Liquid Solution DPP-01

1. On increasing temperature, the value of Henry's constant ________

(A) decreases
(B) increases
(C) remains constant
(D) uncertain

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2. An unknown solution [Molecular wt of solute = 250] is 20% . Molarity of solution is ..
w
[Given density of solution = 1.25 g/mL]
(A) 1 M
(B) 2 M
(C) 3 M
(D) 4 M

3. Which of the following is depend on temperature -

(A) % w/v
(B) % w/w
(C) Molality
(D) Mol fraction

4. The value of Henry’s law constant for some gases at 293 K is given below. Arrange the gases in the
increasing order of their solubility.
He : 144.97 kbar, H2 : 69.16 kbar, N2 : 76.48 kbar, O2 : 34.86 kbar
(A) He < N2 < H2 < O2
(B) O2 < H2 < N2 < He
(C) H2 < N2 < O2 < He
(D) He < O2 < N2 < H2

5. Two beakers A and B containing pure water and aqueous solution are shown. What will be observed
gradually with passage of time ?

(A) Level of water in beaker A becomes lower than that in beaker B

(B) Level of water in beakers A and B remains constant
(C) Level of water in beaker A increases and that in beaker B decreases
(D) Level of both the beakers increases
6. According to Henry law, the solubility of a gas in a given volume of liquid increase with increase in :-
(A) Temperature
(B) Pressure
(C) Both
(D) None

7. Henry's law constant (KH) for methane in benzene at 298 K is 4.5 × 105 mm Hg. If we use the mole fraction
of methane in the solution as a measure of its solubility then calculate the solubility of methane in
benzene at 298 K under 760 mm Hg.
(A) 1.68 × 10–3
(B) 2.72 × 10–4
(C) 3.24 × 10–5
(D) 1.68 × 10–2

8. CO(g) is dissolved in H2O at 30°C and its pressure is 0.020 atm. Henry's law constant for this system is
6.20 × 104 atm. Thus, mole fraction of CO(g) is :-
(A) 1.72 × 10–7
(B) 3.22 × 10–6
(C) 3.22 × 10–5
(D) 3.22 × 10–7

9. A gas 'X' is dissolved in water at 2 bar pressure. Its mole fraction is .02 in solution. The mole fraction of
water when the pressure of gas is doubled at the same temperature.
(A) 0.04
(B) 0.98
(C) 0.96
(D) 0.02

10. The partial pressure ratio PA0 : PB0 for the two volatile liquid A and B are PA0 : PB0 = 1:2 and mole ratio is
XA : XB = 1: 2. What is the mole fraction of A in vapour phase ?
(A) 0.33
(B) 0.25
(C) 0.20
(D) 0.52

11. The vapour pressure of two pure liquids (A) and (B) are 100 and 80 torr respectively. The total pressure
of solution obtained by mixing 2 mole of (A) and 3 mole of (B) would be :-
(A) 120 torr
(B) 36 torr
(C) 88 torr
(D) 180 torr

12. 2 mole each of liquid A and B are dissolved to form an ideal solution. What will be the mole fraction of
B in the vapour phase ?
PA0 = 120 torr and PB0 = 80 torr.
(A) 1/4
(B) 1/2
(C) 3/5
(D) 2/5

13. The Henry law constant for dissolution of a gas in aqueous medium is 3 × 10 2 atm. At what partial
5
pressure of the gas, the molality of gas in aqueous solution will be m.
9
(Answer should be nearest integral value)
 Answer Key

Question 1 2 3 4 5 6 7 8 9 10 11 12 13

Answer B A A A A B A D C C C D 3
 Liquid Solution DPP-02

1. State T(true)/F(false) for following statements regarding given liquid solutions :

I II III
(a) Final volume of solutions if equal volume of compounds are mixed, is in the order: VI = VII < VIII
(b) ΔSmix for solution I and solution II is positive but for solution III it is zero.
(c) Enthalpy change of mixing is negative for solution II and solution III but positive for solution I.
(A) TFF
(B) FFF
(C) TTF
(D) FTT

2. The vapour pressure of the solution of two liquids A(P° = 80 mm) and B(P° = 120 mm) is found to be
100 mm when XA = 0.4. The result shows that
(A) Solution exhibits ideal behaviour
(B) Solution shows positive deviation from ideal behaviour
(C) Solution shows negative deviation from ideal behaviour
(D) Attractive intermolecular forces between A–A in pure liquid A and B–B in pure liquid B are stronger than
those between A–B when mixed in solution.

