Chemistry Class X Reference Study Material
Uploaded by
Debkanta ChakrabortyChemistry Class X Reference Study Material
Uploaded by
Debkanta ChakrabortyCHEMISTRY
REFERENCE STUDY MATERIAL
for
CLASS – X
CHAPTER WISE CONCEPTS, FORMULAS AND
QUESTIONS INLCUDING HOTS QUESTIONS
Prepared by
M. S. KUMARSWAMY, TGT(MATHS)
M. Sc. Gold Medallist (Elect.), B. Ed.
Kendriya Vidyalaya gachibowli
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - A -
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - B -
DEDICATED
TO
MY FATHER
LATE SHRI. M. S. MALLAYYA
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - C -
CHAPTER – 1
CHEMICAL REACTIONS AND EQUATIONS
CHEMICAL REACTIONS
Any change can be classified as physical change and chemical change. Physical changes
can be easily reversed but, it is not easy to reverse a chemical change.
In chemical changes, new substances are formed and it is difficult to regenerate the original
substances. Chemical changes are more permanent than physical changes. Chemical reaction
involves chemical changes.
Chemical reactions are the processes in which new substances with new properties are formed.
During a chemical reaction, atoms of one element do not change into those of another element.
Only a rearrangement of atoms takes place in a chemical reaction.
Magnesium ribbon burns with a dazzling white flame and changes into a white powder. This powder is
magnesium oxide. It is formed due to the reaction between magnesium and oxygen present in the air.
Magnesium Oxygen Magnesium Oxide
Heat (White powder)
(As ribbon) (From air)
The burning of magnesium in air to form magnesium oxide is an example of chemical reaction.
REACTANTS AND PRODUCTS
The substances which take part in a chemical reaction are called reactants.
The new substances produced as a result of chemical reaction are called products.
In the above chemical reaction, there are two reactants : Magnesium and Oxygen but only one
product : Magnesium oxide.
CHARACTERISTICS OF CHEMICAL REACTIONS
In a chemical reaction, reactants are transformed into products.
The important characteristics of chemical reaction are:
Evolution of a gas
Formation of a precipitate
Change in colour
Change in temperature and
Change in state.
Any one of these characteristics can tell us whether a chemical reaction has taken place or not.
CHEMICAL EQUATIONS
The method of representing a chemical reaction with the help of symbols and formulas of the
substances involved in it is known as chemical equation.
A word-equation shows change of reactants to products through an arrow placed
between them. The reactants are written on the left-hand side (LHS) with a plus sign (+)
between them. Similarly, products are written on the right-hand side (RHS) with a plus
sign (+) between them. The arrowhead points towards the products, and shows the
direction of the reaction.
Example: A + B → C + D
In this equation, A and B are called reactants and C and D are called the products.
Arrow shows the direction of chemical reaction. Condition, if any, is written generally
above the arrow.
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 1 -
When hydrogen reacts with oxygen, it gives water. This reaction can be represented
by following chemical equation:
Hydrogen + Oxygen ⇨ Water
H2+O2 →H2O
In first equation words are used and in second symbols of substances are used to write the
chemical equation. For convenience, symbol of substance is used to represent chemical
equations. Chemical Equation is a way to represent the chemical reaction in concise and
informative way.
Chemical equation can be divided into two types – Balanced Chemical Equation and
Unbalanced Chemical Equation.
Balanced Chemical Equation: A balanced chemical equation has number of atoms of each
element equal on both sides.
Example: Zn + H2SO4 → ZnSO4 + H2
In this equation, numbers of zinc, hydrogen and sulphate are equal on both sides, so it is a
balanced chemical equation.
Unbalanced Chemical Equation: If the number of atoms of each element in reactants is not
equal to the number of atoms of each element present in product, then the chemical equation is
called unbalanced chemical equation.
Example: Fe + H2O → Fe3O4 + H2
In this example number atoms of elements are not equal on two sides of the reaction. For
example, on the left hand side only one iron atom is present, while three iron atoms are present
on the right hand side. Therefore, it is an unbalanced chemical equation.
BALANCING A CHEMICAL EQUATION:
To balance the given or any chemical equation, follow these steps:
Fe + H2O → Fe3O4 + H2
Write the number of atoms of elements present in reactants and in products in a table; as shown
here.
Name of atom No. of atoms in reactant No. of atoms in product
Iron 1 3
Hydrogen 2 2
Oxygen 1 4
Balance the atom which is the maximum in number; on either side of chemical equation.
In this equation, the number of oxygen atom is the maximum on the RHS.
To balance the oxygen one needs to multiply the oxygen on the LHS by 4; so that the number
of oxygen atoms becomes equal on both sides.
Fe + 4 x H2O → Fe3O4 + H2
Now, the number of hydrogen atoms becomes 8 on the LHS; which is more than that on the
RHS. To balance it, one needs to multiply the hydrogen on the RHS by 4.
Fe + 4 x H2O → Fe3O4 + 4 x H2
After that number of oxygen and hydrogen atoms becomes equal on both sides. The number of
iron is one on the LHS, while it is three on the RHS. To balance it, multiply the iron on the
LHS by 3.
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 2 -
3 x Fe + 4 x H2O → Fe3O4 + 4 x H2
Now the number of atoms of each element becomes equal on both sides. Thus, this equation
becomes a balanced equation.
Name of atom No. of atoms in reactant No. of atoms in product
Iron 3 3
Hydrogen 8 8
Oxygen 4 4
After balancing, the above equation can be written as follows.
3Fe + 4H2O → Fe3O4 + 4H2
Writing the symbols of Physical States of substances in Chemical equation:
By writing the physical states of substances a chemical equation becomes more
informative. Gaseous state is represented by symbol ‘g’
Liquid state is represented by symbol ‘l’
Solid state is written by symbol ‘s’
Aqueous solution is written by symbol ‘aq’
Writing the condition in which reaction takes place: The condition is generally written
above and/or below the arrow of a chemical equation.
Thus, by writing the symbols of physical state of substances and condition under
which reaction takes place, a chemical equation can be made more informative.
INTEXT QUESTIONS PAGE NO. 6
Q1: Why should a magnesium ribbon be cleaned before it is burnt in air?
Answer : Magnesium is an extremely reactive metal. When stored, it reacts with oxygen to
form a layer of magnesium oxide on its surface. This layer of magnesium oxide is quite stable
and prevents further reaction of magnesium with oxygen. The magnesium ribbon is cleaned by
sand paper for removing this layer so that the underlying metal can be exposed to air.
Question 2: Write the balanced equation for the following chemical reactions.
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ò䈐寽ó侊癗ô筦តõ Hydrogen +
Chlorine → Hydrogen chloride
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ò䈐寽ó侊癗ô筦តõ Barium chloride +
Aluminium sulphate → Barium sulphate + Aluminium chloride
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ò䈐寽ó侊癗ô筦តõ Sodium + Water →
Sodium hydroxide + Hydrogen
Answer :
Question 3: Write a balanced chemical equation with state symbols for the following
reactions.
Solutions of barium chloride and sodium sulphate in water react to give insoluble
barium sulphate and the solution of sodium chloride.
Sodium hydroxide solution (in water) reacts with hydrochloric acid solution (in
water) to produce sodium chloride solution and water.
Answer :
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 3 -
TYPES OF CHEMICAL REACTION
Chemical reactions can be classified in following types:
Combination Reaction
Decomposition Reaction
Displacement Reaction
Double Displacement Reaction
Oxidation and Reduction Reaction
COMBINATION REACTION
Reactions in which two or more reactants combine to form one product are called
COMBINATION REACTION.
A general combination reaction can be represented by the chemical equation given here.
Example: When magnesium is burnt in air (oxygen), magnesium oxide is formed. In
this reaction, magnesium is combined with oxygen.
Mg + O2 → 2MgO
Magnesium + Oxygen ⇨ Magnesium oxide
When carbon is burnt in oxygen (air), carbon dioxide is formed. In this reaction, carbon
is combined with oxygen.
C+O2 →CO2
Carbon + Oxygen ⇨ Carbon dioxide
When hydrogen reacts with chlorine, hydrogen chloride is formed.
H2 + Cl2 → 2HCl
Hydrogen + Chlorine ⇨ Hydrogen chloride
When calcium oxide reacts with water, calcium hydroxide is formed
CaO + H2O → Ca(OH)2
Calcium oxide + Water → Calcium hydroxide
When carbon monoxide reacts with oxygen, carbon dioxide is formed.
2CO + O2 → 2CO2
Carbon monoxide + Oxygen → Carbon dioxide
DECOMPOSITION REACTION
Reactions in which one compound decomposes in two or more compounds or element
are known as DECOMPOSITION REACTION. Decomposition reaction is just opposite
of combination reaction.
A general decomposition reaction can be represented as follows:
Example: When calcium carbonate is heated, it decomposes into calcium oxide and
carbon dioxide
CaCO3 → CaO + CO2
Calcium carbonate → Calcium oxide + Carbon dioxide
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 4 -
When ferric hydroxide is heated, it decomposes into ferric oxide and water
2Fe(OH)3 → Fe2O3 + 3H2O
Ferric hydroxide → Ferric oxide + Water
When lead nitrate is heated, it decomposes into lead oxide, nitrogen dioxide and oxygen.
2Pb(NO3)2 → 2PbO + 4NO2 + O2
Lead nitrate ⇨ Lead oxide + Nitrogen oxide + Oxygen
In above examples, compound is decomposed because of heating, so, these reactions are
called THERMAL DECOMPOSITION REACTION.
ELECTROLYTIC DECOMPOSITION
Reactions in which compounds decompose into simpler compounds because of passing
of electricity, are known as ELECTROLYTIC DECOMPOSITION. This is also known
as ELECTROLYSIS.
Example: When electricity is passed in water, it decomposes into hydrogen and oxygen.
2H2O → 2H2 + O2
PHOTOLYSIS OR PHOTO DECOMPOSITION REACTION
Reactions in which a compound decomposes because of sunlight are known as
PHOTOLYSIS or PHOTO DECOMPOSITION REACTION.
Example: When silver chloride is put in sunlight, it decomposes into silver metal and
chlorine gas.
2AgCl → 2Ag + Cl2
Similarly, when silver bromide is put under sunlight, it decomposes into silver metal
and bromine gas.
2AgBr → 2Ag + Br2
Photographic paper has coat of silver chloride, which turns into grey when exposed to sunlight.
It happens because silver chloride is colourless while silver is a grey metal.
INTEXT QUESTIONS PAGE NO. 10
Question 1: A solution of a substance ‘X’ is used for white washing.
Name the substance ‘X’ and write its formula.
Write the reaction of the substance ‘X’ named in (i) above with water.
Answer : (i) The substance ‘X’ is calcium oxide. Its chemical formula is CaO.
Calcium oxide reacts vigorously with water to form calcium hydroxide (slaked lime).
Question 2: Why is the amount of gas collected in one of the test tubes in Activity 1.7
double of the amount collected in the other? Name this gas.
Answer : Water (H2O) contains two parts hydrogen and one part oxygen. Therefore, the
amount of hydrogen and oxygen produced during electrolysis of water is in a 2:1 ratio.
During electrolysis, since hydrogen goes to one test tube and oxygen goes to another, the
amount of gas collected in one of the test tubes is double of the amount collected in the other.
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DISPLACEMENT REACTION
Reactions in which atoms or ions move from one compound to other to form new
compound are known as DISPLACEMENT REACTION. Displacement reaction is also
known as Substitution Reaction or Single displacement /Replacement Reaction.
A general displacement reaction can be represented using chemical equation as follows:
Displacement reaction takes place only when ‘A’ is more reactive than B. If ‘B’ is more reactive
than ‘A’, then ‘A’ will not displace ‘C’ from ‘BC’ and reaction will not be taken place. Example:
When zinc reacts with hydrochloric acid, it gives hydrogen gas and zinc chloride.
Zn + 2HCl → ZnCl2 + H2
When zinc reacts with copper sulphate, it forms zinc sulphate and copper metal.
Zn + CuSO4 → ZnSO4 + Cu
When silver metal is dipped in copper nitrate, no reaction takes place because silver metal
is less reactive than copper.
Ag + Cu(NO3 )2 → No reaction takes place
DOUBLE DISPLACEMENT REACTION
Reactions in which ions are exchanged between two reactants forming new compounds
are called double displacement reactions.
Example: When solution of barium chloride reacts with the solution of sodium sulphate,
white precipitate of barium sulphate is formed along with sodium chloride.
BaCl2 + Na2SO4 → BaSO4 + 2NaCl
When sodium hydroxide (a base) reacts with hydrochloric acid, sodium chloride and water
are formed.
NaOH + HCl → NaCl + H2O
Double displacement reaction, in which precipitate is formed, is also known as precipitation
reaction. Neutralisation reactions are also examples of double displacement reaction.
EXOTHERMIC AND ENDOTHERMIC REACTION
The chemical reactions which proceed with the evolution of heat energy are called exothermic
reactions.
N2 + 3H2 → 2NH3 + Heat
All combustion reactions are exothermic. Heat energy is liberated as the reaction proceeds.
The chemical reactions which proceed with the absorption of heat energy are called
endothermic reactions.
Most of the combination reactions are endothermic. Most of the decomposition reactions are
exothermic. Respiration is a decomposition reaction in which energy is released. When quick
lime (calcium carbonate) is added to water, it decomposes and releases energy. Cooking
involves chemical reactions which are endothermic as cooking is possible because of heating.
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OXIDATION AND REDUCTION REACTION:
Oxidation: Addition of oxygen or non-metallic element or removal of hydrogen or metallic
element from a compound is known as oxidation.
Elements or compounds in which oxygen or non-metallic element is added or hydrogen or
metallic element is removed are called to be oxidized.
Oxidizing agent: Compounds which can add oxygen or a non-metallic compound or remove
hydrogen or metallic element are known as oxidizing agents.
Reduction: Addition of hydrogen or metallic element or removal of oxygen or non-metallic
element from a compound is called reduction. The compound or element which goes under
reduction is called to be reduced.
Reducing agent: Compounds or elements which can cause reduction are called reducing
agents.
In a chemical reaction oxidation and reduction both take place simultaneously and such
reactions are also known as REDOX REACTIONS. In the word REDOX, ‘Red’ stands for
reduction and ‘Ox’ stands for oxidation.
Example: When iron reacts with air, it forms iron oxide (rust)
4Fe + 3O2 → 2Fe2O3
In this reaction, oxygen is added to iron, thus, iron is oxidized. Here oxygen is oxidizing agent.
When cupric oxide reacts with hydrogen, it gives copper and water.
CuO + H2 → Cu + H2O
In this reaction, oxygen is removed from copper and oxygen is added to hydrogen. So, cupric
oxide is reduced to copper and hydrogen is oxidized to water. Cupric oxide is oxidizing agent
and hydrogen is reducing agent.
When sodium hydroxide reacts with hydrochloric acid, it gives sodium chloride and water.
NaOH + HCl → NaCl + H2O
In this reaction, sodium hydroxide is reduced to sodium chloride since hydrogen is removed
from sodium hydroxide. Hydrochloric acid is oxidized to water, since oxygen is added to
hydrogen chloride and non-metallic element chloride is removed. Sodium hydroxide is
oxidising agent and hydrochloric acid is reducing agent.
In this reaction oxidation and reduction both takes place simultaneously, thus it is an example
of redox reaction.
SIGNIFICANCE OF OXIDATION REDUCTION IN EVERYDAY LIFE:
Respiration is oxidation reaction in which food is oxidized to produce energy.
Iron gets oxidized to form rust; which leads to corrosion of iron in the long run.
Most of the metals react with atmospheric oxygen and it leads to formation of a layer
on the metal article. The metal gets corroded in the long run.
Rusting of iron can be prevented by painting the iron article. This can also be prevented
by applying a layer of zinc over iron article. This process is known as galvanization.
Fried food gets oxidized when exposed to air. This spoils the taste of the food and the
food becomes unfit for consumption. The spoiling of fried food because of oxidation is
called rancidity. Fried food is often packed in airtight packets to prevent rancidity.
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We are able to utilize various types of fuel because of oxidation. Oxidation of fuel
helps in producing energy.
CORROSION
Corrosion is defined as the slow and steady destruction of a metal by the environment. It results
in the deterioration of the metal to form metal compounds by means of chemical reactions with
the environment.
Corrosion is a simple electro chemical reaction. When the surface of iron is in contact
with moisture and other gases in the atmosphere an electrochemical reaction occurs. In this,
impure iron surface acts as the cathode and pure iron acts as anode. H 2CO3 formed from
moisture and CO2 from air acts as electrolyte.
The electrochemical reactions are as follows:
2+ –
Fe → Fe + 2e
– –
O2 + 2H2O + 4e → 4OH
2+ 3+
The Fe ions are oxidised to Fe ions.
3+ –
The Fe ions combine with OH ions to form Fe(OH)3.This becomes rust (Fe2O3.xH2O)
which is hydrated ferric oxide.
METHODS OF PREVENTING CORROSION
Corrosion of metals is prevented by not allowing them to come in contact with
moisture,CO2 and O2.This is achieved by the following methods:
By coating with paints: Paint coated metal surfaces keep out air and moisture.
By coating with oil and grease: Application of oil and grease on the surface of iron tools
prevents them from moisture and air.
By alloying with other metals: Alloyed metal is more resistant to corrosion.
Example: stainless steel.
By the process of galvanization: This is a process of coating zinc on iron sheets by using
electric current. In this zinc forms a protective layer of zinc carbonate on the surface of
iron. This prevents corrosion.
Electroplating: It is a method of coating one metal with another by passing electric current.
Example: silver plating, nickel plating. This method not only lends protection but also
enhances the metallic appearance.
Sacrificial protection: Magnesium is more reactive than iron. When it is coated on the
articles made of steel it sacrifices itself to protect the steel.
RANCIDITY
When fats and oils are oxidised, they become rancid and their smell and taste change.
Rancidity is the chemical decomposition of fats, oils and other lipids.
There are three basic types of rancidity.
Hydrolytic rancidity occurs when water splits fatty acid chains away from the glycerol
backbone in glycerides.
Oxidative rancidity occurs when the double bonds of an unsaturated fatty acid react
chemically with oxygen.
Microbial rancidity refers to a process in which microorganisms such as bacteria use their
enzymes, including lipases, to break down chemical structures in the fat.
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In each case, these chemical reactions result in undesirable odors and flavors. it is a condition
produced by aerial oxidation of unsaturated fat present in foods and other products, marked by
unpleasant odour or flavour.
When a fatty substance is exposed to air, its unsaturated components are converted into
hydroperoxides, which break down into volatile aldehydes, esters, alcohols, ketones, and
hydrocarbons, some of which have disagreeable odours.
Butter becomes rancid by the foregoing process and by hydrolysis, which liberates volatile and
malodorous acids, particularly butyric acid. Saturated fats such as beef tallow are resistant to
oxidation and seldom become rancid at ordinary temperatures.
Usually substances which prevent oxidation (antioxidants) are added to foods containing fats
and oil. Keeping food in air tight containers helps to slow down oxidation.
Rancidity can be avoided by:
Storing food in air tight containers
Storing food in refrigerators
Adding antioxidants
Storing food in an environment of nitrogen
INTEXT QUESTIONS PAGE NO. 13
Question 1: Why does the colour of copper sulphate solution change when an iron nail is
dipped in it?
Answer : When an iron nail is placed in a copper sulphate solution, iron displaces copper
from copper sulphate solution forming iron sulphate, which is green in colour.
Therefore, the blue colour of copper sulphate solution fades and green colour appears.
Question 2: Give an example of a double displacement reaction other than the one given
in Activity 1.10.
Answer : Sodium carbonate reacts with calcium chloride to form calcium carbonate
and sodium chloride.
In this reaction, sodium carbonate and calcium chloride exchange ions to form two
new compounds. Hence, it is a double displacement reaction.
Question 3: Identify the substances that are oxidised and the substances that are reduced
in the following reactions.
Answer : (i) Sodium (Na) is oxidised as it gains oxygen and oxygen gets reduced.
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 9 -
Copper oxide (CuO) is reduced to copper (Cu) while hydrogen (H2) gets oxidised to water
(H2O).
EXERCISE QUESTIONS PAGE NO. 14, 15 and 16
Question 1: Which of the statements about the reaction below are incorrect?
Lead is getting reduced.
Carbon dioxide is getting oxidised.
Carbon is getting oxidised.
Lead oxide is getting reduced.
(a) and (b)
(a) and (c)
(a), (b) and (c)
all
Answer : (i)(a) and (b)
Question 2:
The above reaction is an example of a
combination reaction.
double displacement reaction.
decomposition reaction.
displacement reaction.
Answer : (d) The given reaction is an example of a displacement reaction.
Question 3: What happens when dilute hydrochloric acid is added to iron filings? Tick
the correct answer.
Hydrogen gas and iron chloride are produced.
Chlorine gas and iron hydroxide are produced.
No reaction takes place.
Iron salt and water are produced.
Answer : (a) Hydrogen gas and iron chloride are produced. The reaction is as follows:
Question 4: What is a balanced chemical equation? Why should chemical equations be
balanced?
Answer : A reaction which has an equal number of atoms of all the elements on both sides
of the chemical equation is called a balanced chemical equation.
The law of conservation of mass states that mass can neither be created nor destroyed. Hence,
in a chemical reaction, the total mass of reactants should be equal to the total mass of the
products. It means that the total number of atoms of each element should be equal on both sides
of a chemical equation. Hence, it is for this reason that chemical equations should be balanced.
Question 5: Translate the following statements into chemical equations and then balance
them.
Hydrogen gas combines with nitrogen to form ammonia.
Hydrogen sulphide gas burns in air to give water and sulphur dioxide.
Barium chloride reacts with aluminium sulphate to give aluminium chloride and a
precipitate of barium sulphate.
Potassium metal reacts with water to give potassium hydroxide and hydrogen gas.
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 10 -
Answer :
Question 6: Balance the following chemical equations.
Answer :
Question 7: Write the balanced chemical equations for the following reactions.
Calcium hydroxide + Carbon dioxide → Calcium carbonate + Water
Zinc + Silver nitrate → Zinc nitrate + Silver
Aluminium + Copper chloride → Aluminium chloride + Copper
Barium chloride + Potassium sulphate → Barium sulphate + Potassium chloride
Answer :
Question 8: Write the balanced chemical equation for the following and identify the type
of reaction in each case.
(a)Potassium bromide (aq) + Barium iodide (aq) → Potassium iodide (aq) + Barium
bromide(s)
Zinc carbonate (s) → Zinc oxide (s) + Carbon dioxide (g)
Hydrogen (g) + Chlorine (g) → Hydrogen chloride (g)
Magnesium (s) + Hydrochloric acid (aq) → Magnesium chloride (aq) + Hydrogen (g)
Answer :
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 11 -
Question 9: What does one mean by exothermic and endothermic reactions? Give
examples.
Answer : Chemical reactions that release energy in the form of heat, light, or sound are called
exothermic reactions.
Example: Mixture of sodium and chlorine to yield table salt
In other words, combination reactions are exothermic.
Reactions that absorb energy or require energy in order to proceed are called endothermic
reactions.
For example: In the process of photosynthesis, plants use the energy from the sun to convert
carbon dioxide and water to glucose and oxygen.
Question 10: Why is respiration considered an exothermic reaction? Explain.
Answer : Energy is required to support life. Energy in our body is obtained from the food we
eat. During digestion, large molecules of food are broken down into simpler substances such as
glucose. Glucose combines with oxygen in the cells and provides energy. The special name of
this combustion reaction is respiration. Since energy is released in the whole process, it is an
exothermic process.
Question 11: Why are decomposition reactions called the opposite of combination
reactions? Write equations for these reactions.
Answer : Decomposition reactions are those in which a compound breaks down to form two or
more substances. These reactions require a source of energy to proceed. Thus, they are the
exact opposite of combination reactions in which two or more substances combine to give a
new substance with the release of energy.
Question 12: Write one equation each for decomposition reactions where energy is
supplied in the form of heat, light or electricity. Answer : (a) Thermal decomposition:
(b) Decomposition by light:
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(c) Decomposition by electricity:
Question 13: What is the difference between displacement and double displacement
reactions? Write equations for these reactions.
Answer : In a displacement reaction, a more reactive element replaces a less reactive element
from a compound.
where A is more reactive than B
In a double displacement reaction, two atoms or a group of atoms switch places to form new
compounds.
For example:
Displacement reaction:
Double displacement reaction:
Question 14: In the refining of silver, the recovery of silver from silver nitrate solution
involved displacement by copper metal. Write down the reaction involved. Answer :
Question 15: What do you mean by a precipitation reaction? Explain by giving examples.
Answer : A reaction in which an insoluble solid (called precipitate) is formed is called a
precipitation reaction.
For example:
In this reaction, calcium carbonate is obtained as a precipitate. Hence, it is a precipitation
reaction.
Another example of precipitation reaction is:
In this reaction, barium sulphate is obtained as a precipitate.
Question 16: Explain the following in terms of gain or loss of oxygen with two examples
each. (a) Oxidation (b) Reduction
Answer : (a) Oxidation is the gain of oxygen.
For example:
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In equation (i), H2 is oxidized to H2O and in equation (ii), Cu is oxidised to CuO.
Reduction is the loss of oxygen.
For example:
In equation (i), CO2 is reduced to CO and in equation (ii), CuO is reduced to Cu.
Question 17: A shiny brown-coloured element ‘X’ on heating in air becomes black in
colour. Name the element ‘X’ and the black coloured compound formed.
Answer : ‘X’ is copper (Cu) and the black-coloured compound formed is copper oxide (CuO).
The equation of the reaction involved on heating copper is given below.
Question 18: Why do we apply paint on iron articles?
Answer : Iron articles are painted because it prevents them from rusting. When painted, the
contact of iron articles from moisture and air is cut off. Hence, rusting is prevented. So
presence of air and moisture is essential for rusting to take place.
Question 19: Oil and fat containing food items are flushed with nitrogen. Why?
Answer : Nitrogen is an inert gas and does not easily react with these substances. On the other
hand, oxygen reacts with food substances and makes them rancid. Thus, bags used in packing
food items are flushed with nitrogen gas to remove oxygen inside the pack. When oxygen is not
present inside the pack, rancidity of oil and fat containing food items is avoided.
Question 20: Explain the following terms with one example each.
Corrosion (b) Rancidity
Answer :
Corrosion:
Corrosion is defined as a process where materials, usually metals, deteriorate as a result of a
chemical reaction with air, moisture, chemicals, etc.
For example, iron, in the presence of moisture, reacts with oxygen to form hydrated iron oxide.
This hydrated iron oxide is rust.
(b) Rancidity:
The process of oxidation of fats and oils that can be easily noticed by the change in taste and
smell is known as rancidity.
For example, the taste and smell of butter changes when kept for long.
Rancidity can be avoided by:
Storing food in air tight containers
Storing food in refrigerators
Adding antioxidants
Storing food in an environment of nitrogen
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ASSIGNMENT QUESTIONS SET – 1
CHAPTER – 1
CHEMICAL REACTIONS AND EQUATIONS
VERY SHORT ANSWER TYPE QUESTIONS
How are chemical reactions expressed in the shortest way?
What is the type of reaction in which the reactant gives simpler products?
What is the type of reaction in which two or more reactants combine to a give a single product?
In which type of reaction does an exchange of partners take place?
Why are chemical equations balanced?
What symbol is used to indicate a solution made in water?
What type of reaction does occur during the digestion of food inside our body?
What type of reaction is represented by the following equation?
CaCO3 → CaO + CO2
What type of reaction does occur when silver bromide is exposed to sunlight?
A solution of a substance is used for white-washing. Name the substance with its formula.
Name the type of reaction which is represented by the following equations:
Fe2O3 + 2Al → Al2O3 + 2Fe
Balance the following equation using state symbols: Fe + HCl → FeCl2 + H2.
Express the following statement in the form of a balanced chemical equation: “Sodium reacts
with water to form sodium hydroxide and hydrogen”.
Write the balanced chemical equation for the reaction that occurs between aluminium
hydroxide and sulphuric acid forming aluminium sulphate and water.
What type of reaction does occur when ammonia is allowed to react with hydrogen chloride?
Name the type of reaction involved when a zinc plate is dipped in a solution of copper
sulphate?
In the reaction, CuO(s) + H2(g) → Cu(s) + H2O(l). Pick out the following:
the substance which is oxidised
the substance which is reduced
the oxidizing agent
the reducing agent
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What chemical reaction is involved in the corrosion of iron?
Aluminum metal when burnt in air forms aluminium oxide. Write the balanced chemical
equation for the reaction.
Is the reaction represented by the following reaction a displacement reaction?
2KI + Cl2 → 2KCl + I2
Express the following reaction in the form of a balanced chemical equation: “When a strip of
copper is dipped in a solution of silver nitrate, silver metal is precipitated and a solution
of copper nitrate is produced.”
Write the following equation in a balanced form?
NH3 + O2 → N2 + 2H2O
What is the process called in which a substance is converted into a new substance?
Name the gas evolved when a magnesium ribbon is dropped into dilute sulphuric acid?
Give an example of a double displacement reaction.
Is copper more reactive than iron? Give the equation of the reaction in support of your answer?
Can a combustion reaction be a redox reaction?
Can a double displacement reaction be a redox reaction?
State one characteristics of the chemical reaction when lemon juice is added gradually to
potassium permanganate solution?
Which gas does evolve when dilute HCl is added to sodium carbonate?
Why is photochemical reaction considered an endothermic reaction?
Which term is applied for the process in which unpleasant smell and taste develop in foods
containing fats and oils?
What are the substances called which are added to foods containing fats and oils to protect
them from becoming rancid?
Why are potato chips packaged in nitrogen?
In the refining of silver, silver is obtained from silver nitrate by using copper metal. Write
down the reaction involved?
A shiny brown coloured element when heated in air becomes black. Name the element and the
black coloured substance so formed.
Name the substance which is oxidised in the following reaction:
Ȁ⸀ऀ ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀȀȀȀ̀⠀⤀ Ā ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Why are all
decomposition reactions endothermic?
Ȁ⸀ऀ ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀȀȀȀ̀⠀⤀ Ā ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Is the decomposition
of vegetable matter into compost an exothermic reaction?
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Why is photosynthesis an endothermic reaction?
Balance the following equation:
MNO2 + HCl → MNCl2 + Cl2 + H2O
Na + O2 → Na2O
H2O2 → H2O + O2
Mg(OH)2 + HCl → MgCl2 + H2O
Fe + O2 → Fe2O3
Al(OH)3 → Al2O3 + H2O
NH3 + CuO → Cu + N2 + H2O
Al2(SO4)3 + NaOH → Al(OH)3 + Na2SO4
HNO3 + Ca(OH)2 → Ca(NO3)2 + H2O
NaOH + H2SO4 → Na2SO4 + H2O
BaCl2 + H2SO4 → BaSO4 + HCl
Calcium hydroxide + Carbon dioxide → Calcium carbonate + Water
Aluminium + Copper chloride → Aluminium chloride + Copper
Calcium + Water → Calcium hydroxide + Hydrogen
Sulphur dioxide + Oxygen → Sulphur trioxide
MnO2 + HCl → MnCl2 + Cl2 + H2O
Zn + HCl → ZnCl2
SHORT ANSWER TYPE QUESTIONS
What do you mean by a Chemical reaction? Give an example of a chemical reaction.
What do you mean by a combination reaction? Give an example.
What do you mean by a displacement reaction? Give an example.
What do you mean by a decomposition reaction? Give an example.
What do you mean by a double displacement reaction? Give an example.
Explain the term “Electrolytic decomposition”, giving a suitable example.
Mention any two uses of decomposition reaction.
Give an example of a reaction in which a less reactive non-metal is displaced by a more
reactive non-metal.
Why does the blue colour of copper sulphate change when a piece of iron is dropped into it?
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In the reactions given below, identify the substances that act as oxidizing and reducing agents:
4Na (s) + O2 (g) → 2Na2O (s)
ZnO (s) + C(s) → Zn(s) + CO (g)
Write the balanced chemical equation for the following reactions and identify the type of
reaction in each case:
Potassium chloride (aq) + Barium iodide (aq) → Potassium iodide (aq) + barium chloride
(s)
Zinc carbonate (s) → Zinc oxide (s) + Carbon dioxide (g)
Hydrogen (g) + Chlorine (g) → Hydrogen chloride (g)
(iv) Magnesium (s) + Hydrochloride acid (aq) → Magnesium chloride (aq) +
Hydrogen(g)
Name the type of reaction involved in the reactions represented by the following equations:
CaO + H2O → Ca(OH)2
Zn + CuSO4 → ZnSO4 + Cu
Al2(SO4)3 + 6NH4OH → 2Al(OH)3 + 3(NH4)2SO4
CaCO3 → CaO + CO2
H2 + Cl2 → 2HCl
Why is magnesium ribbon cleaned before burning it in air?
State the characteristics of a chemical reaction.
What is a chemical equation?
Write the balanced chemical equations for the following chemical reactions:
Hydrogen + Chlorine → Hydrogen Chloride
Barium Chloride + Aluminium sulphate → Barium sulphate + Aluminium chloride
Sodium + water → Sodium Chloride + hydrogen
Write a balanced chemical equation with state symbols for the following reactions:
Solutions of barium chloride and sodium sulphate in water react to give a precipitate of
barium sulphate and the solution of sodium chloride.
Sodium hydroxide solution (in water) reacts with hydrochloride acid solution (in water)
to produce sodium chloride solution and water.
