Sec: JR IIT STAR CO-SC (MODEL-A&B) WTM-28 Date: 05-02-2024

Time: 3 Hrs MAIN MODEL Max. Marks: 300

KEY SHEET
PHYSICS
1-10 A A B C C A B A B A

11-20 C D A B A D A D A A

21-30 7 9 3 240 60 6 6 10 864 16

CHEMISTRY
31 32 33 34 35 36 37 38 39 40
D A A C B B B A D A
41 42 43 44 45 46 47 48 49 50
A B B A D B A D C A
51 52 53 54 55 56 57 58 59 60
3 8 3 4 4 5 2 5 2 4
MATHS

61 62 63 64 65 66 67 68 69 70
B D B A B A B D C A
71 72 73 74 75 76 77 78 79 80
A A A B B B C C B B
81 82 83 84 85 86 87 88 89 90
16 0.50 9 16 32 10 63 292 9 13

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SOLUTIONS
PHYSICS
1. Wheat stone bridge
12

6 11 24

12
12  24 6  12
Ce  
12  24 6  12
=8+4 = 12
E dc E 0 b  K  1
2 2
2. F   2Ma
2 dx 2 d
E 2  0 b  K  1
a
4Md
V 2
0
E 2  0 b  k  1
 2 a
4 4Md
20 Ab  k  1
V0  E
Md

3. The equivalent circuit is

C
A
C

C C/2

Ans: C eq  11C / 7

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4. Wnet  Wbattery  Went  U f  U i
Went  U f  U i  Wb
1 1
 CV 2  C 0 V 2  V 2  C  C0 
2 2
  C0  C  V 2 / 2
C  20nF
C 0  C / 1  n   50nF
Went  30  10 9  10 4 / 2  0.15mJ
0 A 3 AK
5. Ce   0
d d 2d
0
3K 3K
3 AKV
Q  Ce V  0
2d
2
Q2 1  3KV 
F  0 A  
2 0 A 2  2d 
6. Initially Finaly
140 140 210 105

360 360 375 420

Q= 210-105=105
2102  2 12 5  6
Vi  Vg      10
2 3 7 2
21  21 28  72  105
   104
2 42
21
  5  10 4
4
 26.25  104
Wb  210  25 106
= 52.5 104
H  26.25  10 4 J
7.

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O Q 0 Q 0 O Q0 Q
  0
2 2

Qi Qi
Q0 1 Q0 Q
   i
2 0 A K 2 0 A  0 A
Q0  1  Q0
 Qi  1   
2  K 4

08. Charge does not flow from one independent loop to another.
1
09. Due to polarization, charge on dielectric slab would be CV 1   .
 K 

So,
Charge on 1 = 0
1  CV
Charge on 2  CV  CV 1  
 K K
1 CV
Charge on 3  CV  1    CV  
 K K
Charge on 4 = 0
10.

Equivalent circuit can be drawn as

[As U and V are at same potential, remove all capacitors between these points]

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11. . Let c be the capacity without slab. Then after removing the slab, net capacity is c/2.
The slab, net capacity is c/2.
CE
Q11  Q21 
2
Before the slab is removed C1  C & C2  kc
 k 
Cnet   c
 k 1
 kCE 
Q1  Q2 
 k  1 
Q21 k  1

Q2 2k
12. Conceptual.
13. Conceptual.
2Q  q  Q  q  q
14. If ‘q’ is the charge on capacitor finally then    showing this
4 0 R  4 0 R  c
Q
equation we get q  .
4 0 R
2
C
15. Equivalent capacitance in series
C  KC  KC
Ceq  
C  KC K 1
3d
16. x y d  x y d
4
3Ed  3d d 
V    x  y   V  E   
4k  4k 4 
  3d  dk  Q  3  k 
V   
0  4k  A 0  4k 
Q A 0  4k 
C   3  k 
V d
1
17. Vi  10C V 2
2
Here V =constant and ‘C’ becomes 1.5 times
1 1
So U f  C f V f2  10C  V 2  1.5Vi
2 2
V 0.5Vi
100  100  50%
V Vi
18. q  CV
kA 0 q
q .Ed  k 
d A 0 E

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7 10 6 7
  3.6 107   2.33
1 3
30 10 4 
4  9 109
19. Equivalent circuit is
A
K1 0
C1  2  K1 0 A
d d
2
A
K 2 0
C2  2  K 2 0 A
d d
2
A
0
C3  2  0 A
d 2d
1 1 A 0  1 K1 K 2 
Ceq    C3    
C1 C2 d  2 K1  K 2 
20. Conceptual
21.

