29-06-2025

1001CJA101001250005 JA

PART-1 : PHYSICS

SECTION-I (i)

1) If system is in equilibrium, find value of m (all string are ideal) (shown angle are in degree) :-

(A) 3.46 kg
(B) 2.46 kg
(C) 1.67 kg
(D) 3.67 kg

2) Vectors and are given as and vector . Find the time when is
perpendicular to .

(A) 4s
(B) 6s
(C) 2s
(D) 5s

3)

A particle is moving along x-axis, its “v2–t” graph is shown below. The acceleration at t = 1sec is :

(A) m/s2

(B)
m/s2
(C)
m/s2
(D) 2 m/s2

4) A block is placed on a rough plank moving with velocity and velocity of block relative to plank is

, find direction of kinetic friction force acting on the block.

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) A block P of mass 4 kg is placed on horizontal rough surface with coefficient of friction μ = 0.6,
and two blocks R and Q of masses 2 kg and 4 kg connected with the help of massless strings A and B
respectively passing over frictionless pulleys as shown, then (g = 10m/s2)

(A) acceleration of block P is zero.

(B) tension in string A is 20 N.
(C) tension in string B is 40 N.
(D) surface contact force on block P is N.

2) In the figure shown, the pulley and thread is ideal and m1 = 4kg, m2 = 1kg, g = 10m/s2 . Choose
the correct option(s) :-

(A) Tension in the thread connecting the blocks is 16 N

(B) Tension in the thread connecting the blocks is 30 N
2
(C) Acceleration of m1 is 6 m/s upwards
2
(D) Acceleration of m1 is 6 m/s downwards

3) Ship A is located 4 km north and 3 km east of ship B. Ship A has a velocity of 20 kmh–1 towards
the south and ship B is moving at 40 kmh–1 in a direction 37° north of east. X and Y-axes are along
east and north directions, respectively. Then which of the options is/are correct?

(A) Velocity of A relative to B is

Position of A relative to B as a function of time is given by
(B)

Velocity of A relative to B is
(C)

(D) Position of A relative to B as a function of time is given by

4) In a situation, a board is moving with a velocity v with respect to earth, while a man A and man B
are running with a velocity 2v with respect to earth and both men are running from the opposite
ends of the board at the same time, as shown. Length of the board is L. If they meet after time T,

then :-

(A) Value of T is L/4 v

(B) Value of T is L/2 v
(C) Displacement of man B with respect to board in time T is 3L/4
(D) Displacement of man A with respect to board in time T is L/4

SECTION-II
1) If system is in equilibrium then find ratio of m1 and m2.

2) The masses of 10 kg and 20 kg respectively are connected by a massless spring as shown in

figure. A force of 200 N acts on the 20 kg mass. At the instant shown, the 10 kg mass has
acceleration 10 m/sec2 then calculate the acceleration of 20 kg mass in m/s2 :

3) A trolley is being pulled up an smooth incline plane by a man sitting on (as shown in figure). He
applies a force of 250 N. If the combined mass of the man and trolley is 200 kg, the acceleration of

the trolley (in m/s2) will be [sin15° = 0.25, g = 10 ms–2]

4) and are two forces of equal magnitude acting at a point O at such an angle that their
resultant has a magnitude equal to that of . If the magnitude of is doubled, then find the angle

(in degree) between the new resultant and . If your answer is N find the value of .

5) Two particles A and B are projected simultaneously from points P and Q respectively as shown in
figure. Particle A was projected vertically while particle B was projected horizontally. If horizontal
and vertical component of PQ are 27 m and 45 m respectively then find the minimum value of VB in

m/s for which a collision is possible between A and B.

6) A particle travelling along a straight line with constant acceleration is observed to travel
consecutive distances of 100 m in times of 30 s and 60 s respectively. The initial velocity (in m/s) of
the particle is :

7) If the velocity of a particle is and its acceleration is and angle between

them is . The value of n is :-

8) A particle is projected up on incline at t = 0 with speed 14 m/s as shown in the figure. At the same
moment a box starts sliding down, the box has 2 small hole at height of 2m on opposite walls. The
particle enters from 1st window and leaves through the other. The width of the box (in m) is. (Assume

friction to be absent everywhere.)

