entire spool of monofilament at once, which can then be
removed and loaded into a 3D printer. Others are designed to dry the monofilament and feed it into the 3D
printer at the same time, which saves time.
It has many advantages over other methods: it provides precise control of temperature and drying
time, which is critical for many types of filament; most dryers have automatic programs for different types
of materials, which simplifies the process; it is also safe, protected from overheating and has safety
systems. The only disadvantage is the cost, because it is the most expensive option among all methods.

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Bohdan Oliinyk, Andriy Zdobytskyi, Ostap Marunych

Using vacuum bags will allow you to maintain the moisture state of the plastic for a long time. They
differ from regular ziplock bags in that they have a hole where you can connect a vacuum cleaner and suck
out all the air. No air = no moisture or other elements that degrade the quality of the thread! To use your
material, you need to take it out, and close it again when you are finished. By the way, you can make the bag
even more effective by adding a few packets of silica gel to it! These are small packets of moisture-absorbing
gel that you have definitely seen in shoe boxes. An alternative to vacuum bags can be airtight boxes or
containers, and it can be anything from food containers to large buckets that you can find in any hardware
store. If you follow these rules, the filament will be stored for a long time without losing its properties.
Example of drying time and temperature of different polymers is given in Table 1.
Table 1
Drying time and temperature of different polymers
Filament Optimal drying Minimum drying time,
Additional recommendations
Type temperature, °C hours
Most common, not very hygroscopic. Suitable for
PLA 40–45 4–6
beginners
Мore flexible than PLA, strong, not stronger than ABS
coPET 50–55 6–8
but devoid of the problem of harmful fumes
Prone to warping at high temperatures. Requires an
ABS 80–85 6–8
enclosed chamber
PETG 70–80 4–6 Good bed adhesion, chemical resistant
TPU 60–70 4–6 Flexible, requires a well-calibrated extruder
Nylon 80–90 8–10 Strong, abrasion resistant, but hygroscopic
ASA 80–85 4–6 UV resistant, good weatherability
Strong, heat resistant, but requires high print
PC 100–110 8–10
temperatures
HIPS 80–85 6–8 Soluble in D-limonene, used for support structures
Improved PLA with higher strength and impact
PLA+ 40–45 4–6
resistance
PET 80–90 6–8 Strong, rigid, chemical resistant
TPU95A 60–70 4–6 Very flexible, used for elastic parts

It is worth remembering that for plastics such as Nylon, Elastan, the option of drying at 40 °C does
not work, but for twice as long. These plastics do not dry in such conditions!
These data are relative, as they can fluctuate depending on how wet the filament is, especially when
it comes to drying time.
These articles are useful and help to better understand how to handle plastic, but the advice on
drying cannot be called accurate and following them does not always lead to the desired result.
Determining specific indicators will allow you to better control the printing process and help achieve
maximum 3D printing quality.
Main Material Presentation
Preparation. The study consists of three stages for each plastic. The stage has three steps, namely:
taking measurements; printing a test model; fixing the result, preparing the filament for the next stage.
Each subsequent stage should improve the quality of the printed object. Printing will be performed
with two types of filament PLA and coPET. Before starting work, you need to make sure that the plastic
used has a sufficiently high percentage of moisture for taking measurements, if not, then ensure that the
quality of the thread ―deteriorates‖.

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Research of the Effect of Filament Humidity on the Quality of 3D Printing

Preparation of a 3D model that will be used as a test model. For this, a vertebra model for an
exoskeleton was chosen (Fig. 1). The selected model consists of various shapes, such as a sphere, a
truncated cube and various types of rounding, which is very good for a test model, and the presence of
which will help to better understand the quality of the printed object.

