10-08-2025

1001CJA101002250007 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A point P moves in counter clockwise direction on a circular path as shown in the figure. The
movement of 'P' is such that it sweeps out a length s = 5t + 5, where s is in meters and t is in

seconds. The radius of the path is 20 m. The acceleration of 'P' when seconds is nearly :

(A) 2 m/s2
(B) 1.5 m/s2
(C) 1.25 m/s2
(D) 3 m/s2

2) A spring of spring constant 5 × 103 N/m is stretched initially by 10 cm from the unstretched
position. Then the work required to stretch it further by another 10cm is-

(A) 12.50 N-m

(B) 18.75 N-m
(C) 75.00 N-m
(D) 62.5 N-m

3) A small body of mass m is allowed to slide on an inclined frictionless track from rest position as
shown in the figure.
Find the minimum height h, so that body may successfully complete the loop of radius ‘r’.

(A)
(B)

(C)

(D)

4) In the figure shown, the system is released from rest. Find the velocity of block A when block B

has fallen a distance 'ℓ'. Assume all pulleys to be massless and frictionless.

(A)

(B)
(C)
(D) None of these

SECTION-I (ii)

1) Symbolic objects constructed out of sticks of equal length and mass. The location of the centre of
mass is described using the coordinate system depicted in the sample.

(A) The centre of mass is at x > 0 and y = 0 for symbol (P)

(B) The centre of mass is at x = 0 and y > 0 for symbol (R, T)
(C) The center of mass is at x > 0 and y > 0 for symbol (Q, S)
(D) The centre of mass is at x = 0 and y = 0 for symbol (T)
2) A bead slides on a fixed frictionless wire bent into a horizontal semicircle of radius R0 as shown in
figure. In addition to any normal forces exerted by the wire, the bead is subjected to an external
force that points directly away from origin and depends on distance r from the origin according to

the formula :-

(A) Given force is a central force.

(B) Given force is a conservative force.

(C)
Work done by external force as bead leaves the track (starting from origin) is

(D)
Speed of bead as it leaves the wire is

3) An arrangement of the masses and pulleys is shown in the figure. Strings connecting masses A
and B with pulleys are horizontal and all pulleys and strings are light. Friction coefficient between
the surface and the block B is 0.2 and between blocks A and B is 0.7. The system is released from

rest. (use g = 10 m/s2)

The magnitude of acceleration of the system is 2 m/s2 and there is no slipping between block A
(A)
and block B.
(B) The magnitude of friction force between block A and block B is 42 N.
(C) Acceleration of block C is 1 m/s2 downwards.
(D) Tension in the string connecting block B and block D is 12 N.

SECTION-II (i)

Common Content for Question No. 1 to 2

A particle is moving on given curve path. At certain instant its velocity and acceleration shown in

figure.
1) Rate of change of speed (in m/s2) of particle at P is :-

2) Radius of curvature (in m) at point P is :-

Common Content for Question No. 3 to 4

During a cycle race, two persons happen to cross a point x simultaneously with speeds 16 m/sec and
12 m/sec respectively. In order to win the race they increase their speeds at the rate 1 m/s2 and 2
m/s2 respectively. Unfortunately both reach the final point y at the same instant of time.

3)

The time t (in sec) required to cover the distance xy is:

4)

Find the distance xy (in m).

SECTION-II (ii)

1) A man can reach directly across a stream of width 20 m in 4 minutes when there is no current and
in 5 minutes when there is a current. Find the velocity of the current in m/min.

2) A particle A is thrown with initial velocity 5 m/s along a frictionless inclined plane of inclination β.
Another particle B is thrown from the same point with initial velocity 10 m/s at an angle α with the
horizontal at the same moment when A is thrown. Both the particle meet again on the inclined plane.

The value of is

3) In the given figure both the blocks are in equilibrium. The acceleration of block 10 kg just after
cut the string is (in m/s2) (Assume both spring identical and massless. String is also massless)
4) A bob is attached to a string of length ℓ = . The string is held horizontal and the bob is
released from this position. At the time when the centripetal acceleration becomes equal in
magnitude to the tangential acceleration, find the speed (in m/s) of the bob. (g = 10 m/s2)

5) A student wants to determine the coefficients of static friction and kinetic friction between a box
and a plank. He places the box on the plank and gradually raises the plank. When the angle of
inclination with the horizontal reaches 30°, the block starts to slip and slides 4.0 m down the plank

in 4.0 s. If is given by , then find the value of β. (µs & µk are coefficient of static friction &
kinetic friction)

6) Potential energy for a conservative force is given as U = x2 –4x + 20. Find the equilibrium position
x of the particles.

