1. The number of radial nodes in 4s C.

Magnetic quantum
and 3p orbitals are respectively number
A. 2,0 D. Azimuthal quantum
B. 3,1 number
C. 2,2 6. Match the following
D. 3,2
2. The radius of the second bohr
orbit for hydrogen atom is
(Plank’s constant (h) = 6.6262 ×
10-34 Js; mass of electron =
9.1091 × 10–31 kg ; charge of
electron (e) = 1.60210 × 10-19 C ;
permitivity of vacuum (ε0) =
8.854185 × 10-12 kg-1 m-3 A2)
A. 1.65 Å
B. 4.76 Å A. A-q; b-p; c-s; d-r
C. 0.529 Å B. A-p ; b-q ; c -s ; d – r
D. 2.12 Å C. A-r ; b – s ; c-p ; d – q
3. Assertion (A) : It is impossible to D. A – q ; b – r , c- s ; d-p
determine the exact position and
exact momentum of an electron
simultaneously . 7. Atomic number and mass
Reason (R) : The path of an number of an element M are 25
electron in an atom is clearly defined. and 52 respectively. The number
A. Both A and R are true and of electrons, protons and
R is the correct neutrons in M2+ ion are
explanation of A. respectively
B. Both A and R are true and A. 25, 25 and 27
R is not the correct B. 25, 27 and 25
explanation of A. C. 27, 25 and 27
C. A is true and R is false. D. 23, 25 and 27
D. Both A and R are false. 8. Assertion (A) : All isotopes of a
4. Which of the following transition given element show the same
will emit maximum energy in type of chemical behaviour .
hydrogen atom Reason (R) : The chemical
A. 4f –> 2s properties of an atom are controlled by
B. 4d –> 2p the number of electrons in the
C. 4p –> 2s atom.
D. All have same energy A. Both A and R are true
5. Two electrons occupying the and R is the correct
same orbital are distinguished explanation of A.
by B. Both A and R are true
A. Spin quantum number but R is not the correct
B. Principal quantum explanation of A.
number C. A is true but R is false.
D. Both A and R are
false.
9. Which of the following statement A. 2p3
is not correct about the B. 2d5
characteristics of cathode rays? C. 4s1
A. They start from the D. 5f6
cathode and move 14. Which of the following orbital is
towards the anode. with the four lobes present on the
B. They travel in straight axis
line in the absence of A. dz2
an external electrical or B. dxy
magnetic field. C. dyz
C. Characteristics of D. dx2-y2
cathode rays do not 15. Statement I : According to Bohr's
depend upon the model of an atom, qualitatively
material of electrodes the magnitude of velocity of
in cathode ray tube. electron increases with decrease
D. Characteristics of in positive charges on the
cathode rays depend nucleus as there is no strong hold
upon the nature of gas on the electron by the nucleus.
present in the cathode Statement II : According to Bohr's
ray tube. model of an atom, qualitatively
10. A transition element X has a the magnitude of velocity of
configuration (Ar)3d4 in its +3 electron increases with decrease
oxidation state. It’s atomic in principal quantum number.
number is A. Both statements I and
A. 22 II are true
B. 19 B. Both statements I and
C. 25 II are false
D. 26 C. Statement I is false and
11. The radius of hydrogen atom in statement II is true
the ground state is 0.53. The D. Statement I is true and
radius of Li2+ ion (atomic number statement II is false
= 3) in a similar state is 16. Match the following
A. 0.53 Column I Colum
B. 1.06 n II
C. 0.59 a. En p. 1/2
D. 0.265 -y