PART-2 : CHEMISTRY

SECTION-I (i)

1) Find the value of double bond equivalent for given compounds

(A) 10
(B) 11
(C) 12
(D) 13

2) Examine the following structures :–

(P) (Q)
Which of the following statement is correct :-

(A) P is tertiary alcohol while Q is tertiary amine

(B) P is primary alcohol while Q is primary amine
(C) P is tertiary alcohol while Q is primary amine
(D) P is primary alcohol while Q is tertiary amine

3) Elements A and B form two compounds B2A3 and B2A. 0.05 mole of B2A3 weighs 9.0 gm and 0.10
mole of B2A weighs 10 gm. Atomic weight of A and B are-

(A) 20 and 30
(B) 30 and 40
(C) 40 and 30
(D) 30 and 20

4) Which of the following is an amphoteric oxide ?

(A) SO3
(B) CaO
(C) Al2O3
(D) Cl2O7

SECTION-I (ii)

1) Which of the following molecules are nonpolar?

(A) PCl5
(B) BF3
(C) SnCl2
(D) CS2

2) In which of the following chemical species hydrogen bonding takes places -

(A) Na2HPO3(s)
(B) K2HPO4(s)
(C) KHCO3(s)
(D) NaHCO3(s)

3) Select the correct statement(s) for one mole of (NH4)3PO4.

(A) Ratio of number of oxygen atoms to number of hydrogen atoms is 1 : 3

(B) Ratio of number of cations to number of anions is 3 : 1
(C) Ratio of number of gm-atoms of nitrogen to gm atoms of oxygen is 3 : 2
(D) Total number of atoms is 20.

4) Which of the following is/are correctly matched :

(A)
→ Isopentane

(B)
→ Isooctane

(C)
→ Neopentane

(D)
→ Tertiary butyl alcohol

SECTION-II

1) Among the following, find out total number of planar species.

SF4, CℓF3, , , SCl2, PCl5, , BrF5

2)

Number of specie(s) from the following which shows hydrogen bonding

H2S, HF, H2O2 , , HNO3, H3BO3, NaHCO3,

3) The oxidation number of sulphur in the sulphur molecule (S8) :-

4) Borax is Na2[B4O5(OH)4].xH2O
Basicity of pyrophosphorus acid is y,

then the value of is :

5) From 0.2 kg of calcium atom, 1.2 × 1024 atoms are removed then find the number of g-atoms of
calcium left ?
[Take : NA = 6 × 1023, Ca = 40]

6) An element has atomic mass 31. Mass of 2.24 litres at 1 atm, 273°C of vapours of element is 6.2
gm. Atomicity of element is

7) How many from the following is/are homocyclic hydrocarbon :

(1) (2) (3) (4) (5)

(6) (7) (8) (9)

8) In the reaction, 4A + 2B + 3C → A4B2C3, what will be the number of moles of product formed,
starting from 1 mole of A, 0.6 mole of B and 0.72 mole of C?

PART-3 : MATHEMATICS

SECTION-I (i)

1) is equal to

(A) 1
(B) 0
(C) –1

(D)
2) If x2 + 2ax + 10 – 3a > 0 for all x ∈ , then
(where a ∈ )

(A) –5 < a < 2

(B) a < –5
(C) a > 5
(D) 2 < a < 5

3) Sum of first 10 terms of the series S = 6 + 16 + 32 + 54 + ... is equal to :

(A) 1200
(B) 1230
(C) 1130
(D) None of these

4) Each set Xr contains 5 elements and each set Yr contains 2 elements and . If
each element of S belong to exactly 10 of the Xr's and to exactly 4 of the Yr's, then n is (where n ∈ )

(A) 10
(B) 20
(C) 100
(D) 50

SECTION-I (ii)

1) Select the correct option(s) from the following :

(A)
If , then the value of is 4.
(B) log2(1 + tan1°) + log2(1 + tan44°) = 1

(C)
If = 1/2 and = 1/3 , then =

(D)
cos0° + cos + =1

2) If x, y, z are positive and distinct real number such that x + y + z = a (where a > 0, a ∈ ) then :

(A)

(B)

(C)
(D)

3) The value of r for which the equation |x – 1| + |x – 3| = r has more than one solution can be

(A) r = 2

(B)