PART-2 : CHEMISTRY

SECTION-I (i)

1)

How many functional groups are present in following compound :

(A) 5
(B) 4
(C) 6
(D) 3

2) The compound that cannot act both as oxidising and reducing agent is :

(A) H2O2
(B) H2SO3
(C) HNO2
(D) H3PO4

3) Which of the following chemical species does not exist :

(A) POF3
(B) XeF5¯
(C) HFO4
(D) NOF3

4) The pair in which both species have same hybridisation and same molecular shape both :

(A) CH4 , H2O

(B) PCl5 , SF4
(C) XeF4 , ICl2¯
+
(D) PCl4 , SiF4

SECTION-I (ii)

1) (I) (II) (III)

Select the correct statement about, I, II & III compounds.

(A) I is having four 2° & four 3° carbons

(B) II is having three 1°, six 2°, three 3° & two 4° carbons
(C) III is having three 1°, three 2° & three 3° carbons
(D) All are homocyclic compounds

2) Which of the following reaction is/are disproportionation reaction(s) :

(A) H2O2 → H2O + O2

–
(B) P4 → H2PO2 + PH3
(C) KClO3 → KCl + O2
– –
(D) I2 → I + IO3
3) The correct statement(s) is/are :

(A) NH3 has lesser dipole moment than that of NF3

(B) The pair of & is not isostructural.
(C) The shape of XeF4 is tetrahedral.
(D) PF5 contains five bond pairs and zero lone pair of electrons on phosphorus

SECTION-II (i)

Common Content for Question No. 1 to 2

Two solutions are shown in the following figure

Container (I) contains 50 ml 40% w/v NaOH

and container (II) contains 50 ml 2M NaOH solution.
Answer the following

1) If final solution have density 1.2 g/ml, then the molality of final solution is:

2) If solution of these containers are mixed together, then the molarity of final solution is

Common Content for Question No. 3 to 4

Hybridisation is the mixing of atomic orbital of comparable energy and the number of hybrid orbitals
formed is equal to the number of pure atomic orbitals mixed up.
From the following given species
, SO3 , XeO2F2 , , , ,
If
x = number of species having atleast one pπ-dπ bond
y = number of species in which atleast one d-orbital is used by central atom in hybridisation
z = number of species having tetrahedral shape

3) Find the value of .

4) Find the value of .

SECTION-II (ii)
1) Number of compounds with 3º amines in the following :

(a) (b) (c) (d)

(e) (f) (g) (h)

2)

Degree of unsaturation of following compound is :

3) 4.6 gm of an organic compound on complete combustion gives only two gases CO2 and H2O having
weight 8.8 gm & 5.4 gm. What will be the sum of number of atoms in its empirical formula.

4) n-factor of acid in given reaction will be :

H3PO4 + NaOH → Na2HPO4 + H2O

5) Consider the following species

NO3– , BF4– , PCl3 , NH3 , CO2 , SF4, NH4+, SF6, IF7
(i) Number of species in which lonepair is present on central atom = P
(ii) Number of hyper valent species = Q
(iii) Number of species in which coordinate bond is present = R

Find the value of .

6) If the average oxidation number of sulphur atom in Na2S4O6 is x, and the average oxidation
number of sulphur atom in H2S2O5 is y. Then value of x × y is :

PART-3 : MATHEMATICS

SECTION-I (i)

1) If the equation x2 – 4x sinθ + tanθ = 0 ; has repeated roots then sum of possible
values of 'θ' is
(A)

(B)

(C)

(D)

2) Possible solution of equation is

(A)

(B)

(C)

(D)

3) Let a1, a2, a3, ... be an arithmetic progression with a1 = 7 and common difference 8. Let T1, T2, T3 ...

be such that T1 = 3 and Tn + 1 – Tn = an for n ≥ 1 then is

(A) 15
(B) 16.50
(C) 17.05
(D) 15.04

4) Minimum value of y = is

(A) 5.50
(B) 4.50
(C) 8.50
(D) 9.50

SECTION-I (ii)

1) If α and β are the roots of the equation x2 – 6x – 4 = 0, then value of expression

is a :-

(A) real number

(B) composite number
(C) prime number
(D) rational number

2) Let x1 & x2 satisfies the equation x2 + 6 = x1+log 5 (x1 > x2) then which of the following is/are true :-
x

2 2
(A) x1 + x2 = 13
(B) 2x1 + 3x2 = 12
(C) x1 & x2 are relatively prime
(D) x1 & x2 are both rational number