12. Number of spectral lines in ∝

Balmer series when ab electron rn
return from 7th orbit to 1st orbit of b. Ln q. -2
hydrogen atom are ∝
A. 5 nx
B. 6 c. En r. -3
C. 21 /V
D. 15 n
13. Which of the following electronic d. Tn s. 1
configuration is not possible. ∝
 Zt B. Both A and R are true but
/n R is not the correct
m explanation of A.
Where En= total energy; ln= C. A is true but R is false.
angular momentum; Kn= kinetic D. Both A and R are false.
energy; Vn= potential energy; Tn= 21. Statement I: The energy of 2s orbital
time period; rn= radius of nth orbit. is less than the energy of 2p orbital for
A. a-s; b-s; c-p; d-q,r hydrogen atom.
B. a-q; b-p; c-r; d-s Statement II: Smaller the size of
C. a-q,r; b-p; c-s; d-s orbit lower is the energy of the orbit.
D. a-p; b-r; c-q; d-s A. Both statements I and II
17. Maximum number of electrons in a are true
subshell of the atom is determined by B. Both statements I and II
the following are false
A. 2l+1 C. Statement I is false and
B. 4l-2 statement II is true
C. 4l +8 D. Statement I is true and
D. 4l +2 statement II is false
18. Which of the following electronic in a 22. Which of the following subshell can
transition hydrogen atom will require the accommodate as many as 10 electrons
largest amount of energy? A. 2d
A. n = 1 to n = 2 B. 3d
B. n = 2 to n = 3 C. 3dxy
C. n = 1 to n = ∞ D. 3dz2
D. n = 3 to n = 5 23. Match the following
19. Calculate the energy in joule
corresponding to light of wavelength 45
nm : (Planck’s constant h = 6.63 × 10-34
Js; speed of light c = 3×108 ms-1)
A. 6.67 × 1015
B. 6.67 × 1011
C. 4.42 × 10-15
D. 4.42 × 10-18
20. Assertion (A) : When an iron rod is
heated in a furnace, the radiation
emitted goes from a lower frequency to
a higher frequency as the temperature A. a-r,s; b-p,s; c-q,r; d-p,q
increases. B. a-p,q; b-r,s; c-p,r; d-q,s
Reason (R) : The energy of a quantum C. a-p,r; b-q,r; c-p,s; d-p,r
of radiation is proportional to its D. a-q,p; b-r,p; c-r,s; d-p,s
frequency. 24. According to Bohr’s theory angular
A. Both A and R are true and momentum of an electron in 6th orbit is
R is the correct A. 2.5 h/π
explanation of A. B. 6 h/π
C. 3 h/π
D. 2.5h/2π
25. The frequency of a wave is 6 × 1015 29. Assertion (A): Black body is an ideal
s-1 . Its wave number would be body that emits and absorbs radiations
A. 105 cm-1 of all frequencies.
B. 2 × 107 m-1 Reason (R): The frequency of
C. 2 × 107 cm-1 radiation emitted by a body goes from a
D. 2 × 105 cm-1 lower frequency to higher frequency with
26. How many 3d electrons can have an increase in temperature.
spin quantum number -1/2? A. Both A and R are true and R is the
A. 5 correct explanation of A.
B. 7 B. Both A and R are true but R is not
C. 8 the explanation of A.
D. 10 C. A is true and R is false.
27. Which of the following is not among D. Both A and R are false.
shortcomings of Bohr’s model 30. The energy of second Bohr orbit of
A. Bohr theory could not the hydrogen atom is -328 kJ mol-1 ;
account for the fine lines in hence the energy of fourth Bohr orbit
the atomic spectrum would be
B. Bohr theory was unable to A. -41 kJ mol-1
account for the splitting of B. -1312 kJ mol-1
the spectral lines in the C. -164 kJ mol-1
presence of magnetic D. -82 kJ mol-1
field 31. The orientation of an atomic orbital
C. Bohr theory failed for He is governed by
atom A. Azimuthal quantum number
D. It did not give information B. Spin quantum number
about energy level C. Magnetic quantum number
28. Statement I: According to Bohr's D. Principal quantum number
model of an atom, qualitatively the 32. Which of the following conclusions
magnitude of velocity of electron could not be derived from Rutherford’s
increases with decrease in positive alpha particle scattering experiment.
charges on the nucleus as there is no A. Most of the space in the atom is
strong hold on the electron by the empty
nucleus. B. The radius of the atom is about 10-
Statement II: According to Bohr's model 10 m while that of nucleus is 10-15
of an atom, qualitatively the magnitude m
of velocity of electron increases with C. Electrons move in a circular path of
decrease in principal quantum number. fixed energy called orbits
A. Both Statement I and Statement II D. Electrons and the nucleus are held
are false together by electrostatic forces of
B. Both Statement I and Statement II attraction
are true 33. Number of angular nodes for 4d
C. Statement I is false but Statement II orbital is
is true A. 4
D. Statement I is true but Statement II B. 3
is false C. 2
D. 1
34. If the Thompson model of the atom C. They have same number of
was correct, then the result of neutrons but different number of
Rutherford's gold foil experiment would electrons
have been : D. Sum of the number of protons and
A. All of the -particles pass through neutrons is same but the number
the gold foil without decrease in of protons is different
speed. 38. Which of the following is responsible
B. -Particles are deflected over a to rule out the existence of definite paths
wide range of angles. or trajectories of electrons?
C. All -particles get bounced back by A. Pauli’s exclusion principle
1800 B. Heisenberg’s uncertainty principle
D. -Particles pass through the gold C. Hund’s rule of maximum
foil deflected by small angles and multiplicity
with reduced speed D. Aufbau principle
35. Match the following 39. The pair of ions having same
electronic configuration is
A. Cr3+ , Fe 3+
B. Fe3+, Mn2+
C. Fe3+, Co3-
D. Sc3+, Cr3+
40. If travelling at same speeds , which
of the following matter waves have the
shortest wavelength
A. Electron
B. Alpha particle (He2+)
C. Neutron
A. (a-r) ; (b-s) ; (c-p) ; (d-q) D. Proton
B. (a-s); (b-p); (c-r); (d-q) 41. In a hydrogen atom , if the energy
C. (a-p); (b-q); (c-s); (d-t) of electron in the ground state is -x eV ;
D. (a-q); (b-t); (c-s); (d-p) then that in the 2nd excited state of He+
is
36. Which of the following statements A. -x eV
about the election is incorrect. B. -4/9x eV
A. It is a negatively charged particle C. +2x eV
B. The mass of electron is equal to D. -9/4x eV
the mass of neutron 42. The de Broglie wavelength of a
C. It is a basic constituent of all particle with mass 1g and velocity 100
atoms m/s is
D. It is a constituent of cathode rays A. 6.63 × 10-35 m
37. Two atoms are said to be isobars if: B. 6.63 × 10-34 m
A. They have same atomic number C. 6.63 × 10-33 m
but different mass number D. 6.63 × 10-36 m
B. They have same number of 43. The uncertainty in momentum of an
electrons but different number of electron is 1×10-5 kg-m/s . The
neutrons uncertainty in its position will be
(h=6.62×10-34 kg-m2/s)
 A. 5.27 × 10-30 m 49. If the energy difference between the
B. 1.05 × 10-26 m ground state and excited state of an
C. 1.05 × 10-28 m atom is 4.4 × 10-19 J. The wavelength of
D. 5.25 × 10-28 m photon required to produce this
44. Match the following transition is
Column I A. 4.5 × 10-7 m
Column II ( frequency)
a. X-rays i. 10-10 Hz B. 4.5 × 10-7 nm
10

