d
»
>
»
>
»
»
»
»
>
>
»
»
»
»
»
»
»
»
»
>
»
>
>»
>
>
»
’
»
d
@
4-
Swi. Edel 24
eX by reson Sourngls
e |
: aes) apse WP
= he mR chy!
“FB v3 sodium, aly
CAMO-BROI0 | _ ee
X
Baemenyoe Aes on st wil
react 2-bano-
NAS is cenbificd a& bret oe
Aa Oe/alvtnal thechon'sen on NAS
in Ans xo baseh on
Ake Chowes guen ia He
Claws . @&
hu D |
RK Ssh, ~~ sah,
& : fy
Tho reactor inlernedcl
15 firmed 10 NAS.
pe) VVVvVvevvVvETVZZIZZITTVTTTTSTSSTSTVVVVVIIseE
© 2. There ene Wo bento rigs 10 he
Lenaodhoapice quien: 19 doloymine- wah
3 th podbetls) ‘pat bly
L most ActvATED fing
ce
Rng A Ine two sabadhenks @ Cr oP Co
G2 AMINO Op Auno =
C1: C=N is he c=Nn
or =o. (Bon Me eG => Deporwirme)
Ring, B Ihc Wo subshtumls @ 07 ond Co
Cy CN is hle CaN (Op 2 4040
of 670 (Op = 07.6)
Cor C1 Ope +023
Rag A is Make Ac Are gy ex myst UM
on fg A- ( elite F 4 0) VVUUVUUVUTVTTTIVISVITITIVTTTVTTVTVVTTTeTET
Be
@
"2. (ctl)
Ci pee vn 40 tho
posted, 1. Ce tnd Cv
Chiorvvahion caus om C4 ord Ce Cokes
Qs Use pacts. (4 ¢ tm) | )
Qh ning A, the ached Bravo 3 ar @
@ 3 E awe
x) 2 ty Wo Heme Anne
Beveee Ob,
eo must be
Bav2ne sire
S. o Kelle 90 EG o-
eo ae we bh
a leaving,
7‘
a ¥ehnO on™ We
o «(Ley ark a”
ch VVUVVUUVVVVVVVVVUVTTTTTTVTVVFITFTVITISwW
3. (cat'd)
ZL
a eel ee ere
4
| 0,40
sol) cha nik) Caer BO
ery “ae ee
i fe WO
Looe
fxn oCVG of
@ Nat RG; a
OO \ tde-dieke
ccs) chlor. Nam,
Soe 7
= MCs \
Da = ja
Mey (< 1
. CHLOE
n-EMYL anitne
Le
Zl fue wt (So
°
wih, vuwvevvVvVV VV EVV V VV T VT VT TTT TTT Te
@
«3. Contd)
gc Ee Kelle NO Rl
§. (cont'd)
> oot
IL
, =
»
NO;
> a
> =
! oa tee leet
» \ Z2xy' 3 ZS @
T
; Oz NOW
: OmetO-71 No Sus
1 @ more stAoE
' “TES careocanans
: SHOWN Ww Re Eveeay
pitckan
,
, “a.
fe
ae
i Je 7
‘ ce
® i 2 nS
co aa ce
® Cpr 0-27 i
RO CARBocATIONS.
Mi
ChE STABIE ston nS RS ENeecy
PiIBatam ® (cont'd) i
ae bogs .
cho
cet | ee
1
Zz!
“h
—
a
cH, Ler et
Thee. two corhecectins
we SAME
Ony oe corboarticn in
Roo Alenay Tac eam
“Voes Nor March Rel 6
Daten Ged
1 Ae
z OO Hao"
Ineo] ID)
NOT AL
inf comm, gH £
Pa
~~~ eee eV rer FF 89STIIGIIIGGGG6
@
©} » §Coonbd)
ar . BH
Ly
.