3) If (x, y ∈ R+) then

(A) x + y = 17
(B) x + y = 16
(C) x – y = 1
(D) x – y = –1

SECTION-II (i)

Common Content for Question No. 1 to 2

A = log10(16)4 + log10(25)8
B = Total number of ordered pairs of (x,y)
If xy – y – 2x = 3 where x,y ∈ I
C = Total number of subsets of A × B
If n(A) = 2 and n(B) = 3

D = Minimum value of for a ∈ R

1) Value of A + B + C + 2D is

2) If value of ABCD is equal to 2k, then value of k is

Common Content for Question No. 3 to 4

Let ƒ(x) = sinx + 2cos2x and g(x) = 4sin2x + tan2x + cot2x + cosec2x (wherever defined) then answer
the following

3) Difference between greatest and least value of ƒ(x) is

4) Number of solutions of g(x) = 6 in [0, 2π] is

SECTION-II (ii)

1) The number of integral values of m for which exactly one root of the equation x2 + mx + (m2 +
6m) = 0 lies in (–2, 0), is -
2)

The least value of ‘n’ such that where is

3) If then total number of integral solutions is :-

4) Let a, b and c be the length of sides of a triangle ABC such that . If r and R
are the radius of incircle and radius of circumcircle of the triangle ABC, respectively, then the value

of is equal to

5) Let S = [0, 2π]. If the number of elements in the set A = {θ ∈ S : sin8θ = 1 + cos10θ} is N then 5N
is

6) The value of is equal to , then value of A is

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. C C B A

SECTION-I (ii)

Q. 5 6 7
A. A,D A,B,C A,D

SECTION-II (i)

Q. 8 9 10 11
A. 8.66 5.00 8.00 160.00

SECTION-II (ii)

Q. 12 13 14 15 16 17
A. 3 3 5 4 9 2

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. C D C D

SECTION-I (ii)

Q. 22 23 24
A. A,B,C,D A,B,D B,D

SECTION-II (i)

Q. 25 26 27 28
A. 6.25 6.00 0.50 0.25

SECTION-II (ii)

Q. 29 30 31 32 33 34
A. 3 9 9 2 2 10

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. C C D A

SECTION-I (ii)

Q. 39 40 41
A. A,B,D A,B,C,D A,C

SECTION-II (i)

Q. 42 43 44 45
A. 100.00 15.00 3.12 to 3.13 4.00

SECTION-II (ii)

Q. 46 47 48 49 50 51
A. 4 5 7 5 10 16
 SOLUTIONS

PART-1 : PHYSICS

1)

s = 5t + 5

= Speed (v) = 5 m/s

at = 0 m/s2

Thus
= 1.25 m/s2

2)

Concept apply work energy theorem.

3)

At b, mg =

By energy conservation , mg (h - 2r) =

h = 5r/2

4)

From constraint we know vB = 2vA

If B moves downward A moves upward also if B moves ℓ than A moves ℓ/2.
From WET for both blocks

5)

Use formula,
6) is a central force, because direction of force is always away from the fix

point origin & work done by this force is zero in any close loop force is
conservative

Work done by the force on bead

7) Friction force between A and B is f1 = 42 N

Friction force between B and surface is
f2 = 18N
Taking A and B as a system

A of whole system For block B : 42 > 10 +

18 + 8
Available force is less than required force so it will not slide with respect to A
So acceleration of the system = 2 m/s2
For block D : T – mg = ma
T = mg + ma = 12 N

8) rate of charge of speed = a1

a1 = 10 cos 30º =

9)

10)
11)
= 128 + 32 = 160 m

12)

13)
uBcos(α + β) = uA

cos(α + β) =

α+β=

14)
kx = 150

just after cut the string

 2kx
150 - 100 = 10a

15)
v2 = 2gℓ cos θ
at = g sin θ = 2g cos θ
tan θ = 2

= 4 m/sec

16)

µs g cos θ = g sin θ ... (i)

anet = (g sin θ – µk g cos θ) ... (ii)

... (iii)
Solve (i), (ii) & (iii)

17)

U = x2 – 4x + 20

⇒ x = 2m

PART-2 : CHEMISTRY
18)

19) (i) H2O2 act as oxidising agent as well as reducing agent depending on condition.
(ii) H2SO3 act as oxidising agent as well as reducing agent depending on condition.
(iii) HNO2 act as oxidising agent as well as reducing agent depending on condition.
(iv) H3PO4 can not act both as oxidising and reducing agent.
H3PO4 can act as only oxidising agent.