How can you explain that respiration is an exothermic reaction?
What do you mean by a precipitation reaction? Explain by giving example.
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What are anti-oxidants? Name two substances which are usually used as anti-oxidants.
State any two ways to prevent the rancidity of food containing oils and fats.
What observations do you expect to get when granulated zinc taken in a test tube is treated
with dilute sulphuric acid?
Give an example of a chemical reaction which take place with fall in temperature.
State on characteristic of chemical reaction taking place when
dilute sulphuric acid is made to react with marble chips.
lemon juice is added to a solution of potassium permanganate.
dilute hydrochloride acid is added to a solution of lead nitrate in the cold.
water is added to quick lime.
Which of the following reactions are exothermic and which are endothermic?
Burning of natural gas
Photosynthesis
Electrolysis of water
Respiration
What would you observe when lead nitrate is heated in a test tube?
Why is respiration considered an exothermic reaction?
Give an example of a decomposition reaction. Describe an activity to illustrate such a reaction
by heating.
When hydrogen is passed over copper oxide, copper and steam are formed. Write a balanced
equation for this reaction and state which of the chemicals are (i) elements (ii)compounds
(iii) reactants (iv) products (v) metals (vi) non-metals
(a) What is a balanced chemical equation? Why should chemical equations be balanced?
(b) Aluminium burns in chlorine to form aluminium chloride. Write a balanced chemical
equation for this reaction.
LONG ANSWER TYPE QUESTIONS
Balance the chemical equations for the following reactions:
Cu + H2SO4 → CuSO4 + SO2 + H2O
NaOH + H2SO4 → Na2SO4 + H2O
Differentiate between balanced and an unbalanced chemical equation.
Write the following chemical equation with state symbols:
CaCO3 → CaO + CO2
2Na + 2H2O → 2NaOH + H2
AgNO3 + NaCl → AgCl + NaNO3
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(iv) 6CO2 + 6H2O → C6H12O6 + 6O2
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀἀĀȀ⸀ऀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ What do you
mean by exothermic and endothermic reactions? Give examples.
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀἀĀȀ⸀ऀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ What is the
difference between displacement and double displacement reactions? Write equations for
these reactions.
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀἀĀȀ⸀ऀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Explain, how
do oxidation and reduction processes occur simultaneously.
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀἀĀȀ⸀ऀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ What is
corrosion? Write the chemical reaction that takes place during the corrosion of iron?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀἀĀȀ⸀ऀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ What are the
various ways to make a chemical equation more informative?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀἀĀȀ⸀ऀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Explain the
following terms: (i) corrosion (ii) Rancidity
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀἀĀȀ⸀ऀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ When metal
X is treated with a dilute acid Y, then a gas Z is evolved which burns readily by making a
little explosion.
Name any two metals which can behave like metal X.
Name any two acids which can behave like acid Y.
Name the gas Z.
Is the gas Z lighter than or heavier than air?
Is the reaction between metal X and acid Y exothermic or endothermic?
By taking a specific example of metal X and dilute acid Y, write a balanced chemical
equation for the reaction which takes place. Also indicate physical state of all the
reactants and products.
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ASSIGNMENT QUESTIONS SET – 2
CHAPTER – 1
CHEMICAL REACTIONS AND EQUATIONS
What is a balanced chemical equation? Why should chemical equations be balanced?
Balance the following chemical equations. a)
NaOH + H2SO4 → Na2SO4 + H2O
b) Hg (NO3)2 + KI → Hg I2 + KNO3
H2+ O2→ H2O
KClO3 → KCl + O2
C3H8 + O2 → CO2 + H2O
Write the balanced chemical equations for the following reactions.
Zinc + Silver nitrate → Zinc nitrate + Silver.
Aluminum + copper chloride → Aluminum chloride + Copper.
Hydrogen + Chlorine. → Hydrogen chloride.
Ammonium nitrate → Nitrogen + Carbon dioxide + water.
Write the balanced chemical equation for the following and indentify the type of reaction in
each case.
Calcium hydroxide (aq) + Nitric acid (aq) → Water (l) + Calcium nitrate (aq)
Magnesium (s) + Iodine (g) → Magnesium Iodide. (s)
Magnesium(s) + Hydrochloric acid(aq) → Magnesium chloride(aq) + Hydrogen(g)
d) Zinc(s) + Calcium chloride (aq) → Zinc Chloride (aq) + Ca(s)
Fe2O3 + 2Al → Al2O3 + 2 Fe.
The above reaction is an example of:
a) Combination reaction b) Decomposition reaction
Displacement reaction d) Double decomposition reaction
What happens when dil.hydrochloric acid is added to iron filings? Chose the correct
answer.
Hydrogen gas and iron chloride are produced.
Chlorine gas and iron hydroxide are produced.
No reaction takes place.
Iron salt and water are produced.
Write an equation for decomposition reaction where energy is supplied in the form of heat/
light/ electricity.
What do you mean by precipitation reaction?
Why is respiration considered as an exothermic reaction? Explain.
What is the difference between displacement and double displacement reactions? Write
equations for these reactions?
What is the use of keeping food in air tight containers?
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What do you mean by corrosion? How can you prevent it?
MnO2 + 4HCl → MnCl2 + 2H2O + Cl2
In the above equation, name the compound which is oxidized and which is reduced?
Match the following:
1)2AgNO3 + Na2CrO4 → Ag2CrO4+ 2NaNO3 ( ) a) combination reactions
2)2 NH3 → N2+ 3H2 ( ) b) decomposition reactions
3)C2H4 + H2O → C2H6O ( ) c) displacement reactions
4)Fe2O3 + 3CO → 2 F2+ 3CO2 ( ) d) double displacement Reactions
Give two examples for oxidation-reduction reaction.
In the refining of silver, the recovery of silver from silver nitrate solution involved
displacement by copper metal. Write the reaction involved.
Explain rancidity.
Name the reactions taking place in the presence of sunlight?
2 PbO(s) + C (s) → 2Pb(s) + CO2 (g)
Which of the following statements are correct for the above?
Lead is reduced. b) Carbon dioxide is oxidized.
Carbon is oxidized. d) Lead oxide is reduced.
(a)and (b) ii) (a) and (c) iii) (a), (b), and (c) d) all.
Balance the following chemical equations including the physical states.
ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ C6H12O6 → C2H5OH +
CO2
ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ Fe + O2 → Fe2O3
ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ NH3 + Cl2 →
N2H4+NH4cl
ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ Na + H2O → NaOH +H2
Balance the chemical equation by including the physical states of the substances for
the following reactions.
ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ Barium chloride and
sodium sulphate aqueous solutions react to give insoluble Barium sulphate and
aqueous solution of sodium chloride.
ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ Sodium hydroxide reacts
with hydrochloric acid to produce sodium chloride and water.
ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀȀ Zinc pieces react with
dilute hydrochloric acid to liberate hydrogen gas and forms zinc chloride
Which of the following is not a physical change?
(a) Boiling of water to give water vapour
(b) Melting of ice to give water
(c) Dissolution of salt in water
(d) Combustion of Liquefied Petroleum Gas (LPG)
The following reaction is an example of a
4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(g)
displacement reaction
combination reaction
redox reaction
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(iv) neutralisation reaction
(i) and (iv)
(ii) and (iii)
(i) and (iii)
(iii) and (iv)
Which of the following statements about the given reaction are correct?
3Fe(s) + 4H2O(g) → Fe3O4(s) + 4H2(g)
Iron metal is getting oxidised
Water is getting reduced
Water is acting as reducing agent
Water is acting as oxidising agent
(i), (ii) and (iii)
(iii) and (iv)
(i), (ii) and (iv)
(ii) and (iv)
Which of the following are exothermic processes?
ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀЀȀ̀⠀⤀ Ā ᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Reaction of water with
quick lime
Dilution of an acid
Evaporation of water
Sublimation of camphor (crystals)
(i) and (ii)
(ii) and (iii)
(i) and (iv)
(iii) and (iv)
Three beakers labelled as A, B and C each containing 25 mL of water were taken. A small
amount of NaOH, anhydrous CuSO4 and NaCl were added to the beakers A, B and C
respectively. It was observed that there was an increase in the temperature of the solutions
contained in beakers A and B, whereas in case of beaker C, the temperature of the solution
falls. Which one of the following statement(s) is(are) correct?
In beakers A and B, exothermic process has occurred.
In beakers A and B, endothermic process has occurred.
In beaker C exothermic process has occurred.
In beaker C endothermic process has occurred.
(i) only
(ii) only
(i) and (iv)
(ii) and (iii)
A dilute ferrous sulphate solution was gradually added to the beaker containing acidified
permanganate solution. The light purple colour of the solution fades and finally disappears.
Which of the following is the correct explanation for the observation?
KMnO4 is an oxidising agent, it oxidises FeSO4
FeSO4 acts as an oxidising agent and oxidises KMnO4
The colour disappears due to dilution; no reaction is involved
KMnO4 is an unstable compound and decomposes in presence of FeSO4 to a colourless
compound.
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Which among the following is(are) double displacement reaction(s)?
Pb + CuCl2 → PbCl2 + Cu
Na2SO4 + BaCl2 → BaSO4 + 2NaCl
C+O2→CO2
CH4 + 2O2 → CO2 + 2H2O
(i) and (iv)
(ii) only
(i) and (ii)
(iii) and (iv)
Which among the following statement(s) is(are) true? Exposure of silver chloride to sunlight
for a long duration turns grey due to
the formation of silver by decomposition of silver chloride
sublimation of silver chloride
decomposition of chlorine gas from silver chloride
oxidation of silver chloride
(i) only
(i) and (iii)
(ii) and (iii)
(iv) only
Solid calcium oxide reacts vigorously with water to form calcium hydroxide accompanied by
liberation of heat. This process is called slaking of lime. Calcium hydroxide dissolves in
water to form its solution called lime water. Which among the following is (are) true about
slaking of lime and the solution formed?
It is an endothermic reaction
It is an exothermic reaction
The pH of the resulting solution will be more than seven
The pH of the resulting solution will be less than seven
(i) and (ii)
(ii) and (iii)
(i) and (iv)
(iii) and (iv)
Barium chloride on reacting with ammonium sulphate forms barium sulphate and ammonium
chloride. Which of the following correctly represents the type of the reaction involved?
Displacement reaction
Precipitation reaction
Combination reaction
Double displacement reaction
(i) only
(ii) only
(iv) only
(ii) and (iv)
Ȁ⸀ĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ䄀ĀȀ⸀ĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Electrolysis
of water is a decomposition reaction. The mole ratio of hydrogen and oxygen gases
liberated during electrolysis of water is
1:1
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2:1
4:1
1:2
Which of the following is(are) an endothermic process(es)?
Dilution of sulphuric acid
Sublimation of dry ice
Condensation of water vapours
Evaporation of water
(i) and (iii)
(ii) only
(iii) only
(ii) and (iv)
In the double displacement reaction between aqueous potassium iodide and aqueous lead
nitrate, a yellow precipitate of lead iodide is formed. While performing the activity if lead
nitrate is not available, which of the following can be used in place of lead nitrate?
Lead sulphate (insoluble)
Lead acetate
Ammonium nitrate
Potassium sulphate
Which of the following gases can be used for storage of fresh sample of an oil for a long
time?
Carbon dioxide or oxygen
Nitrogen or oxygen
Carbon dioxide or helium
Helium or nitrogen
The following reaction is used for the preparation of oxygen gas in the laboratory
Which of the following statement(s) is(are) correct about the reaction?
It is a decomposition reaction and endothermic in nature
It is a combination reaction
It is a decomposition reaction and accompanied by release of heat
It is a photochemical decomposition reaction and exothermic in nature
Which one of the following processes involve chemical reactions?
Storing of oxygen gas under pressure in a gas cylinder
Liquefaction of air
Keeping petrol in a china dish in the open
Heating copper wire in presence of air at high temperature
In which of the following chemical equations, the abbreviations represent the correct states of
the reactants and products involved at reaction temperature?
2H2(l) + O2(l) → 2H2O(g)
2H2(g) + O2(l) → 2H2O(l)
2H2(g) + O2(g) → 2H2O(l)
2H2(g) + O2(g) → 2H2O(g)
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Which of the following are combination reactions?
(i) and (iii)
(iii) and (iv)
(ii) and (iv)
(ii) and (iii)
Write the balanced chemical equations for the following reactions and identify the type of
reaction in each case.
Nitrogen gas is treated with hydrogen gas in the presence of a catalyst at 773K to form
ammonia gas.
Sodium hydroxide solution is treated with acetic acid to form sodium acetate and water.
Ethanol is warmed with ethanoic acid to form ethyl acetate in the presence of concentrated
H2SO4 .
Ethene is burnt in the presence of oxygen to form carbon dioxide, water and releases heat
and light.
Write the balanced chemical equations for the following reactions and identify the type of
reaction in each case.
Thermit reaction, iron (III) oxide reacts with aluminium and gives molten iron and
aluminium oxide.
Magnesium ribbon is burnt in an atmosphere of nitrogen gas to form solid magnesium
nitride.
Chlorine gas is passed in an aqueous potassium iodide solution to form potassium chloride
solution and solid iodine.
Ethanol is burnt in air to form carbon dioxide, water and releases heat.
Complete the missing components/variables given as x and y in the following reactions
Which among the following changes are exothermic or endothermic in nature?
Decomposition of ferrous sulphate
Dilution of sulphuric acid
Dissolution of sodium hydroxide in water
Dissolution of ammonium chloride in water
Write the balanced chemical equations for the following reactions
Sodium carbonate on reaction with hydrochloric acid in equal molar concentrations gives
sodium chloride and sodium hydrogencarbonate.
Sodium hydrogencarbonate on reaction with hydrochloric acid gives sodium chloride,
water and liberates carbon dioxide.
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Copper sulphate on treatment with potassium iodide precipitates cuprous iodide (Cu2 I2),
liberates iodine gas and also forms potassium sulphate.
Identify the reducing agent in the following reactions
Identify the oxidising agent (oxidant) in the following reactions
A solution of potassium chloride when mixed with silver nitrate solution, an insoluble white
substance is formed. Write the chemical reaction involved and also mention the type of the
chemical reaction?
Ferrous sulphate decomposes with the evolution of a gas having a characteristic odour of
burning sulphur. Write the chemical reaction involved and identify the type of reaction.
Why do fire flies glow at night?
Grapes hanging on the plant do not ferment but after being plucked from the plant can be
fermented. Under what conditions do these grapes ferment? Is it a chemical or a physical
change?
Which among the following are physical or chemical changes?
Evaporation of petrol
Burning of Liquefied Petroleum Gas (LPG)
Heating of an iron rod to red hot.
Curdling of milk
Sublimation of solid ammonium chloride
During the reaction of some metals with dilute hydrochloric acid, following observations were
made.
Silver metal does not show any change
The temperature of the reaction mixture rises when aluminium (Al) is added.
The reaction of sodium metal is found to be highly explosive
Some bubbles of a gas are seen when lead (Pb) is reacted with the acid.
Explain these observations giving suitable reasons.
A substance X, which is an oxide of a group 2 element, is used intensively in the cement
industry. This element is present in bones also. On treatment with water it forms a solution
which turns red litmus blue. Identify X and also write the chemical reactions involved.
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Write a balanced chemical equation for each of the following reactions and also classify them.
Lead acetate solution is treated with dilute hydrochloric acid to form lead chloride and
acetic acid solution.
A piece of sodium metal is added to absolute ethanol to form sodium ethoxide and
hydrogen gas.
Iron (III) oxide on heating with carbon monoxide gas reacts to form solid iron and liberates
carbon dioxide gas.
Hydrogen sulphide gas reacts with oxygen gas to form solid sulphur and liquid water.
Why do we store silver chloride in dark coloured bottles?
Balance the following chemical equations and identify the type of chemical reaction.
A magnesium ribbon is burnt in oxygen to give a white compound X accompanied by emission
of light. If the burning ribbon is now placed in an atmosphere of nitrogen, it continues to
burn and forms a compound Y.
Write the chemical formulae of X and Y.
Write a balanced chemical equation, when X is dissolved in water.
Zinc liberates hydrogen gas when reacted with dilute hydrochloric acid, whereas copper
does not. Explain why?
A silver article generally turns black when kept in the open for a few days. The article when
rubbed with toothpaste again starts shining.
Why do silver articles turn black when kept in the open for a few days? Name the
phenomenon involved.
Name the black substance formed and give its chemical formula.
On heating blue coloured powder of copper (II) nitrate in a boiling tube, copper oxide (black),
oxygen gas and a brown gas X is formed
Write a balanced chemical equation of the reaction.
Identity the brown gas X evolved.
Identity the type of reaction.
What could be the pH range of aqueous solution of the gas X?
Give the characteristic tests for the following gases
CO2
SO2
O2
H2
What happens when a piece of
zinc metal is added to copper sulphate solution?
aluminium metal is added to dilute hydrochloric acid?
silver metal is added to copper sulphate solution?
Also, write the balanced chemical equation if the reaction occurs
What happens when zinc granules are treated with dilute solution of H2SO4, HCl, HNO3, NaCl
and NaOH, also write the chemical equations if reaction occurs.
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On adding a drop of barium chloride solution to an aqueous solution of sodium sulphite, white
precipitate is obtained.
Write a balanced chemical equation of the reaction involved
What other name can be given to this precipitation reaction?
On adding dilute hydrochloric acid to the reaction mixture, white precipitate disappears.
Why?
You are provided with two containers made up of copper and aluminium. You are also
provided with solutions of dilute HCl, dilute HNO 3, ZnCl2 and H2O. In which of the above
containers these solutions can be kept?
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CHAPTER – 2
ACIDS, BASES AND SALTS
ACIDS
+ +
Acid is a substance which furnishes H ions or H3O ions when dissolved in water. Acids have
one or more replaceable hydrogen atoms. The word acid is derived from the Latin name
‘acidus’ which means sour taste. Substances with ‘sour taste’ are acids. Lemon juice, vinegar
and grape juice have sour taste, so they are acidic. They change blue litmus to red. They are
colourless with phenolphthalein and pink with methyl orange. There are many substances
which contain acid and hence taste sour, such as curd, tamarind, lemon, etc.
CLASSIFICATION OF ACIDS
Based on their sources : Acids are classified into two types namely organic acids and
inorganic acids.
Organic acids:- Acids present in plants and animals (living beings) are organic
acids eg. HCOOH, CH3COOH (Weak acids).
Inorganic acids:- Acids from rocks and minerals are inorganic acids or mineral acids
eg. HCl, HNO3, H2SO4 (Strong acids).
Based on their basicity
Monobasic acid: - It is an acid which gives one hydrogen ion per molecule of the acid
in solution eg. HCl, HNO3.
Dibasic acid:- It is an acid which gives two hydrogen ions per molecule of
the acid in solution e.g., H2SO4, H2CO3.
Tribasic acid:- It is an acid which gives three hydrogen ions per molecule of the acid
in solution. e.g.,H3PO4,
Based on ionisation
Acids are classified into two types based on ionisation.
Strong acids:- These are acids which ionise completely in water eg.HCl
Weak acids:-These are acids which ionise partially in water eg. CH3COOH
Based on concentration:- Depending on the percentage or amount of acid dissolved in
water acids are classified into concentrated acid and dilute acid.
Concentrated acid:- It is an acid having a relatively high percentage of acid in its
aqueous solution.
Dilute acid:- It is an acid having a relatively low percentage of acid in aqueous solution.
INTEXT QUESTIONS PAGE NO. 18
Question 1: You have been provided with three test tubes. One of them contains distilled
water and the other two contain an acidic solution and a basic solution, respectively. If
you are given only red litmus paper, how will you identify the contents of each test tube?
Answer : If the colour of red litmus paper gets changed to blue, then it is a base and if there is
no colour change, then it is either acidic or neutral. Thus, basic solution can be easily
identified.
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Let us mark the three test tubes as A, B, and C. A drop of the solution in A is put on the red
litmus paper. Same is repeated with solution B and C. If either of them changes colour to blue,
then it is basic. Therefore, out of three, one is eliminated. Out of the remaining two, any one
can be acidic or neutral. Now a drop of basic solution is mixed with a drop of each of the
remaining two solutions separately and then the nature of the drops of the mixtures is checked.
If the colour of red litmus turns blue, then the second solution is neutral and if there is no
change in colour, then the second solution is acidic. This is because acidic and basic solutions
neutralize each other. Hence, we can distinguish between the three types of solutions.
CHEMICAL PROPERTIES OF ACIDS
REACTION OF ACIDS WITH METAL:
Acids give hydrogen gas along with respective salt when they react with a metal.
Metal + Acid → Salt + Hydrogen
Example:
Hydrogen gas and zinc chloride are formed when hydrochloric acid reacts with zinc
metal. Zn + 2HCl → ZnCl2 + H2
Hydrogen gas and sodium chloride are formed when hydrochloric acid reacts with
sodium metal.
2Na + 2HCl → 2NaCl + H2
Hydrogen gas and iron chloride are formed when hydrochloric acid reacts with
iron. Fe + 2HCl → FeCl2 + H2
Hydrogen gas and zinc sulphate are formed when zinc metal reacts with sulphuric
acid Zn + H2SO4 → ZnSO4 + H2
REACTION OF ACIDS WITH METAL CARBONATE:
Acids give carbon dioxide gas and respective salts along with water when they react with
metal carbonates.
Metal carbonate + Acid → Salt + Carbon dioxide + Water
Examples:
Sulphuric acid gives calcium sulphate, carbon dioxide gas, calcium sulphate and
water when it reacts with calcium carbonate.
CaCO3 + H2SO4 → CaSO4 + CO2 + H2O
Sulphuric acid gives sodium sulphate, carbon dioxide gas and water when it reacts
with sodium carbonate.
Na2CO3 + H2SO4 → Na2SO4 + CO2 + H2O
Hydrochloric acid gives carbon dioxide gas, calcium chloride and water when it reacts
with calcium carbonate.
CaCO3 + 2HCl → CaCl2 + CO2 + H2O
Hydrochloric acid gives carbon dioxide gas, sodium chloride along with water when
reacts with sodium carbonate.
Na2CO3 + 2HCl → 2NaCl + CO2 + H2O
Hydrochloric acid gives carbon dioxide, magnesium chloride and water when it reacts
with magnesium carbonate.
MgCO3 + 2HCl → MgCl2 + CO2 + H2O
Nitric acid gives sodium nitrate, water and carbon dioxide gas when it reacts with
sodium carbonate.
2HNO3 + Na2CO3 → NaNO3 + 2H2O + CO2
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REACTION OF ACID WITH HYDROGEN CARBONATES (BICARBONATES):
Acids give carbon dioxide gas, respective salt and water when they react with metal
hydrogen carbonate.
Acid + Metal hydrogen carbonate → Salt + Carbon dioxide + Water
Examples:
Hydrochloric acid gives carbon dioxide, sodium chloride and water when it reacts
with sodium bicarbonate.
NaHCO3 + HCl → NaCl + CO2 + H2O
Sulphuric acid gives sodium sulphate, carbon dioxide gas and water when it reacts
with sodium bicarbonate.
2NaHCO3 + H2SO4 → Na2SO4 + 2CO2 + 2H2O
Sodium bicarbonate is also known as sodium hydrogen carbonate, baking soda,
baking powder, bread soda and bicarbonate of soda.
The gas evolved because of reaction of acid with metal carbonate or metal hydrogen
carbonate turns lime water milky. This shows that the gas is carbon dioxide gas.
This happens because of formation of white precipitate of calcium carbonate.
Ca(OH)2 + CO2 → CaCO3 + H2O
CaCO3 + CO2 + H2O → Ca(HCO3 )2
But when excess of carbon dioxide is passed through lime water, it makes milky colour
of lime water disappear. This happens because of formation of calcium hydrogen
carbonate. As calcium hydrogen carbonate is soluble in water, thus the milky colour of
solution mixture disappears.
REACTION OF ACID WITH MARBLE AND EGG SHELL:
Since, marble and egg shell are made of calcium carbonate, hence when acid is poured
over marble or egg shell, bubbles of carbon dioxide are formed.
USES OF ACIDS
Sulphuric acid (King of chemicals) is used in car battery and in the preparation of
many other compounds.
Nitric acid is used in the production of ammonium nitrate which is used as fertilizer
in agriculture.
Hydrochloric acid is used as cleansing agent in toilet.
Tartaric acid is a constituent of baking powder.
Salt of benzoic acid (sodium benzoate) is used in food preservation.
Carbonic acid is used in aerated drinks.
BASES
Base is a substance which releases hydroxide ions when dissolved in water. It is a substance
which is bitter in taste and soapy to touch (e.g. Washing soda, caustic soda and caustic potash).
They change red litmus to blue. They are pink with phenolphthalein and yellow with methyl
orange.
CLASSIFICATION OF BASES
Ȁ⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀЀĀȀ⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀ Based on ionisation
Strong bases:- These are bases which ionise completely in aqueous solution
eg.NaOH, KOH.
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Weak bases:- These are bases which ionise partially in aqueous solution eg. NH4OH,
Ca(OH)2.
Based on their acidity
Monoacidic base:- It is a base which ionises in water to give one hydroxide ion per
molecule eg.NaOH, KOH.
Diacidic base:- It is a base which ionises in water to give two hydroxide ions per
molecule eg. Ca(OH)2, Mg(OH)2.
Triacidic base:- It is a base which ionises in water to give three hydroxide ions
per molecule eg. Al(OH)3, Fe(OH)3.
Based on the concentration:
Depending on the percentage or amount of base dissolved in water, bases are
classified as concentrated alkali and dilute alkali.
Concentrated alkali:- It is an alkali having a relatively high percentage of alkali in
its aqueous solution.
Dilute alkali:- It is an alkali having a relatively low percentage of alkali in its
aqueous solution.
REACTION OF BASE WITH METALS:
When alkali (base) reacts with metal, it produces salt and hydrogen gas.
Alkali + Metal → Salt + Hydrogen
Example:
Sodium aluminate and hydrogen gas are formed when sodium hydroxide reacts
with aluminium metal.
2NaOH + 2Al + 2H2O → 2NaAlO2 + 2H2
Sodium hydroxide gives hydrogen gas and sodium zincate when reacts with zinc
metal. 2NaOH + Zn → Na2ZnO2 + H2
REACTION OF BASE WITH OXIDES OF NON-METALS:
Non-metal oxides are acidic in nature. For example; carbon dioxide is a non-metal oxide.
When carbon dioxide is dissolved in water it produces carbonic acid.
Therefore, when a base reacts with non-metal oxide both neutralize each other
resulting respective salt and water are produced.
Base + Non-metal oxide → Salt + Water
Example:
Calcium hydroxide gives calcium carbonate and water when it reacts with carbon
dioxide. Ca(OH)2 + CO2 → CaCO3 + H2O
Sodium hydroxide gives sodium carbonate and water when it reacts with carbon
dioxide. 2NaOH + CO2 → Na2CO3 + H2O
USES OF BASES
Sodium hydroxide is used in the manufacture of soap.
Calcium hydroxide is used in white washing the buildings.
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Magnesium hydroxide is used as a medicine for stomach troubles.
Ammonium hydroxide is used to remove grease stains from clothes.
NEUTRALISATION REACTION:
An acid neutralizes a base when they react with each other and respective salt and water
are formed.
Acid + Base → Salt + Water
Since in the reaction between acid and base both neutralize each other, hence it is also
known as neutralization reaction.
Example:
Sodium sulphate and water are formed when sulphuric acid reacts with sodium
hydroxide (a base).
H2SO4 + 2NaOH → Na2SO4 + 2H2O
In similar way, when nitric acid reacts with sodium hydroxide, sodium nitrate and water
are formed.
HNO3 + NaOH → NaNO3 + H2O
Sodium chloride and water are formed when hydrochloric acid reacts with
sodium hydroxide (a strong base).
HCl + NaOH → NaCl + H2O
In similar way, calcium chloride is formed along with water when hydrochloric acid
reacts with calcium hydroxide (a base).
2HCl + Ca(OH)2 → CaCl2 + 2H2O
REACTION OF ACID WITH METAL OXIDES:
Metal oxides are basic in nature. Thus, when an acid reacts with a metal oxide both
neutralize each other. In this reaction, respective salt and water are formed. Acid + Metal
Oxide Salt + Water
Example:
Calcium is a metal, thus calcium oxide is a metallic oxide which is basic in nature. When
an acid; such as hydrochloric acid; reacts with calcium oxide, neutralization reaction
takes place and calcium chloride; along with water; is formed.
2HCl + CaO → CaCl2 + H2O
Similarly, when sulphuric acid reacts with zinc oxide, zinc sulphate and water are
formed. H2SO4 + ZnO → ZnCl2 + H2O
When hydrochloric acid reacts with aluminium oxide, aluminium chloride and water
are formed.
Al2O3 + 6HCl → 2AlCl3 + 3H2O
INTEXT QUESTIONS PAGE NO. 22
Question 1: Why should curd and sour substances not be kept in brass and copper
vessels?
Answer : Curd and other sour substances contain acids. Therefore, when they are kept in brass
and copper vessels, the metal reacts with the acid to liberate hydrogen gas and harmful
products, thereby spoiling the food.
Question 2: Which gas is usually liberated when an acid reacts with a metal? Illustrate
with an example. How will you test for the presence of this gas? Answer : Hydrogen gas is
usually liberated when an acid reacts with a metal.
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Take few pieces of zinc granules and add 5 ml of dilute H2SO4. Shake it and pass the gas
produced into a soap solution. The bubbles of the soap solution are formed. These soap bubbles
contain hydrogen gas.
We can test the evolved hydrogen gas by its burning with a pop sound when a candle is
brought near the soap bubbles.
Question 3: Metal compound A reacts with dilute hydrochloric acid to produce
effervescence. The gas evolved extinguishes a burning candle. Write a balanced chemical
equation for the reaction if one of the compounds formed is calcium chloride. Answer :
COMMON IN ACID AND BASE
Acids give hydrogen gas when they react with metal. This shows that all acids contain
hydrogen. For example: Hydrochloric acid (HCl), sulphuric acid (H 2SO4), nitric acid (HNO3),
etc.
When an acid is dissolved in water, it dissociates hydrogen. The dissociation of hydrogen ion in
aqueous solution is the common property in all acids. Because of dissociation of hydrogen ion
in aqueous solution, an acid shows acidic behavior.
Example:
+ −
Hydrochloric acid (HCl) gives hydrogen ion (H ) and chloride ion (Cl ) when it
is dissolved in water.
+ −
HCl (aq) → H + Cl
+ −−
Sulphuric acid (H2SO4) gives hydrogen ion (H ) and sulphate ion (SO4 ) in
+ −−
water. H2SO4 (aq) → H + SO4
+ −
Nitric acid (HNO3) gives hydrogen ion (H ) and nitrate ion (NO3 ) in
+ −
water. HNO3 (aq) → H + NO3
− +
Acetic acid (CH3COOH) gives acetate ion (CH3COO ) and hydrogen ion (H ).
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− +
CH3COOH (aq) → CH3COO H
Hydrogen ion which is produced by acid (when acid is combined with water molecule),
−
exists in the form of hydronium ion (H3O ) in aqueous solution. That’s why hydrogen ion
+
is always written with suffix (aq), such as H (aq).
− −
HCl + H2O → H3O + Cl
− −−
H2SO4 + H2O → H3O + SO4
Thus, because of dissociation of hydrogen ions; acid shows its acidic behavior.
Acids conduct electricity in their aqueous solution because of dissociation of hydrogen ion.
Hydrogen ion in aqueous solution conducts electricity.
A dry acid, such as dry hydrochloric acid does not change the colour of blue litmus paper to red
because a dry acid does not dissociate hydrogen ion. This is the cause that a moist litmus paper
is used to check the acidic or basic character of a gas.
Acidic behavior of carbon dioxide gas:
Carbon dioxide gas produces carbonic acid when dissolved in water. This carbonic
acid dissociates hydrogen ion and carbonate ion in the aqueous solution.
+ −−
CO2 + H2O → H2CO3 → H + CO3
Are all compounds which contain hydrogen, necessarily acids?
No, all compounds which contain hydrogen are not acid. For example; glucose (C 6H12O6),
methyl alcohol (CH3OH), etc. are not acid in spite of the fact that they contain hydrogen. This
is because these compounds do not dissociate hydrogen ion in their aqueous solution.
Common in all Base:
A base dissociates hydroxide ion in water, which is responsible for the basic behavior of
a compound. Example:
When sodium hydroxide is dissolved in water, it dissociates hydroxide ion and sodium
+ −
ion. NaOH (aq) → Na + OH
Similarly, when potassium hydroxide is dissolved in water, it dissociates hydroxide ion
and potassium ion.
+ −
KOH (aq) → K + OH
Thus, base shows its basic character because of dissociation of hydroxide ion.
NEUTRALISATION REACTION:
When an acid reacts with a base, the hydrogen ion of acid combines with the hydroxide ion
of base and forms water. As these ions combine together and form water; instead of
remaining free, thus both neutralize each other.
− +
OH + H → H2O
Example:
When sodium hydroxide (a base) reacts with hydrochloric acid, sodium hydroxide breaks
into sodium ion and hydroxide ion and hydrochloric acid breaks into hydrogen ion and
chloride ion. Hydrogen ion and hydroxide ion combine together and form water, while
sodium ion and chloride ion combine together and form sodium chloride.