Fig. 1. Model in Simplify 3D environment


Preparing the environment and setting the printing parameters. To generate gcode from the stl
format, the Simplify 3D slicer program was used (Fig. 1, 2). The main printing parameters: generating
supports; model filling 25 %; table temperature 70°C and 50°C for coPET and PLA, respectively; nozzle
temperature 235 °C and 220 °C for coPET and PLA, respectively; also when printing PLA, maximum air
was used.
Stage 1. A hygrometer was used in conjunction with a vacuum pump to measure the filament
humidity. The measurement of humidity in the filament was carried out as follows: the plastic with the
hygrometer was sealed, it was decided to leave the package for some time to stabilize the device’s
indicators. After this time, the values were fixed and the ―measured‖ filament was sent for printing.
Different colors of plastic were used when printing, but the manufacturer and type of plastic did not
change, so we can say that this did not affect the research.
coPET. The spool was stored in the wrong conditions for about 4 months, namely not packed in a
sealed bag. It was decided to start working with it. The initial measurement showed 61 % humidity.
During printing, a slight crackling sound was heard, this is the process of moisture evaporation from
the filament, as a result of which characteristic bubbles appeared on the model.

a b
Fig. 2. The part is printed on coPET, humidity 61 % (a); the part is printed in PLA, humidity 60 % (b)
After completing the printing (Fig. 2) and analyzing the result, we can conclude that at a humidity of
61 %, the object turned out to be of poor quality. You can see the unevenness of the layers, it seems that
the printer is not calibrated. But this is just the result of the formation of bubbles during extrusion.

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Bohdan Oliinyk, Andriy Zdobytskyi, Ostap Marunych

PLA. Since at the beginning of the research, the PLA plastic spools were stored in compliance with
the requirements, their first use fell, as it turned out later, on stage 2. After that, the filament was placed in
a humid room and was there for two weeks. As a result, the initial measurement was 60 % humidity.
As with coPET printing, a characteristic crackling appeared. After removing from the table, various
bumps and funnels are visible over the entire area of the part, this is the result of moisture evaporation
from the filament. It is worth noting that the humidity indicator is not much different from coPET, but the
part looks better, this is due to the fact that although the hygroscopicity indicator of PLA is high, it does
not have such a negative impact as in other types of plastics. Also, there is another indicator of filament
humidity on the object – filament stretching (Fig. 2), in simple words, threads appear at the end of a layer
and the transition to the next one.
It is also worth mentioning that when printing with coPET filament, the printer was forced to stop
due to a blockage inside the nozzle. This is precisely the result of printing with a polymer with excessive
moisture.
After printing, the spool with the filament was disconnected and sent for drying. A food dehydrator
was used for drying. This choice is due to the fact that, at the time of the study, there was no special dryer
for the filament. Since the drying temperature of the studied plastics is not high, the use of an oven was
impractical.
The coPET spool was dried at a temperature of 59–60 °C for 4 and a half hours.
PLA plastic was dried for 4 hours and 30 minutes at a temperature of 42 °C.
Stage 2. Repeated measurements showed that the moisture content in coPET is 40 %, in PLA – 44 %.

a b
Fig. 3. The part is printed on coPET, humidity 40 % (a); the part is printed in PLA, humidity 44 % (b)
The object printed with coPET plastic (Fig. 3, a) shows that changing the moisture content by 21 %
for the better gave a positive result. When enlarged, the presence of layer displacement is visible, but not as
strong as it was at the 1st stage. In general, the print quality improved.
At this stage, the test model was modernized, namely, the shape of the processes (wings) of the
vertebra changed. This helped to avoid the use of supports in some places, and as a result, reduce the
consumption of printing material.
When changing the PLA moisture content from 60 % to 44 %, the print quality improved, but
funnels and bumps can still be seen on the parts (Fig. 3, b). At the correct angle of incidence of light on a
white object, the bumps leave a shadow and it becomes easier to notice them (Fig. 3). It is worth noting
that the quality of printing of the outer rounded shapes has increased, but the inner plane has almost not
changed in quality. There are also thin threads, which indicate the tension of the thread, as in the previous
stage.
After fixing the results, the plastic must be dried again. The technology remains the same, first the
dehydrator is heated to the desired temperature, the coil is placed in the dehydrator box. The indicators are
checked every 20 minutes to prevent them from changing by more than 1 unit.