(C) r = 2025

(D)

4) Let a = sin 10°, b = sin 50°, c = sin 70° then

(A)

(B)

(C)

(D)

SECTION-II

1) Let x, y > 0. If x3y2 = 215, then the least value of 3x + 2y is

2) If , where π < x < , then 80(tan2x – cosx) is equal to :

3) If the sum of series is equal to 5, then d is

equal to :

4) The value of is equal to -

5) The sum of all values of x satisfying the equation is

6) Let a1, a2, ... an, be real numbers such that

then find the value of
(where n ∈ )

7) If the roots of the equation x3 – 21x2 + 102x – 28 = 0 are in A.P. with common difference 'd' then

is

8) If the number of integral value(s) of 'a' is 'λ', so that the graph of y = 16x2 + 8(a + 5)x – 7a – 5 is

always above the x-axis, then is equal to

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A D B B

SECTION-I (ii)

Q. 5 6 7 8
A. A,B,C,D A,D A,B A,C,D

SECTION-II

Q. 9 10 11 12 13 14 15 16
A. 15.00 5.00 1.25 6.00 9.00 3.88 to 3.89 2.00 20.20 to 20.23

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. C C C C

SECTION-I (ii)

Q. 21 22 23 24
A. A,B,D B,C,D A,B A,B,C,D

SECTION-II

Q. 25 26 27 28 29 30 31 32
A. 4.00 6.00 0.00 2.50 3.00 4.00 4.00 0.24

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 33 34 35 36
A. A A B B

SECTION-I (ii)

Q. 37 38 39 40
A. A,B,C,D B,D A,C,D A,B,C
 SECTION-II

Q. 41 42 43 44 45 46 47 48
A. 40.00 109.00 0.10 -4.00 3.00 10.10 0.45 2.40
 SOLUTIONS

PART-1 : PHYSICS

1) ... (i)
Also T = mg ... (ii)
from (i) & (ii)

2) If two vectors are perpendicular then

50 – 10t = 0
t = 5sec

3)

From the given graph

v2 = 2t

va = 1

v at t = 1 sec is

m/sec2

4)

friction will act opposite to the relative velocity.

5)
f = 20N (< 24N)
So block will not move

Contact force
6)
FT = 3g
FT = 30 N
F = ma
30 = 5a
a = 6 m/s2

40 – T = 4 × 6
T = 16 N

7)
VA = 20(– )
VB = 40 cos 37 + 40 sin 37

= 40 × + 40 ×
= 32 + 24

= –20 – ( )
= –32 – 44 k/h
At time = 0
=( )
at time t

= (3 – 32t) + (4 – 44t)

8)

At the plane VAB = 4V

9)

10)
FS = ma
FS = 10 × 10
FS = 100

200 – 100 = 20a

a=

11)
T = 250 N
750 – 200g sin 15° = 200 a
 12)
2θ + 2α = 180°
∴ θ + α = 90°

13) Writing position of A and B at time t.

For A, x = 0; y = VA t – gt2

For B : x = 27 –VB t; y = 45 – gt2

For collision both particle must be at a same place in air

Now, yQ > 0 ⇒ 45 – 5t2 > 0 ⇒ t < 3 sec. ⇒

14)

100 = S = u(30) + (a)(30)2 ...(1)

200 = u(90) + (a)(90)2 ...(2)

15)

16)

PART-2 : CHEMISTRY

17)

– Ph gr → 4
 ring → 5
–C≡N →2
– COOH → 1
__________________
Total DEB = 12

18) Tertiary alcohol is when –OH group is directly connected to a 3° c–atom while tertiary
amine is, when nitrogen is directly connected with 3–carbon atoms.

19) Mass of 0.05 Moles of B2A3 = 9 g

Mass of 1 mole of B2A3 = = 180 g

Mass of 0.10 moles of B2A = 10 g

Mass of 1 mole of B2A = = 100 g

2B + 3A = 180 g ....(i)
2B + A = 100 g ....(ii)
____________________
A = 40 g
B = 30 g

20) Al2O3 amphoteric

CaO Basic
SO3, Cl2O7 acidic

21) SnCl2 is Polar (Bent shape)

22) (A)Na2HPO3(s) (B) K2HPO4(s)

(C) KHCO3(s) (D) NaHCO3(s)

Hydrogen bond is formed when hydrogen is covalently bonded to more EN atom like F, O, N.