− + + −
NaOH + HCl → OH + Na + H + Cl → NaCl + H2O
DILUTION OF ACID AND BASE:
The concentration of hydrogen ion in an acid and hydroxide ion in a base; per unit volume;
shows the concentration of acid or base.
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By mixing of acid to water, the concentration of hydrogen ion per unit volume decreases.
Similarly, by addition of base to water the concentration of hydroxide ion per unit volume
decreases. This process of addition of acid or base to water is called dilution and the acid or
base is called diluted.
The dilution of acid or base is exothermic. Thus, acid or base is always added to water and
water is never added to acid or base. If water is added to a concentrated acid or base a lot of
heat is generated, which may cause splashing out of acid or base and may cause severe damage
as concentrated acid and base are highly corrosive.
INTEXT QUESTIONS PAGE NO. 25
Question 1: Why do HCl, HNO3, etc., show acidic characters in aqueous solutions while
solutions of compounds like alcohol and glucose do not show acidic character?
Answer : The dissociation of HCl or HNO 3 to form hydrogen ions always occurs in the
+ +
presence of water. Hydrogen ions (H ) combine with H2O to form hydronium ions (H3O ).
The reaction is as follows:
Although aqueous solutions of glucose and alcohol contain hydrogen, these cannot dissociate
in water to form hydrogen ions. Hence, they do not show acidic character.
Question 2: Why does an aqueous solution of an acid conduct electricity?
Answer : Acids dissociate in aqueous solutions to form ions. These ions are responsible for
conduction of electricity.
Question 3: Why does dry HCl gas not change the colour of the dry litmus paper?
Answer : Colour of the litmus paper is changed by the hydrogen ions. Dry HCl gas does not
+
contain H ions. It is only in the aqueous solution that an acid dissociates to give ions. Since in
this case, neither HCl is in the aqueous form nor the litmus paper is wet, therefore, the colour of
the litmus paper does not change.
Question 4: While diluting an acid, why is it recommended that the acid should be added
to water and not water to the acid?
Answer : Since the process of dissolving an acid in water is exothermic, it is always
recommended that acid should be added to water. If it is done the other way, then it is possible
that because of the large amount of heat generated, the mixture splashes out and causes burns.
+
Question 5: How is the concentration of hydronium ions (H 3O ) affected when a solution
of an acid is diluted?
+
Answer : When an acid is diluted, the concentration of hydronium ions (H 3O ) per unit
volume decreases. This means that the strength of the acid decreases.
−
Question 6: How is the concentration of hydroxide ions (OH ) affected when excess base
is dissolved in a solution of sodium hydroxide?
−
Answer : The concentration of hydroxide ions (OH ) would increase when excess base is
dissolved in a solution of sodium hydroxide.
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STRENGTH OF ACID AND BASE
Acids in which complete dissociation of hydrogen ion takes place are called strong acid.
Similarly, bases in which complete dissociation of hydroxide ion takes place are called strong
base.
In mineral acids, such as hydrochloric acid, sulphuric acid, nitric acid, etc. hydrogen ion
dissociates completely and hence they are considered as strong acid. Since, in organic acids
hydrogen ions do not dissociate completely, so they are weak acid.
Alkalis are water soluble base, thus in alkali; complete dissociation of hydroxide ions takes
place and they are considered as strong base.
The complete dissociation of hydrogen ions or hydroxide ions is shown by a single arrow. The
incomplete dissociation of hydrogen ions or hydroxide ions is denoted by double arrow.
Example of complete dissociation:
+ −
NaOH (aq) → Na + OH
+ −
HCl → H + Cl
Example of incomplete dissociation:
++ −−
Mg(OH)2 → Mg + OH
Although acetic acid being an organic acid is a weak acid, but concentrated acetic acid
is corrosive and can damage the skin if poured over it.
pH – MEASUREMENT OF STRENGTH OF ACID AND BASE
pH stands for the power of hydrogen ion concentration in a solution. pH values decide whether
a solution is acidic or basic or neutral. pH scale was introduced by S.P.L. Sorenson. It is
mathematically expressed as
+
pH = -log10[H ]
+ 7
For neutral solution [H ] = 10– M; pH = 7
+ –7
For acidic solution [H ] > 10 M; pH < 7
–
When OH ions are taken into account the pH expression is replaced by pOH
–
pOH = -log10[OH ]
The strength of acid or base depends upon the hydrogen ion concentration. If the concentration
of hydrogen ion is greater than hydroxide ion, the solution is called acidic. If the concentration
of hydrogen ion is smaller than the hydroxide ion, the solution is called basic. If the
concentration of hydrogen ion is equal to the concentration of hydroxide ion, the solution is
called neutral solution.
pH is a scale which quantifies the concentration of hydrogen ion in a solution. The range of pH
scale is between 0 to 14.
The pH value decreases with increase in hydrogen ion concentration. If the value of pH is 0,
this shows maximum hydrogen ion concentration. pH value equal to 14 shows lowest hydrogen
ion concentration. pH value equal to 7 shows the hydrogen ion concentration is equal to
hydroxide ion concentration.
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A neutral solution, such as distilled water has value of hydrogen ion concentration equal to 7 on
pH scale. The acidic solution has value of hydrogen ion concentration less than 7 on pH scale.
The basic solution has value of hydrogen ion concentration greater than 7 on pH scale.
In pH scale ‘p’ stands for ‘potenz’. Potenz is a German word which means ‘power’ or
‘potential’. Here; ‘H’ stands for hydrogen ion. Thus, pH means the potential of hydrogen or
power of hydrogen.
IMPORTANCE OF pH IN EVERYDAY LIFE
pH in human body
Using pH factor the healthiness of our body is predicted. At pH level 6.9, the body
becomes prone to viral infections like colds, cough and flu. Cancer cells thrive
inside the body at a pH of 5.5.
The pH of a normal, healthy human skin is 4.5 to 6. Proper skin pH is essential for
a healthy complexion.
pH of stomach fluid is approximately 2.0. This fluid is essential for the digestion
of food.
Human blood pH range is 7.35 to 7.45. Any increase or decrease in this value, leads
to diseases. The ideal pH for blood is 7.4.
pH of normal saliva ranges between 6.5 to 7.5.
White enamel coating in our teeth is calcium phosphate, hardest substance in our
body. It does not dissolve in water. If pH of mouth falls below 5.5, the enamel gets
corroded. Toothpastes are generally basic, and is used for cleaning the teeth, can
neutralize the excess acid and prevent tooth decay.
pH in soil
In agriculture, the pH of soil is very important. Citrus fruits require slightly
alkaline soil, while rice requires acidic soil and sugar cane requires neutral soil.
pH in rain water
pH of rain water is approximately 7 showing high level of its purity and neutrality. If
rain water is polluted by SO2 and NO2, acid rain occurs, bringing the pH value less
than 7.
INDICATOR:
Substances which show the acidic or basic behavior of other substance by change in colour are
known as indicator.
Type of Indicator: There are many types of indicators. Some common types of indicators
are Natural
Olfactory Indicator
Synthetic Indicator
Universal Indicator
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NATURAL INDICATOR
Indicators obtained from natural sources are called natural indicators. Litmus, turmeric, red
cabbage, China rose, etc. are some common natural indicators used widely to show the
acidic or basic character of substances.
LITMUS
Litmus is obtained from lichens. The solution of litmus is purple in colour. Litmus paper
comes in two colour – blue and red.
An acid turns blue litmus paper red.
A base turns red litmus paper blue.
TURMERIC
Turmeric is another natural indicator. Turmeric is yellow in colour. Turmeric solution or
paper turns reddish brown with base. Turmeric does not change colour with acid.
RED CABBAGE
The juice of red cabbage is originally purple in colour. Juice of red cabbage turns reddish
with acid and turns greenish with base.
OLFACTORY INDICATORS
Substances which change their smell when mixed with acid or base are known as
olfactory indicators. For example onion, vanilla, clove, etc.
ONION
Paste or juice of onion loses its smell when added with base. It does not change its smell
with acid.
VANILLA
The smell of vanilla vanishes with base, but it’s smell does not vanishes with an acid.
Olfactory indicators are used to ensure the participation of visually impaired students
in laboratory.
SYNTHETIC INDICATOR
Indicators that are synthesized in laboratory are known as synthetic indicators. For
example; phenolphthalein, methyl orange, etc.
Phenolphthalein is a colourless liquid. It remains colourless with acid but turns into pink with
a base.
Methyl orange is originally orange in colour. It turns into red with acid and turns into yellow with base.
Indicator Original colour Acid Base
Red litmus Red No change Blue
Blue litmus Blue Red No change
Turmeric Yellow No change Reddish brown
Red cabbage juice Purple Reddish Greenish yellow
Phenolphthalein Colourless Colourless Pink
Methyl orange Orange Red Yellow
Onion n/a No change Smell vanishes
Vanilla n/a No change Smell vanishes
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UNIVERSAL INDICATOR:
Using a litmus paper, phelophthalein, methyl orange, etc. only the acidic or basic character of a
solution can be determined, but use of these indicators does not give the idea about the strength
of acid or base. So, to get the strength as well as acidic and basic nature of a given solution
universal indicator is used.
Universal indicator shows different colour over the range of pH value from 1 to 14 for a given
solution. Universal indicator is available both in the form of strips and solution. Universal
indicator is the combination of many indicators, such as water, propanol, phelophthalein,
sodium salt, sodium hydroxide, methyl red, bromothymol blue monosodium salt, and thymol
blue monosodium salt. The colour matching chart is supplied with universal indicator which
shows the different colours for different values of pH.
INTEXT QUESTIONS PAGE NO. 28
Question 1: You have two solutions, A and B. The pH of solution A is 6 and pH of
solution B is 8. Which solution has more hydrogen ion concentration? Which of this is
acidic and which one is basic?
Answer : A pH value of less than 7 indicates an acidic solution, while greater than 7 indicates a
basic solution. Therefore, the solution with pH = 6 is acidic and has more hydrogen ion
concentration than the solution of pH = 8 which is basic.
+
Question 2: What effect does the concentration of H (aq) ions have on the nature of the
solution?
+
Answer : Concentration of H (aq) can have a varied effect on the nature of the solution. With
+ +
an increase in H ion concentration, the solution becomes more acidic, while a decrease of H
ion causes an increase in the basicity of the solution.
+
Question 3: Do basic solutions also have H (aq) ions? If yes, then why are these basic?
+
Answer :Yes, basic solution also has H (aq) ions. However, their concentration is less as
compared to the concentration of OH− ions that makes the solution basic.
Question 4: Under what soil condition do you think a farmer would treat the soil of his
fields with quick lime (calcium oxide) or slaked lime (calcium hydroxide) or chalk
(calcium carbonate)?
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Answer : If the soil is acidic and improper for cultivation, then to increase the basicity of soil,
the farmer would treat the soil with quick lime or slaked lime or chalk.
SALT
Salts are the ionic compounds which are produced after the neutralization reaction between
acid and base. Salts are electrically neutral. There are number of salts but sodium chloride
is the most common among them. Sodium chloride is also known as table salt or common
salt. Sodium chloride is used to enhance the taste of food.
CHARACTERISTICS OF SALT:
Most of the salts are crystalline solid
Salts may be transparent or opaque
Most of the salts are soluble in water
Solution of salts conducts electricity. Salts conduct electricity in their molten state
also The salt may be salty, sour, sweet, bitter and umami (savoury) Neutral salts are
odourless
Salts can be colourless or coloured
Classification of salts
Normal salts
A normal salt is obtained by complete neutralization of an acid by a base
NaOH + HCl → NaCl + H2O
Acid salts
Acid salts are derived by the partial replacement of hydrogen ions of an acid by a
metal. When a calculated amount of a base is added to a polybasic acid, acid salt is
obtained, as follows.
NaOH + H2SO4 → NaHSO4 + H2O
Basic salts
Basic salts are formed by the partial replacement of hydroxide ions of a diacidic or triacidic
base by an acid radical. A basic salt may further reacts with an acid to give a normal salt.
Pb(OH)2 + HCl → Pb(OH)Cl + H2O
Diacidic base Basic salt
Double salts
Double salts are formed by the combination of saturated solution of two simple salts
in equimolar ratio followed by crystallization. e.g. potash alum
FAMILY OF SALT:
Salts having common acidic or basic radicals are said to belong to same family.
Example
Sodium chloride (NaCl) and Calcium chloride (CaCl2) belong to chloride family.
Calcium chloride (CaCl2) and calcium sulphate (CaSO4) belong to calcium family.
Zinc chloride (ZnCl2) and Zinc sulphate (ZnSO4) belong to zinc family.
ACIDIC, BASIC AND NEUTRAL SALTS
NEUTRAL SALT
Salts produced because of reaction between strong acid and strong base are neutral in
nature. The pH of value of such salts is equal to 7, i.e. neutral. Example; Sodium chloride,
sodium sulphate, potassium chloride, etc.
Sodium chloride (NaCl) is formed after the reaction between hydrochloric acid (a strong
acid) and sodium hydroxide (a strong base).
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NaOH + HCl → NaCl + H2O
SODIUM SULPHATE (Na2SO4)
It is formed after the reaction between sodium hydroxide (a strong base) and sulphuric acid
(a strong acid).
2NaOH + H2SO4 → Na2SO4 + 2H2O
Potassium chloride (KCl): It is formed after the reaction between potassium hydroxide
(a strong base) and hydrochloric acid (a strong acid).
KOH + HCl → KCl + H2O
ACIDIC SALT
Salts which are formed after the reaction between a strong acid and weak base are called
acidic salt. The pH value of acidic salt is lower than 7. Example: ammonium sulphate,
ammonium chloride, etc.
Ammonium chloride is formed after reaction between hydrochloric acid (a strong acid)
and ammonium hydroxide (a weak base).
NH4OH + HCl → NH4Cl + H2O
Ammonium sulphate is formed after reaction between ammonium hydroxide (weak base)
and sulphuric acid (a strong acid).
2NH4OH + H2SO4 → (NH4 )2SO4 + 2H2O
BASIC SALT
Salts which are formed after the reaction between weak acid and strong base are called
basic salt. For example; sodium carbonate, sodium acetate, etc.
Sodium carbonate is formed after the reaction between sodium hydroxide (a strong base)
and carbonic acid (a weak base).
H2CO3 + 2NaOH → Na2CO3 + 2H2O
Sodium acetate is formed after the reaction between a strong base, sodium hydroxide and
a weak acid, acetic acid.
CH3COOH + NaOH → CH3COONa + H2O
CAUSE OF FORMATION OF ACIDIC, BASIC AND NEUTRAL SALT:
When a strong acid reacts with a weak base, the base is unable to fully neutralize the acid.
Due to this an acidic salt is formed in this case.
When a strong base reacts with a weak acid, the acid is unable to fully neutralize the base.
Due to this a basic salt is formed in this case.
When equally strong acid and base react they fully neutralize each other. Due to this a
neutral salt is formed in this case.
pH Value Of Salt:
Neutral salt: The pH value of a neutral salt is almost equal to 7.
Acidic salt: The pH value of an acidic salt is less than 7.
Basic salt: The pH value of a basic salt is more than 7.
COMMON SALT (SODIUM CHLORIDE)
Sodium chloride (NaCl) is also known as common or table salt. It is formed after the reaction
between sodium hydroxide and hydrochloric acid. It is a neutral salt. The pH value of sodium
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chloride is about 7. Sodium chloride is used to enhance the taste of food. Sodium chloride
is used in manufacturing of many chemicals.
IMPORTANT CHEMICALS FROM SODIUM CHLORIDE:
SODIUM HYDROXIDE (NaOH)
Sodium hydroxide is a strong base. It is also known as caustic soda or Iye. It is obtained by
the electrolytic decomposition of solution of sodium chloride (brine). In the process of
electrolytic decomposition of brine (aqueous solution of sodium chloride), brine decomposes
to form sodium hydroxide. In this process, chlorine is obtained at anode and hydrogen gas is
obtained at cathode as byproducts. This whole process is known as Chlor-Alkali process.
2NaCl + 2H2O → 2NaOH + Cl2 + H2
USE OF PRODUCTS AFTER THE ELECTROLYSIS OF BRINE:
Hydrogen gas is used as fuel, margarine, in making of ammonia for fertilizer, etc.
Chlorine gas is used in water treatment, manufacturing of PVC, disinfectants, CFC,
pesticides. It is also used in manufacturing of bleaching powder and hydrochloric acid.
Sodium hydroxide is used for de-greasing of metals, manufacturing of paper, soap,
detergents, artificial fibres, bleach, etc.
BLEACHING POWDER (CaOCl2 ):
Bleaching powder is also known as chloride of lime. It is a solid and yellowish white in colour.
Bleaching powder can be easily identified by the strong smell of chlorine.
When calcium hydroxide (slaked lime) reacts with chlorine, it gives calcium
oxychloride (bleaching powder) and water is formed.
Ca(OH)2 + Cl2 → CaOCl2 + H2O
Aqueous solution of bleaching powder is basic in nature. The term bleach means removal
of colour. Bleaching powder is often used as bleaching agent. It works because of
oxidation. Chlorine in the bleaching powder is responsible for bleaching effect.
USE OF BLEACHING POWDER:
Bleaching powder is used as disinfectant to clean water, moss remover, weed
killers, etc.
Bleaching powder is used for bleaching of cotton in textile industry, bleaching of
wood pulp in paper industry.
Bleaching powder is used as oxidizing agent in many industries, such as
textiles industry, paper industry, etc.
BAKING SODA (NaHCO3 )
Baking soda is another important product which can be obtained using byproducts of chlor-
alkali process. The chemical name of baking soda is sodium hydrogen carbonate (NaHCO3 )
or sodium bicarbonate. Bread soda, cooking soda, bicarbonate of soda, sodium bicarb, bicarb
of soda or simply bicarb, etc. are some other names of baking soda.
Baking soda is obtained by the reaction of brine with carbon dioxide and ammonia. This
is known as Solvay process.
NaCl + CO2 + NH3 + H2O → NH4Cl + NaHCO3
In this process, calcium carbonate is used as the source of CO2 and the resultant calcium
oxide is used to recover ammonia from ammonium chloride.
PROPERTIES OF SODIUM BICARBONATE:
Sodium bicarbonate is white crystalline solid, but it appears as fine powder.
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Sodium hydrogen carbonate is amphoteric in nature.
Sodium hydrogen carbonate is sparingly soluble in water.
Thermal decomposition of sodium hydrogen carbonate (baking soda).
When baking soda is heated, it decomposes into sodium carbonate, carbon dioxide
and water.
2NaHCO3 + heat → Na2CO3 + CO2 + H2O
Sodium carbonate formed after thermal decomposition of sodium hydrogen
carbonate; decomposes into sodium oxide and carbon dioxide on further heating.
Na2CO3 → Na2O + CO2
This reaction is known as dehydration reaction.
USE OF BAKING SODA:
Baking soda is used in making of baking powder, which is used in cooking as
it produces carbon dioxide which makes the batter soft and spongy. Baking
soda is used as antacid.
Baking soda is used in toothpaste which makes the teeth white and plaque free.
Baking soda is used in cleansing of ornaments made of sliver.
Since, sodium hydrogen carbonate gives carbon dioxide and sodium oxide on
strong heating, thus it is used as fire extinguisher.
BAKING POWDER:
Baking powder produces carbon dioxide on heating, so it is used in cooking to make the
batter spongy. Although baking soda also produces carbon dioxide on heating, but it is not
used in cooking because on heating; baking soda produces sodium carbonate along with
carbon dioxide. The sodium carbonate; thus produced; makes the taste bitter.
2NaHCO3 + heat → Na2CO3 + CO2 + H2O
Baking powder is the mixture of baking soda and a mild edible acid. Generally, tartaric acid
is mixed with baking soda to make baking powder.
NaHCO3 + C4H6O6 → CO2 + H2O + Na2C4H4O6
When baking powder (mixture of baking soda and an edible acid) is heated, the sodium
carbonate formed because of heating of baking soda neutralizes after reacting with tartaric
acid and sodium tartarate salt is formed. The smell of sodium tartarate is pleasant and taste is
good. This makes the cake or any other food tasty.
WASHING SODA (SODIUM CARBONATE)
Sodium carbonate is manufactured by the thermal decomposition of sodium
hydrogen carbonate obtained by Solvay process.
NaCl + CO2 + NH3 + H2O → NH4Cl + NaHCO3
NaHCO3 + C4H6O6 → CO2 + H2O + Na2C4H4O6
The sodium carbonate obtained in this process is dry. It is called soda ash or anhydrous
sodium carbonate. Washing soda is obtained by rehydration of anhydrous sodium carbonate.
Na2CO3 + 10H2O → Na2CO3.10H2O
Since there are 10 water molecules in washing soda, hence it is known as Sodium
bicarbonate decahydrate.
Sodium carbonate is a crystalline solid and it is soluble in water when most of the
carbonates are insoluble in water.
USE OF SODIUM CARBONATE:
It is used in cleaning of cloths; especially in rural areas.
In making of detergent cake and powder.
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In removing permanent hardness of water.
It is used in glass and paper industries.
Water of crystallization: Many salts contain water molecule and are known as hydrated salts.
The water molecule present in salt is known as water of crystallization.
Examples:
COPPER SULPHATE PENTAHYDRATE (CuSO4.5H2O)
Blue colour of copper sulphate is due to presence of 5 molecules of water. When copper
sulphate is heated, it loses water molecules and turns into grey-white colour, which is known
as anhydrous copper sulphate. After adding water; anhydrous copper sulphate becomes blue
again.
CuSO4.5H2O + heat → CuSO4
FERROUS SULPHATE HEPTAHYDRATE (FeSO4.7H2O)
The green colour of Ferrous sulphate heptahydrate; commonly known as ferrous sulphate;
is due to the presence of 7 molecules of water in it.
PLASTER OF PARIS
Plaster of Paris is obtained by heating of gypsum, a hydrated salt of calcium.
1 3
CaSO4.2H2O + Heat → CaSO4. H2O + H2O
2 2
After addition of water Plaster of Paris is again converted into gypsum.
1 3
CaSO4. H2O + H2O → CaSO4.2H2O
2 2
Plaster of Paris is used in making of toys, designer false ceiling, etc. Doctors use Plaster
of Paris to set the fractured bone.
INTEXT QUESTIONS PAGE NO. 33
Question 1: What is the common name of the compound CaOCl2?
Answer : The common name of the compound CaOCl2 is bleaching powder.
Question 2: Name the substance which on treatment with chlorine yields bleaching
powder?
Answer : Calcium hydroxide [Ca (OH)2], on treatment with chlorine, yields bleaching powder.
Question 3: Name the sodium compound which is used for softening hard water.
Answer : Washing soda (Na2CO3.10H2O) is used for softening hard water.
Question 4: What will happen if a solution of sodium hydrocarbonate is heated? Give the
equation of the reaction involved.
Answer : When a solution of sodium hydrocarbonate (sodium hydrogencarbonate) is heated,
sodium carbonate and water are formed with the evolution of carbon dioxide gas.
Question 5: Write an equation to show the reaction between Plaster of Paris and water.
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Answer : The chemical equation for the reaction of Plaster of Paris and water can be
represented as
EXERCISE QUESTIONS PAGE NO. 34 and 35
Question 1: A solution turns red litmus blue, its pH is likely to be
(a) 1 (b) 4 (c) 5 (d) 10
Answer : (d) Bases turn red litmus blue and acids turn blue litmus red. Basic solution has a pH
value more than 7. Since the solution turns red litmus blue, its pH is likely to be 10.
Question 2: A solution reacts with crushed egg-shells to give a gas that turns lime-water
milky. The solution contains
NaCl (b) HCl (c) LiCl (d) KCl Answer :
(b) The solution contains HCl.
Question 3: 10 mL of a solution of NaOH is found to be completely neutralised by 8 mL
of a given solution of HCl. If we take 20 mL of the same solution of NaOH, the amount of
HCl solution (the same solution as before) required to neutralise it will be (a) 4 mL (b)
8mL (c) 12 mL (d) 16 mL
Answer : (d) 16 mL of HCl solution will be required.
Question 4: Which one of the following types of medicines is used for treating
indigestion?
(a) Antibiotic (b) Analgesic (c) Antacid (d) Antiseptic Answer : (c) Antacid is
used for treating indigestion.
Question 5: Write word equations and then balanced equations for the reaction taking
place when −
dilute sulphuric acid reacts with zinc granules.
dilute hydrochloric acid reacts with magnesium ribbon.
dilute sulphuric acid reacts with aluminium powder.
dilute hydrochloric acid reacts with iron filings.
Answer : (a) Sulphuric acid + Zinc → Zinc sulphate + Hydrogen
Hydrochloric acid + Magnesium → Magnesium chloride + Hydrogen
Sulphuric acid + Aluminium → Aluminium sulphate + Hydrogen
Hydrochloric acid + Iron → Ferric chloride + Hydrogen
Question 6: Compounds such as alcohols and glucose also contain hydrogen but are not
categorized as acids. Describe an activity to prove it.
Answer : Two nails are fitted on a cork and are kept it in a 100 mL beaker. The nails are then
connected to the two terminals of a 6-volt battery through a bulb and a switch. Some dilute HCl
is poured in the beaker and the current is switched on. The same experiment is then performed
with glucose solution and alcohol solution.
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Observations:
Result:
HCl dissociates into H+ and Cl− ions. These ions conduct electricity in the solution resulting in
the glowing of the bulb. On the other hand, the glucose solution does not dissociate into ions.
Therefore, it does not conduct electricity.
Conclusion:
From this activity, it can be concluded that all acids contain hydrogen but not all compounds
containing hydrogen are acids.
That is why, though alcohols and glucose contain hydrogen, they are not categorised as acids.
Question 7: Why does distilled water not conduct electricity, whereas rain water does?
Answer : Distilled water is a pure form of water and is devoid of any ionic species. Therefore,
it does not conduct electricity. Rain water, being an impure form of water, contains many ionic
species such as acids and therefore it conducts electricity.
Question 8: Why do acids not show acidic behaviour in the absence of water?
Answer : Acids do not show acidic behaviour in the absence of water because the dissociation
of hydrogen ions from an acid occurs in the presence of water only. It is the hydrogen ions that
are responsible for the acidic behaviour.
Question 9: Five solutions A, B, C, D and E when tested with universal indicator showed
pH as 4, 1, 11, 7 and 9, respectively. Which solution is
neutral?
strongly alkaline?
strongly acidic?
weakly acidic?
weakly alkaline?
Neutral → Solution D with pH 7
Strongly alkaline → Solution C with pH 11
Strongly acidic → Solution B with pH 1
Weakly acidic → Solution A with pH 4
Weakly alkaline → Solution E with pH 9
The pH can be arranged in the increasing order of the concentration of hydrogen ions as: 11 <
9<7<4<1
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Question 10: Equal lengths of magnesium ribbons are taken in test tubes A and B.
Hydrochloric acid (HCl) is added to test tube A, while acetic acid (CH3COOH) is added
to test tube B. In which test tube will the fizzing occur more vigorously and why?
Answer : The fizzing will occur strongly in test tube A, in which hydrochloric acid (HCl) is
added. This is because HCl is a stronger acid than CH3COOH and therefore produces hydrogen
gas at a faster speed due to which fizzing occurs.
Question 11: Fresh milk has a pH of 6. How do you think the pH will change as it turns
into curd? Explain your answer.
Answer : The pH of milk is 6. As it changes to curd, the pH will reduce because curd is acidic
in nature. The acids present in it decrease the pH.
Question 12: A milkman adds a very small amount of baking soda to fresh milk.
Why does he shift the pH of the fresh milk from 6 to slightly alkaline?
Why does this milk take a long time to set as curd?
Answer : (a) The milkman shifts the pH of the fresh milk from 6 to slightly alkaline because in
alkaline condition, milk does not set as curd easily.
Since this milk is slightly basic than usual milk, acids produced to set the curd are neutralized
by the base. Therefore, it takes a longer time for the curd to set.
Question 13: Plaster of Paris should be stored in a moisture-proof container. Explain
why?
Answer : Plaster of Paris (POP) should be stored in a moisture-proof container because Plaster
of Paris, a powdery mass, absorbs water (moisture) to form a hard solid known as gypsum.
Question 14: What is a neutralization reaction? Give two examples.
Answer : A reaction in which an acid and base react with each other to give a salt and water is
termed as neutralization reaction. In this reaction, energy is evolved in the form of heat. For
example:(i)
During indigestion (caused due to the production of excess of hydrochloric acid in the
stomach), we administer an antacid (generally milk of magnesia, Mg(OH) 2 which is basic in
nature). The antacid neutralizes the excess of acids and thus gives relief from indigestion.
Question 15: Give two important uses of washing soda and baking soda.
Answer : Two important uses of washing soda and baking soda are as follows:
(1) Washing soda:
It is used in glass, soap, and paper industries.
It is used to remove permanent hardness of water.
(2) Baking soda:
It is used as baking powder. Baking powder is a mixture of baking soda and a mild acid known
as tartaric acid. When it is heated or mixed in water, it releases CO2 that makes bread or cake
fluffy.
It is used in soda-acid fire extinguishers.
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ASSIGNMENT QUESTIONS SET – 1
CHAPTER – 2
ACIDS, BASES AND SALTS
VERY SHORT ANSWER TYPE QUESTIONS
Name two natural indicators.
Name two indicators that are usually used in chemical laboratories to indicate acidic/basic
nature of a solution.
What is the general name of bases that are soluble in water?
What is an acid?
Define base
What is the action of an acid on blue litmus paper?
Name two natural substances that contain acid.
What is the oxide of a metal called?
Are all bases alkalis?
Which type of substance is used to indicate an acid or a base?
What is the common element present in all acids?
Give the name and formula of two mineral acids.
Common salt contains a substance which is hygroscopic. Name the substance and write its
formula.
Name any two organic acids.
What is the common to all bases?
Name two sources of common salt.
How do metals react with acid?
Name two metals that react with a base to produce hydrogen gas.
Which gas is evolved when sodium carbonate reacts with hydrochloric acid?
What happens when carbon dioxide gas is passed into lime water?
Name a sodium compound which loses its water of crystallization on exposure to air.
A compound of metal is obtained mainly from sea water. Write the name and formula of the
compound.
What is the common name and formula of sodium hydroxide?
What is the reaction called in which an acid and a base nullify the effect of each other?
Name the salt which was an important symbol in India’s struggle for freedom?
Name a sodium compound used as a cleansing agent for domestic purposes.
Why does and aqueous solution of an acid conduct electricity?
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The pH of a solution is 4. What is the nature of the solution?
A solution reacts with crushed egg-shells to give a gas that turns lime water milky. Say,
whether the solution contains an acid or a base.
Which type of medicine is used to treat indigestion?
Which compound of a metal is a constituent of many dry soap powders?
Name the acid which is used as a bathroom cleaner.
What is the action of litmus on an aqueous solution of ammonium chloride?
Why is a basic substance used to treat a honey-bee sting?
A solution turns blue litmus re. What is it pH value?
Which one is more acidic, pH = 2 or pH = 5?
Which one of the two solutions is more basic, pH = 8 or pH = 11?
What is the nature of the salt which dissolves in water to produce a solution which turns blue
litmus to red?
A milkman adds some baking soda to fresh milk. How will the pH of the fresh milk change?
What is the pH of a solution which is neither acidic nor basic?
What is the chemical formula of common salt?
Name the process by which sodium hydroxide is made by electrolysis of brine?
Give the chemical name and formula of washing soda?
Mention the property of sodium carbonate that makes it useful as an ingredient for dry soap
powders.
Name the carbonate of a metal which is soluble in water.
What is soda ash?
State whether the aqueous solution of washing soda is acidic or alkaline?
Name the substance which on being treated with chlorine yields bleaching powder.
Write the chemical formula of plaster of paris.
Write an equation to show the reaction between plaster of paris and water.
Write the chemical formula of quicklime.
Name a compound of calcium which is used for whitewashing.
Which compound of calcium is used for making cement and glass?
Write an equation to show the reaction between quicklime and water.
Which compound of calcium is used to produce limelight?
Write the chemical name and formula of baking soda?
Name a compound of sodium which is used in fire extinguisher.
Write the chemical name and formula of bleaching powder?
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+
Two solutions have pH number 4 and 9 respectively which solution has more H ion
concentration?
Which compound of calcium is used for disinfecting water?
Why should cured and sour substances not be kept in brass and copper vessel?
Name a compound of calcium which hardens on being mixed with water.
Write down the molecular formula for one strong and one weak acid.
Explain why plaster of Paris should be stored in a moisture proof container?
Name the gas evolved when dil. sulphuric acid acts on sodium carbonate.
What is the use of common salt in soap industry?
Which compound of calcium is used in paper and textile industries?
What do you observe when a burning candle is brought near the test-tube containing hydrogen
gas?
Name the indicator used to measure pH values over the whole range.
A white, solid substance is used to disinfect water, and it makes wool shrink-proof. Name the
substance.
How many water of crystallization an present in copper sulphate crystals?
Write the name and formula of a compound which contains ten molecules of water of
crystallization?
Name a sodium compound which is used in softening hard water.
A white powdery substance smells of chlorine and is used for disinfecting drinking water.
What is the name of substance?
What happen when anhydrous copper sulphate is moistened with water?
Name the substance produced by the action of chlorine on dry slaked lime.
Name the compound of calcium used for bleaching cloth.
A compound is used to make casts for statues and for holding broken limbs and joints in place.
What is this compound?
Write chemical equation to represent the action of dilute hydrochloric acid on bleaching
powder?