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Research of the Effect of Filament Humidity on the Quality of 3D Printing

The coPET coil was in the middle of drying for 3 hours, the temperature indicator was 60 °C. PLA
plastic was dried for 3 hours at a temperature of 41–42 °C.
Stage 3. As a result of the extreme measurements, we have the following figures: the moisture
content in coPET is 27 % and in PLA – 33 %.
During the printing process, there were no more obvious signs that the filament contains a large
amount of moisture, namely, when laying layers, the formation of balls that would form when water
evaporates from the filament during the extrusion process was not noticed. Also, the material did not crack
and no unnecessary tension appeared.
Having analyzed the coPET object (Fig. 4), we can say that the print quality has significantly
improved. All previous defects have disappeared, the layers have become uniform and identical in
appearance, and the surface of the part has become smoother. On the plane of the part, traces of the end of
the layer remained, when the extruder remains in place for some time and the molten plastic continues to
flow through the nozzle. These traces will remain on the object, since this is how the 3D printer works.

a b
Fig. 4. The part is printed on coPET, humidity – 27 % (a); the part is printed in PLA, humidity – 33 % (b)
After printing with PLA filament and analyzing the resulting part, it is possible to note an
improvement in the quality of the printed part (Fig. 4, a)). Defects in the form of funnels, pits and bumps
are not observed on the plane of the object. The absence of tension and a significant improvement in the
quality of the internal area also indicate excellent print quality (Fig. 4, b)).
Results and Discussion
So, in the images you can see a clear difference in the quality of the parts. Before starting work, the
printer was calibrated, and the printing parameters for a single filament did not change throughout the
study. This suggests that the quality of the printing process and the quality of the printed object directly
depended on the state of the polymer, namely on its humidity. Fig. 5 shows the assessment of print quality
and details depending on the moisture content of the filament.

10
Print quality (arbitray units)

8
6
4
2
65 60 55 50 45 40 35 30 25 20
Humidity (%)

Fig. 5. Аssessment of print quality

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Bohdan Oliinyk, Andriy Zdobytskyi, Ostap Marunych

The graph shows that humidity has a greater effect on coPET, while in the case of PLA the
difference in quality is noticeable but has a smaller effect.
To assess the print quality, the following parameters were taken into account: surface roughness,
presence of thread tension, number of defects (bubbles, bulges on small-area elements) per plane in
percent, adhesion of the part to the table, and printing of overhanging elements (bridges).
Drying was done using a food dehydrator, which entailed a number of nuances. This method of
drying requires constant monitoring of the indicators and their correction as needed. Almost every such
dehydrator requires a design change for the need to dry plastic. Such changes can be irreversible, so it is
worth carefully considering such actions if the device is not intended to be used for such tasks constantly.
The filament coil can be dried directly using a 3D printer, or rather a heated bed. To do this, you
need to place the coil on the printing work area and set the bed heating parameter. However, this method
has many disadvantages. The heat is concentrated directly above the bed, which means the filament will
not heat up evenly, from the bottom up. This may not be suitable for printers with a small work area,
without a bed heating function and plain open printers. But while the drying process is in progress, printing
cannot take place, and vice versa. This is the biggest drawback of this method.
The total drying time of each coil is 7 hours 30 minutes, and the percentage of moisture evaporation
per unit of time was determined by calculations:
(1)
where x – percentage of moisture evaporation per unit, %; y1 – moisture content before drying, %; y2 –
moisture content after drying, %; t1 – drying time, min; t2 – desired calculation time (1 hour), min.
The value for coPET filament is 4.6 % for the first drying and 4.3 % for the second.
And for PLA plastic the values are as follows: 3.5 for the first drying and 3.6 for the second.
As a result, it turns out that in 1 hour of drying, a coPET type polymer at a temperature of 60 °C
loses 4.5 % of moisture, and a PLA polymer loses 3.5 % of moisture at a temperature of 60 °C.
temperature of 42 °C.
Fig. 6 shows in the form of a graphical dependence how the % humidity of the filaments changed in
relation to the drying time.