In (A) OPTION ‘H’ is covalently bonded to phosphorous so hydrogen bond is not formed.

23)

3NH4+ cations and 1 PO43– anion in one molecule.

Total number of atoms in 1 mole (NH4)3PO4 = 20 NA.

24)

Based on theory

25)

CℓF3, , SCl2 , are planar.

26)

HF, H2O2, HNO3, H3BO3, ( ----H – F) shows hydrogen

bonding.
So total 6 species shows H bonding.

In H2S and no hydrogen attached with (F,N,O) so no hydrogen bonding.

27)

S8 Ox. No. → 0

28)

x=8
z=2

29)
 Initial moles of Ca =

Removed moles of Ca =
Remaining moles of Ca = 5 – 2 = 3.

30) Let the element Xn

where n → atomicity
PV = nRT (n → no. of moles)

1 × 2.24 =
⇒n=4

31) Homocyclic hydrocarbon are

1, 3, 7, 8

32) 4A + 2B + 3C —→ A4B2C3
1 mole 0.6 mole 0.72 mole
In the above reaction, reactant 'C' will be the limiting reactant and it will decide yield product.
∵ from 3 moles of C; 1 mole product is formed

∴ from 0.72 moles of C =

= 0.24 moles of product

PART-3 : MATHEMATICS

33)

34)
x2 + 2ax + 10 –3a > 0
D>0
⇒ b2 – 4ac < 0
⇒ 4a2 – 4(10 – 3a) < 0
⇒ a2 + 3a – 10 < 0
⇒ (a + 5) (a – 2) < 0
⇒ a ∈ (–5, 2)

35) Tn = 3n2 + n + 2
Sn = n3 + 2n2 + 3n

36)

The correct is (B)

Since, , we get n(S) = 100

But each element of S belong to exactly 10 of the Xr' is

So, are the number of distinct elements in S.

Also each element of S belong to exactly 4 of the Yr' and each Yr contain 2 elements. If S has n
number of Yr in it. Then

which gives n = 20

37)

(A)

⇒ (3sinx – sin3x) cos3x + (3cosx + cos3x) sin3x =

⇒ 3[sinx cos 3x + cosx sin3x] =

⇒ sin 4x =
⇒8 sin4x = 4

(C) cosα + cosβ =

…(i)

sinα + sinβ =

…(ii)
Dividing Eq. (ii) by Eq.(i). we get

(D) cos0° + cos +

= + +

= + +
=1+0+0+0=1

38) A.M. > H.M.

A.M. > G.M.

39) Graph → for more than solution

40) abc = sin10° . sin50° . sin70°

= sin10° . sin(60° – 10°) . sin(60° + 10°)

41) Using AM ≥ GM

(3x + 2y)min = 40

42) ,π<x<

tanx = cosx =
80(tan2x – cosx)

= 45 + 64 = 109
43)

50d = 5

44) R = log2 sin + log2 sin + log2

sin + log2 sin – log25

R = log2 – log25

= log2 – log25

= log2 – log25

= log2 {(1 – cos 72°) (1 – cos144°)} – log25

= log2 {(1 – sin18°) (1 + cos 36°)} – log25

= log2 – log25

= log2 – log25

= log2 – log25 = log2 – log25

= log25 – log216 – log25 = – 4

45)

3x – 5 = 9 + (x – 2) –
2x = 12 –
x=
x–6=–
x2 + 36 – 12x = 9(x – 2)
x2 – 21x + 54 = 0
sum = 3

46)

a1 = 1, a2 = 2, ... an = n

47) Let roots are a – d, a, a + d with common diff. = d

⇒ a + d + a + a – d = 21 ⇒ a = 7
also a(a2 – d2) = 28
⇒ 49 – d2 = 4 ⇒ d2 = 45

48) ƒ(x) = 16x2 + 8(a + 5)x – (7a + 5) > 0

for ∀ x ∈ R
∴ D < 0 ⇒ D = 64{(a + 5)2 + 7a + 5} < 0
⇒ (a2 + 17a + 30) < 0
⇒ (a + 15)(a + 2) < 0

⇒ a ∈ (–15, –2)