Represent the reaction between plaster of paris and water in the form of an equation.
SHORT ANSWER TYPE QUESTIONS
What is an acid? Give some examples of organic and inorganic acids.
What is a base? Give examples?
What is an indicator? Give some examples of indicators?
What is litmus?
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Describe some natural acid-base indicators, other than litmus.
What are olfactory indicators?
What do you mean by concentrated and dilute acid solutions?
Explain why brass and copper vessels are not used to keep curd and sour substances?
Name the gas which is liberated when metals react with an acid. Give an example. How is the
presence of the gas tested?
HCL, HNO3 etc. show acidic behavior in aqueous solutions but aqueous solutions of alcohol
and glucose do not behave like acids. Explain why?
What would be the nature of solutions when the following salts are dissolved separately in
water?
NaCl
Na2CO3
CH3COONa
CuSO4
(NH4)2SO4
Na2SO4
What are the functions of sodium chloride in human body?
Given below are the pH values of four different liquids : 7.0, 14.0, 4.0, 2.0
Which of these could be that of
lemon juice.
distilled water
1 M sodium hydroxide solution
tomato juice
Why does an aqueous solutions of an acid conduct electricity?
During the dilution of an acid, it is advised that acid should be added to water, not water to
acid. Why?
Ac acid solution is diluted with water. How does the concentration of hydrogen ions change?
What is the pH of a solution?
A metal compound when treated with dilute hydrochloride acid forms calcium chloride and a
gas. The gas evolved extinguishers a burning splinter. Write the equation for the reaction
that occurs.
Why does the colour of dry litmus paper not change in contact with dry HCL gas?
–
How is the concentration of OH ions change when excess of base is dissolved in a a solution
of sodium hydroxide?
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What will happen if solid sodium hydrogencarbonate or a solution of it is heated? Give the
equation of the reaction involved?
Give two important uses of washing soda.
Give two important uses of baking soda.
A baker found that the cake prepared by him was hard and small in size. Which ingredient had
he forgotten to add that would have made the cake fluffy? Give reasons.
How is soda ash obtained from washing soda crystals? Support your answer by a chemical
equation.
How does a fire extinguisher work?
Why is an aqueous solution sodium carbonate alkaline in nature?
A given compound of sodium is used to remove hardness of water and also as a reagent in the
laboratory. Identify the compound and mention two of its uses.
How is bleaching powder prepared? Give the reaction.
What happens when bleaching powder is left exposed to air?
State three important uses of bleaching powder?
(i) Name the chemical used in hospitals for setting fractured bones.
State the name of the above chemical and its formula.
How is the above compound prepared?
What is gypsum? What happens when gypsum is heated to 393k?
Explain giving reasons: “Potassium hydrogentartrate is a component of baking powder used in
making cakes”.
A white amorphous powder emits a greenish yellow gas having a smell of chlorine. It is used to
remove yellowness of white clothes in laundries. Identify the powder. Write the chemical
equation involved in its preparation.
You are provided with two solutions A and B having pH 6 and 8 respectively. Which of the
+
solutions does contain more H ion concentration? Which of them is acidic and which one
basic?
+
Do basic solution also have H ions. If yes, then why are they basic?
What do the farmers do to treat the soil when it becomes too acidic?
What effect does a bee-sting produce on human body? What is its remedy?
What is the chemical substance injected into a man’s skin when (a) an ant stings him (b) a
nettle-leaf stings him?
Suggest remedy to get relief from the effects of the stings.
How are the lives of aquatic animals affected with change in pH of the river water?
Explain the following: “Distilled water does not conduct electricity, but rain water does”.
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Why is an aqueous solution of sodium chloride neutral, whereas that of ammonium chloride
acidic?
An efflorescent white, crystalline substance dissolves in water to produce an alkaline solution.
The substance is used as a cleansing agent. Identify the substance and mention two uses it.
A white, powdery compound of calcium is used for making toys and casts of statues. It hardens
when mixed with water. Identify the compound. Write the chemical equation of its
preparation.
What is the chemical formula of plaster of paris? How is it prepared? State the common and the
chemical names of the compound formed when plaster of paris mixed with water?
State two uses of the following:
Sodium hydroxide
Chlorine
Hydrogen
Hydrochloric acid
(a) What is the common name of the compound CaOCl2.
(b) Name the raw material used for the preparation of plaster of paris.
(c) Which property of plaster of paris is utilized in making casts for broken limbs in
hospitals?
What happens when a cold and concentrate solution of sodium chloride reacts with ammonia
and carbon dioxide? Write the chemical equation of the reaction which takes place.
Write the chemical formula of ammonium chloride. Explain why an aqueous solution of
ammonium chloride is acidic in nature? Illustrate your answer with the help of a chemical
equation.
LONG ANSWER TYPE QUESTIONS
What is baking soda? How is it obtained from sodium chjloride? Mention any two uses of
baking soda.
What is the commercial name of bleaching powder? How is bleaching powder prepared? What
are its different uses?
What do you mean by the strength of an acid? What are strong and weal acids?
What do you mean by the strength of a base? What are strong and weak base?
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Three test tubes A, B and C contain distilled water, a basic solution and an acid solution
separately. How would you identify the contents of the test tubes with the help of a red
litmus paper only?
What are the different uses of sodium carbonate (Washing soda)?
State the important properties of washing soda.
What happens when carbon dioxide gas is passed through limewater? Give equations for the
reactions that take place.
With the help of universal indicator the pH values of solutions A, B, C, D and E were found to
be 5, 2, 12, 7 and 10 respectively. Say which solution is
neutral
strongly base
strongly acidic
weakly acid
weakly basic
Discuss briefly the reactions occurring when a concentrated solution of sodium chloride (brine)
is electrolyzed?
Explain how is washing soda produced using sodium chloride as one of the raw materials?
(a) What is a salt? Give the names and formula of any two salts. Also name the acids and bases
from which these salts may be obtained.
What is meant by hydrated and anhydrous salts? Explain with example.
(a) What is plaster of paris? Write its chemical formula.
How is plaster of paris prepared? Write the chemical equation of the reaction involved.
Explain why plaster of paris should be stored in a moisture proof container.
State two important uses of plaster of paris.
(a) What is bleaching powder? Write its chemical formula.
How is bleaching powder prepared? Write the chemical equation of the reaction involved.
State two important uses of bleaching powder.
(a) What happens when zinc granules are heated with sodium hydroxide solution? Write
chemical equation of the reaction which takes place.
What happens when basses react with nonmetals oxides? Explain with the help of an
example. What does this reaction tell us about the nature of non-metal oxides?
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ASSIGNMENT QUESTIONS SET – 2
CHAPTER – 2
ACIDS, BASES AND SALTS
The colour of neutral litmus solution is a)
red (b) blue (c) purple (d) yellow
Which of the following indicators is an olfactory indicator?
(a) litmus (b) vanilla (c) turmeric (d) phenolphthalein
Which one is suitable method to find the accurate pH value?
(a) pH meter (b) pH paper (c) Universal indicator (d) Litmus solution
Which one of the following statements is correct about universal indicator?
(a) It is a mixture of HCl and NaOH
(b) It is a mixture of many indicators
(c) It is a solution of phenolphthalein in alcohol
(d) It is a solution of phenolphthalein in water.
Which of the following properties are shown by dilute HCl?
(1) It turns blue litmus red
(2) It turns red litmus blue
(3) It reacts with zinc and a gas is evolved
(4) It reacts with solid sodium carbonate to give brisk effervescence
(a) 1 and 2 (b) 1 and 3 (c) 1, 3 and 4 (d) 2, 3 and 4
A teacher gave two test tubes – one containing water and the other containing sodium
hydroxide solution to two students. Then he asked them to identify the test tube
containing sodium hydroxide solution. Which one of the following can be used for
correctly identifying the test tube containing the solution of sodium hydroxide?
(a) Blue litmus (b) Red litmus (c) Sodium carbonate solution (d) Dilute HCl
Metallic oxides are ________ in nature, but non-metallic oxides are __________ in nature.
The information in which alternative completes the given statement?
(a) neutral, acidic (b) acidic, basic (c) basic, neutral (d) basic, acidic
When a drop of unknown solution X is placed on a strip of pH paper, a deep red colour is
produced. This sample is which one of these?
(a) NaOH (b) HCl (c) Water (d) CH3COOH
A student tests a sample drinking water and reports its pH value as 6 at room temperature.
Which one of the following might have been added in water?
Calcium chloride (b) Sodium chloride (c) Sodium bicarbonate (d) Bleaching powder
Solid sodium bicarbonate was placed on a strip of pH paper. The color of the strip
turned red (b) did not change (c) turned green and slightly yellow (d) turned pink
Four drops of red litmus solution were added to each of the following samples. Which one
turns red litmus blue?
Alcohol (b) Distilled water (c) Sodium hydroxide sol (d) HCl
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The pH of which of the following samples can not be found directly using pH paper?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Lemon
juice (b) Dilute HCl (c) Solid sodium bicarbonate (d) Solution of a detergent.
Which of the following natural sources contains oxalic acid?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ lemon (b)
orange (c) tomato (d) tamarind
The acid found in an ant sting is
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ acetic acid
(b) citric acid (c) tartaric acid (d) methanoic acid
To relieve pain caused due to acidity, we can take
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ sour milk
(b) lemon juice (c) orange juice (d) milk of magnesia
What are the products obtained when potassium sulphate reacts with barium iodide in an
aqueous medium?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ KI and
BaSO4 (b) KI, Ba and SO2 (c) K, I2 and BaSO4 (d) K, Ba, I2 and SO2
Which of the following salts is basic in nature?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ NH4NO3
(b) Na2CO3 (c) Na2SO4 (d) NaCl
Which of the following salts has the minimum pH value?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ (NH4)2SO
4 (b) NaHCO3 (c) K2SO4 (d) NaCl
You are given four unknown solutions I, II, III, and IV. The pH values of these solutions are
found to be 3, 7, 8, and 10 respectively. Among the given solutions, which solution has
the highest hydrogen ion concentration?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ I (b) II (c)
III (d) IV
Which one of the following is required to identify the gas evolved when dilute hydrochloric
acid reacts with zinc metal?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ blue litmus
paper (b) red litmus paper (c) a burning slinter (d) lime water
Zinc reacts with an acid as well as with a base to liberate hydrogen. On the basis of this
what should be the nature of the zinc metal?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ basic (b)
acidic (c) amphoteric (d) neutral
When you test the solutions of sodium bicarbonate, sodium hydroxide, hydrochloric acid
and acetic acid with universal indicator, in which case would you get a red colour?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ sodium
bicarbonate (b) hydrochloric acid (c) sodium hydroxide (d) acetic acid
The pH of a sample of pure water is 7 at room temperature. What is its pH when a pinch of
solid sodium bicarbonate is dissolved in it?
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ vary near to
7 (b) less than 7 (c) more than 7 (d) exactly 7
If an unknown solution turns blue litmus red, then the pH of the solution is more likely to
be (a) 12 (b) 10 (c) 7 (d) 4
What is the pH of a 0.00001 molar HCl solution?
(a)1 (b)9 (c)5 (d)4
There are alternate acid base theories that define an acid as any species that can
{hint: According to Bronsted-Lowry theory, an acid is any species that can donate a
proton to another species.}
ĀĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ donate a
proton (2) donate an electron (c) accept a proton (d) accept an electron
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What happens when a solution of an acid is mixed with a solution of a base in a test tube?
The temperature of the solution increases
The temperature of the solution decreases
The temperature of the solution remains the same
Salt formation takes place
(a) (i) only (b) (i) and (iii)
(ii) and (iii) (d) (i) and (iv)
An aqueous solution turns red litmus solution blue. Excess addition of which of the
following solution would reverse the change?
Baking powder
Lime
Ammonium hydroxide solution
Hydrochloric acid
During the preparation of hydrogen chloride gas on a humid day, the gas is usually passed
through the guard tube containing calcium chloride. The role of calcium chloride taken
in the guard tube is to
absorb the evolved gas
moisten the gas
absorb moisture from the gas
absorb Cl– ions from the evolved gas
Compounds such as alcohols and glucose contain hydrogen but are not categorized as
acids. Describe an activity to prove it.
Why does distilled water not conduct electricity, whereas rain water does?
Why do acids not show acidic behavior in the absence of water?
Five solutions A, B, C, D and E when tested with universal indicator showed pH as 4, 1,
11, 7 and 9, respectively, which solution is: a) neutral b) strongly alkaline? c) strongly
acidic d) weakly acidic e) weakly alkaline
Arrange the pH in increasing order of hydrogen ion concentration.
What is a neutralization reaction? Give two examples.
What happens when an acid or base is mixed with water?
Equal lengths of magnesium ribbons are taken in test tubes A and B. Hydrochloric acid is
added to test tube A, while acetic acid is added to test tube B. The concentrations taken for
both the acids are same in which test tube the reaction occur more vigorously and why?
Fresh milk has a pH of 6. How does the pH change as it turns to curd? Explain your
answer.
A milkman adds a very small amount of baking soda to fresh milk.
a) Why does he shift the pH of the fresh milk from 6 to slightly
alkaline? b) Why does this milk take a long time to set as curd?
Why does tooth decay start when the pH of mouth is lower than 5.5?
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 59 -
Ȁ⸀ĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ How does the flow
of acid rain water into a river make the survival of aquatic life in a river difficult?
Ȁ⸀ĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Dry hydrogen
chloride gas does not turn blue litmus whereas hydrochloric acid does. Why?
Ȁ⸀ĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ What is
meant by “water of crystallization” of a substance? Describe an activity to
demonstrate water of crystallization.
Ȁ⸀ĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Plaster of paris
should be stored in a moisture – proof container. Explain why?
Ȁ⸀ĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ What is baking
powder? How does it make the cake soft and spongy?
Ȁ⸀ĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Give two
important uses of washing soda and baking soda.
Ȁ⸀ĀЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀĀĀ̀ЀȀ̀⠀Ā⤀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ WHO AM I?
I can roughly measure pH value from 0-14.
I am called antichlor and am used to remove excess chlorine from clothes when
treated with bleaching powder.
I am a product of gypsum and am used to making chalks and fire proof materials. I
am a compound of calcium and can be used for disinfecting drinking water as well as
for decolourisation.
I give different smell in acid and base solution.
I am an oxide capable of showing properties for both acids and bases.
I am a covalent compound and conducts electricity in aqueous
medium. I am a salt of potassium hydroxide and nitric acid.
I am the term used when a solid becomes liquid when exposed to moist
air. I am derived from tomato and turn blue litmus into red.
47.The colour of methyl orange indicator in acidic medium is: ( )
a) Yellow b) green c) orange d) red
48.The colour of phenolphthalein indicator in basic solution is: ( )
a) Yellow b) green c) pink d) orange
49.What is the colour methyl orange in alkaline medium? ( )
a) orange b) yellow c) red d) blue
50.A solution turns red litmus blue, its pH will be: ( )
a) 1 b) 4 c) 5 d) 10
A solution reacts with crushed egg-shells to give a gas that turns lime-water Milky, the
solution contains: ( )
a) NaCl b) HCl c) LiCl d) KCl
52. Why is universal indicator a better one than litmus paper? ( )
Litmus paper can only be used for acids.
Litmus paper can only be used for alkalis.
Universal indicator goes green if something is neutral.
Universal indicator is useful for all ranges of pH of the solution.
53. Water soluble bases are known as? ( )
a) neutral b) base c) acid d) alkali
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Which of one of the following pairs of substances when mixed together produces table salt. ( )
Sodium thiosulphate and sulpur dioxide
Hydro chloric acid and sodium hydroxide
Chlorine and oxygen
Nitric acid and sodium hydrogen carbonate
55.What colour would hydrochloric acid (pH=1) turn universal indicator. ( )
a) Orange b) purple c) yellow d) red
56.Which one of the following medicines is used for treating indigestion. ( )
a) Antibiotic b) analgesic c) antacid d) antiseptic
57.If magnesium reacts with hydrochloric acid, what gas is produced? ( )
a) Hydrogen b) oxygen c) carbon dioxide d) chlorine
58.Which of the following is the most accurate way of representing neutralization? ( )
a) Acid + base → neutral solution
b) Acid + base → salt + water
c) Acid + base → sodium chloride + hydrogen
d) Acid + base → acidic solution
Classify the following examples as acid, base or salt:
Mg (OH)2 ____________ KCl _____________ HCl ____________
H3 PO4 ____________ HBr _____________ Al (OH)3 _____________
KNO2 ____________ NaCl _____________
Ba (OH)2 ____________ HFO4 _____________
Fill in the following blanks:
A ____________ taste is a characteristic property of all acids in aqueous solution.
Acids react with some metals to produce _____________ gas
Aqueous acid solutions conduct electricity because they have ________
Acid reacts with base to produce a ________ and water.
Acid turn methy orange to ____________ colour. Bases
tend to taste _____________ and feel ____________
Aqueous basic solutions conduct electricity because they have ___________.
Bases react with ______________ to produce a salt and ______________
Bases turn phenolphthalein to _________________ colour.
Match the following:
a) Plaster of Paris () 1)CaO Cl2
b) Gypsum () 2)NaHCO3
c) Bleaching powder () 3)Na2 CO3
d) Baking soda () 4)CaSO4 .½H2O
e) Washing soda () 5)CaSO4 .2H2O
Which of the following salts does not contain water of crystallisation?
Blue vitriol
Baking soda
Washing soda
Gypsum
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Sodium carbonate is a basic salt because it is a salt of
strong acid and strong base
weak acid and weak base
strong acid and weak base
weak acid and strong base
Calcium phosphate is present in tooth enamel. Its nature is
(a) basic (b) acidic (c) neutral (d) amphoteric
Ȁ⸀ĀĀĀĀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ㴀ĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ A sample of soil is
mixed with water and allowed to settle. The clear supernatant solution turns the pH
paper yellowish-orange. Which of the following would change the colour of this pH
paper to greenish-blue?
Lemon juice
Vinegar
Common salt
An antacid
Ȁ⸀ĀĀĀĀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ㴀ĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Which of the following
gives the correct increasing order of acidic strength?
Water <Acetic acid <Hydrochloric acid
Water <Hydrochloric acid <Acetic acid
Acetic acid <Water <Hydrochloric acid
Hydrochloric acid <Water <Acetic acid
Ȁ⸀ĀĀĀĀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ㴀ĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ If a few drops of a
concentrated acid accidentally spills over the hand of a student, what should be done?
Wash the hand with saline solution
Wash the hand immediately with plenty of water and apply a paste of sodium
hydrogencarbonate
After washing with plenty of water apply solution of sodium hydroxide on the hand
Neutralise the acid with a strong alkali
Ȁ⸀ĀĀĀĀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ㴀ĀȀ⸀ĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀĀᜀ Sodium
hydrogencarbonate when added to acetic acid evolves a gas. Which of the
following statements are true about the gas evolved?
It turns lime water milky
It extinguishes a burning splinter
It dissolves in a solution of sodium hydroxide
It has a pungent odour
(i) and (ii) (b) (i), (ii) and (iii)
(ii), (iii) and (iv) (d) (i) and (iv)
Common salt besides being used in kitchen can also be used as the raw material for making
washing soda
bleaching powder
baking soda
slaked lime
(i) and (ii) (b) (i), (ii) and (iv)
(i) and (iii) (d) (i), (iii) and (iv)
One of the constituents of baking powder is sodium hydrogen carbonate, the other
constituent is
hydrochloric acid
tartaric acid
acetic acid
sulphuric acid
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To protect tooth decay we are advised to brush our teeth regularly. The nature of the tooth
paste commonly used is
acidic
neutral
basic
corrosive
Which of the following statements is correct about an aqueous solution of an acid and of a
base?
Higher the pH, stronger the acid
Higher the pH, weaker the acid
Lower the pH, stronger the base
Lower the pH, weaker the base
(a) (i) and (iii) (b) (ii) and (iii)
(c) (i) and (iv) (d) (ii) and (iv)
The pH of the gastric juices released during digestion is
(a) less than 7
(b) more than 7
(c) equal to 7
(d) equal to 0
Which of the following phenomena occur, when a small amount of acid is added to water?
Ionisation
Neutralisation
Dilution
Salt formation
(i) and (ii) (b) (i) and (iii)
(ii) and (iii) (d) (ii) and (iv)
Which one of the following can be used as an acid–base indicator by a visually impared
student?
Litmus
Turmeric
Vanilla essence
Petunia leaves
Which of the following substance will not give carbon dioxide on treatment with dilute
acid?
Marble
Limestone
Baking soda
Lime
Which of the following is acidic in nature?
Lime juice
Human blood
Lime water
Antacid
In an attempt to demonstrate electrical conductivity through an electrolyte, the following
apparatus (see below Figure) was set up. Which among the following statement(s)
is(are) correct?
Bulb will not glow because electrolyte is not acidic
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Bulb will glow because NaOH is a strong base and furnishes ions for conduction.
Bulb will not glow because circuit is incomplete
Bulb will not glow because it depends upon the type of electrolytic solution
(i) and (iii) (b) (ii) and (iv)
(ii) only (c) (iv) only
Which of the following is used for dissolution of gold?
Hydrochloric acid
Sulphuric acid
Nitric acid
Aqua regia
Which of the following is not a mineral acid?
Hydrochloric acid
Citric acid
Sulphuric acid
Nitric acid
Which among the following is not a base?
NaOH
KOH
NH4OH
C2H5 OH
Which of the following statements is not correct?
All metal carbonates react with acid to give a salt, water and carbon dioxide
All metal oxides react with water to give salt and acid
Some metals react with acids to give salt and hydrogen
Some non metal oxides react with water to form an acid
Which of the following is(are) true when HCl (g) is passed through water?
It does not ionise in the solution as it is a covalent compound.
It ionises in the solution
It gives both hydrogen and hydroxyl ion in the solution
It forms hydronium ion in the solution due to the combination of hydrogen ion with
water molecule
(a) (i) only (b) (iii) only
(c) (ii) and (iv) (d) (iii) and (iv)
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84. Which of the following statements is true for acids?
(a) Bitter and change red litmus to blue
(b) Sour and change red litmus to blue
(c) Sour and change blue litmus to red
(d) Bitter and change blue litmus to red
85. Which of the following are present in a dilute aqueous solution of hydrochloric acid?
–
(a) H3O+ + Cl
–
(b) H3O+ + OH
– –
(c) Cl + OH
(d) unionised HCl
86. Identify the correct representation of reaction occurring during chloralkali process
(a) 2NaCl(l) + 2H O(l) → 2NaOH(l) + Cl(g) + H (g)
2 2 2
(b) 2NaCl(aq) + 2H2O(aq) → 2NaOH(aq) + Cl2(g) + H2 (g)
(c) 2NaCl(aq) + 2H O(l) → 2NaOH(aq) + Cl(aq) + H (aq)
2 2 2
(d) 2NaCl (aq) + 2H O (l) → 2NaOH (aq) + Cl(g) + H (g)
2 2 2
What will be the action of the following substances on litmus paper? Dry HCl gas,
Moistened NH3 gas, Lemon juice, Carbonated soft drink, Curd, Soap solution.
Name the acid present in ant sting and give its chemical formula. Also give the common
method to get relief from the discomfort caused by the ant sting.
A student prepared solutions of (i) an acid and (ii) a base in two separate beakers. She
forgot to label the solutions and litmus paper is not available in the laboratory. Since
both the solutions are colourless, how will she distinguish between the two?
How would you distinguish between baking powder and washing soda by heating?
Salt - A commonly used in bakery products on heating gets converted into another salt B
which itself is used for removal of hardness of water and a gas C is evolved. The gas C
when passed through lime water, turns it milky. Identify A, B and C.
In one of the industrial processes used for manufacture of sodium hydroxide, a gas X is
formed as by product. The gas X reacts with lime water to give a compound Y which
is used as a bleaching agent in chemical industry. Identify X and Y giving the
chemical equation of the reactions involved.
What are strong and weak acids? In the following list of acids, separate strong acids from
weak acids. Hydrochloric acid, citric acid, acetic acid, nitric acid, formic acid, sulphuric
acid.
When zinc metal is treated with a dilute solution of a strong acid, a gas is evolved, which is
utilised in the hydrogenation of oil. Name the gas evolved. Write the chemical equation of
the reaction involved and also write a test to detect the gas formed.
In the following schematic diagram for the preparation of hydrogen gas as shown in below
Figure, what would happen if following changes are made?
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In place of zinc granules, same amount of zinc dust is taken in the test tube
Instead of dilute sulphuric acid, dilute hydrochloric acid is taken
In place of zinc, copper turnings are taken
Sodium hydroxide is taken in place of dilute sulphuric acid and the tube is heated.
For making cake, baking powder is taken. If at home your mother uses baking soda instead of
baking powder in cake,
how will it affect the taste of the cake and why?
how can baking soda be converted into baking powder?
what is the role of tartaric acid added to baking soda?
A metal carbonate X on reacting with an acid gives a gas which when passed through a
solution Y gives the carbonate back. On the other hand, a gas G that is obtained at anode
during electrolysis of brine is passed on dry Y, it gives a compound Z, used for
disinfecting drinking water. Identity X, Y, G and Z.
A dry pellet of a common base B, when kept in open absorbs moisture and turns sticky. The
compound is also a by–product of chloralkali process. Identify B. What type of reaction
occurs when B is treated with an acidic oxide? Write a balanced chemical equation for
one such solution.
A sulphate salt of Group 2 element of the Periodic Table is a white, soft substance, which can
be moulded into different shapes by making its dough. When this compound is left in open
for some time, it becomes a solid mass and cannot be used for moulding purposes.
Identify the sulphate salt and why does it show such a behaviour? Give the
reaction involved.
Identify the compound X on the basis of the reactions given below. Also, write the name
and chemical formulae of A, B and C.
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CHAPTER – 3
METALS AND NON-METALS
Metals occupy the bulk of the periodic table, while non-metallic elements can only be found on
the right-hand-side of the Periodic Table . A diagonal line, drawn from boron (B) to polonium
(Po), separates the metals from the nonmetals. Most elements on this line are metalloids,
sometimes called semiconductors. This is because these elements exhibit electrical properties
intermediate to both, conductors and insulators. Elements to the lower left of this division - line
are called metals, while elements to the upper right of the division - line are called non-metals.
On the basis of their general physical and chemical properties, every element in the
periodic table can be termed either a metal or a nonmetal.
PHYSICAL PROPERTIES OF METALS:
Physical state - Metals are solids at room temperature e.g. sodium, aluminium, potassium,
magnesium. There are exceptions to this. Mercury and gallium are metals but they are in
liquid state at room temperature.
Luster – Metals have a shining surface called luster when freshly prepared. They have a
quality of reflecting light from their surface and they can be polished e.g. metals like gold,
silver, copper show this property.
Malleability - Metals can be beaten into thin sheets. This property is called malleability.
Due to this property, metals can be rolled into sheets e.g. aluminium, copper, zinc can be
beaten into sheets.
Ductility - Metals can be drawn into thin wires. This property is called ductility. For
example, 100 grams of silver can be drawn into a thin wire about 200 meters long.
Hardness – Metals are generally hard e.g. iron, cobalt, nickel. There are few exceptions to
this. Sodium and potassium are soft and they can be cut with a knife.
Sound: Metals produce ringing sound, so, metals are called sonorous. Sound of metals is
also known as metallic sound. This is the cause that metal wires are used in making musical
instruments.
Conduction – Generally, metals are good conductors of heat and electricity because they
have free electrons. Silver and copper are the two best conductors . Relatively, lead and
bismuth are poor conductors of heat and electricity.
Density - Metals generally have high density and they are heavy. Iridium and osmium have
the highest densities while lithium has the lowest density.
Melting and boiling point – Metals usually have high melting point and boiling point. For
example, iron, cobalt and nickel have high melting and boiling point. Tungsten has the
highest melting point. There are some exceptions to this. For example , most of the alkali
metals have low melting and boiling point.
Strength: Most of the metals are strong and have high tensile strength. Because of this big
structures are made using metals, such as copper and iron.
Color: Most of the metals are grey in color. But gold and copper are exceptions.
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INTEXT QUESTIONS PAGE NO. 40
Question 1: Give an example of a metal which
(i) is a liquid at room temperature. (ii) can be easily cut with a knife.
(iii) is the best conductor of heat. (iv) is a poor conductor of heat.
Answer : (i) Metal that exists in liquid state at room temperature → Mercury
Metal that can be easily cut with a knife → Sodium
Metal that is the best conductor of heat → Silver
Metals that are poor conductors of heat → Mercury and lead
Question 2: Explain the meanings of malleable and ductile.
Answer : Malleable: Substances that can be beaten into thin sheets are called malleable. For
example, most of the metals are malleable.
Ductile: Substances that can be drawn into thin wires are called ductile. For example, most of
the metals are ductile.
CHEMICAL PROPERTIES OF METALS
REACTION WITH OXYGEN:
Most of the metals form respective metal oxides when react with oxygen.
Metal + Oxygen → Metal oxide
Examples:
Reaction of magnesium metal with oxygen: Magnesium metal gives magnesium oxide when
reacts with oxygen. Magnesium burnt with dazzling light in air and produces lot of heat.
2Mg + O2 → 2MgO
Reaction of aluminium metal with oxygen: Aluminium metal does not react with oxygen at
room temperature but it gives aluminium oxide when burnt in air.
4Al + 3O2 → 2Al2O3
Reaction of potassium with oxygen: Potassium metal forms potassium oxide when reacts
with oxygen.
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4K + O2 → 2K2O
Reaction of sodium with oxygen: Sodium metal forms sodium oxide when reacts with
oxygen.
4Na + O2 → 2Na2O
Lithium, potassium, sodium, etc. are known as alkali metals. Alkali metals react vigorously
with oxygen.
Reaction of Iron metal with oxygen: Iron does not react with oxygen at room temperature.
But when iron is heated strongly in air, it gives iron oxide.
3Fe + 2O2 → Fe3O4
Iron fillings give sparkle in flame when burnt.
Reaction of copper metal with oxygen: Copper does not react with oxygen at room
temperature but when burnt in air, it gives copper oxide.
2Cu + O2 → 2CuO
Reaction of zinc metal with oxygen: Zinc does not react with oxygen at room temperature.
But it gives zinc oxide when heated strongly in air.
2Zn + O2 → 2ZnO
REACTION OF METALS WITH WATER:
Metals form respective metal hydroxide and hydrogen gas when react with
water. Metal + Water → Metal hydroxide + Hydrogen
Most of the metals do not react with water. However, alkali metals react vigorously with water.
Examples:
Reaction of sodium metal with water: Sodium metal forms sodium hydroxide and liberates
hydrogen gas along with lot of heat when reacts with water.
Na + H2O → NaOH + H2
Reaction of aluminium metal with water: Reaction of aluminium metal with cold water is
too slow to come into notice. But when steam is passed over aluminium metal; aluminium
oxide and hydrogen gas are produced.
2Al + 3H2O → Al2O3 + 2H2
Reaction of zinc metal with water: Zinc metal produces zinc oxide and hydrogen gas when
steam is passed over it. Zinc does not react with cold water.
Zn + H2O → ZnO + H2
Reaction of Iron with water: Reaction of iron with cold water is very slow and come into
notice after a long time. Iron forms rust (iron oxide) when reacts with moisture present in
atmosphere.
Iron oxide and hydrogen gas are formed by passing of steam over iron metal.
3Fe + 4H2O → Fe3O4 + 4H2
Reaction of potassium metal with water: Potassium metal forms potassium hydroxide and
liberates hydrogen gas along with lot of heat when reacts with water.
K+H2O→ KOH+H2
Reaction of calcium metal with water: Calcium forms calcium hydroxide along with
hydrogen gas and heat when reacts with water.
Ca + 2H2O → Ca(OH)2 + H2
Reaction of magnesium metal with water: Magnesium metal reacts with water slowly and
forms magnesium hydroxide and hydrogen gas.
Mg + 2H2O → Mg(OH)2 + H2
When steam is passed over magnesium metal, magnesium oxide and hydrogen gas are
formed.
Mg + H2O → MgO + H2
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REACTION OF METALS WITH DILUTE ACID:
Metals form respective salts when react with dilute acid.
Metal + dil. acid → Metal salt + Hydrogen
Examples:
Reaction of aluminium with dilute hydrochloric acid: Aluminium chloride and hydrogen gas
are formed.
2Al + 6HCl → 2AlCl3 + 3H2
Reaction of zinc with dilute sulphuric acid: Zinc sulphate and hydrogen gas are formed
when zinc reacts with dilute sulphuric acid. This method is used in laboratory to produce
hydrogen gas.
Zn + H2SO4 → ZnSO4 + H2
Reaction of sodium metal with dilute acid: Sodium metal gives sodium chloride and
hydrogen gas when react with dilute hydrochloric acid.
2Na + 2HCl → 2NaCl + H2
Reaction of potassium with dilute sulphuric acid: Potassium sulphate and hydrogen gas are
formed when potassium reacts with dilute sulphuric acid.
2K + H2SO4 → K2SO4 + H2
Reaction of magnesium metal with dilute hydrochloric acid: Magnesium chloride and
hydrogen gas are formed when magnesium reacts with dilute hydrochloric acid.
Mg + 2HCl → MgCl2 + H2
Copper, gold and silver are known as noble metals. These do not react with water or dilute
acids.
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METAL OXIDES: CHEMICAL PROPERTIES
Metal oxides are basic in nature. Aqueous solution of metal oxides turns red litmus blue.