A D E
B C F
2C C 2C C 2C

B/F


2C
C

  2C  O
C E

2C C


A/D

22. A&C
5 29
C1  3  1 
6 6
6 2 58
A & B: C 2  2   
5 3 15
C 2 58 6 12 4
   
C1 15 29 15 5
q0
23. E0 
 0 A1
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q0
8E 0 
3 0 A 2
1 3A 2

8 A1
1 1
24. Energy = Ceff V 2  1.2   0  20  20   240 0
2 2
0r1 A 0r2 A
25. C1  , C2 
t1 t2
Let A be the voltage of conducting foil. As the capacitors are connected in series, so charge on the
capacitors should be same Q1  Q2
C1 100  V   C2V
0r1 A 0r2 AV
100  V    V  60V
t1 t2
26. Initial charge on C = 18CV
Initial charge on 3C = 54CV
Let final common potential difference = V 
Q final  Qinitial
9CV   3CV   18CV  54CV  V   6V
A 0
27. Ci   4 F
d
A 0 A 0 4 F
Cf     6 F
t  1 1 2
d t  d 1   
k  2 6 3
q2
28. U , As C = constant, U  q 2
2c
2
U 2  q2  U
    q12  1 q22
U1  q1  U2
1
29. Initial energy stored in the capacitor U i  CV 2  1008 pJ
2
After inserting porcelain plate, k = 7
1 CV 2
Uf   144 pJ
2 k
Constant M.E with which plate oscillates back and forth U i  U f  1008  144  864 pJ
30. In parallel combination, U i  U f  1008  144  864 pJ
1 
 C1V 2 
U 2   1  C1  1
When connected across 1V battery, then 1  
U2  1 2 4 C2 4
 C2V 
2 
C2  8 F and C1  2  F

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C1C2 2  8 16
Now C1 and C2 are connected in series combination, Cequivalent     1.6  F
C1  C2 2  8 10

CHEMISTRY
SOLUTION

31.

32.

33.

34. LiAlH4 Reduces ester, aldehyde and ketones.

35. In esterification, alcohol contributes H and acid gives OH in loss of water
36. H2CrO4 doesn’t oxidize 30 alcohol.
37. PCC converts 20 alcohol to ketone.
38. In hydroboration alkenes are converted to alcohols according to anti-Markovnikov’s rule.

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39.

Product is R-2-Chlorobutane.
40. According to stability of carbocation, as dehydration involves formation of carbocation.
41. Polar aprotic solvent favours SN 2 mechanism.
42. Ring expansion, so q will migrate.
45. According to carbocation stability.
46.

47. Rate of SN1reaction is a

t-Bu X > iso – PrX > EtX > MeX
So order of activation energy
t-Bu X < iso – PrX < EtX < MeX
and order of ionization energy
t-BuX < iso-PrX < EtX < MeX
48.

49. More is development of + ve charge on carbon bearing OH, more easily is attack of Cl – .
50. Cis alkenes on reaction with OsO4 given meso product.
51. X can be

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Total 9 alkenes are formed and after fractional distillation 6 are separated.

MATHS
2
61) t2  t1 
t1
62) Normal Condition al 3  2alm2  m 2 n  0

63) Conceptual

64) a  mc  0 where y  mx  c

65) Use S1  S11

66) 67)

2
 t 2  tT  2  0
T  t 
68) Condition is t
tR    0  T2 8  0
69)

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70)

71)

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72)

73)

74)

75)

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76)

77)

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78)

79) ( B) y   x  k is normal to y 2  12 x if k  6(1)  3(1)3  using c  2am  am3 

80)

81) We have, y 2  8 x  4 y  4 or ( y  2) 2  8( x  1) Focal chord passes through the focus

(2, 1) and (3, 0) (as x  intercept is 3). So, equation of focal chord is y  x  3.

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Now, the length of focal chord of parabola y 2  4ax making an angle ‘  ’ with positive x  axis is
4a cos esc 2 . For given parabola, a  2 and   450 (as slope of chord is I ).
So, length of focal chord is 4  2  cos ec 2 450  16

82) Let point P be (t 2 , t ) . Tangent at point P is 2ty  x  t 2 . Tangent meets x -axis at Q( t 2 , 0)

Area of triangle OPQ is 4 sq. units.