b. UV ii. 1010 Hz C. 4.5 × 10-7 um

c. Long radio iii. 1016 Hz D. 4.5 × 10-7 cm
waves 50. The probability density plots of 1s
d. Microwave iv. 18
10 Hz and 2s orbitals are given below

45. Assertion (A) : The number of

electrons ejected from a metal surface
depend upon the frequency of light.
Reason (R) : There is a time lag
between the striking of light beam and The density of dots in a region
the ejection of electrons from the metal represents the probability density of
surface. finding electrons in the region.
A. Both A and R are true and R is the On the basis of above diagram which of
correct explanation of A. the following statements is incorrect?
B. Both A and R are true but R is not A. 1s and 2s orbitals are spherical
the correct explanation of A. in shape.
C. A is true but R is false. B. The probability of finding the
D. Both A and R are false. electron is maximum near the
46. For single-electron species the nucleus
correct order of energy of given orbitals C. The probability of finding the
is electron at a given distance is
A. 5p>5s>4f>4d equal in all directions.
B. 3s=3p=3d>2s=2p>1s D. The probability density of
C. 3d>3p>3s=2p>2s>1s electrons for 2s orbital
D. 3d>3p>3s>2p>2s>1s decreases uniformly as
distance from the nucleus
47. Isoelectronic species are increases.
A. CO, CN-, NO+, C22-
B. CO-, CN, NO, C22-
C. CO+, CN+, NO-, C2
D. D)CO, CN, NO, C2

48. The energies of orbitals in a multi

electron system depends on
A. n only
B. n + l both
C. l only
D. m only