REACTION OF METAL OXIDES WITH WATER:
Most of the metal oxides are insoluble in water. Alkali metal oxides are soluble in water.
Alkali metal oxides give strong base when dissolved in water.
Examples:
Reaction of sodium oxide with water: Sodium oxide gives sodium hydroxide when reacts
with water.
Na2O + H2O → 2NaOH
Reaction of magnesium oxide with water: Magnesium oxide gives magnesium hydroxide
with water.
MgO + H2O → Mg(OH)2
Reaction of potassium oxide with water: Potassium oxide gives potassium hydroxide when
reacts with water.
K2O + H2O → 2KOH
Reaction of zinc oxide and aluminium oxide: Aluminium oxide and zinc oxide are insoluble
in water. Aluminium oxide and zinc oxide are amphoteric in nature. An amphoteric
substance shows both acidic and basic character. It reacts with base like acid and reacts
with acid like a base.
When zinc oxide reacts with sodium hydroxide, it behaves like an acid. In this reaction,
sodium zicate and water are formed.
ZnO + 2NaOH → Na2ZnO2 + H2O
Zinc oxide behaves like a base when reacts with acid. Zinc oxide gives zinc chloride and
water on reaction with hydrochloric acid.
ZnO + 2HCl → ZnCl2 + H2O
In similar way aluminium oxide behaves like a base when reacts with an acid and behaves
like an acid when reacts with a base.
Aluminium oxide gives sodium aluminate along with water when reacts with sodium
hydroxide.
Al2O3 + 2NaOH → 2NaAlO2 + H2O
Aluminium oxide gives aluminium chloride along with water when it reacts with
hydrochloric acid.
Al2O3 + 6HCl → 2AlCl3 + 3H2O
REACTIVITY SERIES OF METALS
A series of metallic elements arranged in the increasing or decreasing order of their reactivity is
called a reactivity series of metals.
In the reactivity series, copper, gold, and silver are at the bottom and hence least reactive.
These metals are known as noble metals.
The most active metal, potassium, is at the top of the list and the least reactive metal, gold, is at
the bottom of the list. Although hydrogen is a non-metal it is included in the activity series due
to the fact that it behaves like a metal in most chemical reactions i.e., the hydrogen ion has a
positive charge [H+] like other metals.
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Following points become evident from the activity series of metals.
The higher the metal in the series, the more reactive it is i.e., its reaction is fast and more
exothermic.
This also implies that the reverse reaction becomes more difficult i.e., the more reactive a
metal, the more difficult it is to extract it from its ore. The metal is also more susceptible to
corrosion with oxygen and water.
The reactivity series can be established by observation of the reaction of metals with water,
oxygen or acids.
Within the general reactivity or activity series, there are some periodic table trends:
Down Group 1(I) the "Alkali Metals", the activity increases Cs > Rb > K > Na > Li.
Down Group 2(II) the activity increases e.g., Ca > Mg.
In the same period, the Group 1 metal is more reactive than the group II metal and the
group II metal is more reactive than the Group III metal and all three are more reactive
than the "Transition Metals". e.g., Na > Mg > Al (in Period 3) and K > Ca > Ga > Fe/Cu
/ Zn etc. (in Period 4)
REACTION OF METALS WITH SOLUTION OF OTHER METAL SALTS:
Reaction of metals with solution of other metal salt is displacement reaction. In this reaction
more reactive metal displace the less reactive metal from its salt.
Metal A + Salt of metal B → Salt of metal A + Metal B
Examples:
Iron displaces copper from copper sulphate solution.
Fe + CuSO4 → FeSO4 + Cu
Similarly, aluminium and zinc displace copper from the solution of copper
sulphate. 2Al + 3CuSO4 → Al2(SO4 ) 3 + 3Cu
Zn + CuSO4 → ZnSO4 + Cu
In all the above examples, iron, aluminium and zinc are more reactive than copper. That’s why
they displace copper from its salt solution.
When copper is dipped in the solution of silver nitrate, it displaces silver and forms copper
nitrate.
Cu + 2AgNO3 → Cu(NO3 )2 + 2Ag
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In this reaction copper is more reactive than silver and hence displace silver from silver nitrate
solution forming copper nitrate.
Silver metal does not react with copper sulphate solution. Because silver is less reactive than
copper and not able to displace copper from its salt solution.
Ag + CuSO4 → No reaction
Similarly, when gold is dipped in the solution of copper nitrate, no reaction takes place.
Because copper is more reactive than gold.
Au + CuSO4 → No reaction
In similar way no reaction takes place when copper is dipped in the solution of aluminium
nitrate. Because copper is less reactive than aluminium.
Al(NO3 )3 + Cu → No reaction
PHYSICAL PROPERTIES OF NON-METALS
Physical state – Non-metals can exist in solid or liquid or gaseous state at room
temperature. . For example, carbon, sulphur, phosphorus, iodine are in solid state, bromine
is in liquid state while oxygen, nitrogen, chlorine are in gaseous state at room temperature.
Luster – Non-metals do not have luster. They do not reflect light from their surface.
(exception – diamond and iodine ) Non-metals have dull appearance. For example, sulphur,
phosphorus and carbon show this property.
Malleability - Non-metals are non-malleable. If solids, they are brittle i.e. they break or
shatter on hammering. For example, coal, sulphur, phosphorus are brittle.
Ductility – Non-metals can not be drawn into thin wires. So they are not ductile.
Hardness – Non-metals are usually not hard. They are soft. For example, coal, sulphur and
phosphorus are soft. Diamond is exception to this. It is the hardest substance known.
Sonority: Non-metals are not sonorous, i.e. they do not produce a typical sound no being
hit.
Conduction - Non- metals are usually poor conductors of heat and electricity. However,
carbon in the form of gas carbon and graphite is exception to this. These forms of carbon
are good conductors of electricity.
Density – Non- metals which are gases have low density. Solid non-metals have low to
moderate density. They are medium light. For example, sulphur, phosphorus and boron
have densities 1.82, 2.07 and 2.34 respectively. . However, diamond has high density which
is about 3.5.
Melting and boiling point – Non-metals usually have low melting and boiling points. For
example, phosphorus, sulphur, and iodine have melting points 440, 1150 and 1140 C
respectively and boiling points 2800 , 4450 and 1840C respectively. . However, carbon,
silicon and boron possess very high melting and boiling points.
Tensile strength – Non-metals have low tensile strength i.e. they have no tenacity.
Color: Non-metals are of many colors.
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CHEMICAL PROPERTIES OF NON-METALS
REACTION OF NON-METALS WITH OXYGEN:
Non-metals form respective oxide when react with oxygen.
Non-metal + Oxygen → Non-metal oxide
Examples:
When carbon reacts with oxygen, carbon dioxide is formed along with production of
heat. C + O2 → CO2 + Heat
When carbon is burnt in insufficient supply of air, it forms carbon monoxide. Carbon
monoxide is a toxic substance. Inhaling of carbon monoxide may prove fatal.
2C + O2 → 2CO + Heat
Sulphur gives sulphur dioxide when react with oxygen. Sulphur caught fire when exposed to
air.
S+O2→ SO2
When hydrogen reacts with oxygen it gives water.
2H2 + O2 → 2H2O
NON-METAL OXIDE:
Non-metal oxides are acidic in nature. Solution of non-metal oxides turns blue litmus red.
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Examples:
Carbon dioxide gives carbonic acid when dissolved in water.
CO2 + H2O → H2CO3
Sulphur dioxide gives sulphurous acid when dissolved in water.
SO2 + H2O → H2SO3
Sulphur dioxide gives sulphur trioxide when it reacts with oxygen.
2SO2 + O2 → 2SO3
Sulphur trioxide gives sulphuric acid when dissolved in water.
SO3 + H2O → H2SO4
REACTION OF NON-METAL WITH CHLORINE:
Non metals give respective chloride when they react with chlorine gas.
Non-metal + Chlorine → Non-metal chloride
Examples:
Hydrogen gives hydrogen chloride and phosphorous gives phosphorous trichloride when
react with chlorine.
H2 + Cl2 → 2HCl
P4 + 6Cl2 → 4PCl3
REACTION OF METAL AND NON-METAL
Many metals form ionic bonds when they react with non-metals. Compounds so formed are
known as ionic compounds.
Ions: Positive or negative charged atoms are known as ions. Ions are formed because of loss or
gain of electrons. Atoms form ion to obtain electronic configuration of nearest noble gas, this
means to obtain stable configuration.
Positive ion: A positive ion is formed because of loss of electrons by an atom. Following are
some examples of positive ions.
Examples:
Sodium forms sodium ion because of loss of one electron. Because of loss of one electron;
one positive charge comes over sodium.
+ −
Na → Na + e
Similarly; potassium gets one positive charge by loss of one electron.
+ −
K→K +e
Magnesium forms positive ion because of loss of two electrons. Two positive charges come
over magnesium because of loss of two electrons.
++ −
Mg → Mg + 2e
Similarly calcium gets two positive charges over it by loss of two
++ −
electrons. Ca → Ca + 2e
Negative ion: A negative ion is formed because of gain of electron. Some examples are given
below.
Examples:
Chlorine gains one electron in order to achieve stable configuration. After loss of one
electron chlorine gets one negative charge over it forming chlorine ion.
− −
Cl + e → Cl
Similarly, fluorine gets one negative charge over it by gain of one electron forming chloride
ion; in order to achieve stable configuration.
− −
F+e →F
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Oxygen gets two negative charge over it by gain of two electrons forming oxide ion; in
order to obtain stable configuration.
− −−
O + 2e → O
USES OF METALS
Metals find number of applications. Some of them are given below.
Zinc metal is used for galvanizing iron , in anti corrosion material, in medicinal fields
and in alloys.
Iron is used as a construction material in bridges, houses, ships etc. Iron, in the form of
steel is used for making domestic utensils.
Tin is used for soldering, for preparing foils, for metal coatings to prevent chemical
action and corrosion, for panel lighting etc.
Lead is used in making water pipes, in pigments, batteries, in alloys etc.
Titanium finds extensive use in aircraft industries
Pure metals, which display zero resistance to electrical currents, are called
superconductors. Hg, Nb are examples of superconductors. They become superconductors
below a critical temperature of 4.2 K and 9.2 K respectively. Superconductors have many
applications in research and industry.
Almost all metals including Zr, Ti find wide applications in atomic and space
programmes and experiments.
Mercury is used in thermometers.
Silver, gold and platinum are precious metals and they are used in making ornaments.
Radioactive metals like uranium and plutonium are used in nuclear power plants to produce
atomic energy via nuclear fission.
USES OF NON - METALS
Non - metals find number of applications. Some of them are given below.
Sulphur is used in making compounds like sulpha drugs, sulphuric acid, in matches, in
gun powder , for vulcanization of rubber etc.
Boron, in the form of compound borax, is used in making skin ointments.
Phosphorus is used in making crackers.
Oxygen is used for respiration.
Chlorine, in the form of bleaching powder, is used for purification of water.
Carbon is used as a fuel, as electrodes ( graphite ), as a reducing agent in metallurgy.
Oxygen, hydrogen and nitrogen are used by all living things, they are the 'building blocks'
of life.
Iodine is used to prevent thyroid problems.
Bromine is used in the preparation of dyes.
Some compounds of fluorine (such as sodium fluoride, stannous fluoride ) are added
to toothpastes to prevent dental decays or formation of cavities.
INTEXT QUESTIONS PAGE NO. 46
Question 1: Why is sodium kept immersed in kerosene oil?
Answer : Sodium and potassium are very reactive metals and combine explosively with air as
well as water. Hence, they catch fire if kept in open. Therefore, to prevent accidental fires and
accidents, sodium is stored in kerosene oil.
Question 2: Write equations for the reactions of
iron with steam
calcium and potassium with water
Answers:
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Question 3: Samples of four metals A, B, C and D were taken and added to the following
solution one by one. The results obtained have been tabulated as follows.
Use the Table above to answer the following questions about metals A, B, C and D.
Which is the most reactive metal?
What would you observe if B is added to a solution of copper (II) sulphate?
Arrange the metals A, B, C and D in the order of decreasing reactivity.
Answer: Explanation
A + FeSO4 → No reaction, i.e., A is less reactive than iron
A + CuSO4 →Displacement, i.e., A is more reactive than copper B
+ FeSO4 → Displacement, i.e., B is more reactive than iron B +
ZnSO4 →No reaction, i.e., B is less reactive than zinc
C + FeSO4 → No reaction, i.e., C is less reactive than iron C +
CuSO4 →No reaction, i.e., C is less reactive than copper C +
ZnSO4 →No reaction, i.e., C is less reactive than zinc
C + AgNO3 → Displacement, i.e., C is more reactive than silver
D + FeSO4/CuSO4/ZnSO4/AgNO3 →No reaction, i.e., D is less reactive than iron, copper,
zinc, and silver
From the above equations, we obtain:
B is the most reactive metal.
If B is added to a solution of copper (II) sulphate, then it would displace copper. B
+ CuSO4 →Displacement
The arrangement of the metals in the order of decreasing reactivity is:
B>A>C>D
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Question 4: Which gas is produced when dilute hydrochloric acid is added to a reactive
metal? Write the chemical reaction when iron reacts with dilute H2SO4.
Answer: Hydrogen gas is evolved when dilute hydrochloric acid is added to a reactive metal.
When iron reacts with dilute H2SO4, iron (II) sulphate with the evolution of hydrogen gas is
formed.
Question 5: What would you observe when zinc is added to a solution of iron (II)
sulphate? Write the chemical reaction that takes place.
Answer: Zinc is more reactive than iron. Therefore, if zinc is added to a solution of iron (II)
sulphate, then it would displace iron from the solution.
IONIC BONDS
Ionic bonding is the complete transfer of valence electron(s) between atoms. It is a type of
chemical bond that generates two oppositely charged ions. In ionic bonds, the metal loses
electrons to become a positively charged cation, whereas the nonmetal accepts those electrons
to become a negatively charged anion. Ionic bonds require an electron donor, often a metal, and
an electron acceptor, a nonmetal.
Ionic bonding is observed because metals have few electrons in their outer-most orbitals. By
losing those electrons, these metals can achieve noble gas configuration and satisfy the octet
rule. Similarly, nonmetals that have close to 8 electrons in their valence shells tend to readily
accept electrons to achieve noble gas configuration. In ionic bonding, more than 1 electron can
be donated or received to satisfy the octet rule. The charges on the anion and cation correspond
to the number of electrons donated or received. In ionic bonds, the net charge of the compound
must be zero.
FORMATION OF IONIC BOND:
The positive ions (cations) and negative ions (anions) that are formed experience the
electrostatic forces and get attracted to form chemical bond. As this bond is between charged
particles known as ions, it is called ionic bond. Sometimes based on the forces being
electrostatic, the bond is also called the electrostatic bond. As the valence concept has been
explained in terms of electrons, it is also called the electrovalent bond.
Thus, we can define ionic bond as follows: The electrostatic attractive force that keeps cation
and anion together to form a new electrically neutral entity is called ‘ionic bond’.
EXAMPLES
FORMATION OF SODIUM CHLORIDE (NaCl):
In sodium chloride; sodium is a metal (alkali metal) and chlorine is non-metal.
Atomic number of sodium = 11
Electronic configuration of sodium: 2, 8, 1
Number of electrons in outermost orbit = 1
Valence electrons = Electrons in outermost orbit = 1
Atomic number of chlorine = 17
Electronic configuration of chlorine: 2, 8, 7
Electrons in outermost orbit = 7
Therefore, valence electrons = 7
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Sodium has one valence electron and chlorine has seven valence electrons. Sodium requires
losing one electron to obtain stable configuration and chlorine requires gaining one electron in
order to obtain stable electronic configuration. Thus, in order to obtain stable configuration
sodium transfers one electron to chlorine.
After loss of one electron sodium gets one positive charge (+) and chlorine gets one negative
charge after gain of one electron. Sodium chloride is formed because of transfer of electrons.
Thus, ionic bond is formed between sodium and chlorine. Since, sodium chloride is formed
because of ionic bond, thus it is called ionic compound. In similar way; potassium chloride
(KCl) is formed.
FORMATION OF MAGNESIUM CHLORIDE (MgCl2):
The atomic number of magnesium is 12
Electronic configuration of magnesium: 2, 8, 2
Number of electrons in outermost orbit = 2
Valence electron = 2
Atomic number of chlorine = 17
Electronic configuration of chlorine: 2, 8, 7
Electrons in outermost orbit = 7
Therefore, valence electrons = 7
Magnesium loses two electrons in order to obtain stable electronic configuration. Each of the
two chlorine atoms gains one electron lost by magnesium to obtain stable electronic
configuration. The bonds so formed between magnesium and chlorine are ionic bonds and
compound (magnesium chloride) is an ionic compound.
FORMATION OF CALCIUM CHLORIDE: (CaCl2):
Atomic number of calcium is 20.
Electronic configuration of calcium: 2, 8, 8, 2
Number of electrons in outermost orbit = 2
Valence electron = 2
Valence electrons of chlorine = 7
Calcium loses two electrons in order to achieve stable electronic configuration. Each of the two
chlorine atoms on the other hand gains one electron losing from calcium to get stability. By
losing of two electrons calcium gets two positive charges over it. Each of the chlorine atoms
gets one positive charge over it.
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The bonds formed in the calcium chloride are ionic bonds and compound (calcium chloride) is
an ionic compound. In similar way; Barium chloride is formed. Formation of Calcium oxide
(CaO):
Valence electron = 2
Atomic number of oxygen is 8
Electronic configuration of oxygen is: 2, 6
Number of electrons in outermost orbit = 6
Valence electron = 6
Calcium loses two electrons and gets two positive charges over it in order to get stability.
Oxygen gains two electrons; lost by calcium and thus gets two negative charges over it.
Bond formed between calcium oxide is ionic bond. Calcium oxide is an ionic compound. In
similar way; magnesium oxide is formed.
PROPERTIES OF IONIC COMPOUND:
Physical nature: Ionic compounds are solids and are somewhat hard because of the strong
force of attraction between the positive and negative ions. These compounds are generally
brittle and break into pieces when pressure is applied.
Melting and Boiling points: Ionic compounds have high melting and boiling points. This is
because a considerable amount of energy is required to break the strong inter-ionic
attraction.
Solubility: Electrovalent compounds are generally soluble in water and insoluble in solvents
such as kerosene, petrol, etc.
Conduction of Electricity: The conduction of electricity through a solution involves the
movement of charged particles. A solution of an ionic compound in water contains ions,
which move to the opposite electrodes when electricity is passed through the solution. Ionic
compounds in the solid state do not conduct electricity because movement of ions in the
solid is not possible due to their rigid structure. But ionic compounds conduct electricity in
the molten state. This is possible in the molten state since the elecrostatic forces of
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attraction between the oppositely charged ions are overcome due to the heat. Thus, the ions
move freely and conduct electricity.
INTEXT QUESTIONS PAGE NO. 49
Question 1: (i) Write the electron-dot structures for sodium, oxygen and magnesium.
Show the formation of Na2O and MgO by the transfer of electrons.
What are the ions present in these compounds?
Answer: (i) The representation of elements with valence electrons as dots around the
elements is referred to as electron-dot structure for elements.
(ii)
+ 2− 2+ 2−
(iii) The ions present in Na2O are Na and O ions and in MgO are Mg and O ions.
Question 2: Why do ionic compounds have high melting points?
Answer: Ionic compounds have strong electrostatic forces of attraction between the ions.
Therefore, it requires a lot of energy to overcome these forces. That is why ionic compounds
have high melting points.
OCCURENCE AND EXTRACTION OF METALS
Metals occur in nature in free as well as combined form. Metals having low reactivity show
little affinity for air, moisture, carbon dioxide or other non-metals present in nature. Such
metals may remain in elemental or native (free) state in nature. Such metals are called "noble
metals" as they show the least chemical reactivity. For example gold, silver, mercury and
platinum occur in free state.
On the other hand, most of the metals are active and combine with air, moisture, carbon dioxide
and non-metals like oxygen, sulphur, halogens, etc. to form their compounds, like oxides,
sulphides, carbonates, halides and silicates. i.e., they occur in nature in a combined state.
A naturally occurring material in which a metal or its compound occurs is called a mineral. A
mineral from which a metal can be extracted economically is called an ore.
An ore is that mineral in which a metal is present in appreciable quantities and from
which the metal can be extracted economically.
Metals found at the bottom of reactivity series are least reactive and they are often found in
nature in free-state; such as gold, silver, copper, etc. Copper and silver are also found in the
form of sulphide and oxide ores.
Metals found in the middle of reactivity series, such as Zn, Fe, Pb, etc. are usually found in the
form of oxides, sulphides or carbonates.
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Metals found at the top of the reactivity series are never found in free-state as they are very
reactive, e.g. K, Na, Ca, Mg and Al, etc.
Many metals are found in the form of oxides because oxygen is abundant in nature and is very
reactive.
TABLE : SOME IMPORTANT ORES
EXTRACTION OF METALS
Metals can be categorized into three parts on the basis of their reactivity: most reactive,
medium reactive and least reactive.
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CONCENTRATION OF THE ORE:
Ores that are mined from the earth are usually contaminated with large amount of impurities
such as soil and sand etc.
Concentration or Dressing means, simply getting rid of as much of the unwanted rocky material
as possible before the ore is converted into the metal. The impurities like clay are called
gangue.
Enrichment of the ore: Physical methods are used to enrich the ore. In many cases, it is
possible to separate the metal compound from unwanted rocky material by physical
means. A common example of this involves froth flotation.
The physical methods adopted in dressing the ore (or) enriching the ore depends upon
difference between physical properties of ore and gangue.
METHODS USED TO ENRICH THE ORE
Hand picking
If the ore particles and the impurities are different in one of the properties like colour, size
etc. Then using that property the ore particles are handpicked separating them from other
impurities.
Washing
Ore particles are crushed and kept on a slopy surface. They are washed with controlled flow of
water. Less densive impurities are carried away by water flow, leaving the more densive ore
particles behind.
Froth flotaton
This method is mainly useful for sulphide ores which have no wetting property whereas the
impurities get wetted. The ore with impurities is finely powdered and kept in water taken in a
flotation cell. Air under pressure is blown to produce froth in water. Froth so produced, takes
the ore particles to the surface whereas impurities settle at the bottom. Froth is separated and
washed to get ore particles.
Magnetic separation
If the ore or impurity, one of them is magnetic and the other non-magnetic they
are separated using electromagnets.
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EXTRACTION OF CRUDE METAL FROM THE ORE:
After concentration and dressing of ore that obtained earth, we get a concentrated or enriched
ore. To extract metal from this enriched ore it is converted into metallic oxide by reduction
reaction. Then this metallic oxide further reduced to get a metal with certain impurities.
Extraction of the metal from its ores depends on the reactivity of the metal.
Arrange the metal in decreasing order of their reactivity is known as activity series. The
classification of the metals on the basis of their reactivity:
EXTRACTION OF METALS AT THE TOP OF THE ACTIVITY SERIES:
(K, Na, Ca, Mg and Al). Simple chemical reduction methods like heating with C, CO etc to
reduce the ores of these metals are not feasible. The temperature required for the reduction is
too high and more expensive. To make the process economical, electrolysis methods are to be
adopted. Again the electrolysis of their aqueous solutions also is not feasible because water in
the solution would be discharged at the cathode in preference to the metal ions.
The only method viable is to extract these metals by electrolysis of their fused compounds. For
example to extract Na from NaCl, fused NaCl is electrolysed with steal cathode (-) and graphite
anode (+). The metal (Na) will be deposited at cathode and chloride liberated at the anode. At
+ - - -
Cathode 2Na + 2e ’! 2Na; and At Anode 2Cl ’! Cl2 + 2e
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EXTRACTION OF METALS IN THE MIDDLE OF THE ACTIVITY SERIES: (Zinc,
iron, tin, lead and copper): The ore of these metals are generally present as Sulphides or
Carbonates in native. Therefore prior to reduction of ores of these metals, they must be
converted into metal oxides. Sulphide ores are converted into oxides by heating them strongly
in excess of air. This process is known as roasting. Generally the sulphide ores are roasted to
convert them into oxides before reducing them to metal.
Eg: 2PbS + 3O2 → 2PbO + 2SO2
The metal oxides are then reduced to the corresponding metal by using suitable reducing agent
such as carbon
Reduction of metal oxides with carbon: The oxides are reduced by coke in a closed furnace
which gives the metal and carbon monoxide (CO).
0
Eg: PbO + C → Pb + CO at 1400 C
Reduction of oxide ores with CO. Eg: Fe2O3 + 3CO → 2Fe + 3O2 in blast furnace
Auto (self) reduction of sulphide ores: In the extraction of Cu from its sulphide ore, the
ore is subjected partial roasting in air to give its oxide.
2Cu2S + 3O2 → 2Cu2O + 2SO2
When the supply of air is stopped and the temperature is raised.
The rest of the sulphide reacts with oxide and forms the metal and
SO2. 2Cu2O + Cu2S → 6Cu + 2SO2
Reduction of ores (compounds) by more reactive metals.
0
Eg: TiCl4 + 2Mg → Ti + 2MgCl2 at 850 C
0
TiCl4 + 4Na → Ti + 4NaCl at 850 C
Thermite process: When highly reactive metals such as sodium, calcium, aluminium etc., are
used as reducing agents, they displace metals of lower reactivity from the compound. These
displacement reactions are highly exothermic. The amount of heat evolved is so large that the
metals produced in molten state. This type of reaction is used in thermite process. The reaction
of Iron (III) oxide (Fe2O3), with aluminium is used to join railings of railway tracks or cracked
machine parts. This reaction is known as the thermite reaction.
2Al + Fe2O3 → Al2O3 + 2Fe + Heat
2Al + Cr2O3 → Al2O3 + 2Cr + Heat
C) EXTRACTION OF METALS AT THE BOTTOM OF THE ACTIVITY SERIES (AG, HG ETC)
Metals at bottom of the activity series are often found in free state. They reactivity with other
atoms is very low. The oxides of these metals can be reduced to metals by heat alone and
sometimes by displacement from their aqueous solutions.
When cinnabar (HgS) whch is an ore of mercury, heated in air, it is first converted into (HgO)
then reduced to mercury on further heating.
Eg: 2HgS + 3O2 → 2HgO + 2SO2 → 2HgO → 2Hg + O2 on heating
Displacement from aqueous solutions: Eg: Ag2S
- - 2-
+ 4CN → 2[Ag(CN)2] + S
- 2-
2[Ag(CN)2] (aq) + Zn(s) → [Zn(CN)4] (aq) + 2Ag(s)
Here Ag2S is dissolved in say KCN solution to get dicyanoargentate (I) ions.
From these ions Ag is precipitated by treating with Zn dust powder.
PURIFICATION OF THE CRUDE METAL:
The metal obtained by the reduction of the ore is usually contaminated with impurities like
unchanged ore, other metals present in the ore and non metals from the anions in the ore.
For example, the (blister) copper obtained from its sulphide ore is a compound of copper iron
pyrites (CuFeS2). It contains some copper sulphide, iron and sulphur. It is purified by suitable
methods including electrolysis. The process of obtaining the pure metal from the impure metal
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is called refining of the metal. Refining of the metal involves several types of processes. Some
refining methods are given below:
Distillation
Poling
Liquation
Electrolysis etc.
The process that has to be adopted for purification of a given metal depends on the nature of
the metal and its impurities?
Distillation: This method is very useful for purification of low boiling metals like zinc and
mercury whether contain high boiling metals as impurities. The extracted metal in the
molten state is distilled to obtain the pure metal as distillate.
Poling: The molten metal is stirred with logs (poles) of green wood. The impurities are
removed either as gases or they get oxidized and form scum (slag) over the surface of the
molten metal. Blister copper is purified by this method. The reducing gases, evolved from
the wood, prevent the oxidation of copper.
Liquation: In this method a low melting metal like tin can be made to flow on a slopy surface
to separate it from high melting impurities.
Electrolytic refining: In this method, the impure metal is made to act as anode. A strip of the
same metal in pure form is used as cathode. They are put in a suitable electrolytic bath
containing soluble salt of the same metal. The required metal gets deposited on the cathode
in the pure form. The metal, constituting the impurity, goes as the anode mud.
The reactions are:
n+ -
Anode: M → M + ne
n+ -
Cathode: M + ne → M (M = pure metal )
Where n = 1,2,3, ...
We use this electrolytic method to refine copper.
For this an impure copper is taken as anode and pure copper strips are taken as cathode. The
electrolyte is a acidified solution of copper sulphate. As a result of electrolysis copper in
pure form is transferred from the anode to the cathode.
2+ -
Anode: Cu → Cu + 2e
2+ -
Cathode: Cu + 2e → Cu
The suitable impurities go into the solution, where as insoluble impurities from the
blister copper deposited at the bottom of anode as anode mud which contains antimony.
Selenium, tellurium, silver, gold and platinum; recovery of these elements may meet the cost
of refining.
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Zinc may also be refined this way.
CORROSION
Most of the metals keep on reacting with the atmospheric air. This leads to formation of a layer
over the metal. In the long run, the underlying layers of the metal keep on getting lost due to
conversion into oxides or sulphides or carbonate, etc. As a result, the metal gets eaten up. This
process is called corrosion.
Rusting of Iron: Rusting of iron is the most common form of corrosion. When iron articles;
like gate, grill, fencing, etc. come in contact with moisture present in air, the upper layer of iron
turns into iron oxide. Iron oxide is brown-red in color and is known as rust. This phenomenon
is called rusting of iron.
If rusting is not prevented in time, the whole iron article would turn into iron oxide. This is also
known as corrosion of iron. Rusting of iron gives huge loss every year.
Prevention of Rusting: For rusting, iron must come in contact with oxygen and water. Rusting
is prevented by preventing the reaction between atmospheric moisture and the iron article. This
can be done by painting, greasing, galvanization, electroplating, etc.
METHODS OF PREVENTION OF CORROSION
There are various methods of preventing corrosion and rusting of iron. Our main
concern is to know the various methods to prevent the rusting of iron because iron is a
strategic metal as it plays a very important role in the development of a nation. Some of
the important methods of prevention of corrosion are as follows:
Painting
This is a common method of preventing iron from rusting. You might have observed that
your parents paint iron gate in the garden and iron grills in your house. This painting
prevents rusting by providing a coating over iron objects.
Oiling and greasing
To put a layer of oil and grease on the iron objects also prevents them from rusting. Iron
parts of various machines and vehicles are oiled and greased to prevent rusting and to
minimize friction.
Galvanization
In this method we put a layer of zinc metal on the iron objects and this process is known as
galvanization. This method is used on large scale for making galvanized iron sheets for
making boxes and for roof covering. Galvanised iron sheets are used to make drum, trunks
and other iron containers. Galvanised iron sheets are also used for building roofs and
manhole covers. In brief, galvanization prevents rusting in a big way.
Alloying
This is a very good method for improving the quality of different metals. In this method a
particular metal with other metal or non-metal is mixed in a fixed proportion to improve its
quality like resistance towards corrosion, strength , hardness, shining and high tensile
strength. For example iron metal can not be used for making utensils because it will rust but
when it is mixed with nickel and chromium metal it becomes stainless steel.
INTEXT QUESTIONS PAGE NO. 55
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Question 1: Metallic oxides of zinc, magnesium and copper were heated with the
following metals.
In which cases will you find displacement reactions taking place?
Answer :
Answer:
Metal Zinc Magnesium Copper
Zinc oxide No reaction Displacement No reaction
Magnesium oxide No reaction No reaction No reaction
Copper oxide Displacement Displacement No reaction
Question 2: Which metals do not corrode easily?
Answer: More reactive a metal is, more likely it is to be corroded. Therefore, less reactive
metals are less likely to get corroded. This is why gold plating provides high resistance to
corrosion.
Question 3: What are alloys?
Answer: Alloys are homogeneous mixtures of two or more elements. The elements could be
two metals, or a metal and a non-metal. An alloy is formed by first melting the metal and then
dissolving the other elements in it. For example, steel is an alloy of iron and carbon.
EXERCISE QUESTIONS PAGE NO. 56 and 57
Question 1: Which of the following pairs will give displacement reactions?
NaCl solution and copper metal
MgCl2 solution and aluminium metal
FeSO4 solution and silver metal
AgNO3 solution and copper metal. Answer :
(d) AgNO3 solution and copper metal
Question 2: Which of the following methods is suitable for preventing an iron frying pan from
rusting?
Applying grease
Applying paint
Applying a coating of zinc
all of the above.
Answer : (c) Applying a coating of zinc (We can also apply grease and paint to prevent iron
from rusting. However, in case of iron frying pan, grease and paint cannot be applied because
when the pan will be heated and washed again and again, the coating of grease and paint would
get destroyed.)
Question 3: An element reacts with oxygen to give a compound with a high melting point.
This compound is also soluble in water. The element is likely to be
calcium
carbon
silicon
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(d) iron
Answer : (a) The element is likely to be calcium.
Question 4: Food cans are coated with tin and not with zinc because
zinc is costlier than tin.
zinc has a higher melting point than tin.
zinc is more reactive than tin.
zinc is less reactive than tin.
Answer : (c) Food cans are coated with tin and not with zinc because zinc is more reactive than
tin.
Question 5: You are given a hammer, a battery, a bulb, wires and a switch.
How could you use them to distinguish between samples of metals and non-metals?
Assess the usefulness of these tests in distinguishing between metals and non-metals.