3. Two components A and B form an ideal solution. The mole fractions of A and B in ideal solution are
XA and XB while that in vapour phase, these components have their mole fractions as YA and YB. Then, the
1 1
slope and intercept of plot of vs. will be :-
YA XA
PAo PBo − PAo
(A) ,
PBo PBo
PAo PBo − PAo
(B) ,
PBo PBo
PBo PBo
(C) ,
PAo PBo − PAo
PAo
(D) PAo − PBo ,
PBo
4. The diagram given below is a vapour pressure-composition diagram for a binary solution of A and B. In
the solution, A–B interactions are –

(A) similar to A–A and B–B interactions

(B) greater than A–A and B–B interactions
(C) smaller than A–A and B–B interactions
(D) unpredictable

5. Which of the following is incorrect for an ideal solution :-

(A) Hmix = 0 and Vmix = 0
(B) Vmix = 0 and Smix > 0
(C) Hmix > 0 and Smix > 0
(D) Gmix < 0 and Smix > 0

6. A binary solution of liquid A and B will show positive deviation from Raoult's law if it fulfils the following
condition :-
(1) PA > PAoXA and PB > PBoXB
(2) The inter molecular force of A–B < A–A, B–B
(3) Hmix is positive
(4) Vmix is negative
(A) 1, 2 and 4 are True
(B) 1, 2 are wrong
(C) 1, 2, 3 are true
(D) 1, 3, 4 are true

7. Total vapour pressure of mixture of 1 mol volatile component A(PAo = 100 mmHg) and 3 mol of volatile
component B (PBo = 60 mmHg) is 75 mm. For such case :-
(A) There is positive deviation from Raoult's law
(B) Boiling point has been lowered
(C) Force of attraction between A and B is smaller than that between A and A or between B and B
(D) All the above statements are correct
8. Liquids A and B form an ideal solution. A certain solution of A and B contains 25 mole percent of A,
whereas the vapours in the equilibrium with the solution at 298 K contains 50 mole percent of A. The
ratio of vapour pressures of pure A to that of pure B at 298 K, is
(A) 1:1
(B) 3:1
(C) 1:3
(D) 2:1

9. Two liquids A and B have vapour pressure in the ratio PA0 : PB0 = 1 : 3 at a certain temperature. Assume
A and B form an ideal solution and the ratio of mole fractions of A to B in the vapour phase is 4 : 3. Then
the mole fraction of B in the solution at the same temperature is:-
1
(A)
5
2
(B)
3
4
(C)
5
1
(D)
4

10. Two liquids A and B have PA0 and PB0 in the ratio of 1 : 3 and the ratio of number of moles of A and B in
liquid phase are 1 : 3 then mole fraction of 'A' in vapour phase in equilibrium with the solution is equal
to:-
(A) 0.1
(B) 0.2
(C) 0.5
(D) 1.0

11. At 40°C, the vapour pressure (in torr) of methyl alcohol (A) and ethyl alcohol (B) solution is represented
by :
 P0   P0 
Ps = 120 XA + 138 ; where XA is mole fraction of methyl alcohol. The value of lim  B  and lim  A 
XA → 0 X XB → 0 X
 B  A
are :-
(A) 138, 258
(B) 258, 138
(C) 120, 138
(D) 138, 125
 Answer Key

Question 1 2 3 4 5 6 7 8 9 10 11

Answer B C B C C C D B A A A
 Liquid Solution DPP-03

1. The unit of ebullioscopic constant is _______

(A) K kg mol–1 or K (molality)–1
(B) mol kg K–1 or K–1 (molality)
(C) kg mol–1 K–1 or K–1 (molality)–1
(D) K mol kg–1 or K (molality)

2. When common salt is dissolved in water

(A) Melting Point of the solution increases.
(B) Boiling Point of the solution increases.
(C) Boiling Point of the solution decreases.
(D) Both Melting Point and Boiling Point is decreased.