Bie
@ \
, OS
(ae a
OY .Q
‘on Ou
EWAN TOMS
501 5S
RAcemic
@
wwvwewervsTsvesssTTTTTTSCOTCTSSFECCED gq (contd)
Tw
DY) *
PL
yg, cutee
[: uf °
Not oS i i
CHIRAL
°
: weno Ope -0.27
i ACETYL Op Fto.8 LCV EewTETTT TTT TO TTTTTTSTVSTTesese
Hom
@
* \.Coprt'd)
MOET S ring 15 most reactte in GAS
ose On He SUN of Op voltcs
gee Og Sy ee We
Tre +o.23
qin< "0 26
T= to.23
@ 1 canto °
@" COA, cheds CAMS
1 Gra or PRRA
fe ©
ot.
1
-
aT “2 27
|_ Oro, bas |
St
( ZN
: cho
© ~~ +++ eee ewes
a
e
18. BASE cataLyoen Hypesryss oF
Bewome eer 1S “SLonet! when!
BDG OW “THE Betas Rng
Puente
aleohel
@
=slons hydelysis
sees hydvoles)
oo ay FQ) Hypaelys5
cerbonjic Od
© ian “2° Alesha
2 ALCO, ---+-++ +e eee ewww
“I$
12 contd) Be ALcoHoL
Xe.
ERG Hypeoryas
Vhydiahi s| eee acid
= Be proto.
Wah KtlaOy atl amne soups (eed) ta
Tt WH ad Ob group 4 TE Once
ft NO 6 - COR Goa > ge te GHG
whch stable He tctrahedral momediole
to Re base -cachalyz hydolys ord T ae
Nowe of THe ores
ABs
Nop >
entalyst
“The compeund ray “The codalyet pomoles
hen Undergo an gererchicn of the
TEwTRamalecomand corko aka at Ca
Fredel-Cradts Puno, B reacts with
veachon He corocabon at
@ : Cu Csub-@ Co is
a © ye derestur ~ rewst
alle es react O- since Cann? |
W Sreacht @ of p- |
De 4 { rene”
= 1 | A ess bod 1s erie laetw4 0, od |
so | Cu, geructhg 0 br trembered rm
Ve
@ Nox tBu! comocechen
lohe elechoprile
@ 1
“OL © Ci
dvecte 40 Ca ond
Co
* Oct, @Cz
dweets 40 Cs ond
Cs
“thio Cris
sae 0s LEK @
ce and +Bu @
Ca 1 Smee @ Vea
@Cs
Ro MONO ALEYLATIO
PRomers Foam
Each of dese wera
ailkyleted Geeclueks
Conhives 46 veoct
w/b. corbscachien
|
| '
,
,
’
,
,
’
,
'
@
@
: 7
1i(owd) © ye coms,
@ at Po ig
b 4
. i] — > ae
cee a
BN et
- CH @Ci des to t= |
ty od Ge e— 7
Oct, @ C2 directs te FROM, @, two
Cs Dianeycates
\roduds Som
4Py deck 4o Cy (mr cues @ CA * Ce
ond Co ane ow OU,
pup &Bu ‘ved
to These poschons)
on
& SP cor
id
— aul
CG pees
cu, @ C ditals to Ce Fron © oy 4
OM, @ C2 ad ABy duecet DiAieyareD Predver™
to Cs = Rods @ Ce Forts
par ® © on
% H nucleophile,
. oe ae fon es
18. cl awe] fean C\ lava,
< grove, Tesubhag ia
ZN INVERSiN of
\ CONFIGURAM od
get a ct
°° “S CIS hs
: aS pro
ch \o the only product
Formed
C15- 2-pregyl cyclo-
@ — kexanol
IF. Congak acl of a seceuaey Arcotlor,
He product atler the anygen of the
OH accepts pect
WoL,
a.
‘Arcot,
Ww
10H
OH ae @on,
Ga Comseaare ACID
g
A ov
@ y ct
ce oe hve
> NO Als av
> +
> ce
ae
Noy,
oS
> Rey
» ae ae <
ré@ 28 te ae re
» ! oy? \
»
»
»
»
»
; 4 oe
» Nhe yi
»
>
’
>
» @
’
’