Answer : (a) With the hammer, we can beat the sample and if it can be beaten into thin sheets
(that is, it is malleable), then it is a metal otherwise a non-metal. Similarly, we can use the
battery, bulb, wires, and a switch to set up a circuit with the sample. If the sample conducts
electricity, then it is a metal otherwise a non-metal.
The above tests are useful in distinguishing between metals and non-metals as these are
based on the physical properties. No chemical reactions are involved in these tests.
Question 6: What are amphoteric oxides? Give two examples of amphoteric oxides.
Answer : Those oxides that behave as both acidic and basic oxides are called amphoteric
oxides. Examples: aluminium oxide (Al2O3), zinc oxide (ZnO)
Question 7: Name two metals which will displace hydrogen from dilute acids, and two
metals which will not.
Answer : Metals that are more reactive than hydrogen displace it from dilute acids. For
example: sodium and potassium. Metals that are less reactive than hydrogen do not displace it.
For example: copper and silver.
Question 8: In the electrolytic refining of a metal M, what would you take as the anode,
the cathode and the electrolyte?
Answer : In the electrolytic refining of a metal M:
Anode → Impure metal M
Cathode → Thin strip of pure metal M
Electrolyte → Solution of salt of the metal M
Question 9: Pratyush took sulphur powder on a spatula and heated it. He collected the
gas evolved by inverting a test tube over it, as shown in figure below.
What will be the action of gas on
dry litmus paper?
moist litmus paper?
Write a balanced chemical equation for the reaction taking place.
Answer :
(i) There will be no action on dry litmus paper.
Since the gas is sulphur dioxide (SO2), it turns moist blue litmus paper to red because sulphur
dioxide reacts with moisture to form sulphurous acid.
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(b)
Question 10: State two ways to prevent the rusting of iron.
Answer : Two ways to prevent the rusting of iron are:
Oiling, greasing, or painting: By applying oil, grease, or paint, the surface becomes water proof
and the moisture and oxygen present in the air cannot come into direct contact with iron.
Hence, rusting is prevented.
Galvanisation: An iron article is coated with a layer of zinc metal, which prevents the iron to
come in contact with oxygen and moisture. Hence, rusting is prevented.
Question 11: What type of oxides are formed when non-metals combine with oxygen?
Answer : Non-metals combine with oxygen to form acidic oxides.
For example:
Question 12: Give reasons
Platinum, gold and silver are used to make jewellery.
Sodium, potassium and lithium are stored under oil.
Aluminium is a highly reactive metal, yet it is used to make utensils for cooking.
Carbonate and sulphide ores are usually converted into oxides during the process of
extraction.
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Answer : (a) Platinum, gold, and silver are used to make jewellery because they are very
lustrous. Also, they are very less reactive and do not corrode easily.
Sodium, potassium, and lithium are very reactive metals and react very vigorously with air as
well as water. Therefore, they are kept immersed in kerosene oil in order to prevent their
contact with air and moisture.
Though aluminium is a highly reactive metal, it is resistant to corrosion. This is because
aluminium reacts with oxygen present in air to form a thin layer of aluminium oxide. This
oxide layer is very stable and prevents further reaction of aluminium with oxygen. Also, it is
light in weight and a good conductor of heat. Hence, it is used to make cooking utensils.
Carbonate and sulphide ores are usually converted into oxides during the process of extraction
because metals can be easily extracted from their oxides rather than from their carbonates and
sulphides.
Question 13: You must have seen tarnished copper vessels being cleaned with lemon or
tamarind juice. Explain why these sour substances are effective in cleaning the vessels.
Answer : Copper reacts with moist carbon dioxide in air to form copper carbonate and as a
result, copper vessel loses its shiny brown surface forming a green layer of copper carbonate.
The citric acid present in the lemon or tamarind neutralises the basis copper carbonate and
dissolves the layer. That is why, tarnished copper vessels are cleaned with lemon or tamarind
juice to give the surface of the copper vessel its characteristic lustre.
Question 14: Differentiate between metal and non-metal on the basis of their chemical
properties.
Answer :
Metals Non-metals
Metals are electropositive. Non-metals are electronegative.
They react with oxygen to form basic They react with oxygen to form acidic or
oxides. neutral oxides.
These have ionic bonds. These have covalent bonds.
They react with water to form oxides and They do not react with water.
hydroxides. Some metals react with cold
water, some with hot water, and some with
steam.
They react with dilute acids to form a salt They do not react with dilute acids. These
and evolve hydrogen gas. However, Cu, are not capable of replacing hydrogen.
Ag, Au, Pt, Hg do not react.
They react with the salt solution of metals. These react with the salt solution of non-
Depending on their reactivity, displacement metals.
reaction can occur.
They act as reducing agents (as they can These act as oxidising agents (as they can
easily lose electrons). gain electrons).
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Question 15: A man went door to door posing as a goldsmith. He promised to bring back
the glitter of old and dull gold ornaments. An unsuspecting lady gave a set of gold bangles
to him which he dipped in a particular solution. The bangles sparkled like new but their
weight was reduced drastically. The lady was upset but after a futile argument the man
beat a hasty retreat. Can you play the detective to find out the nature of the solution he
had used?
Answer : He must have dipped the gold metal in the solution of aqua regia − a 3:1 mixture of
conc. HCl and conc. HNO3. Aqua regia is a fuming, highly corrosive liquid. It dissolves gold
in it. After dipping the gold ornaments in aqua regia, the outer layer of gold gets dissolved and
the inner shiny layer appears. That is why the weight of gold ornament reduced.
Question 16: Give reasons why copper is used to make hot water tanks and not steel (an
alloy of iron).
Answer : Copper does not react with cold water, hot water, or steam. However, iron reacts
with steam. If the hot water tanks are made of steel (an alloy of iron), then iron would react
vigorously with the steam formed from hot water.
That is why copper is used to make hot water tanks, and not steel.
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ASSIGNMENT QUESTIONS SET – 1
CHAPTER – 3
METALS AND NON-METALS
Which metal is the best conductor of electricity?
Which metal is poorest conductor of electricity?
Which metal is best conductor of heat ?
Which metal other than mercury is liquid at room temperature?
Which metal is poorest conductor of heat?
What is the nature of oxides of metal?
What is the nature of oxides of non- metal?
Which non-metal conduct electricity?
Graphite, allotrope of carbon conduct electricity.
Which non-metal is lusturous?
Why metals are hard and have high melting point?
What is an amalgam?
What are the constituents of solder?
Name the green coloured compound which appears on the surface of copper utensils?
Why the item made of silver turns black when exposed to air?
Why do silver ornaments loose their shine when kept for some time?
Name a metal other than aluminium that is covered with an oxide film layer.
Name one metal and one non-metal which exists in liquid state at room temperature?
Name a non-metal which is lustrous and a metal which is non-lustrous.
Name two metal which have very low melting point.
If copper metal is heated over a flame, it develops a coating. What is the colour and
composition of this coating?
Why is sodium metal kept immersed in kerosene oil?
Name one metal which react with very dilute HNO3 to evolve hydrogen gas.
A non-metal X exists in two different forms Y and Z. Y is the hardest natural substance,
whereas Z is a good conductor of electricity. Identify X, Y, and Z.
An element A form two oxides AO and AO2.The oxide AO is neutral whereas the oxide AO2
is acidic in nature. Would you call element A a metal or non-metal.
In the refining of silver the recovery of silver from silver nitrate solution involves displacement
by copper metal. Give the reason for the same.
Name two metals which are both ductile as well as malleable.
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The reaction of iron (III) oxide Fe2O3 with aluminium is used to join cracked iron parts of
machines.
Give reason for the following: (a) Ionic compounds conduct electricity in the molten state.
Give reason for the following: Metals can be given different shapes according to our needs.
How will you test for the gas which is liberated when hydrochloric acid reacts with an active
metal?
Which reducing agent is used in the reduction of alumina?
What are metalloids?
Why are titanium and chromium classified as strategic metals?
Which one of the following metals does not react with oxygen even at high temperatures?(i)
Calcium (ii) Gold (iii) Sodium
Give reasons for the following : Addition of some silver to pure gold for making ornaments.
Give reason for the following: Alumina is dissolved in molten cryolite for electrolysis to obtain
aluminum metal.
Write the chemical equation to represent the reaction taking place between sodium metal and
cold water.
Why is tungsten metal selected for making filaments of incandescent lamp bulbs?
Name a metal which offer higher resistance to the passage of electricity than copper.
Write the chemical equation for the reaction of hot aluminium with steam.
How does the metal magnesium differ from the metal calcium in their reaction with water?
What is seen to happen when a piece of sodium metal is dropped into water?
What are amphoteric oxides? Give an example.\
Name two metals that react with dil.HNO3 to evolve H2 gas ?
Why metals like potassium and sodium catch fire when treated with water?
Why sodium is kept immersed in kerosene oil?
Which gas is produced when dil. HCl is added to a reactive metal? Write the chemical reaction
when iron reacts with dil. H2SO4?
What would you observe when zinc is added to a solution of iron(II) sulphate ?write the
chemical reaction that takes place.
Why ionic compounds have high melting points?
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What do you mean by roasting? How it is different from calcination? In which types of ores
roasting is done?
Define :- (i) Ore, (ii) Mineral.
Name two metals which are found in nature in the free state.
Define :- (i) Enrichment of Ores (ii) Gangue.
Write short notes on electrolytic refining of metals.
Name the conditions which are essential for corrosion.
What is Galvanisation? Write its use.
Write suitable example, explain how a metal low in the activity series can be extracted?
Write three properties of ionic compounds.
What is anodizing? What is its use?
What is aqua regia? What is its use?
What do you mean by thermite reaction? What is its use?
Why active metals do not liberate H2 gas when treated with dil. HNO3?
Sometimes the ore itself acts as a reducing agent. Give an example.
An alkali metal A gives a compound B (molecular mass=40) on reacting with water .The
compound B gives a soluble compound C on treatment with aluminium oxide. Identify A,
B, and C and give the reaction involved.
An element A burns with golden flame in air .It reacts with another element B, atomic number
17 to give a product C .An aqueous solution of product C on electrolysis gives a
compound D and liberates hydrogen .Identify A, B, C and D. Also write down the
equations for the reactions involved.
A metal which is used in thermite process, when heated with oxygen gives an oxide B, which is
amphoteric in nature .Identify the metal and its ore and give the reaction involved.
Give reasons
Copper is used to make hot water tanks but steel is not.
Tarnished copper vessels being cleaned with lemon or tamarind juice.
Metal sulphides occur mainly in rocks but metal halides occur mostly in sea and lake waters.
A salt which does not conduct electricity in the solid state becomes a good conductor in molten
state
Why ionic compounds have high melting points?
Why sodium is kept immersed in kerosene oil?
Why metals like potassium and sodium catch fire when treated with water?
Why metals are hard and have high melting point?
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A metal M does not liberate hydrogen from acids but reacts with oxygen to give a black colour
product. Identify M and black coloured product and also explain the reaction of M with
oxygen.
Given below are the steps for extraction of copper from its ore .Write the reaction involved
(i)Roasting of copper (I) sulphide.
(ii)Reduction of copper (I) oxide with copper (1) sulphide.
Draw a neat and well labelled diagram for electrolytic refining of copper.
A metal is found in liquid state in nature .It is less reactive than hydrogen .It occurs as sulphide
ore .Describe the reactions how can we extract this metal from its ore .Name the ore also.
Explain why
Aluminium cannot be extracted by reducing alumina with carbon.
(ii)Concentrated HNO3 can be stored in aluminum containers.
(iii)Aluminium is used for making transmission wires.
24 carat gold cannot be used for making ornaments.
Which of the following property is generally not shown by metals?
Electrical conduction
Sonorous in nature
Dullness
Ductility
The ability of metals to be drawn into thin wire is known as
ductility
malleability
sonorousity
conductivity
Aluminium is used for making cooking utensils. Which of the following properties of
aluminium are responsible for the same?
Good thermal conductivity
Good electrical conductivity
Ductility
High melting point
(i) and (ii) (b) (i) and (iii)
(ii) and (iii) (d) (i) and (iv)
Which of the following property is generally not shown by metals?
Electrical conduction
Sonorous in nature
Dullness
Ductility
The ability of metals to be drawn into thin wire is known as
ductility
malleability
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sonorousity
conductivity
Aluminium is used for making cooking utensils. Which of the following properties of
aluminium are responsible for the same?
Good thermal conductivity
Good electrical conductivity
Ductility
High melting point
(i) and (ii) (b) (i) and (iii)
(ii) and (iii) (d) (i) and (iv)
Which one of the following metals do not react with cold as well as hot water?
Na
Ca
Mg
Fe
Which of the following oxide(s) of iron would be obtained on prolonged reaction of iron
with steam?
FeO
Fe2O3
Fe3O4
Fe2O3 and Fe3O4
What happens when calcium is treated with water?
It does not react with water
It reacts violently with water
It reacts less violently with water
Bubbles of hydrogen gas formed stick to the surface of calcium
(a) (i) and (iv) (b) (ii) and (iii)
(c) (i) and (ii) (d) (iii) and (iv)
Generally metals react with acids to give salt and hydrogen gas. Which of the following acids
does not give hydrogen gas on reacting with metals (except Mn and Mg)?
(a) H2SO4
(b) HCl
(c) HNO3
(d) All of these
The composition of aqua-regia is
(a) Dil.HCl : Conc. HNO3
3 : 1
(b) Conc.HCl : Dil. HNO3
3 : 1
(c) Conc.HCl : Conc.HNO3
3 : 1
(d) Dil.HCl : Dil.HNO3
3 : 1
Which of the following are not ionic compounds?
KCl
HCl
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CCl4
NaCl
(i) and (ii) (b) (ii) and (iii)
(iii) and (iv) (d) (i) and (iii)
Which one of the following properties is not generally exhibited by ionic compounds?
Solubility in water
Electrical conductivity in solid state
High melting and boiling points
Electrical conductivity in molten state
Which of the following metals exist in their native state in nature?
Cu
Au
Zn
Ag
(i) and (ii) (b) (ii) and (iii)
(ii) and (iv) (d) (iii) and (iv)
Metals are refined by using different methods. Which of the following metals are refined by
electrolytic refining?
Au
Cu
Na
K
(i) and (ii) (b) (i) and (iii)
(ii) and (iii) (d) (iii) and (iv)
Silver articles become black on prolonged exposure to air. This is due to the formation of
Ag3N
Ag2O
Ag2S
Ag2S and Ag3N
Galvanisation is a method of protecting iron from rusting by coating with a thin layer of
Gallium
Aluminium
Zinc
Silver
Stainless steel is very useful material for our life. In stainless steel, iron is mixed with
Ni and Cr
Cu and Cr
Ni and Cu
Cu and Au
If copper is kept open in air, it slowly loses its shining brown surface and gains a green coating.
It is due to the formation of
CuSO4
CuCO3
Cu(NO3)2
CuO
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Generally, metals are solid in nature. Which one of the following metals is found in liquid state
at room temperature?
Na
Fe
Cr
Hg
Which of the following metals are obtained by electrolysis of their chlorides in molten state ?
Na
Ca
Fe
Cu
(i) and (iv) (b) (iii) and (iv)
(i) and (iii) (d) (i) and (ii)
Generally, non-metals are not lustrous. Which of the following nonmetal is lustrous?
Sulphur
Oxygen
Nitrogen
Iodine
Which one of the following four metals would be displaced from the solution of its salts by
other three metals?
Mg
Ag
Zn
Cu
2 mL each of concentrated HCl, HNO3 and a mixture of concentrated HCl and concentrated
HNO3 in the ratio of 3 : 1 were taken in test tubes labelled as A, B and C. A small piece
of metal was put in each test tube. No change occurred in test tubes A and B but the metal
got dissolved in test tube C respectively. The metal could be
Al
Au
Cu
Pt
An alloy is
an element
a compound
a homogeneous mixture
a heterogeneous mixture
An electrolytic cell consists of
positively charged cathode
negatively charged anode
positively charged anode
negatively charged cathode
(a) (i) and (ii) (b) (iii) and (iv)
(c) (i) and (iii) (d) (ii) ad (iv)
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During electrolytic refining of zinc, it gets
deposited on cathode
deposited on anode
deposited on cathode as well as anode
remains in the solution
An element A is soft and can be cut with a knife. This is very reactive to air and cannot be kept
open in air. It reacts vigorously with water. Identify the element from the following
Mg
Na
P
Ca
Alloys are homogeneous mixtures of a metal with a metal or nonmetal. Which among the
following alloys contain non-metal as one of its constituents?
Brass
Bronze
Amalgam
Steel
Which among the following statements is incorrect for magnesium metal?
It burns in oxygen with a dazzling white flame
It reacts with cold water to form magnesium oxide and evolves hydrogen gas
It reacts with hot water to form magnesium hydroxide and evolves hydrogen gas
It reacts with steam to form magnesium hydroxide and evolves hydrogen gas
Which among the following alloys contain mercury as one of its constituents?
Stainless steel
Alnico
Solder
Zinc amalgam
Reaction between X and Y, forms compound Z. X loses electron and Y gains electron. Which
of the following properties is not shown by Z?
Has high melting point
Has low melting point
Conducts electricity in molten state
Occurs as solid
The electronic configurations of three elements X, Y and Z are X — 2, 8; Y — 2, 8, 7 and Z —
2, 8, 2. Which of the following is correct?
X is a metal
Y is a metal
Z is a non-metal
Y is a non-metal and Z is a metal
Although metals form basic oxides, which of the following metals form an amphoteric oxide?
Na
Ca
Al
Cu
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Generally, non-metals are not conductors of electricity. Which of the following is a good
conductor of electricity?
Diamond
Graphite
Sulphur
Fullerene
Electrical wires have a coating of an insulting material. The material, generally used is
Sulphur
Graphite
PVC
All can be used
Which of the following non-metals is a liquid?
Carbon
Bromine
Phosphorus
Sulphur
Which of the following can undergo a chemical reaction?
MgSO4 + Fe
ZnSO4 + Fe
MgSO4 + Pb
CuSO4 + Fe
Iqbal treated a lustrous, divalent element M with sodium hydroxide. He observed the formation
of bubbles in reaction mixture. He made the same observations when this element was
treated with hydrochloric acid. Suggest how can he identify the produced gas. Write
chemical equations for both the reactions.
During extraction of metals, electolytic refining is used to obtain pure metals.
Which material will be used as anode and cathode for refining of silver metal by this
process?
Suggest a suitable electrolyte also.
In this electrolytic cell, where do we get pure silver after passing electric current?
Why should the metal sulphides and carbonates be converted to metal oxides in the process of
extraction of metal from them?
Generally, when metals are treated with mineral acids, hydrogen gas is liberated but when
metals (except Mn and Mg), treated with HNO3, hydrogen is not liberated, why?
Compound X and aluminium are used to join railway tracks.
Identify the compound X
Name the reaction
Write down its reaction.
When a metal X is treated with cold water, it gives a basic salt Y with molecular formula XOH
(Molecular mass = 40) and liberates a gas Z which easily catches fire. Identify X, Y and Z
and also write the reaction involved.
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A non-metal X exists in two different forms Y and Z. Y is the hardest natural substance,
whereas Z is a good conductor of electricity. Identify X, Y and Z.
The following reaction takes place when aluminium powder is heated with MnO2
Is aluminium getting reduced?
Is MnO2 getting oxidised?
What are the constituents of solder alloy? Which property of solder makes it suitable for
welding electrical wires?
A metal A, which is used in thermite process, when heated with oxygen gives an oxide B,
which is amphoteric in nature. Identify A and B. Write down the reactions of oxide B
with HCl and NaOH.
A metal that exists as a liquid at room temperature is obtained by heating its sulphide in the
presence of air. Identify the metal and its ore and give the reaction involved.
Give the formulae of the stable binary compounds that would be formed by the combination of
following pairs of elements.
Mg and N2
Li and O2
Al and Cl2
K and O2
What happens when
ZnCO3 is heated in the absence of oxygen?
a mixture of Cu2O and Cu2S is heated?
A non-metal A is an important constituent of our food and forms two oxides B and C. Oxide B
is toxic whereas C causes global warming
Identify A, B and C
To which Group of Periodic Table does A belong?
Give two examples each of the metals that are good conductors and poor conductors of heat
respectively.
Name one metal and one non-metal that exist in liquid state at room temperature. Also name
two metals having melting point less than 310 K (37°C)
An element A reacts with water to form a compound B which is used in white washing. The
compound B on heating forms an oxide C which on treatment with water gives back B.
Identify A, B and C and give the reactions involved.
An alkali metal A gives a compound B (molecular mass = 40) on reacting with water. The
compound B gives a soluble compound C on treatment with aluminium oxide. Identify A,
B and C and give the reaction involved.
Give the reaction involved during extraction of zinc from its ore by
roasting of zinc ore
calcination of zinc ore
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A metal M does not liberate hydrogen from acids but reacts with oxygen to give a black colour
product. Identify M and black coloured product and also explain the reaction of M with
oxygen.
An element forms an oxide A2O3 which is acidic in nature. Identify A as a metal or non-metal.
A solution of CuSO4 was kept in an iron pot. After few days the iron pot was found to have a
number of holes in it. Explain the reason in terms of reactivity. Write the equation of the
reaction involved.
A non-metal A which is the largest constituent of air, when heated with H2 in 1:3 ratio in the
presence of catalyst (Fe) gives a gas B. On heating with O2 it gives an oxide C. If this
oxide is passed into water in the presence of air it gives an acid D which acts as a strong
oxidising agent.
Identify A, B, C and D
To which group of periodic table does this non-metal belong?
Give the steps involved in the extraction of metals of low and medium reactivity from their
respective sulphide ores.
Explain the following
Reactivity of Al decreases if it is dipped in HNO3
Carbon cannot reduce the oxides of Na or Mg
NaCl is not a conductor of electricity in solid state whereas it does conduct electricity in
aqueous solution as well as in molten state
Iron articles are galvanised.
Metals like Na, K, Ca and Mg are never found in their free state in nature.
Given below are the steps for extraction of copper from its ore.
Write the reaction involved.
Roasting of copper (1) sulphide
Reduction of copper (1) oxide with copper (1) sulphide.
Electrolytic refining
Draw a neat and well labelled diagram for electrolytic refining of copper
Of the three metals X, Y and Z. X reacts with cold water, Y with hot water and Z with steam
only. Identify X, Y and Z and also arrange them in order of increasing reactivity.
An element A burns with golden flame in air. It reacts with another element B, atomic number
17 to give a product C. An aqueous solution of product C on electrolysis gives a
compound D and liberates hydrogen. Identify A, B, C and D. Also write down the
equations for the reactions involved.
Two ores A and B were taken. On heating ore A gives CO2 whereas, ore B gives SO2. What
steps will you take to convert them into metals?
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ASSIGNMENT QUESTIONS SET – 2
CHAPTER – 3
METALS AND NON-METALS
Which of the following can be beaten into thin sheets?
Zinc (b) Phosphorus (c) Sulphur (d) Oxygen
Which of the following statements is correct?
All metals are ductile.
All non-metals are ductile.
Generally, metals are ductile.
Some non-metals are ductile.
Which of the following is not a metal?
copper
sulphur
aluminium
iron
The substance that will be flattened on beating with a hammer is
crystal of iodine
lump of sulphur
piece of coal
zinc granule
Arun has learnt that non-metals on beating with a hammer are generally broken into pieces.
Which of the following is a nonmetal?
iron nail
aluminium wire
copper plate
piece of coal
Materials which can be drawn into wires are called ductile. Which of the following is not a
ductile material?
silver
copper
sulphur
aluminium
Metals are generally hard. Which of the following metals is an exception and can be cut
with a knife?
iron
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sodium
gold
magnesium
Metals are generally solid. Which of the following metals is in the liquid state at room
temperature?
mercury
silver
aluminium
sodium
Metals generally react with dilute acids to produce hydrogen gas. Which one of the
following metals does not react with dilute hydrochloric acid?
magnesium
aluminium
iron
copper
Which of the following reacts with cold water vigorously?
carbon
sodium
magnesium
sulphur
The metal which produces hydrogen gas on reaction with dilute hydrochloric acid as well as
sodium hydroxide solution is
copper
iron
aluminium
sodium
Which of the following non-metals reacts and catches fire on exposure to air?
phosphorus
nitrogen
sulphur
hydrogen
Generally metallic oxides are basic and non-metallic oxides are acidic in nature. Solution of
which of the following oxides in water will change the colour of blue litmus to red?
sulphur dioxide
magnesium oxide
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iron oxide
copper oxide
Which of the following property is not responsible for copper to be used as electrical
conduction wires?
ductility
colour
good conductor of electricity
it is solid
Fill in the blanks :
Phosphorus is very __________ non-metal.
Metals are __________ conductors of heat and __________.
Iron is __________ reactive than copper.
Metals react with acids to produce __________ gas.
A substance is malleable, ductile and electropositive in nature. What type of substance is
it?
What property of a metal makes it possible to draw it into wires?
Why are metals good conductors?
Name the metal which is commonly used for making cooking utensils
Fill in the blanks:
__________ is liquid metal
__________ is only liquid Non metals
__________, __________ and __________ are soft metal
__________ is the hardest natural substance
__________ and __________ are have low melting points. They melt in the palm of the
hand
Metals can be beaten into thin sheets so they are called __________
Non metals are bad conductors of electricity except __________
Metals react with oxygen to form __________ oxides
Some metal oxides show acidic and basic properties. They are called __________. Eg :-
Aluminum oxide, Zinc oxide etc.
Al2O3 + 6HCl __________ + 3H2O
Al2O3 + NaOH __________ + H2O
__________ and __________ does not react with oxygen even at high temperature.
Metals like potassium and sodium react vigorously with oxygen and catch fire if kept in
open. Hence they are stored in __________ to prevent burning.
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Magnesium reacts only with __________ water to form magnesium hydroxide and
hydrogen.
Metals like aluminium, iron and zinc react only with __________ to form the metal oxides
and hydrogen.
__________ gas is not evolved when metals react with nitric acid (HNO3) because it is a
strong oxidising agent
A more reactive metal displaces a __________ reactive metal from its salt solution
The arranging of metals in the decreasing order of their reactivity is called
__________ series of metals.
Metals lose electrons and become positive ions. So they are called __________
elements
Non metals __________ electrons and become negative ions. So they are called electro
negative elements
__________ are compounds formed by the transfer of electrons from a metal to a non
metal.
If one of the metals in an alloy is mercury, it is called an __________
__________ is the damage caused to metals due to the reaction of metals with oxygen,
moisture, carbon dioxide etc.
Some elements show properties of both metals and non metals. They are called
__________
__________ is a mixture of concentrated nitric acid and concentrated hydrochloric acid in
the ratio 1:3.
Name one electrovalent compounds in each case in which ;
(i)One atom combines with one other atom
(ii)One atom combines with two other atoms
(iii)One atom combines with three other atoms
Give reasons for the following :
Aluminium foils are used to wrap food items.
Immersion rods for heating liquids are made up of metallic substances.
Copper cannot displace zinc from its salt solution.
Sodium and potassium are stored in kerosene.
Can you store lemon pickle in an aluminium utensil? Explain.
Write the electron dot structure for oxygen and magnesium.
Show the formation of Na2O and CaO by the transfer of electrons.
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Write an activity to show that ionic compounds are good conductors of electric current in
their aqueous solution.
Why is aluminum extracted from alumina by electrolytic reduction and not by reducing
with carbon?
Why is ZnO called an amphoteric oxide? Give the support to your answer. Give equation
for the following
Iron is heated with steam.
Magnesium reacts with water.
iron reacts with dil.HCl
What would you observe when zinc is added to a solution of iron (II) sulphate? Write the
chemical reaction that takes places.
A trivalent metal X is manufactured by the process of electrolysis, It is the most abundant
metal in the earth’s crust. Identify the metal and state its two uses.
Which gas is always produced when a metal reacts with a dilute Write chemical reaction
when iron reacts with dil. H2SO4.
What is the activity series of metals? Rearrange the following metals in an increasing order
of reactivity: Aluminum, Zinc, Mercury.
What is meant by the term ‘enrichment of ore’ ? name four Methods generally used for
enrichment of ores.
You must have seen tarnished copper vessels being cleaned with lemon or tamarind juice.
Explain why these sour substances are effective in cleaning the vessels.
Write a balanced chemical equation for the reaction of the following metals with water: (i)
Ca (ii) Zn (iii) Fe
Define the terms:(i) Mineral (ii) Ore and (iii) Gangue
Explain how the following metals are obtained from their compounds by the reaction
process:
Metal ‘X’ , which is low in reactivity series.
Metal ‘Y’, which is middle in reactivity series.
Metal ‘Z’ which is high up in the reactivity series.
Give reasons:
The surface of some metals acquires a dull appearance when exposed to air for a long
time.
A salt which does not conduct electricity in the solid state becomes a good conductor in
molten state
What will happen if a :
Strip of zinc is immersed in a solution of copper sulphate.
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Strip of copper is kept immersed in a solution of silver nitrate
Explain why: (i) Conc. HNO3 can be stored in aluminium container.
Aluminium is used for making transmission wires.
24 carat gold can not be used for making ornaments.
Aluminium is used for making cooking utensils.
Metals generally do not form compounds with hydrogen.
An element X on reacting with O2 forms X2O.This Oxide dissolves in water and turns blue
litmus paper red. Predict the nature of element whether it is a metal or a non metal.
An element E combines with O2 to form an oxide E2O, which is a good conductor of
electricity. i) How many electrons will be present in the outer most shell of E? ii) Write
the formula of the compound formed when it combines with Chlorine.
What happens when
(a) Dilute sulphuric acid is poured on a copper plate?
(b) Iron nails are placed in copper sulphate solution?
Write word equations of the reactions involved.
Saloni took a piece of burning charcoal and collected the gas evolved in a test tube.
(a) How will she find the nature of the gas ?
(b) Write down word equations of all the reactions taking place in this process.
One day Reeta went to a jeweller’s shop with her mother. Her mother gave old gold jewellery
to the goldsmith to polish. Next day when they brought the jewellery back, they found that
there was a slight loss in its weight. Can you suggest a reason for the loss in weight?
Name two soft metals which can be cut with a knife.
Which non-metal is essential for our life and all living beings inhale it during breathing?
Name two major non-metals which are present in fertilisers and enhance the growth of
plants.
Which non-metal is used to disinfect water?
A purple coloured non-metal forms a brown solution in alcohol which is applied on
wounds as an antiseptic. Name the nonmetal.
Zinc sulphate forms a colourless solution in water. Will you observe any colour on adding
copper turning in it?
Why are bells made of metals?
Which liquid metal is used for making thermometers?
Which of the following metals can displace the other two metals from their salt solutions?
zinc, iron, copper
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Arun bought a statue made of copper. To her surprise it acquired a dull green coating after a
couple of months. Explain the reason.
Find out the names of three metals and three non-metals from the box given below:
Fill in the blanks to complete the following paragraph.
The name of the product formed in the reaction of sulphur and
_____________ is sulphur dioxide gas. When sulphur dioxide is
dissolved in_________________, sulphurous acid is formed. The
sulphurous acid turns _____________ litmus paper to ____________.
Generally oxides of __________ are acidic in nature.
After completing the paragraph write two questions which you can raise on the basis of this
information.
Arun prepared a blue coloured solution of copper sulphate in beaker A and placed an iron
nail in it. Mahesh prepared a yellowish green solution of ferrous sulphate in beaker B
and placed a copper wire in it. What changes will they observe in the two beakers after
an hour?
Complete the crossword given in below with the help of the clues.
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Across
Which is generally hard, ductile, malleable and sonorous.
A metal is called so it can be drawn into wires.
Metal bells are used because of this property.
Down
A metal generally used for making jewellery.
A metal which is liquid at room temperature.
A metal which reacts with acid as well as base to form hydrogen gas.
Substances used to enhance the growth of plants.
Property by virtue of which metals can be beaten into thin sheets.
A doctor prescribed a tablet to a patient suffering from iron deficiency. The tablet does not
look like iron. Explain.
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Iron is more reactive than copper. Can you write an activity to show this?
In the given figure you find that the bulb glows when an iron nail is placed between two ends
of wire. Complete the following sentences on the bases of this fact.
__________ is a metal.
Metals are good __________ of electricity.
If in the above figure iron nail is replaced by a wooden stick, will the bulb glow or not? Justify
your answer.
Why is sodium kept preserved in kerosene?
What is the activity series of metals? Arrange the metals Zn, Mg, A;, Cu and Fe in decreasing
order of reactivity.
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CHAPTER – 4
CARBON AND ITS COMPOUND
CARBON: INTRODUCTION
Carbon is the fourth most abundant element in the universe by mass. It is also the second most
abundant element in the human body after oxygen. It is the 15th most common element in the
Earth’s crust. Carbon was discovered in prehistory and it was known to the ancients. They used
to manufacture charcoal by burning organic material.
Carbon is a non-metal. It belongs to the fourteenth group or IV A group in the modern
periodical table. The elements of this group have four electrons in the valence shell.
Atomic Number: 6
Electronic configuration: 2, 4
Valence electrons: 4
Property: Non-metal
Compounds having carbon atoms among the components are known as carbon compounds.
Previously, carbon compounds could only be obtained from a living source; hence they are
also known as organic compounds.
BONDING IN CARBON: COVALENT BOND
Bond formed by sharing of electrons is called covalent bond. Two of more atoms share
electrons to make their configuration stable. In this type of bond, all the atoms have similar
rights over shared electrons. Compounds which are formed because of covalent bond are called
COVALENT COMPOUNDS.