3. A liquid freeze at 7ºC and boils at 77ºC. If values of K f and Kb of this liquid are 5.6 K-kg/mole and 2.5 K-
kg/mole respectively, then ratio of molar latent heat of fusion (in kJ/mol) to molar latent heat of
vaporisation (in kJ/mol) for the liquid is -
(A) 1 : 1
(B) 7 : 2
(C) 2 : 7
(D) 7 : 3

4. 60 gm urea was dissolved in 1L water. Find amount of water vapourised if temperature of the solution is
raised to 101.5°C.
[Given Kb (water) = 0.5 k kg mol–1, density of water = 1 gm mL–1]
(A) 450 g
(B) 633.33 g
(C) 650 g
(D) 666.67 g

5. A solution containing 0.1 g of a non-voltatile organic substance P(molecular mass 100) in 100g of
benzene raises the boiling point of benzene by 0.2°C, while a solution containing 0.1 g of another non-
volatile substance Q in the same amount of benzene raises the boiling point of benzene by 0.4°C. What
is the ratio of molecular masses of P and Q ?
(A) 1 : 2
(B) 2 : 1
(C) 1 : 4
(D) 4 : 1
6. Vapour pressure of solute containing 6gm non-volatile solute in 180 gm of water is 20 torr. If 1 mole of
water is further added into the solution so that vapour pressure increases by 0.02 torr. Calculate vapour

pressure of pure water.

(A) 20.22 torr

(B) 20.02 torr

(C) 19.78 torr

(D) 19.88 torr

7. At a certain temperature when glucose is dissolved in water lowering in vapour pressure is 0.6 mmHg.

What will be the vapour pressure of glucose solution if molality is 1/18?

(A) 200 mm Hg
(B) 300 mm Hg
(C) 600 mm Hg

(D) 720 mm Hg

8. Elevation of boiling point of 1 molar aqueous glucose solution (density = 1.2 g/ml) is
(A) Kb

(B) 1.20 Kb

(C) 1.02 Kb

(D) 0.98 Kb

9. In three beakers labelled as (A), (B) and (C), 100 mL of water, 100 mL of 1M aqueous solution of glucose

and 100 mL of 0.5 M aqueous solution of urea are taken respectively and kept at same temperature.

Which of the following statements is correct ?

(A) Vapour pressure in all the three beakers is same.

(B) Vapour pressure of beaker B is highest among all.

(C) Vapour pressure of beaker C is highest among all.

(D) Vapour pressure of beaker B is lower than that of C and vapour pressure of beaker C is lower than that of A.

10. In the depression of freezing point experiment, it is found that

(A) The vapour pressure of the solution is less than that of pure solvent

(B) The vapour pressure of the solution more than that of pure solvent
(C) Only solute molecules solidify at the freezing point

(D) solution molecules solidify at the freezing point

11. The value of Kb is given by RTb2/1000 X. In this relation X is :-
(A) Density of solution
(B) H°f of solvent
(C) Latent heat of vaporisation
(D) Enthalpy of vaporisation

12. The freezing point of a 4% aqueous solution of A' is equal to the freezing point of 10% aqueous solution
of B'. If the molecular weight of 'A' is 60 than the molecular weight of B' will be :-
(A) 160
(B) 90
(C) 45
(D) 180

13. Determine the boiling point of a mixture containing 1560 g benzene (molar mass = 78) and 1125 g
chlorobenzene (molar mass = 112.5) using the following graph at atmospheric pressure of 1000 torr :-

(A) 90°
(B) 100°C
(C) 110°C
(D) 120°C

14. Which of the following mixture of solutions cannot form any type of azeotropes ?
(A) HCl + H2O
(B) CH3COCH3 + CHCl3
(C) C2H5Br + C2H5I
(D) C2H5OH + H2O

15. An azeotropic mixture of two liquid has a boiling point higher than either of them when it:-
(A) show positive deviation from Raoult's law
(B) shows negative deviation from Raoult's law
(C) show ideal behaviour
(D) is saturated
 Answer Key

Question 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Answer A B C D B A C D D A C A B C B
 Liquid Solution DPP-04

1. Consider following solutions :

(P) 1M aqueous glucose solution
(Q) 1M aqueous sodium chloride solution
(R) 1M aqueous ammonium phosphate solution
(S) 1M benzoic acid in benzene
Select the INCORRECT statements -
(A) πP = πS
(B) πR > πS
(C) πR > πQ
(D) πQ > πP

2. If 'α' is degree of dimerization of CH3COOH in benzene, then Van't Haff factor 'i' for calculation of
colligative properties is.
(A) 1 + α

(B) 1 –
2

(C) 1 +
2
(D) 1 + 2α

3. When 20 g of naphtholic acid (C11H8O2) is dissolved in 50 g of benzene (Kf = 1.72 K kg mol–1), a freezing
point depression of 2 K is observed. The Van’t Hoff factor (i) is
(A) 0.5
(B) 1
(C) 2
(D) 3

