Sec: JR.

IIT _*CO-SC(MODEL-B) Date: 04-02-24

Time: 3 Hrs Max. Marks: 186
04-02-24_JR.IIT_STAR CO-SC(MODEL-B) _JEE ADV_WAT-38_SYLLABUS
MATHEMATICS: PRESENT WEEK (80%): CIRCLE: Equation of Normal and its
Properties, Equation of Chord whose midpoint is given, Co-Normal
points, Common Tangent to Circle and Parabola / Two Parabolas
PREVIOUS WEEK(20%): Parabola: Equation of Parabola, Equation of
Parabola (Standard from, Foci, Directrix, Eccentricity, Parametric form),
Tangent and its Properties, Chord of contact
PHYSICS: PRESENT WEEK (80%): Introduction to dielectrics, discussion on effect
of dielectric when introduced in to a capacitor (isolated or in a circuit).
Energy related and switching problems of capacitors involving dielectrics
(Exclude: RC Circuits)
PREVIOUS WEEK (20%): CAPACITORS: Introduction, types of
capacitors, combination of capacitors in series and in parallel, general
capacitor circuits without involvement of dielectric, Energy stored in a
capacitor (without dielectric), charge flown and heat generated problems
when switch is thrown from one position to other (Exclude: Dielectric)
CHEMISTRY: PRESENT WEEK (80%): Alcohols: Preparation of alcohols from alkene,
akyl halides, amines, aldehydes, ketones and carboxylic acid and
derivatives, Physical propertties, reactions: esterification, dehydration,
with metals, conversion into alkyl chlorides, oxidation into aldehyde,
ketones and carboxylic acids, Lucas test, victor meyer test (Exclude:
MPV reduction, exceptions of LAH & SBH, swern oxidation)
Glycol and glycerol: Preparation, reaction with conc. HI, PI3, HIO4,
glycerol with oxalic acid, pinacol-pinacolone rearrangement
PREVIOUS WEEK (20%): Aryl halides: preparation using EAS,
Sandmayer reaction, Mechanism of SNAr reactions (Exclude: Benzyne
mechanism & cine substitution) and EAS Reactions chlorobenzene,
Fittig, Wurtz-Fittig Grignard reagent: Preparation and properties of
Grignard reagent & Organo lithium
Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 186

MATHEMATICS :
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Questions with Integer Answer Type
Sec – III(Q.N : 14 – 18) 3 0 5 15
(Single digit integer 0 to 9 Only)
Total 18 62

PHYSICS :
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 23) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 24 – 31) 4 -2 8 32
(Partial Marking +1)
Questions with Integer Answer Type
Sec – III(Q.N : 32 – 36) 3 0 5 15
(Single digit integer 0 to 9 Only)
Total 18 62

CHEMISTRY :
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 41) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 42 – 49) 4 -2 8 32
(Partial Marking +1)
Questions with Integer Answer Type
Sec – III(Q.N : 50 – 54) 3 0 5 15
(Single digit integer 0 to 9 Only)
Total 18 62

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.

1. The mirror image of the parabola y 2  4 x in the tangent to the parabola at the point (1, 2)
is
2 2
A)  x  1  4  y  1 B)  x  1  4  y  1
2 2
C)  x  1  4  y  1 D)  x  1  4  y  1

2. If a chord, which is not a tangent, of the parabola y 2  16 x has the equation 2 x  y  p, and
midpoint (h, k), then which of the following is (are) possible value(s) of p, h and k?
A) p  1, h  1, k  3 B) p  2, h  3, k  4
C) p  2, h  2, k  4 D) p  5, h  4, k  3
3. From the point (15, 12), three normals are drawn to the parabola y2 = 4x. Then the
centroid of triangle formed by three co-normals points is
A) (26/3, 0) B) (6, 0) C) (16/3, 0) D) (4, 0)
4. Normals at two points  x1 , y1  and  x2 , y2  of the parabola y 2  4 x meet again on the
parabola, where x1  x2  4. Then | y1  y2 | is equal to

A) 2 B) 2 2 C) 4 2 D) none of these
5. If two chords drawn from the point A(4, 4) to the parabola x 2  4 y are bisected by the
line y = mx, the interval in which m lies is
A)  2 2, 2 2  B)  ,  2    2,  