FORMATION OF COVALENT BONDS
Covalent band is the chemical bond formed through the sharing of electrons between
two non-metal atoms.
Compounds which have covalent bonds are called covalent compounds.
Examples of covalent compounds or molecules are chlorine, Cl2, carbon dioxide, CO2,
ammonia, NH3, water, H2O, and tetrachloromethane (carbon tetrachloride), CCl 4.
During the formation of covalent molecules, each non-metal covalent atom provides one,
two or three electrons to be shared with other atoms. The bond formed is called a
covalent bond.
Through this process, each non-metal atom in covalent molecules will achieve stable
electron arrangement.
The type of covalent bond formed in a covalent compound depends on the number of
electron pairs shared between non-metal atoms.
Covalent bonds are of three types: Single, double and triple covalent bond.
SINGLE COVALENT BOND
A single covalent bond is the covalent bond formed through the sharing of a pair of
electrons between two non-metal atoms.
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Each non-metal atom contributes one electron for sharing to achieve a stable electron
arrangement.
Example of single covalent compound are chlorine gas, Cl2, hydrogen chloride, HCl, water,
H2O, methane, CH4, ammonia, NH3, and tetrachloromethane, CCl4.
Single covalent bonds can also be formed between different non-metal atoms.
Formation of hydrogen molecule (H2)
Atomic Number of H = 1
Electronic configuration of H = 1
Valence electron of H = 1
Hydrogen forms a duet, to obtain stable configuration. This configuration is similar to
helium (a noble gas).
Since, hydrogen has one electron in its valence shell, so it requires one more electron to form
a duet. So, in the formation of hydrogen molecule; one electron from each of the hydrogen
atoms is shared.
Formation of hydrogen chloride (HCl):
Valence electron of hydrogen = 1
Atomic number of chlorine = 17
Electronic configuration of chlorine: 2, 8, 7
Electrons in outermost orbit = 7
Valence electron = 7
Formation of chlorine molecule (Cl2):
Valence electron of chlorine = 7
Formation of water (H2O)
Valence electron of hydrogen = 1
Atomic number of oxygen = 8
Electronic configuration of oxygen = 2, 6
Valence electron = 6
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Formation of Methane (CH4)
Valence electron of carbon = 4
Valence electron of hydrogen = 1
DOUBLE COVALENT BOND
Double covalent bond is the type of covalent bond formed through the sharing of two
pairs of electrons between two non-metal atoms.
Examples of molecules which have double covalent bonds are oxygen, O2, and carbon
dioxide, CO2.
During the formation of double bond, each non-metal atom contributes two pairs of
electrons to be shared to achieve a stable electron arrangement.
Formation of oxygen molecule (O2):
Valence electron of oxygen = 2
In the formation of oxygen molecule, two electrons are shared by each of the two oxygen
atoms to complete their stable configuration.
In oxygen, the total number of shared electrons is four, two from each of the oxygen atoms.
So a double covalent bond is formed.
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Formation of Carbon dioxide (CO2):
Valence electron of carbon = 4
Valence electron of oxygen = 6
In carbon dioxide two double covalent bonds are formed.
Formation of Ethylene (C2H4):
Valence electron of carbon = 4
Valence electron of hydrogen = 1
TRIPLE COVALENT BOND
The triple covalent bond is the type of covalent bond formed through the sharing of three
pairs of electrons between two non-metal atoms.
Example of molecule which has triple covalent bonds is the nitrogen molecule, N2.
Formation of Nitrogen (N2):
Atomic number of nitrogen = 7
Electronic configuration of nitrogen = 2, 5
Valence electron = 5
In the formation of nitrogen, three electrons are shared by each of the nitrogen atoms. Thus
one triple bond is formed because of the sharing of total six electrons.
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Properties of Covalent Bond:
Intermolecular force is smaller.
Covalent bonds are weaker than ionic bond. As a result, covalent compounds have
low melting and boiling points.
Covalent compounds are poor conductor of electricity as no charged particles are formed in
covalent bond.
Since, carbon compounds are formed by the formation of covalent bond, so carbon
compounds generally have low melting and boiling points and are poor conductor
of electricity.
ALLOTROPY
Allotropy is defined as the property by which an element can exist in more than one form
that are physically different but chemically similar.
Allotropes of carbon
Carbon exists in three allotropic forms. They are crystalline form (diamond and
graphite), amorphous form (coke,charcoal) and fullerene.
In diamond each carbon atom is bonded to four other carbon atoms forming a rigid
three dimensional structure , accounting for it’s hardness and rigidity.
General properties of diamond are
It is a colourless transparent substance with extraordinary brilliance due to its
high refractive index.
It is quite heavy.
It is extremely hard (hardest natural substance known).
It does not conduct electricity (because of the absence of free electrons).
It has high thermal conductivity and high melting point.
It burns on strong heating to form carbon dioxide.
In graphite each carbon atom is bonded to three other carbon atoms in the same plane giving
hexagonal layers held together by weak vander Waals forces accounting for softness.
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General properties of graphite are
It is a greyish black opaque substance.
It is lighter than diamond, feels soft and slippery to touch.
It is a good conductor of electricity (due to the presence of free electrons) but bad
conductor of heat.
It burns on strong heating to form carbon dioxide.
Fullerenes form another type of carbon allotropes. The first one was identified to contain
60 carbon atoms
in the shape of a football. (C-60). Since this looks like the geodesic dome designed by the
US architect
Buck Minster Fuller, it is named as Buck Minster Fullerene.
General Properties of fullerenes are
These are dark solids at room temperature.
These are neither too hard nor too soft.
These are the purest allotrophic forms of carbon because of the absence of free valencies
or surface bonds.
On burning, these produce only carbon dioxide gas.
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VERSATILE NATURE OF CARBON
Initially, compounds of carbon could only be obtained from living sources and there was no
way of synthesizing them. Hence, carbon compounds are also known as organic compounds.
Carbon forms a large number of compounds. So far, formulae of about 3 million carbon
compounds are known.
Cause of formation of such a large number of compounds by carbon:
Carbon can form bonds with other carbon atoms. This property of carbon is known as
CATENATION. Because of catenation, carbon can form a long chain; while making bond
with other carbon atoms. Carbon can make single, double and triple bonds by catenation.
Carbon can form branched chain; along with straight chain; while combining with carbon
atoms, i.e. because of the property of catenation.
Due to the valency of four, carbon is capable of bonding or pairing with four other carbon
atoms or with the atoms of some other monovalent elements. It also forms compounds with
oxygen, nitrogen, sulphur, hydrogen and many other elements. This gives rise to
compounds with specific properties which depend on the element other than carbon present
in the molecule.
Bonds which carbon forms with other elements are very strong thus, making these
compounds very stable. The main reason for such strong bond formation is the small size of
carbon. As a result, the shared pair of electrons are tightly held by the nucleus.
ORGANIC COMPOUNDS
The compounds of carbon except its oxides, carbonates and hydrogen carbonate salts, are
known as organic compounds. These compounds were initially extracted from natural
substances and was believed that some vital force was necessary for the synthesis of these
compounds (vital force theory).
HYDROCARBONS
(Hydrogen + Carbon = Hydrocarbon) Compounds formed because of the combination of
hydrogen and carbon are known as hydrocarbons. These are regarded as the parent organic
compounds and all other compounds are considered to be derived from them by the
replacement of one or more hydrogen atoms by other atoms or groups of atoms. Hydrocarbons
can be divided into various classes as shown in below:
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ALIPHATIC HYDROCARBONS
The word aliphatic is derived from the Greek word aleiphar meaning fat. Aliphatic
hydrocarbons were named so because they were derived from fats and oils. Hydrocarbons can
be acyclic compounds, which are straight chain compounds, or cyclic compounds, which have
rings of carbon atoms.
AROMATIC HYDROCARBONS
The word aromatic is derived from the word aroma meaning fragrance. The aromatic
compounds have a characteristic smell. Structurally, they include benzene and its derivative.
The aliphatic hydrocarbons can be divided into two categories: saturated hydrocarbons and
unsaturated hydrocarbons. In saturated hydrocarbons, carbon atoms are linked to each other
by single bonds whereas in unsaturated hydrocarbons, multiple bond (double and triple bonds)
are present between
carbon atoms.
SATURATED HYDROCARBONS
Alkanes
General formula = CnH2n+2 Suffix : ane
These are the organic compounds which contain carbon – carbon single bond. These were earlier
named as paraffins(Latin : meaning little affinity) due to their least chemical reactivity.
According to IUPAC system, these are named as alkanes (ane is suffix with root word).
UNSATURATED HYDROCARBONS
These are hydrocarbons which contain carbon to carbon double bonds or carbon to
carbon triple bonds in
their molecules.These are further classified into two types: alkenes and alkynes.
i)Alkenes: General formula: CnH2n Suffix : ene
The hydrocarbons containing atleast one carbon to carbon double bond are called alkenes.They
have the general formula CnH2n .These were previously called olefins (Greek : olefiant – oil
forming) because the lower gaseous members of the family form oily products when treated
with chlorine.
In IUPAC system, the name of alkene is derived by replacing suffix “ane” of the correspding
alkane by “ene”. For example,
In higher alkenes, the position of the double bond, can be indicated by assigning numbers 1,
2, 3, 4, ……to the carbon atoms present in the molecule.
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ii) Alkynes: General formula: CnH2n-2 Suffix : yne
The hydrocarbons containing carbon to carbon triple bond are called alkynes. Alkynes are
named in the same way as alkenes i.e., by replacing suffix ane of alkane by yne. In higher
members, the position of triple bond is indicated by giving numbers 1, 2, 3, 4, ….to the
carbon atom in the molecule.
HOMOLOGOUS SERIES
A homologous series is a group or a class of organic compounds having similar structure
and similar chemical properties in which the successive compounds differ by a CH2 group.
Characteristics of homologous series
Each member of the series differs from the preceeding or succeeding member by a common
difference of CH2 and by a molecular mass of 14 amu (amu = atomic mass unit).
All members of homologous series contain same elements and the same functional groups.
All members of homologous series have same general molecular formula.
e.g Alkane = CnH2n + 2
Alkene = CnH2n
Alkyne = CnH2n – 2
The members in homologous series show a regular gradation in their physical
properties with respect to increase in molecular mass.
The chemical properties of the members of the homologous series are similar.
All members of homologous series can be prepared by using same general method.
IMPORTANCE OF HOMOLOGOUS SE RIES
It helps to predict the properties of the members of the series that are yet to be prepared.
Knowledge of homologous series gives a systematic study of the members.
The nature of any member of the family can be ascertained if the properties of the
first member are known.
FUNCTIONAL GROUP
Functional group may be defined as an atom or group of atoms or reactive part which is
responsible for the characteristic properties of the compounds.
The chemical properties of organic compounds are determined by the functional groups
while their physical properties are determined by the remaining part of the molecule.
CLASSIFICATION OF ORGANIC COMPOUNDS BASED ON FUNCTIONAL
GROUP
1. ALCOHOLS
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Alcohols are carbon compounds containing –OH group attached to alkyl group. The general
formula of alcohol is R-OH where ‘R’ is an alkyl group and –OH is the functional group.
The IUPAC name of alcohol is derived by replacing –e, in the word alkane, by the suffix –ol.
Hence we get the name alkanol.
2. ALDEHYDES
Aldehydes are carbon compounds containing -CHO group attached to alkyl group or
hydrogen atom. The general formula of aldehydes is R – CHO where ‘R’ is an alkyl group
or hydrogen atom and – CHO is the functional group.
The IUPAC name of aldehyde is derived by replacing –e, in the word alkane, by the suffix –al.
Hence we get the name “alkanal”.
3. KETONES
Ketones are carbon compounds containing carbonyl – CO – group attached to two alkyl
groups. The general formula of ketone is R-CO-R’ where R and R’ are alkyl groups and
– CO – is the functional group.
The IUPAC name of ketone is derived by replacing –e, in the word alkane, by the suffix -one.
Hence we get the name “alkanone”.
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4. CARBOXYLIC ACIDS
Carboxylic acids are carbon compounds containing –COOH group attached to a hydrogen
atom or alkyl group. The general formula of acid is R-COOH where ‘R’ is a hydrogen
atom or alkyl group and –COOH is the functional group.
The IUPAC name of acid is derived by replacing – e, in the word alkane, by the suffix –
oic acid. Hence we get the name “alkanoic acid”.
ISOMERISM
Carbon compounds or organic compounds with same molecular formula can show
different structures and hence, different properties. This phenomenon is called isomerism
and compounds are called isomers.
For example, following two arrangements are possible for butane, an alkane with four C
atoms (C4H10)
Such pair of isomers is called chain isomers and the isomerism is called chain
isomerism. Thus, chain isomers are the compounds that have same molecular formula
but differ in the arrangement of carbon chains.
NOMENCLATURE OF CARBON COMPOUNDS
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In general, the names of organic compounds are based on the name of basic carbon chain
modified by a prefix (phrase before) or suffix (phrase after) showing the name of the
functional group.
Following steps are used to write the name of an organic compound
Step 1 Count the number of carbon atoms in the given compound and write the root word for
it (Root word upto 10 carbon atoms are tabulated below.)
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Step 2 If the compound is saturated, add suffix ‘ane’ to the root word, but if is unsaturated, add
suffix ‘ene’ and ‘yne’ for double and triple bonds respectively.
For example,CH3CH2CH3 contains three C atoms so root word is ‘prop’ and it contains
only single
bonds, so suffix used is ‘ane’. Hence, the name of this compound is propane.
Similarly, the compound CH3CH == CH2 is named as propene as here suffix ‘ene’ is used
for double bond.
Step 3 If functional group is present in the compound, it is indicated by adding its
suffix (which are given in the table above).
Prefix ‘iso’ and ‘neo’represent the presence of one or two carbon atoms respectively as
side chain.
If the functional group is named as a suffix, the final ‘e’ of alkane (or alkene or alkyne) is
substituted by appropriate suffix.
If the functional group and subtituents are not present at first carbon, then their location is
indicated by digits 1,2,3... .
INTEXT QUESTIONS PAGE NO. 68
Q1. How many structural isomers can you draw for pentane?
Ans:
Pentane (C5H12) has a skeleton of five carbon atoms. It can exist as straight chain as well
as two branched chains. The possible structural isomers have been shown below.
Q2. What are the two properties of carbon which lead to the huge number of carbon
compounds we see around us?
Ans:
The two features of carbon that give rise to a large number of compounds are as follows:
Catenation − It is the ability to form bonds with other atoms of carbon.
Tetravalency − With the valency of four, carbon is capable of bonding with four other
atoms.
Q3. What will be the formula and electron dot structure of cyclopentane?
Ans:
General formula of cycloalkane = CnH2n
In cyclopentane n = 5,
Formula of cyclopentane, C5H5 × 2 = C5H10
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Electron dot structure of cyclopentane
Q4. Draw the structures for the following compounds.
Ethanoic acid (ii) Bromopentane*
Butanone (iv) Hexanal.
Are structural isomers possible for
bromopentane? Ans:
Ethanoic acid
(ii) Bromopentane
(iii) Butanone
(iv) Hexanal.
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Yes, isomers of bromopentane are
(i) CH3CH2CH2CH2CH 2Br
1-bromopentane
Q5. How would you name the following compounds?
Ans:
(a) CH3 – CH2 – Br
Bromoethane (because for two carbons, root word is ‘eth’)
(b)
Formaldehyde or methanal (because for single carbon, root word is ‘meth’)
(c) CH3CH2CH2CH2CHC≡≡C,
1-hexyne (because for 6 carbons, root word is ‘hex’ and for triple bond suffix is ‘yne’.)
CHEMICAL PROPERTIES OF CARBON COMPOUNDS
COMBUSTION
All the carbon compounds burn in oxygen and yield carbon dioxide and water vapour.
Heat and light are also released during this process. This reaction is called combustion.
C + O2 → CO2 + heat and light
CH4 + O2 → CO2 + H2O + heat and light
CH3CH2OH + O2 → CO2 + H2O + heat and light
Further, once carbon and its compounds ignite, they keep on burning without the
requirement of additional energy. That’s why these compounds are used as fuels.
Saturated hydrocarbons give a clean flame due to their complete combustion whereas,
unsaturated hydrocarbons give a yellow flame with lots of black smoke as they do not
undergo complete combustion.
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OXIDATION
Oxidation is a process of intake of oxygen and removal of hydrogen. Those substances which
are capable of providing oxygen to other substances are called oxidising agents. e.g., alk.
KMnO4 and acidified K2Cr2O7 can both behave as oxidising agents.
ADDITION REACTION
The reaction in which a reagent adds completely on a substance without the removal of small
molecules are called addition reactions. For example, addition of hydrogen (in the presence of
catalysts like Palladium or Nickel) to unsaturated hydrocarbons, yields saturated hydrocarbons
(Hydrogenation).
Hydrogenation (addition of hydrogen) of vegetable oil (which are unsaturated compounds)
in the presence of nickel catalyst gives ghee (saturated compounds). This process is called
hardening of oils.
SUBSTITUTION REACTION
The reactions in which a reagent substitutes (replaces) an atom or a group of atoms from the
reactant (substrate) are called substitution reactions. These are generally shown by saturated
compounds and benzene.
Most of the saturated hydrocarbons are fairly inert and unreactive in the presence of most
reagents. So, presence of sunlight is necessary for their substitution reactions.
When chlorine is added to hydrocarbons at a rapid rate, in the presence of sunlight, Cl replaces
H atom one by one.
FUELS AND FLAMES
FUELS
Those carbon compounds which have stored energy in them and burn with heat and light are
called fuels. The released energy (heat or light) is utilised for various purposes like for cooking
food, running machines in factories, etc. In fuels, the carbon can be in free state as present in
coal, coke and charcoal or in combined state as present in petrol, LPG, kerosene, petroleum,
natural gas, etc. Those fuels which were formed by the decomposition of the remains of the
pre-historic plants and animals (fossils) burried under the earth long ago, are called fossils
fuels.
For example, coal, petroleum and natural gas.
COAL
It is a complex mixture of compounds of carbon, hydrogen and oxygen and some free carbon
alongwith traces of nitrogen and sulphur.
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It was formed by the decomposition of plants and trees buried under the earth millions of years
ago.
PETROLEUM
It is a dark viscous foul smelling oil and is also known as rock oil or black gold. It was formed
by the decomposition of the remains of extremely small plants and animals buried under the sea
millions of years ago.
FLAME
A flame is the region where combustion (or burning) of gaseous substances takes place.
Depending upon the amount of oxygen available and burning of fuels, flames are of following
two types
Blue or Non-luminous Flame
When the oxygen supply is sufficient, the fuels burn completely producing a blue flame. Since,
light is not produced during this type of combustion, so the flame is called non-luminous (non-
light giving flame), e.g., burning of LPG in gas stove.
Yellow or Luminous Flame
In the insufficient supply of air, the fuels burn incompletely and produce yellow flame. The
colour of the flame is yellow because of the presence of unburnt carbon particles. This flame
produces light so also known as luminous flame. e.g., burning of wax vapours.
INTEXT QUESTIONS PAGE NO. 71
Q1. Why is the conversion of ethanol to ethanoic acid an oxidation reaction?
Ans:
Since the conversion of ethanol to ethanoic acid involves the addition of oxygen to ethanol,
it is an oxidation reaction.
Q2. A mixture of oxygen and ethyne is burnt for welding. Can you tell why a mixture of
ethyne and air is not used?
Ans:
When ethyne is burnt in air, it gives a sooty flame. This is due to incomplete combustion
caused by limited supply of air. However, if ethyne is burnt with oxygen, it gives a clean flame
with temperature 3000°C because of complete combustion. This oxy-acetylene flame is used
for welding. It is not possible to attain such a high temperature without mixing oxygen. This is
the reason why a mixture of ethyne and air is not used.
SOME IMPORTANT CARBON COMPOUNDS – ETHANOL AND ETHANOIC ACID
Almost all the compounds are useful to us in a number of ways. Most of the fuels, medicines,
paints, explosives, synthetic polymers, perfumes and detergents are basically organic
compounds. In fact, organic chemistry has made our life colourful and also comfortable. Two
commercially important compounds are ethanol and ethanoic acid
ETHANOL (C2H5OH)
Ethanol or ethyl alcohol or simply alcohol is one of the most important members of the
family of alcohols.
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(1) Manufacture of ethanol from molasses
Molasses is a dark coloured syrupy liquid left after the crystallization of sugar from the
concentrated sugar cane juice. Molasses still contain about 30% of sucrose which can not be
separated by crystallization. It is converted into ethanol by the following steps:
(i) Dilution
Molasses is first diluted with water to bring down the concentration of sugar to about 8 to
10 percent.
(ii) Addition of ammonium salts
Molasses usually contains enough nitrogenous matter to act as food for yeast during
fermentation. If the nitrogen content of the molasses is poor, it may be fortified by the
addition of ammonium sulphate or ammonium phosphate.
(iii) Addition of yeast
The solution from step (ii) is collected in large ‘fermentation tanks’ and yeast is added to it.
The mixture is kept at about 303K for a few days.During this period, the enzymes invertase
and zymase present in yeast, bring about the conversion of sucrose into ethanol.
The fermented liquid is technically called wash.
FERMENTATION is the slow chemical change taking place in an organic compound
by the action of enzymes leading to the formation of smaller molecules.
(iv) Distillation of wash
The fermented liquid containing 15 to 18 percent alcohol and the rest of the water, is now
subjected to fractional distillation. The main fraction drawn, is an aqueous solution of ethanol
which contains 95.5% of ethanol and 4.5% of water. This is called rectified spirit. This
mixture is then heated under reflux over quicklime for about 5 to 6 hours and then allowed to
stand for 12 hours. On distillation of this mixture, pure alcohol (100%) is obtained. This is
called absolute alcohol.
PROPERTIES OF ETHANOL
PHYSICAL PROPERTIES
Ethanol is a clear liquid with burning taste.
Its boiling point is 351K which is higher than corresponding alkane.
It is completely miscible with water in all proportions.
CHEMICAL PROPERTIES
(i) DEHYDRATION
Intra molecular dehydration : Ethanol, when heated with excess conc. H2SO4 at 443 K
undergoes intra molecular dehydration (i.e. removal of water within a molecule of ethanol).
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Inter molecular dehydration : When excess of alcohol is heated with conc. H2SO4 at 413K
two molecules condense by losing a molecule of water to form ether (i.e. removal of water
from two molecules of ethanol).
Reaction with sodium : Ethanol reacts with sodium metal to form sodium ethoxide and
hydrogen gas.
Oxidation : Ethanol is oxidized to ethanoic acid with alkaline KMnO4 or acidified
K2Cr2O7
During this reaction, orange colour of K2Cr2O7 changes to green. Therefore, this reaction
can be used for the identification of alcohols.
Esterificaiton : Ethanol reacts with ethanoic acid in the presence of conc.H2SO4 (catalyst) to
form ethyl ethanoate and water. The compound formed by the reaction of an alcohol with
carboxylic acid is known as ester (fruity smelling compound) and the reaction is called
esterification.
Dehydrogenation : When the vapour of ethanol is passed over reduced copper catalyst at
573 K, it is dehydrogenated to acetaldehyde.
USES OF ETHANOL
As an anti-freeze in automobile radiators.
As a preservative for biological specimen.
As an antiseptic to sterilize wounds in hospitals.
As a solvent for drugs, oils, fats, perfumes, dyes, etc.
In the preparation of methylated spirit (mixture of 95% of ethanol and 5% of methanol),
rectified spirit (mixture of 95.5% of ethanol and 4.5% of water), power alcohol (mixture
of petrol and ethanol) and denatured sprit (ethanol mixed with pyridine).
In cough and digestive syrups.
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EVIL EFFECTS OF CONSUMING ALCOHOL
If ethanol is consumed, it tends to slow down metabolism of our body and depresses the
central nervous system.
It causes mental depression and emotional disorder.
It affects our health by causing ulcer, high blood pressure, cancer, brain and liver damage.
Nearly 40% accidents are due to drunken drive.
Unlike ethanol, intake of methanol in very small quantities can cause death.
Methanol is oxidized to methanal (formaldehyde) in the liver and methanal reacts rapidly
with the components of cells.
Methanal causes the protoplasm to get coagulated, in the same way an egg is coagulated by
cooking. Methanol also affects the optic nerve, causing blindness.
ETHANOIC ACID (CH3COOH)
Ethanoic acid is most commonly known as acetic acid and belongs to a group of acids called
carboxylic acids. Acetic acid is present in many fruits and sour taste of fruits is because of this
acid.
PREPARATION OF ETHANOIC ACID
Ethanol on oxidation in the presence of alkaline potassium permanganate or
acidified potassium dichromate gives ethanoic acid.
PROPERTIES OF ETHANOIC ACID
PHYSICAL PROPERTIES
Ethanoic acid is a colourless liquid and has a sour taste.
It is miscible with water in all proportions.
Boiling point (391 K) is higher than corresponding alcohols, aldehydes and ketones.
On cooling, pure ethanoic acid is frozen to form ice like flakes. They look like glaciers, so it
is called glacial acetic acid.
CHEMICAL PROPERTIES
Ethanoic acid is a weak acid but it turns blue litmus to red.
Reaction with metal
Ethanoic acid reacts with metals like Na, K, Zn, etc to form metal ethanoate and hydrogen gas.
Reaction with carbonates and bicarbonates.
Ethanoic acid reacts with carbonates and bicarbonates and produces brisk effervescence due
to the evolution of carbon dioxide.
Reaction with base
Ethanoic acid reacts with sodium hydroxide to form sodium ethanoate and water.
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Decarboxylation (Removal of CO2)
When sodium salt of ethanoic acid is heated with soda lime (Solid mixure of 3 parts of
NaOH and 1 part of CaO) methane gas is formed.
USES OF ETHANOIC ACID
For making vinegar which is used as a preservative in food and fruit juices.
As a laboratory reagent.
For coagulating rubber from latex.
In the preparation of dyes, perfumes and medicine.
INTEXT QUESTIONS PAGE NO. 74
Q1. How would you distinguish experimentally between an alcohol and a carboxylic acid?
Ans:
Sodium bicarbonate test (NaHCO3 test)
Alcohol + NaHCO3 → No effervescence
Acid + NaHCO3 → Brisk effervescence
The sample which produces brisk effervescence when treated with NaHCO3 due to release
of CO2 is a carboxylic acid.
Q2. What are oxidising agents?
Ans:
Those substances which are capable of providing oxygen to other substances are called
oxidising agents. e.g., alk. KMnO4 and acidified K2Cr2O7 can both behave as oxidising agents.
SOAPS AND DETERGENTS
Most dirt is oily in nature and as you
know, oil does not dissolve in water. The
molecules of soap are sodium or potassium
salts of long-chain carboxylic acids. The
ionic-end of soap dissolves in water while
the carbon chain dissolves in oil. The soap
molecules, thus form structures called
micelles (see the below figure) where one
end of the molecules is towards the oil
droplet while the ionic-end faces outside.
This forms an emulsion in water. The soap
micelle thus helps in dissolving the dirt in
water and we can wash our clothes clean.
MICELLES
Soaps are molecules in which the two ends
have differing properties, one is
hydrophilic, that is, it dissolves in water,
while the other end is hydrophobic, that is,
it dissolves in hydrocarbons. When soap is
at the surface of water, the hydrophobic
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‘tail’ of soap will not be soluble in water and the soap will align along the surface of water with
the ionic end in water and the hydrocarbon ‘tail’ protruding out of water. Inside water, these
molecules have a unique orientation that keeps the hydrocarbon portion out of the water. This
is achieved by forming clusters of molecules in which the hydrophobic tails are in the interior
of the cluster and the ionic ends are on the surface of the cluster. This formation is called a
micelle.
Soap in the form of a micelle is able to clean, since the oily dirt will be collected in the centre
of the micelle. The micelles stay in solution as a colloid and will not come together to
precipitate because of ion-ion repulsion. Thus, the dirt suspended in the micelles is also easily
rinsed away. The soap micelles are large enough to scatter light. Hence a soap solution appears
cloudy.
INTEXT QUESTIONS PAGE NO. 76
Q1. Would you be able to check if water is hard by using a detergent?
Ans:
Detergents are ammonium or sulphonate salts of long chain carboxylic acids. Unlike soap, they
do not react with calcium and magnesium ions present in hard water to form scum. They give a
good amount of lather irrespective of whether the water is hard or soft. This means that
detergents can be used in both soft and hard water. Therefore, it cannot be used to check
whether the water is hard or not.
Q2. People use a variety of methods to wash clothes. Usually after adding the soap, they
‘beat’ the clothes on a stone, or beat it with a paddle, scrub with a brush or the mixture is
agitated in a washing machine. Why is agitation necessary to get clean clothes? Ans:
A soap molecule has two parts namely hydrophobic and hydrophilic. With the help of these, it
attaches to the grease or dirt particle and forms a cluster called micelle. These micelles remain
suspended as a colloid. To remove these micelles (entrapping the dirt), it is necessary to
agitate clothes.
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EXERCISE QUESTIONS PAGE NO. 77 and 78
Q1. Ethane, with the molecular formula C2H6 has
6 covalent bonds.
7 covalent bonds.
8 covalent bonds.
9 covalent bonds.
Ans:
Structure of C2H6 is
It is clear that it has 7 covalent bonds.
Q2. Butanone is a four-carbon compound with the functional group
carboxylic acid.
aldehyde.
ketone.
alcohol.
Ans: (c) In butanone, the function group is ketone (one)
Q3. While cooking, if the bottom of the vessel is getting blackened on the outside, it means
that
the food is not cooked completely.
the fuel is not burning completely.
the fuel is wet.
the fuel is burning completely.
Ans: (b) The unburnt particles of the fuel present in smoke blacken the vessel from outside.
Q4. Explain the nature of the covalent bond using the bond formation in CH3Cl.
Ans:
Atomic number of
C = 6; H = 1; Cl = 17
Electronic configuration
KL KLM K
C2 4 Cl 2 8 7 H 1
C needs 4 electrons to complete its octet, H needs 1 and Cl needs 1 electron.
C shares its 4 electrons with each of the 3 H-atoms and 1 with chlorine atom. It thus forms
4 covalent bonds as shown.
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Q5. Draw the electron dot structures for
ethanoic acid.
H2S.
propanone.
F2 .
Ans:
(a) ethanoic acid.
H2S.
propanone.
(d) F2 .
Q6. What is an homologous series? Explain with an example.
Ans:
A homologous series is a series of carbon compounds that have different numbers of carbon atoms but
contain the same functional group.
Example of homologous series
Alkane series CnH2n + 2
CH4 Methane, C2H6 Ethane
C3H8 Propane, C4H10 Butane C5H12 Pentane
It can be noticed that there is a difference of −CH2 unit between each successive compound.
Q7. How can ethanol and ethanoic acid be differentiated on the basis of their physical
and chemical properties?
Ans:
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I. Distinction based on physical properties
Smell Ethanoic acid has a pungent smell. Ethanol has a pleasant smell.
Melting point Ethanol has lower melting point (150 K) than ethanoic acid (290 K).
Physical state Ethanoic acid is solid (glacial acetic acid) in winters but ethanol is always a
liquid.
II. Distriction based on chemical properties
Action with sodium hydrogen carbonate On adding a small amount of sodium hydrogen
carbonate to ethanoic acid, carbon dioxide gas is evolved with brisk effervescence.
However, no such reaction noticed in case of ethanol.
Action with caustic alkalies Ethanoic acids reacts with both sodium hydroxide (NaOH)
and potassium hydroxide (KOH) to form corresponding salt and water. Ethanol fails to react
with either of these.
Q8. Why does micelle formation take place when soap is added to water? Will a
micelle be formed in other solvents such as ethanol also? Ans:
A soap is a sodium or potassium salt of long chain fatty acids. It has one polar end and one
non-polar end. The polar end is hydrophilic in nature i.e., this end is attracted towards water.
The non-polar end is hydrophobic but lipophilic, i.e., it is attracted towards hydrocarbons.
When soap is added to water, soap molecules arrange themselves in a cluster to keep the non-
polar portion out of water such that the non-polar ends are in the interior of the cluster and the
polar ends are on the surface of the cluster. Since the dirt present on clothes is organic in nature
and insoluble in water, the hydrophobic ends of the clusters attach themselves to the dirt. This
cluster formation in which the dirt is entrapped is the micelle. Micelle formation does not occur
in alcohol because the alkyl chain of soap becomes soluble in alcohol.
Q9. Why are carbon and its compounds used as fuels for most applications?
Ans:
Carbon burns in oxygen (air) to form carbon dioxide and water.
During this reaction a large amount of heat and light are released. Further, once ignited carbon
and its compounds keep on burning without the requirement of additional energy. Hence, they
are used as fuels.
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Q10. Explain the formation of scum when hard water is treated with soap.
Ans:
Soap does not work properly when the water is hard. A soap is a sodium or potassium salt of
long chain fatty acids. Hard water contains salts of calcium and magnesium. When soap is
added to hard water, calcium and magnesium ions present in water displace sodium or
potassium ions from the soap molecules forming an insoluble substance called scum. A lot of
soap is wasted in the process.
Reaction taking place are shown below.
Q11. What change will you observe if you test soap with litmus paper (red and blue)?
Ans:
Since soap is basic in nature, it will turn red litmus blue. However, the colour of blue litmus
will remain blue.
Q12. What is hydrogenation? What is its industrial application?