0 0 1
1 2
 t t 1  4
2 2
t 0 1
3
 t  8  t  2 ( t  0)
1
m 
2
83) Let on the parabola (a, b)  (t 2 , 2t )  A
Then equation of tangent to parabola at A is ty  x  t 2 This line touches the circle also.
3  0  t2
 3
1 t2
 (3  t 2 ) 2  9(1  t 2 )  t 4  3t 2  0
 t  0,  3, 3
So, A  (3, 2 3) and equation of tangent is 3 y  x  3.
Equation of normal to circle perpendicular to the above tangent is y   3 x  3 3.
3 3 3
Solving above lines we get point of contact on the circle  ,  .
2 2 
 3
 2(a  c)  2  3    9
 2
84) Equation of parabola is y 2  12 x .
Let P  (3t12 , 6t1 ) and Q  (3t2 2 ,6t2 )
Tangent at P and Q intersect at R( ,  ) .
   3t1t2 and   3(t1  t2 )
Also, 6t1 :6t2  3 :1

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 t2  3t1
 2 9(t1  t2 )2 (4t1 ) 2
   2  16
 3t1t2 t1
1
85) Equation of tangent to parabola y 2  4 x having slope m is y  mx  .
m
Equations of tangents to circle ( x  4)2  y 2  16 having slope m are y  m( x  4)  4 1  m 2
1
For common tangent  4 m  4 1  m 2
m
1
m  
2 2
1
For m  , point of contact on the parabola is (8, 4 2) to the circle is
2 2
(8  4) 2  (4 2)2  16  32  32 .
86) Vertex and focus of parabola P1 are A(3, 2) and B(4, 4) respectively. If C is the foot of perpendicular
on the axis of the parabola, then C  (2, 0) . AB is the axis of the parabola. Its slope is 2 . So, equation of
directrix is x  2 y  2 . Its image in the line x  2 y  6 is x  2 y  10
1 
87) Focus of parabola y 2  2 x is  , 0  . Let the center of the circle having radius 2 units be (h, k ) .
2 
1 
 Its equation will be ( x  h)2  ( y  k )2  4 This circle passes through the points (0, 0) and  , 0 
2 
1
 (1 / 2  h ) 2  k 2  h 2  k 2  4 or h  .
4
2 2 2
2 63  1  63 
1/ 16  k  4 or k   So, possible equations of circles are  x     y    4.
4  4  4 
2 2 2
 1  1  63 
If parabola y   x     and circle  x     y    4. touch then
 4  4  4 
63 8  63
  2  .
4 4
2 2 2
 1  1  63 
If parabola y   x     and circle  x     y    4 touch then
 4  4  4 
63 8  63
  2  .  4  8   63 or (4  8)2  63 .
4 4
88) Equation of tangent at P(1,3) to the curve x 2  2 x  4 y  9  0 is y  x  2  A  (0, 2)
Equation of line passing through P and parallel to the line x  3 y  6 is x  3 y  8
This line meets parabola y 2  4 x at B(16,8) ), which lies on the line 2  3 y  8 .  ( AB ) 2  292
3
89) Equation of normal to parabola y 2  6 x at point P having parameter ' r ' is y  tx  3t  t 3
2
 3 3 3
If it passes through the point  3,  , then   3t  3t  t 3  t 3  I  t  I
 2 2 2

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3  3 
Now P   t 2 , 3t   ( ,  )  2(   )  2   3   9
2  2 
dy
90) y  2 x2  x  2   4 x  1 Let the coordinates of P be (h, k ) . Then the normal at P is
dx
1
yk   ( x  h) Normal passes through the point Q(6, 4) .
4h  1
1
4  k   (6  h )  (4 h  1)(4  k )  6  h  0 Also, k  2h 2  h  2
4h  1
 (4 h  1)(4  2h 2  h  2)  6  h  0  (4h  1)(2 h2  h  2)  h  6  0
 8h 3  6h 2  7 h  2  h  6  0  4h 3  3h 2  3h  4  0  h  1, k  5
1 0 0
1
So, area of OPS  1 1 5  13
2
1 6 4

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