4. A graph of osmotic pressure (π) vs molarity (M) of aqueous solution of NaCl at room temperature is
given below. The slope of the line represents :-

(A) Concentration
(B) Universal gas constant
(C) RT
(D) None of these
5. Which of the following 0.1 M aqueous solutions will have lowest freezing point ?
(A) Potassium sulphate
(B) Sodium chloride
(C) Urea
(D) Glucose

6. Which of the following is CORRECT for the aqueous solutions of the following salts assuming 100%
ionisation.
(A) 0.5 M of MgSO4 & 0.25 M of Na3PO4 are isotonic.
(B) 0.5 M MgSO4 is hypertonic to 0.25 M of Na3PO4
(C) 0.25 M Na3PO4 is hypotonic to 0.5 M MgSO4
(D) 0.25 M of MgSO4 & 0.5 M Na3PO4 are isotonic.

7. Which one of the following aqueous solutions will exhibit highest boiling point?
(A) 0.01M Na2SO4
(B) 0.01M KNO3
(C) 0.015M urea
(D) 0.015M glucose

8. Amongst the following, the solution which shows highest osmotic pressure is
(A) 0.05 M NaCl
(B) 0.10 M BaCl2
(C) 0.05 M FeCl3
(D) 0.05 M Na2SO4

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9. Which of the following is isotonic with 15% glucose solution (sp. gr = 1.2) :
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(A) 1 M CaCl2
(B) 1 N CaCl2
(C) 0.5 M NaCl
(D) 0.5 M urea

10. For which of the following aq. solution freezing point is maximum -
(A) 0.1 M urea
(B) 0.1M NaCl
(C) 0.05 M AlCl3
(D) 0.15 M glucose
11. Mark the correct relationship between the boiling points of very dilute solutions of BaCl 2 (t1) and KCl
(t2), having the same molarity
(A) t1 = t2
(B) t1 > t2
(C) t2 > t1
(D) t2 is approximately equal to t1

12. Which solution will show the maximum vapour pressure at 300 K
(A) 1 M C12H22O11
(B) 1 M CH3COOH
(C) 1 M CaCl2
(D) 1 M NaCl

13. Van't Hoff factor for a dilute aqueous solution of HCN is 1.00002. The percent degree of dissociation of
the acid is :-
(A) 2 × 10–5
(B) 2 × 10–4
(C) 2 × 10–3
(D) 2 × 10–2

14. Deci molar solution of potassium ferricyanide K 3[Fe(CN)6] has osmotic pressure of 3.94 atm at 27°C.
Hence percent ionisation of K3[Fe(CN)6] is
(A) 10%
(B) 30%
(C) 40%
(D) 20%

15. Which one of the following aqueous solution will exhibit highest boiling point :-
(A) 0.019 M urea
(B) 0.02 M KNO3
(C) 0.02 M Na2SO4
(D) 0.019 M glucose

16. Select the incorrect option.

(A) For solution showing +ve deviation, there is minima in boiling point curve
(B) Boiling Point of aq. solution of 0.1 M, KCl is greater than that of 0.1 M glucose solution
(C) Osmotic pressure is a colligative property
(D) Colligative properties are defined for non-ideal solutions
17. In a solution, if three molecules of solute undergoes association as : 3A A3, then to evaluate degree

of association 'a' the formula will be :-

3(1 − i)
(A)  =
2
i −1
(B)  =
2
3(i − 1)
(C)  =
2
i −1
(D)  =
3

18. An aqueous solution contains 3% and 1.8% by wt. urea and glucose respectively. What is the freezing
point of solution ? (Kf = 1.86°C/m):-
(A) -1.172°C
(B) –2.27°C
(C) –1.5°C
(D) None of these

19. X3Y2 (i = 5) when reacted with A2B3 (i = 5) in aqueous solution given brown colour. These are separated
by a semipermeable membrane AB as shown. Due to osmosis there is :-

(A) Brown colour formation in side x

(B) Brown colour formation in side y
(C) Formation in both of sides x and y
(D) No brown colour formation
 Answer Key

Question 1 2 3 4 5 6 7 8 9 10
Answer A B A D A A A B C A
Question 11 12 13 14 15 16 17 18 19
Answer B A C D C D A A D