C)  , 2 2  2    2 2  2,   D) none of these

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases

6. Let a variable circle touches a line, which is tangent to the parabola y 2  4 x at (4, 4) and
variable circle passes through focus of the parabola y 2  4 x . If locus of its centre is conic
‘C’, then
A) directrix of conic ‘C’ is x – 2y + 4 = 0
B) focus of conic ‘C’ is (4, 0)
C) latus rectum of conic ‘C’ is 2 5
D) axis of the conic ‘C’ is 2x + y – 2 = 0
7. If two distinct tangents to the parabola y 2  4ax can become normal to the circle
x 2  y 2  2ax  2by  c  0, then

A) a2  4b2 B) b2  4a 2
|b| |b| |a| |a|
C) a    ,  D) b    , 
 2 2   2 2 

8. If roots of the equation 3k 2  3k  2  0 are slope of tangents drawn from P  ,   on the

parabola y 2  8x and let tangents touch the parabola at A and B, then which of the
following is/are correct?
3 3

A) area of triangle PAB is

 33 2 B) area of triangle PAB is
 57  2
4 4
5 5
C) AB  33 D) AB  57
2 2
9. A normal drawn to the parabola y2 = 4ax meets the curve again at Q such that the angle
subtended by PQ at the vertex is 90°. Then the coordinates of P can be
A) 8a, 4 2a  B) 8a, 4a  C)  2a, 2 2a  D)  2a, 2 2a 

10. If two distinct chords of a parabola y2 = 4ax passing through (a, 2a) are bisected on the
line x + y = 1, then the length of the latus rectum can be
A) 2 B) 1 C) 4 D) 3

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
11. The tangent PT and the normal PN to the parabola y 2  4ax at a point P on it meet its
axis at points T and N, respectively. The locus of the centroid of the triangle PTN is a
parabola whose:
2a
A) vertex is  , 0  B) directrix is x = 0
 3 
2a
C) latus rectum is D) focus is (a, 0)
3
12. Let P be the point on the parabola y 2  4 x which is at the shortest distance from the
center S of the circle x 2  y 2  4 x  16 x  64  0 . Let Q be the point on the circle dividing
the line segment SP internally. Then
A) SP  2 5
B) SQ : QP   5  1 : 2

C) the x-intercept of the normal to the parabola at P is 6

1
D) the slope of the tangent to the circle at Q is
2

13. If the parabolas y 2  4 px, p  0 and y 2  4  x  2  have only one common normal, the axis,

then p 
A) (0, 1) B) (1, 2) C)  2,   D)  0,  
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases

14. The maximum number of common normals of y2 = 4ax and x2 = 4by is equal to
15. If the normal to the parabola y 2  4ax at three points  ap 2 , 2ap  ,  aq 2 , 2aq  and  ar 2 , 2ar  are

concurrent, then the common roots of equations px2 + qx + r = 0 and a(b – c)x2 + b(c – a)
x + c(a – b) = 0 is
16. The equation of the line touching both the parabolas y2 = 4x and x2 = –32y is ax + by + c
= 0. Then the value of a + b + c is
17. If the line x + y = 6 is a normal to the parabola y2 = 8x at point (a, b), then the value of a
+ b is

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
18. PQ is any focal chord of the parabola y2 = 8x. Then the length of PQ can never be less
than.
PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.

19. Two capacitors C1  2 F and C2  1 F are charged to same potential V = 100V, but with
opposite polarity as shown in the fig. The switches S1and S2 are closed. The ratio of final
energy to the initial energy of the system is:

1 1
(a) 1 (b) (c) 1/ 9 (d)
2 4
20. Initially the circuit is in steady state. When the switch S is closed, the heat generated in
the circuit will be:

 2C 3 2C
(a) (b) 2 2C (c) (d) Zero
2 2
21. An insulator plate is passed between the plates of a capacitor. Then current:

(a) Always flows from A to B

(b) Always flows form B to A
(c) First flows from A to B and then from B to A
(d) First flows from B to A and then from A to B

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
22. A dielectric slab of area A and thickness d is inserted between the plates of capacitor of
area 2 A and distance between the plates d with a constant speed  as shown in figure.
The capacitor is connected to a battery of emf  . The current in the circuit varies with
time as:

23. Two identical capacitors 1 and 2 are connected in series to a battery as shown in figure.
Capacitor 2 contains a dielectric slab of dielectric constant K as shown in figure.
Q1and Q2 are the charges stored in the capacitors. Now the dielectric slab is removed and

the corresponding charges are Q1' and Q2' , then

Q1' K  1 Q2' K  1 Q2' K  1 Q1' K

(a)  (b)  (c)  (d) 
Q1 K Q2 2 Q2 2K Q1 2

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases

24. Three capacitors each having capacitance C = 2 F are connected with a battery of emf=
30 V as shown in figure. When the switch S is closed:

(a) The amount of the charge flown through the battery is 20 C
(b) The heat generated in the circuit is 0.6 mJ
(c) The energy supplied by the battery is 0.6 mJ]
(d) The amount of charge flown through the switch S is 60 C
25. A parallel plate capacitor of plate area A and separation d is charged to a potential V and
then battery is removed. Now a slab of dielectric constant K is introduced between the
plates of the capacitor. If Q, E and W denote the charge, electric field between the plates
(after introducing the slab) and the work done on the system in the process of
introducing the slab then:
 0 AV  0 KAV V  0 AV 2  1
(a) Q  (b) Q  (c) E  (d) W  1  K 
d d kd 2d

26. A parallel capacitor is charged from a cell and then isolated from it. The separation
between the plates isolated is now increased.
(a) the forced of attraction between the plates will increased
(b) the field in the region between the plates will not change
(c) the energy stored in the capacitor will increase
(d) the potential difference between the plates will decrease

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
27. In the adjacent figure, half of the space between the plates of a parallel plate capacitor is
filled with dielectric material of constant K. Then which of the plots are possible:

28. An uncharged capacitor having capacitance C is connected across a battery of emf  .

Now the capacitor is disconnected and then reconnected across the same battery but with
reversed polarity. Then:
(a) after reconnection, thermal energy produced in the circuit will be equal to 2C 2
(b) after reconnection ,thermal energy produced in the circuit will be equal to two –
third of the total energy supplied by the battery
(c) after reconnection, no energy is supplied by the battery
(d) after reconnection, whole of the energy supplied by the battery is converted into heat
29. A parallel plate air capacitor is connected to a battery. The quantities charge, voltage,
electric field and electrostatic energy associated with this capacitor are given by
Q0 , V0 , E0 and U 0 respectively. A dielectric slabs is now introduced to fill the space

between the plates with battery still in connection. The corresponding quantities are now
given by Q, V, E and U related to the previous ones are:

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
a) Q  Q0 2) V  V0 3) E  E0 4) U  U 0
30. A dielectric slab fills the space between the plates of a parallel-plate capacitor. The
magnitude of the bound charge on the slab is 75% of the magnitude of the free charge on
the plates. The capacitance is 480 F and the maximum charge that can be stored on the
capacitor is 240 0 L2 Emax , where Emax is the breakdown field:
(a) the dielectric constant for the dielectric slab is 4
(b) without the dielectric, the capacitance of the capacitor would be 360 F
(c) the plate are is 60L2
(d) if the dielectric slab is having the same area as the capacitor plate but the width half
that of the capacitor, the capacitance would be 192 F
31. Identical dielectric slabs are inserted into two identical capacitors A and B. These
capacitors and a battery are connected as shown in the figure. Now the slab of capacitor
B is pulled out with battery remaining connected:

(a) During the process, charge flow form a to b

(b) Finally charge on capacitor B will be less than that on A
(c) During the process work is done by the external force F, part of which appears as
heat in the circuit
(d) During the process internal energy of the battery increases
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases
32. The potential across a 3 F capacitor is 12 V when it is not connected to anything. It is
then connected in parallel with an uncharged 6  F capacitor. At equilibrium, and the
potential difference V across 3 F capacitor is?

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
33. The plates of a parallel plate capacitor are charged up to 100 V. A 2 mm thick insulator
sheet is inserted between the plates. Then to maintain the same potential difference, the
distance between capacitor plates is increased by 1.6 mm. The dielectric constant of the
insulator is:
34. A parallel plate capacitor of area A, plate separation d and capacitance C is filled with
three different dielectric materials having dielectric constants k1  2 , k2  4 and k3  3 as
shown. If a single dielectric material is to be used to have the same capacitance C in this
capacitor, then its dielectric constant k is given by (nearly)

35. A capacitor is filled with an insulator and a certain potential difference is applied to its
plates. The energy stored in the capacitor is U. Now the capacitor is disconnected from
the source and the insulator is pulled out of the capacitor. The work performed against
the forces of the electric field in pulling out the insulator is 4U. Then dielectric constant
of the insulator is:
36. Three conducting plates are placed parallel to one another as shown in the figure. The
outer plates are neutral and connected by a conducting wire. The inner plate is isolated
and carries a total charge amounting to 10  C . The charged densities on upper and lower
5 1
face of middle plate are 1 and  2 . Find .
2

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
37. What is true for the equilibrium reaction ?

