1.

6 Chapter 1

62. For CuSO4·5H2O, which is the correct mole contain 10.46% bromine by mass. The value of n is
relationship? (Br = 80)
(a) 9 × Mole of Cu = Mole of O (a) 20 (b) 21
(b) 5 × Mole of Cu = Mole of O (c) 19 (d) 22
(c) 9 × Mole of Cu = Mole of O2 67. A compound contains 36% carbon by mass. If
(d) Mole of Cu = 5 × Mole of O each molecule contains two carbon atoms, the
63. The percentage of Fe(III) present in iron ore number of moles of compound in its 10 g is
Fe0.93 O1.00 is (Fe = 56) (a) 66.67 (b) 0.15
(a) 94 (b) 6 (c) 0.30 (d) 1.5
(c) 21.5 (d) 15 68. The percentage of oxygen in a compound is 4%. Its
64. A quantity of 5 g of a crystalline salt when minimum molecular mass will be
rendered anhydrous lost 1.8 g of water. The (a) 100 (b) 400
formula mass of the anhydrous salt is 160. The (c) 200 (d) 32
number of molecules of water of crystallization in
the salt is 69. In Dumas method, 0.2 g of an organic nitrogenous
compound gave 28 ml of N2 (volume reduced to
(a) 3 (b) 5 0oC and 1 atm). What is the percentage of nitrogen
(c) 2 (d) 1 by mass in the compound?
65. Cortisone is a molecular substance containing (a) 17.5 (b) 8.75
21 atoms of carbon per molecule. The mass (c) 35.0 (d) 14.0
percentage of carbon in cortisone is 69.98%. What
is the molecular mass of cortisone? 70. A quantity of 0.2 g of an organic compound
containing C, H and O on combustion yielded
(a) 180.05 (b) 360.1 0.147 g CO2 and 0.12 g water. The percentage of
(c) 312.8 (d) 205.8 oxygen in it is
66. A polystyrene of formula Br3C6H2(C8H8) n was (a) 73.29% (b) 78.45%
prepared by heating styrene with tribromobenzyl (c) 83.23% (d) 89.50%
peroxide in the absence of air. It was found to

Empirical and Molecular Formula

71. The empirical formula of an organic gaseous 73. A compound having the empirical formula,
compound containing carbon and hydrogen is C3H4O has a molecular weight of 170 ± 5. The
CH2. The volume occupied by certain mass of molecular formula of the compound is
this gas is exactly half of the volume occupied (a) C3H4O (b) C6H8O2
by the same mass of nitrogen gas under identical
(c) C6H12O3 (d) C9H12O3
conditions. The molecular formula of the organic
gas is 74. It was found from the chemical analysis of a gas
(a) C2H4 (b) CH2 that it has two hydrogen atoms for each carbon
atom. At 0oC and 1 atm, its density is 1.25 g per
(c) C6H12 (d) C4H8
litre. The formula of the gas would be
72. A compound has carbon, hydrogen and oxygen (a) CH2 (b) C2H4
in 3 : 3 : 1 atomic ratio. If the number of moles
(c) C2H6 (d) C4H8
in 1 g of the compound is 6.06 × 10−3, then the
EXERCISE I

molecular formula of the compound will be 75. A quantity of 1.4 g of a hydrocarbon gives 1.8
(a) C 3H 3O g water on complete combustion. The empirical
formula of hydrocarbon is
(b) C 6H 6O 2
(c) C 9H 9O 3 (a) CH (b) CH2
(d) C12H12O4 (c) CH3 (d) CH4

M01 Advanced Problems in Physical Chemistry xxxx 01.indd 6 7/16/2019 2:17:05 PM