20)

The correct answer is option (C) : HFO4 does not have vacant orbital.

21) PCl4⊕ → sp3 hybridisation , tetrahedral shape

SiF4 → sp3 hybridisation , tetrahedral shape

22)
23) In option-A : Oxygen atom oxidised as well as reduced.
In option-B : Phosphorus atom oxidised as well as reduced.
In option-D : Iodine atom oxidised as well as reduced.
​

24)

25)

= 6.25 m

26)

(I)
V1 = 50 ml
(II) M2 = 2M, V2 = 50 ml

27) x = 4
[SO3 , XeO2F2 , , ]
y=2
[ , XeO2F2]

28) x = 4
 [SO3 , XeO2F2 , , ]
y=2
[ , XeO2F2]
z=2
[ , ]

29)

The correct answer is (3)

30)

Degree of unsaturation
= No. of π Bonds + No. of Rings
=5+4=9

31) Mass of C =

Mass of H =
∴ Mass of O = 1.6
∴ Empirical formula = C2H6O.

32) As 2H+ ions are replaced by base hence n-factor is 2.

33)

The correct answer is 2

34)

Average O.N. of 'S' in Na2 S4O6 = X = 2.5

Average O.N. of 'S' in H2S2O5 = Y = 4

PART-3 : MATHEMATICS

35) D = 0
16sin2θ – 4tanθ = 0

⇒ 16sin2θ =
4sinθ.cosθ = 1

sin2θ =

36) cosx =

37) a1 = 7, d = 8
Tn+1 – Tn = an ∀ n ≥ 1
Sn = T1 + T2 + T3 + ... + Tn–1 + Tn
Sn = T1 + T2 + T3 + ... + Tn–1 + Tn
on subtraction
Tn = T1 + a1 + a2 + ... + an–1
Tn = 3 + (n – 1)(4n – 1)
Tn = 4n2 – 5n + 4

T20 = 1504

38) Put sin2x = cosec2x = I

39) ...(1) ...(2)

adding (1) and (2)
α17 + β17 – 4(α15 + β15) = 6(α16 + β16)
(α8 + β8)2 – 217 = α16 + β16 + 2(αβ)8 – 217 = α16 + β16

40) x2 + 6 = x.5 x2 – 5x + 6 = 0
x = 2 and x = 3
(a)
(b)

41) log2(log2(log3x)) = 0 and log2(log3(log2y)) = 0 x = 9, y = 8

42)
A = 16
xy – y = 2x + 3

x = 2, y = 7
x = 6, y = 3
x = 0, y = –3
x = – 4, y = 1 Total 4 sol. (B = 4)
n(A × B) = 2 × 3 = 6
number of subsets of A × B = 26 = 64
C = 64

(D = 8)

43)

A = 16
xy – y = 2x + 3

x = 2, y = 7
x = 6, y = 3
x = 0, y = –3
x = – 4, y = 1 Total 4 sol. (B = 4)
n(A × B) = 2 × 3 = 6
number of subsets of A × B = 26 = 64
C = 64

(D = 8)

44) ƒ(x) = –2sin2x + sinx + 2

Put ⇒

Put sinx = 1 ⇒

Put sinx = –1 ⇒

45) (4sin2x + cosec2x) + (tan2x + cot2x) = 6

(2sinx – cosecx)2 + 4 + tan2x + cot2x = 6

when

46) f(d) • f(e) < 0 (4 – 2m + m2 + 6m) (m2 + 6m) < 0

(m + 2)2 m(m + 6) < 0

Check : f(d) • f(e) = 0

(m + 2)2 (m2 + 6m) = 0

47)

(n – 2)x2 + 8x + n + 4 > 0 ∀ x ∈ R
⇒ 64 – 4(n – 2) (n + 4) < 0 ⇒ 16 – (n2 + 2n – 8) < 0
⇒ n2 + 2n – 24 > 0
⇒ (n + 6) (n – 4) > 0 ⇒ n > 4 as n ∈ N ⇒ n > 5.

48) |x – 1| + 2 ≤ 5
⇒ |x – 1| ≤ 3
⇒ –3 ≤ x – 1 ≤ 3
⇒ –2 ≤ x ≤ 4
∴ Integral value of x = –2, –1, 0, 1, 2, 3, 4

49) Let
∴ a + b = 7λ, b + c = 8λ, a + c = 9λ
⇒ a + b + c = 12
⇒ a = 4λ, b = 3λ, c = 5λ
Clearly, c2 = a2 + b2

∴ ∠C = 90° ⇒
Using Δ = rs,

50) Only & is possible

51) Expand about 1st row