O O
|| ||

cat
CH 3  C  OH  CH 3  OH  
 CH 3  C  O  CH 3  H 2O

A) The use of equimolar quantities of CH 3OH and CH 3COOH will give the greatest yield

of the ester at equilibrium

B) Removal of water will increase the amount of ester at equilibrium

C) Addition of CH 3COOCH 3 will cause the formation of equal an equal number of moles

of water
D) Application of pressure increases the amount of ester at equilibrium

38. The structure of the product formed in the reaction given below is :

39.

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
40. Rank the transition states that occur during the following reaction steps in order of
increasing stability (least  most stable )
 
1) H 3C  O H 2  CH 3  H 2O 2)  CH 3 3 C  O H 2   CH 3 3 C   H 2O

3)  CH 3 2 CH  O H 2   CH 3 2 CH   H 2O
A) 1  2  3 B) 2  3  1 C) 1  3  2 D) 2  1  3

CHO
|
2 HIO4
41. CH  OH   Products obtained in the above reaction are :
|
CH 2  OH

A) HCHO, HCO2 H B) HCHO, 2 HCO2 H

C) CO2 , 2 HCO2 H D) CO2 , HCHO, HCO2 H
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases
42. Select the best method for the preparation of the following compounds :

A) Reactin of cyclohexanone with CH 3 Li

B) Reaction of 1-methylcyclohexene with Hg  OAC 2 followed by NaBH 4

C) Reaction of cyclohexene with BH 3 ; NaOH / H 2O2 , following by CH 3 Br

D) Reaction of cyclohexene with MCPBA, followed by CH 3 MgBr

Product (D) in above reaction is :

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP

44.

45. O O A formed in this reaction is

|| ||
 3
i CH MgBr  one mol 
CH 3CCH 2CH 2COCH 2CH 3   A
ii  H 3O

OH O
| ||
A) CH 3CCH 2CH 2COCH 2CH 3 B) O O
| || ||
CH 3 CH 3CCH 2CH 2CCH 3

CH 3 CH 3
| |
C) D) CH 3CCH 2CH 2CCH 3
| |
OH OH

46. Reagent which can’t be used to carryout this conversion are :

A) LiAlH 4 B) N 2 H 4 / OH  /  C) N 2 H 4 / H 2O2 D) Zn  Hg  HCl

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP

CH 3
|
NaI , Acetone
47. CH 3  C  CH  CH 2    X  major
|
Br

CH 3
|
A) CH 3 B) CH 3  C  CH  CH 2
| |
CH 2  C  CH  CH 2
I

CH 2  C  CH  CH 3
|
C) D) I

48. Which of the following substrate (s) upon treating with a base at higher temperature will
yield predominantly Hoffmann’s product
CH 3CH 2CH 2CHCH 3 CH 3CH 2CH 2CHCH 3
| |
A) F B) I

CH 3  CH  CH  CH 3
| |
C) D) Ph Br

49. To accomplish the following conversion which set of reagents can be used :
C6 H 5CH  CH  CH 2OH  C6 H 5CH  CH  CHO

A) O3 / H 2O2 B)  t  BuO 5 Al / CH 3COCH 3 3) KMnO4 , H  4) MnO2

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Narayana IIT Academy 04-02-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-38_QP
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases

50.

Number of   Hydrogen atoms in Hydrocarbon formed as major product

51.

Identify total number of monochloro products ?

52. How many compounds are more reactive than towards S N 1 (hydrolysis ) ?

i) ii) CH 3  CH 2  Cl iii) iv)

v) vi) CH 2  CH  Cl vii) CH 3  Cl viii)

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53. How many compounds do not give ether as major product by Williumson ether synthesis
 
in presence of N a O CH 3 (sodium methoxide)

i) ii) CH 3  CH 2  Cl iii)

iv) v) vi) CH 2  CH  Cl

Vii CH 3  Cl viii)

54. Number of reactions in which aldehyde can be obtained as one of the product.
Cu CrO3
i) CH 3  CH 2OH 
5000 C
 ii) CH 3  CH 2  CH 2  OH 
Pyridine 

H  Pd
2
CH 3  C  Cl 
BaSO4 
||
iii) O iv)

 i DIBAL  H ,low temperature H3O 

v) CH 3  C  N 
ii H O / H 

 vi) CH 3  CH  NH  
  2

O3
vii) viii) CH 3  CH  CH  CH 3 
Zn

ix)

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