DPP :-3 ( Henry’s law and Raoult’s law )
Q.1) The normal boiling point of water is 373 k . Vapour pressure of water at temperature T
is 19 mmHg . If enthalpy of vapourisation is 40.67 KJ/mol .then temperature T would be .(
Use : log 2 = 0.3 . R : 8.3 JK-1 mol-1 ) :
A) 250 K. B) 291 .4 K. C) 230 k. D 290 K
Q .2) For an ideal binary liquid solution with PAo > PBo , which relation between XA ( mole
fraction of A in liquid phase ) and YA (mole fraction in vapour phase ) is correct.
A) YA < YB B) XA > XB. C) YA/YB > XA / XB. D) YA/YB < XA/XB.
Q.3) An ideal solution has two components A and B . A is more volatile than B , i.e , PAo > PBo
and also PAo > Ptotal .If XA and YA are mole fraction of components A in liquid and vapour
phases, then :
A) XA = YA. B) XA > YA C) XA < YA D) Data insufficient.
Q.4) Why is the solubility of Glauber ‘S salt ( Na2SO4.10H2O ) first increases upto 32.4oC and
then decrease?
Q.5) Value of Henry constant KH
A) Increases with decrease in temperature
B) Decrease with increase in temperature
C) Increase with increase in temperature
D) Remain same .
Q.6) Predict which gas among the given pair of gases will be more soluble in water.At 293K ,
He (KH = 144.97 K Bar ) or O2 (kH = 34.86 KBar )
Q.7) What is the importance of Henry’s law constant.
Q 8) Answer the following questions:
(A) State Henry’s law and explain why are the tanks used by scuba divers filled with air
diluted with helium ( 11.7%Helium , 56.2% nitrogen and 32.1% Oxygen)
Or
B) Assume that argon exerts a partial pressure of 6 bar . Calculate the solubility of organ
gas in water .( Given Henry ‘s law constant for argon dissolved in water , KH = 40 KBar) . ( Ans
:- 1.5 X 10-4 )
Q.9) An unknown gas ‘X’ is dissolved in water at 2.5 bar pressure and has mole fraction 0.04
in solution.The mole fraction of ‘X’ gas when the pressure of gas is doubled at the same
temperature is . ( Ans :- 0.08 )
10) What type of intermolecular interaction exists in the pair of methanol and acetone?
11) On mixing liquid X and Y , the volume of the resulting solution increases.what type of
deviation from Raoult’s law is shown by the resulting solution? What change in temperature
would after mixing liquids X and Y ?
12) Four solutions were made by mixing
i) Ethanol and acetone ii) Carbon di sulphide and acetone iii) Phenol and aniline
iV) Chloroform and acetone
Predict which solutions will exhibit positive and which solution will exhibit negative
deviation from Raoult’s law . Explain your answer.
Q.13) A solution was prepared by dissolving 5g of non – volatile solute in 95g of water . if
has a vapour pressure of 23.375 mm Hg at 298 K . Calculate the molar mass of solute .[
vapour pressure of pure water at 298 K is 23 .75 mmHg ] .(Ans :- 60g/mol)
Q.14) Two volatile liquid A and B are mixed in mole ratio 1:3, to form an ideal liquid solution
Vapour pressure of pure. A and B are 600 torr and 200 torr. Volume of container for vapour
is 76 litre.
(R=1/12 Litre ATM/K/Mole)
Calculate the mole of A in vapour phase at 300 K, assuming negligible amount of vapour is
present compared to liquid in container ( Hint : moles in vapour phase = yA x moles in liquid
phase) ( Ans = 0.6 mole)
Q.15) The liquids X and Y from ideal solution having vapour pressures 200 and 100 mm Hg
respectively. Calculate the mole fraction of component X in vapour phase in equilibrium
with an equimolar solution of the two . ( Ans = 0.59 )