PLA (first drying) coPET (first drying)


PLA (second drying) coPET (second drying)
20
Polymer moisture (%)

30
40
50
60

0 30 60 90 120 150 180 210 240 270 300


Drying time (minutes)

Fig. 6. Plastic drying out over time


As can be seen, the coPET polymer is better able to dry and generally shows better quality results.
However, as the moisture content increases, the quality drops significantly. PLA polymer dries less
intensively, but is generally more loyal to the humidity parameter.
The printing process depends on many factors, one of which is the quality of the polymer with which
printing is carried out. If during the preliminary extrusion of part of the filament from the nozzle bubbles
appear on the material and a slight crackling sound is heard, you should not start printing. This is one of
the most visible consequences of the moisture of the thread. Further use of such a filament will not only

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Research of the Effect of Filament Humidity on the Quality of 3D Printing

manifest itself in reduced quality of printed objects, but will most likely lead to nozzle clogging. And as a
result of cleaning and repairing the device.
Conclusions
The study included printing a test model with several types of polymer with different percentages of
moisture content for each. The value of this variable was monitored and fixed, provided that the highest
print quality was achieved and, as a result, the maximum quality of the printed object was achieved. This
helped to assess the quality based on several parameters. Calculations were also made that show how the
moisture value changes over time during drying.
On the basis of this, the corresponding graphs were created.
The result demonstrates a significant improvement in quality when observing the correct
requirements for filament moisture and adjusting the printing process accordingly for each plastic.
Added recommendations for drying reels on the printer table; this method is relatively the most
affordable and does not require equipment preparation in most cases, although it has a number of
disadvantages.
Nowadays, 3D modeling and 3D printing occupy a large niche in the field of manufacturing various
parts and objects. A very common technology is FDM, it is used both in home use and by larger
organizations. Printers with FDM technology use a polymer in the form of a thread that is wound on a
spool, the printing process is performed by fusing one layer onto another.
There are many types of filament on the market, each has its own properties and is used in different
areas, for individual tasks. It is important to store the filament correctly so that it does not change its
properties or lose them. The filament must be dried so that excess moisture does not affect the quality of
the print. The principle of drying is the same for all types of plastic, but the methods for each are different.
References
[1] ASTM F2792-12a, Standard terminology for additive manufacturing technologies. ASTM International.
West Conshohocken, PA, 2012.
[2] W. Yuanbin, Blache, & X. Xun, ―Selection of additive manufacturing processes‖, Rapid Prototyping
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[3] A. Muller, & S. Karevska, ―How will 3D printing make your company the strongest link in the value chain?‖,
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Bohdan Oliinyk, Andriy Zdobytskyi, Ostap Marunych

Богдан Олійник1, Андрій Здобицький2, Остап Марунич3


1
Кафедра систем автоматизованого проєктування, Національний університет ―Львівська політехніка‖,
вул. С. Бандери, 12, Львів, Україна,
E-mail: [email protected], ORCID 0009-0001-3725-7446
2
Кафедра систем автоматизованого проєктування, Національний університет ―Львівська політехніка‖,
вул.С. Бандери, 12, Львів, Україна, E-mail: [email protected], ORCID 0000-0001-8044-9593
3
Кафедра систем автоматизованого проєктування, Національний університет ―Львівська політехніка‖,
вул. С. Бандери, 12, Львів, Україна, E-mail: [email protected]
ДОСЛІДЖЕННЯ ВПЛИВУ ВОЛОГОСТІ НИТКИ НА ЯКІСТЬ 3D ДРУКУ
Отримано: Листопад 15, 2024 / Переглянуто: Листопад 20, 2024 / Прийнято: Листопад 25, 2024
© Олійник Б., Здобицький А., Марунич О., 2024
Анотація. У статті досліджено процес 3D-друку моделі з кількома типами ниток за різних від-
сотків вологості матеріалу. Через унікальні характеристики окремих пластиків кожен відбиток
потребує попереднього налаштування як принтера, так і процесу друку, також важливо підготувати
відповідний матеріал. Нехтування хоча б одним із цих нюансів призведе до некоректного друку і, як
наслідок, до погіршення якості деталі. Мета дослідження – на основі порівняння фізичних об’єктів,
надрукованих у різних умовах та за різної вологості матеріалу, визначити значення відсотка вмісту
вологи в найпоширеніших видах філамента за умови високоякісного друку. Тест-об’єктом вибрано
модель екзоскелета хребця. Результат засвідчив істотне покращення якості у разі дотримання пра-
вильних вимог щодо вологості нитки та відповідного регулювання процесу друку для кожного
пластику.
Ключові слова: 3D-друк, нитка, вологість, якість деталей, 3D-принтер, екзоскелет хребця.

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