Ans:
Hydrogenation is the process of addition of hydrogen. Unsaturated hydrocarbons are added
with hydrogen in the presence of palladium and nickel catalysts to give saturated hydrocarbons.
This reaction is applied in the hydrogenation of vegetables oils, which contain long chains of
unsaturated carbons.
Q13. Which of the following hydrocarbons undergo addition reactions:
C2H6, C3H8, C3H6, C2H2 and CH4.
Ans:
Unsaturated hydrocarbons containing double/ triple bond undergo addition reactions.
So, C3H6 and C2H2 will undergo addition reactions.
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Q14. Give a test that can be used to differentiate chemically between butter and cooking
oil.
Ans:
Butter contains saturated compounds while cooking oil contains unsaturated compounds. Since
unsaturated compounds are oxidised by alkaline KMnO4 with disappearance of its pink colour.
When cooking oil is treated with a few drops of alkaline KMnO4, pink colour of
KMnO4 disappears. With butter however, the pink colour KMnO4 does not disappear
Q15. Explain the mechanism of the cleaning action of soaps.
Ans:
Cleansing action of soaps:
The dirt present on clothes is organic in nature and insoluble in water. Therefore, it cannot be
removed by only washing with water. When soap is dissolved in water, its hydrophobic ends
attach themselves to the dirt and remove it from the cloth. Then, the molecules of soap arrange
themselves in micelle formation and trap the dirt at the centre of the cluster. These micelles
remain suspended in the water. Hence, the dust particles are easily rinsed away by water.
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ASSIGNMENT QUESTIONS SET – 1
CHAPTER – 4
CARBON AND ITS COMPOUND
Which of the following is not a saturated hydrocarbon ?
Cyclohexane.
Benzene.
Butane
isobutene
The bond between two identical non metallic atom has a pair of electron ?
un equally shared between two atoms.
Transferred completely from one atom to another.
With identical spins
Unequally shared between them.
Covalent compounds are generally
Soluble in water
Insoluble in water
Ionize in water
Hydrolyse in water
Propane with the molecular formula C3H8 has
7covalent bonds
8 covalent bonds
9 covalent bonds
10 Covalent bonds.
A hydrocarbon reacts with ammonical cuprous chloride solution to form a red precipitate
.The hydrocarbon
is i)ethane ii)ethene
iii)butane iv)1-
propyne
Which of the following substance is added to denature Ethanol ?
i)methanolii)pyridine
iii)copper sulphate iv)all of them
Which of the following is not an allotropic form of carbon
i)fluorineii)fullerene
iii)diamondiv)graphite
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Which of the following represents the correct decreasing order of hydrogen atoms ?
i)alkanes , alkenes , alkynes
ii)alkanes , alkaynes , alkenes
iii)alkenes , alkynes , alkanes
iv)alkynes , alkanes , alkenes
Detergents are sodium or potassium salts of long chain of ;-
i)aldehydes
ii)ketones
iii)carboxylic acid
iv)sulphonic acid
Which of the following represents the structure of N2 Mmolecule ?
N≡ N
N=N
N-N
None of the above
In double covalent bond there is sharing of
2 electrons
4 electrons
6 electrons
3 electrons
Cation is formed when
atom gains electrons
atom loses electrons
proton is lost by the atom
atom shared by electrons
The total no. of electrons that take part in forming a bond in N2 is
2
4
6
10
Which of the following has the weakest carbon-carbon strength?
i)C2H2
ii)C2H4
iii)C2H6
iv)all have the same bond strength
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Which of the following salt when dissolved in water produce hard water.
calcium sulphate
magnesium bicarbonate
calcium chloride
any of the above
Which of the following is not a saturated hydrocarbon ?
cyclohexane
benzene
butane
isobutane
The bond between two identical nonmetallic atom has a pair of electron ?
unequally shared between two atoms
transferred completely from one atom to another
With identical spins
Equally shared between them
Covalent compounds are generally –
Soluble in water
insoluble in water
Ionize in water
hydrolyse in water
Propane with molecular formula C3H8 has –
7 covalent bonds
8 covalent bonds
9 covalent bonds
10 covalent bonds
A hydrocarbon reacts with ammonical cuprous chloride solution to form a red precipitate,
the hydrocarbon is –
Ethane
ethane
butane
1-propyne
Which of the following substance is added to denature Ethanol?
i) Methanol ii) pyridine iii) copper sulphate iv)
all of these
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Which of the following is not an allotropic form of carbon ?
fluorine
fullerene
diamond
graphite
Which of the following represents the correct deceasing order of hydrogen atoms ?
alkanes, alkenes, alkynes
alkanes, alkynes, alkenes
alkenes, alkynes, alkanes
alkynes, alkanes, alkenes
Detergents are sodium or potassium salts of long chain of :
aldehydes
ketones
carboxylic acid
sulphonic acid
In double covalent bond there is a sharing of
2 electrons
4 electrons
6 electrons
3 electrons
Cation is formed when
atom gains electrons
atom losses electrons
proton is lost by the atom
atom shared by electrons
The total number of electrons that take part in forming a bond in N2 is
2
4
6
10
Which of the following has the weakest carbon-carbon strength ?
C2H2
C2H4
C2H6
all have the same bond strength
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Which of the following salt when dissolved in water produce hard water ?
calcium sulphate
magnesium bicarbonate
calcium chloride
any of the above.
The two colours seen at the extreme ends of the pH charts are:-
red and blue
ii)red and green
green and blue
orange and green
Carboxylic acids on heating with P2O5 gives:-
ethers
alcohol
carbonyl compounds
anhydrides
Synthetic flavours contain:-
unsaturated acids
esters
dilute carboxylic acids
hydroxyl acids
Out of the following which one is used as preservative for pickle and sauces:-
i) esters ii) acetone iii) aldehyde iv) acetic acid
Brisk effervescences produced when a pinch of Na2CO3 is added to CH3COOH is due to
the formation of :-
i) H2 gas ii) CO2 gas
4
When an acetic acid reacts with an alcohol in the presence of conc. H2SO4:-
i) esters are formed ii) ketones are formed iii) aldehydes are
formed iv) none of these
Sodium bi carbonate solution is added to dilute Ethanoic acid. It is observed that:-
a gas evolves
a solid settles at the bottom
the mixture becomes vapour
the colour of the mixture becomes light Yellow
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Ethanoic acid was added to sodium bicarbonate sol. And the gas evolved was tested with a
burning splinter. The following four observations were reported:-
the gas burns with the pop sound and the flame gets extinguished.
the gas does not burn out but the splinter burns with a pop sound
the flame extinguishes and the gas does not burn
the gas burns with a blue flame and the splinter burns brightly.
1
2
3
4
2ml of ethanoic acid was taken in each test tube 1 and 2 .A red litmus paper was introduced in
test tube 1 and a pH paper was introduced in test tube 2. The experiment was performed by
4 students A, B, C, D and they reported their observation as given in the table. Student
action on red action on litmus PH paper
A) Turned blue turned pink
B) Remains unchanged turned
green C) Turned blue turned blue
D) Remains unchanged turned pink
The correct observation is reported in
A
B
C
D
Acetic acid was added to a solid X kept in a Test tube. A colourless, odourless gas Y was
evolved. The gas was passed through the lime water, which turned milky. It concludes
that:-
solid X is NaOH and the gas Y is CO2
solid X is Na2CO3 and the gas Y is CO2
solid X is sodium acetate and the gas y is CO2
solid X is sodium chloride and the gas Y is CO2
Why is carbon tetravalent?
The formula of a hydrocarbon is CnH2n. Name the family to which it belongs and also
predicts its nature.
What is the valency of carbon in CH3-CH3, CH2=CH2 and HC=CH ?
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Out of butter and ground nut oil , which is unsaturated in Nature?
Why is high temperature not favourable for alcoholic fermentation?
Name a cyclic unsaturated hydrocarbon, containing three double bonds?
What is the difference in the molecular mass of any two adjacent homologues?
Which has triple bond ; C2H4 ,C3H6 and C3H4 ?
Which substance is added to denature ethyl alcohol?
Which ions are responsible for making water hard?
Name the catalyst commonly used in hydrogenation of oil to form fats?
Write the name and molecular formula of alcohol derived from butane ?
Which gas is evolved when sodium carbonate or bicarbonate is added to ethanoic acid?
What is SCUM ?
What are hydrophobic and hydrophilic parts in soaps?
How much percentage of earth’s crust constitutes carbon element ?
What do you mean by covalency ?
What is covalent bond ?
What is functional group ?
What is organic chemistry ?
What name is given to the reaction which take place when Ethanoic acid reacts with ethanol in
the presence of conc. Sulphuric acid ? Name the products obtained in this reaction.
What is bromination ? Write the structural formula of product obtained on bromination of
propene.
Define covalency ?
Write the structural formula of the isomers of n-butane?
Name the organic acid present in vinegar. Write its Chemical formula also.
The structural formula of an ester is HCOOCH2CH2CH3 write the formula of acid and the
alcohol from which it is made ?
What happens when ethanol reacts with
sodium
potassium permanganate solution.
Which of the following hydrocarbons undergo addition reactions : C2H6, C3H8, C3H6, C2H2
and CH4.
What is hydrogenation? Write its industrial application.
Give a test that can be used to differentiate between butter and cooking oil ?
Give the names of the functional group;-
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–CHO
-C=O
( iii) –OH
–COOH
Explain the following terms : a)
Etherification
b) Saponification
c) Dehydration
An organic compound A having molecular fomula C2H4O2 reacts with Sodium metal Na
evolves a gas B which readily catches fire. A also reacts with Ethanol in the presence of
concentrated Sulphuric acid to form a sweet smelling substance C in making perfumes.
a) Identify the compounds A, B and C.
b) Write balanced chemical equation to represent the conversion of
(i). Compound A to compound B.
(ii). Compound A to compound C.
Give the name of the following :
a) An Aldehyde derived from Ethane.
b) Ketone derived from Butane.
c) The compound obtained by the Oxidation of Ethanol by Chromic anhydride.
Write chemical equations of the reactions of Ethanoic acid with : a)
Sodium
b) Sodium Carbonate
c) Ethanol in the presence of conc. H2SO4.
Give a test to distinguish between: a)
Ethane and Ethene
b) Ethanol with Ethanoic
acid. c) Soaps and detergents.
Complete the following reactions: a)
H2C=CH2 + H2O H2SO4
b) HC≡CH + Br2
c) C2H5OH + Na
d) CH3COOH + C2H5OH
Two carbon compounds A and B have the molecular formula C3H8 and C3H6 respectively.
Which one of the two each most likely to show addition reaction? Justify your
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answer. Explain with the help of a chemical equation, how an addition is useful in
vegetable Ghee industry.
What substance should be oxidised to prepare acetic acid (CH3COOH)? How can ethanol and
Ethanoic acid be differentiated?
Write down the difference between soap and detergents.
An organic compound A is widely used as a preservative in pickles and has a molecular
formula C2H4O2. This compound reacts with ethanol to form a sweet smelling compound
B.
Identify the compound A.
Write the chemical equation for its reaction with Ethanol to form compound B.
How can we get compound A back from B?
Name the process and write corresponding chemical equation.
Which gas is produced when compound A reacts with washing soda? Write the chemical
equation
An organic compound X with a molecular formula C2H6O undergoes oxidation with in
presence of alkaline KMnO4 to form a compound Y. X on heating in presence of Conc.
H2SO4 at 443K gives Z.which on reaction with H2O in presence of H2SO4 gives back
`X.` `Z` reacts with Br2 (aq) and decolorizes it. Identify X, Y, & Z.and write the
reactions involved.
An organic compound ‘A’ is widely used as a preservative in pickles and has a molecular
formula C2H2O2. This compound reacts with ethanol to form a sweet smelling compound
‘B.
(i) Identify the compound ‘A’
(ii) Write the chemical equation for its reaction with ethanol to form compound ‘B’. (iii)
How can we get compound ‘A’ back from ‘B’?
(iv) Name the process and write corresponding chemical equation.
(v) Which gas is produced when compound ‘A’ reacts with washing soda? Write the
chemical equation.
Hydrocarbon `X` and `Y` having molecular formulae C 3H8 and C3H6 respectively. Both are
burnt in different spatula on the bunsen flame. Indicate the color of the flame produced by
`X` and `Y`. Identify `X` and `Y`. Write the structural formulae.
A compound `X` has molecular formula C4H10. It undergoes substitution reaction readily
than addition reaction. It burns with blue flame and is present in LPG. Identify `X` and give
the balanced equation for its combustion and substitution reaction with C l2 in presence of
sunlight.
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`A` compound works well with hard water. It is used for making shampoos & products for
cleaning clothes. A is not 100% biodegradable and causes water pollution. `B` does not
work well with hard water. It is 100% biodegradable and does not create water pollution.
Identify A & B.
An organic compound P with molecular formula C 2H6O is an active ingredient of all alcoholic
drinks. It is also used in medicines such as tincture iodine, cough syrups. Identify `P`. Drop
a small piece of sodium into the test tube containing `P`.A new compound `Q` is formed
with the evaluation of colorless and odorless gas Name the gas evolved and compound `Q`
write the chemical reaction.
A cyclic compound `X` has molecular formula C6H6. It is unsaturated and burns with sooty
flame. Identify `X` and write its structural formula. Will it decolorize bromine water or not
and why?
An organic compounds `A` is a constituent of antifreeze and has the molecular formula C 2H6O.
upon reaction with alkaline KMnO 4, the compound `A` is oxidized to another `B` with
formula C2H6O2. Identify the compound A` and `B`. Write the chemical equation for the
reaction which leads to the formulation of `B`
Two compounds `X` and `Y` have the same formula C 2H4O2. One of them reacts with sodium
metal to liberate H2 and CO2 with NaHCO3. Second one does not reacts with Na metal and
NaHCO3 but undergo hydrolysis with NaOH to form salt of carboxylic acid and compound
`Z` which is called wood spirit. Identify `X`, `Y`, and `Z` and write chemical equation for
the reaction involved.
A compound `X` with molecular formula C 2H4 burns with a sooty flame. It decolourise
bromine water. Identify `X`. Will it dissolve in water or not? Will it conduct electricity in
aq. Solution? Will it have high melting point or low melting point ?
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ASSIGNMENT QUESTIONS SET – 2
CHAPTER – 4
CARBON AND ITS COMPOUND
Carbon exists in the atmosphere in the form of
carbon monoxide only
carbon monoxide in traces and carbon dioxide
carbon dioxide only
coal
Which of the following statements are usually correct for carbon compounds? These
are good conductors of electricity
are poor conductors of electricity
have strong forces of attraction between their molecules
do not have strong forces of attraction between their molecules
(a) (i) and (iii) (b) (ii) and (iii)
(c) (i) and (iv) (d) (ii) and (iv)
A molecule of ammonia (NH3) has
(a) only single bonds
(b) only double bonds
(c) only triple bonds
(d) two double bonds and one single bond
Buckminsterfullerene is an allotropic form of
(a) phosphorus
(b) sulphur
(c) carbon
(d) tin
Oils on treating with hydrogen in the presence of palladium or nickel catalyst form fats.
This is an example of
(a) Addition reaction
(b) Substitution reaction
(c) Displacement reaction
(d) Oxidation reaction
In which of the following compounds, — OH is the functional group?
(a) Butanone (b) Butanol
(c) Butanoic acid (d) Butanal
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Which of the following are correct structural isomers of butane?
(i) and (iii) (b) (ii) and (iv)
(i) and (ii) (d) (iii) and (iv)
In the below given reaction, alkaline KMnO4 acts as
reducing agent
oxidising agent
catalyst
dehydrating agent
Structural formula of ethyne is
The soap molecule has a
hydrophilic head and a hydrophobic tail
hydrophobic head and a hydrophilic tail
hydrophobic head and a hydrophobic tail
hydrophilic head and a hydrophilic tail
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Which of the following is the correct representation of electron dot structure of nitrogen?
Identify the unsaturated compounds from the following
Propane
Propene
Propyne
Chloropropane
(i) and (ii) (b) (ii) and (iv)
(iii) and (iv) (d) (ii) and (iii)
Chlorine reacts with saturated hydrocarbons at room temperature in the
absence of sunlight
presence of sunlight
presence of water
presence of hydrochloric acid
In the soap micelles
the ionic end of soap is on the surface of the cluster while the carbon chain is in the
interior of the cluster.
ionic end of soap is in the interior of the cluster and the carbon chain is out of the
cluster.
both ionic end and carbon chain are in the interior of the cluster
both ionic end and carbon chain are on the exterior of the cluster
Pentane has the molecular formula C5H12. It has
5 covalent bonds
12 covalent bonds
16 covalent bonds
17 covalent bonds
Ethanol reacts with sodium and forms two products. These are
sodium ethanoate and hydrogen
sodium ethanoate and oxygen
sodium ethoxide and hydrogen
sodium ethoxide and oxygen
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Structural formula of benzene is:
The correct structural formula of butanoic acid is
Vinegar is a solution of
50% – 60% acetic acid in alcohol
5% – 8% acetic acid in alcohol
5% – 8% acetic acid in water
50% – 60% acetic acid in water
Mineral acids are stronger acids than carboxylic acids because
mineral acids are completely ionised
carboxylic acids are completely ionised
mineral acids are partially ionised
carboxylic acids are partially ionised
(a) (i) and (iv) (b) (ii) and (iii) (c) (i) and (ii) (d) (iii) and (iv)
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Carbon forms four covalent bonds by sharing its four valence electrons with four univalent
atoms, e.g. hydrogen. After the formation of four bonds, carbon attains the electronic
configuration of
helium
neon
argon
krypton
The correct electron dot structure of a water molecule is
Which of the following is not a straight chain hydrocarbon?
Which among the following are unsaturated hydrocarbons?
(i) and (iii) (b) (ii) and (iii)
(ii) and (iv) (d) (iii) and (iv)
Which of the following does not belong to the same homologous series?
(a) CH4 (b) C2H6
(c) C3H8 (d) C4H8
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The name of the compound CH3 — CH2 — CHO is
Propanal
Propanone
Ethanol
Ethanal
The heteroatoms present in CH3 — CH2 — O — CH2— CH2Cl are
oxygen
carbon
hydrogen
chlorine
(i) and (ii) (b) (ii) and (iii)
(iii) and (iv) (d) (i) and (iv)
Which of the following represents saponification reaction?
The first member of alkyne homologous series is
ethyne
ethene
propyne
methane
Draw the electron dot structure of ethyne and also draw its structural formula
Why detergents are better cleansing agents than soaps? Explain.
Name the functional groups present in the following compounds
CH3 CO CH2 CH2 CH2 CH3
CH3 CH2 CH2 COOH
CH3 CH2 CH2 CH2 CHO
CH3 CH2 OH
How is ethene prepared from ethanol? Give the reaction involved in it.
Intake of small quantity of methanol can be lethal. Comment.
A gas is evolved when ethanol reacts with sodium. Name the gas evolved and also write the
balanced chemical equation of the reaction involved.
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Write the names of the following compounds
Identify and name the functional groups present in the following compounds.
A compound X is formed by the reaction of a carboxylic acid C2H4O2 and an alcohol in
presence of a few drops of H2SO4. The alcohol on oxidation with alkaline KMnO4
followed by acidification gives the same carboxylic acid as used in this reaction. Give the
names and structures of (a) carboxylic acid, (b) alcohol and (c) the compound X. Also
write the reaction.
Ethene is formed when ethanol at 443 K is heated with excess of concentrated sulphuric
acid. What is the role of sulphuric acid in this reaction? Write the balanced chemical
equation of this reaction.
Carbon, Group (14) element in the Periodic Table, is known to form compounds with many
elements. Write an example of a compound formed with
chlorine (Group 17 of Periodic Table)
oxgygen (Group 16 of Periodic Table)
In electron dot structure, the valence shell electrons are represented by crosses or dots. (a)
The atomic number of chlorine is 17. Write its electronic configuration (b) Draw the
electron dot structure of chlorine molecule.
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Catenation is the ability of an atom to form bonds with other atoms of the same element. It is
exhibited by both carbon and silicon. Compare the ability of catenation of the two
elements. Give reasons.
Unsaturated hydrocarbons contain multiple bonds between the two C-atoms and show
addition reactions. Give the test to distinguish ethane from ethene.
Write the structural formulae of all the isomers of hexane.
What is the role of metal or reagents written on arrows in the given chemical reactions?
A salt X is formed and a gas is evolved when ethanoic acid reacts with sodium
hydrogencarbonate. Name the salt X and the gas evolved. Describe an activity and draw
the diagram of the apparatus to prove that the evolved gas is the one which you have
named. Also, write chemical equation of the reaction involved.
What are hydrocarbons? Give examples.
Give the structural differences between saturated and unsaturated hydrocarbons with two
examples each.
What is a functional group? Give examples of four different functional groups.
Name the reaction which is commonly used in the conversion of vegetable oils to fats.
Explain the reaction involved in detail.
Write the formula and draw electron dot structure of carbon tetrachloride.
What is saponification? Write the reaction involved in this process.
Esters are sweet-smelling substances and are used in making perfumes. Suggest some activity
and the reaction involved for the preparation of an ester with well labeled diagram.
A compound C (molecular formula, C2H4O2) reacts with Na – metal to form a compound R
and evolves a gas which burns with a pop sound. Compound C on treatment with an
alcohol A in presence of an acid forms a sweet smelling compound S (molecular formula,
C3H6O2). On addition of NaOH to C, it also gives R and water. S on treatment with NaOH
solution gives back R and A. Identify C, R, A, S and write down the reactions involved.
Draw the possible isomers of the compound with molecular formula C3H6O and also give
their electron dot structures.
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How would you bring about the following conversions? Name the process and write the
reaction involved.
ethanol to ethene.
propanol to propanoic acid.
Explain the given reactions with the examples
Hydrogenation reaction
Oxidation reaction
Substitution reaction
Saponification reaction
Combustion reaction
An organic compound A on heating with concentrated H2SO4 forms a compound B which
on addition of one mole of hydrogen in presence of Ni forms a compound C. One mole
of compound C on combustion forms two moles of CO2 and 3 moles of H2O. Identify
the compounds A, B and C and write the chemical equations of the reactions involved.
Define Allotropy.
What is vinegar ?
What is combustion ?
How can you differentiate saturated and unsaturated Hydrocarbon on the basis of burning
behaviour ?
Give two advantages of synthetic detergents over soaps ?
What are substitution reactions ?
Differentiate between diamond and graphite.
Discuss the method of preparation of soap in the laboratory.
Write five ill effects of alcohol drinking.
Differentiate between ionic compounds and covalent compounds.
Give some important properties of ethanol (ethyl alcohol).
Give five main advantages of synthetic detergents over soaps.
Write important uses of (a) ethanol and (b) ethanoic acid.
72. What happens when ethanol reacts with (i) sodium (ii) potassium permanganate
solution.
An organic acid ‘X’ is a liquid which often freezes during winter time in cold countries, has
the molecular formula, C2H4O2. On warming it with ethanol in the presence of a few
drops of concentrated sulphuric acid, a compound ‘Y’ with a sweet smell is formed
(i) Identify ‘X’ and ‘Y’. (ii) Write a chemical equation for the reaction involved.
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Write name of the following –
Alkaline earth metal belonging to the third period
The alkali metal atom having largest atomic radius
The halogen atom belonging to fourth period
The element having lowest ionization energy
The element having second lowest electronegativity
Organic compound 'x' of molecular formula C2H4O2 gives brisk effervescence with sodium
bi carbonate . give name and molecular formula of x with balanced equation
Soaps are not considered as effective cleansing agent. Why?
How does melting and boiling points of hydrocarbon change with the increase in molecular
mass ?
Write down the relevant chemical equation involved in decolourisation.
A compound X has molecular formula C3H4 one mole of X reacts with 2 moles of
hydrogen to yield a compound Y deduce the structure of X and Y.
What is dehydration reaction? Give one example.
What is hydrolysis?
Why doesn’t soap form micelles in ethanol as they form in water?
Three elements X,Y and Z belong to 17TH group but to 2nd 3th and 4th period respectively.
Number of valance electrons in X is 7Find the number of valance electrons in X and Z.
What is the use of oxyacetylene flame?
What is observed on adding 5% solution of alkaline potassium permanganate solution drop
by drop to some warm ethanol taken in testube.
Write the name of the compound formed during chemical reaction.
How would you distinguish experimentally between an alcohol and a carboxylic acid on
the basis of a chemical property?
Why are vegetable oils healthy as compared to vegetable ghee ? how are vegetable oils
converted into vegetable ghee name the process.
When acetic acid reacts with X, a salt is formed which on reaction with soda lime gives a
gas Y. Identify X and Y
“Alkenes form a homologous series" Explain.
Why does Ethanoic acid called glacial acetic acid? (Imp.)
Why is the conversion of ethanol to ethanoic acid an oxidation reaction? (Imp.)
A mixture of ethyne and oxygen is burnt for welding. Can you tell why a mixture of ethyne
and air is not used? (Imp.)
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Why is the conversion of ethanol to ethanoic acid considered an oxidation reaction?
Who was the first to suggest the classification of chemical compounds into inorganic
compounds and organic compounds?
Why are the compounds of carbon studied as a separate branch of chemistry?
Compounds like calcium carbide, carbon monoxide, carbon dioxide, calcium carbonate
etc., are considered as inorganic compounds although they have carbon atoms in their
molecule. Give reason.
Why compounds like B-B, Si-Si, and S-S do not exist in nature?
What is “Buckminster fullerene”? And why it is called so?
Name the first organic compound obtained from an inorganic source in the laboratory. Who
synthesized it?
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CHAPTER – 5
PERIODIC CLASSIFICATION OF ELEMENTS
In the beginning of 18th century Joseph Louis Proust stated that hydrogen atom is the building
material and atoms of all other elements are simply due to the combination of number of
hydrogen atoms. (It is to be noted that at his time the atomic weight of all elements were given
as whole numbers and the atomic weight of hydrogen was taken as one.)
DOBEREINER’S TRIADS
A German chemist Johann Wolfgang Dobereiner (1829) noted that there were groups of
elements with three elements known as triads. Elements in each group or a triad possess with
similar chemical properties. Dobereiner discovered that “the relative atomic mass of the middle
element in each triad was close to the average of the relative atomic masses of the other two
elements”. This statement is called the Dobereiner’s law of Triads.
In this table, atomic mass of sodium is equal to arithmetic mean of atomic masses of lihtium and
potassium. Similarly, atomic mass of strontium is equal to arithmetic mean of atomic masses of calcium
and barium.
LIMITATION OF DOBEREINER’S TRIADS:
All the then known elements could not be arranged in the form of triads.
The law failed for very low mass or for very high mass elements. In case of F, Cl, Br,
the atomic mass of Cl is not an arithmetic mean of atomic masses of F and Br.
As the techniques improved for measuring atomic masses accurately, the law was unable
to remain strictly valid.
NEWLANDS’ LAW OF OCTAVES
Newlands law of octaves states that when elements are arranged in the ascending order of their
atomic masses they fall into a pattern in which their properties repeat at regular intervals. Every
eighth element starting from a given elements resembles in its properties to that of the starting
element.
LIMITATION OF NEWLANDS’ OCTAVES:
Newlands’ Octaves could be valid upto calcium only; as beyond calcium, elements do not
obey the rules of Octaves.
Newlands’ Octaves was valid for lighter elements only.
It appears that Newlands did not expect the discovery of more elements than 56 which were
discovered till his time.
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More than one element had to be placed in some of the groups; in order to place the
elements having similar properties in one group. But in order to do so, he also put some
dissimilar elements in same group.
Iron; which has similar property as cobalt and nickel, was placed far from them.
Cobalt and nickel were placed in the group with chlorine and fluorine in spite of having
different properties.
In spite of above limitations; Newlands was the first scientist who arranged the elements in
order of their increasing relative atomic masses.
INTEXT QUESTIONS PAGE NO. 81
Q1. Did Dobereiner’s triads also exist in the columns of Newlands’ Octaves? Compare
and find out.
Ans:
Yes. Lithium, sodium and potassium; beryllium; magnesium and calcium are two triads
that also exist in the columns of Newland’s octaves.
Q2. What were the limitations of Dِbereiner’s classification?
Ans:
Please see above notes
Q3. What were the limitations of Newlands’ Law of Octaves?
Ans:
Please see above notes
MENDELEEV’S PERIODIC TABLE
Mendeleef arranged the elements known at that time in a chart in a systematic order in the
increasing order of their atomic weights. He divided the chart into 8 vertical columns known as
groups. Each group is divided into A, B sub groups. Each column contained elements of
similar chemical properties.
The elements in the first column, for example, react with oxygen to form compounds with the
general formula R2O. For example, Li, Na and K when react with oxygen form compounds like
Li2O, Na2O and K2O respectively.
Elements of the second column react with oxygen to form compounds with the general formula
RO. For example, Be, Mg and Ca when react with oxygen form BeO, MgO and CaO.
Mendeleef tried to explain the similarities of elements in the same group in terms of their
common valency.
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THE PERIODIC LAW:
Based on Mendeleeff’s observations regarding the properties of elements in the periodic
table, a law known as the periodic law of the properties of elements was proposed.
“The law states that the physical and chemical properties of the elements are a
periodic function of their atomic weights.”
SALIENT FEATURES AND ACHIEVEMENTS OF THE MENDELEEFF’S PERIODIC
TABLE:
Groups and sub-groups: There are eight vertical columns in Mendeleeff’s periodic table called
as groups. They are represented by Roman numerals I to VIII. Elements present in a given
vertical column (group) have similar properties. Each group is divided into two sub-group
‘A’ and ‘B’. The elements within any sub-group resemble each other to great extent. For
example, sub-group IA elements called ‘alkali metals’ (Li, Na, K, Rb, Cs, Fr) resemble
each other very much.
Periods: The horizontal rows in Mendeleeff’s periodic table are called periods. There are seven
periods in the table, which are denoted by Arabic numerals 1 to 7. A period comprises the
entire range of elements after which properties repeat themselves.
Predicting the properties of missing elements: Based on the arrangement of the elements in the
table he predicted that some elements were missing and left blank spaces at the appropriate
places in the table.
Mendeleef believed that some new elements would be discovered definitely. He
predicted the properties of these new additional elements in advance purely
depending on his table. His predicted properties were almost the same as the observed
properties of those elements after their discovery.
He named those elements tentatively by adding the prefix ‘eka’ (eka is a Sanskrit numeral
means one) to the name of the element immediately above each empty space. The predicted
the properties of elements namely eka-aluminium, eka-boron, eka-aluminium and eka-
silicon were close to the observed properties of Scandium, Gallium and Germanium
respectively which were discovered later.
Correction of atomic mass: the correct placement of elements in Mendeleeff’s
periodic table helped in correcting the atomic masses of some elements like,
Beryllium, Indium, Gold.
For example, At the time of Mendeleef, beryllium was given atomic weight
13.5. Atomic weight = equivalent weight × valency
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The equivalent weight of Be was found experimentally as 4.5 and its valency was
understood as 3. Therefore atomic weight of beryllium was given as 4.5 × 3 = 13.5.
With this atomic weight it had to be placed in a wrong group in the table. He said that
its valency should be only 2 and then its atomic weight then would be 4.5 × 2 =
9. If atomic weight of ‘Be’ is 9 it would fit in the second group and its properties
practically are similar to Mg, Ca etc., of the second group elements. He also helped
in the calculation of the correct atomic weights of ‘Indium’ and ‘Gold’ in this
manner.
Some anomalous series of elements like ‘Te’ and ‘I’ were observed in the table. The
anomalous series contained element with more atomic weight like ‘Te’ (127.6 u)
placed before the element with less atomic weight like ‘I’ (126.9 u). Mendeleeff
accepted minor inversions in the order of increasing atomic weight when these
inversions resulted in elements being placed in the correct groups.
It was the extraordinary thinking of Mendeleeff that made the chemists to accept the
periodic table and recognise Mendeleeff more than anyone else as the originator of the
periodic law.
LIMITATIONS OF MENDELEEFF’S PERIODIC TABLE:
Position of hydrogen: The position of hydrogen in the table is not certain because it can be
placed in group IA as well as in group VIIA as it resembles both with alkali metals of IA
group and halogens of VIIA group.
Anomalous pair of elements: Certain elements of highest atomic mass precede those with
lower atomic mass.
For example, tellurium (atomic mass 127.6) precedes iodine (atomic mass 126.9).
Cobalt and nickel: argon and potassium which were placed in table by deviating the basis
of classification (placement in ascending order of atomic masses).
For example, potassium (atomic mass 39) placed after argon (atomic mass 40).
Similar situation was found in pairs of cobalt and nickel and tellurium, iodine.
Dissimilar elements placed together: elements with dissimilar properties were placed in same
group as sub-group A and sub-group B. For example, alkali metal like Li, Na, K etc., of IA
group have little resemblance with coinage metals like Cu, Ag, Au of IB group.
Some similar elements separated: some similar elements like ‘copper and mercury’ and
‘silicon and thalium’ etc are placed in different groups of the periodic table.
Position of isotopes: isotopes of elements are placed in the same position in the table.
INTEXT QUESTIONS PAGE NO. 85
Q1. Use Mendeléev’s Periodic Table to predict the formulae for the oxides of
the following elements:
K, C, AI, Si, Ba.
Ans:
Oxygen is a member of group VIA in Mendeleef’s Periodic Table. Its valency is 2.
Similarly, the valencies of all the elements listed can be predicted from their respective
groups. This can help in writing the formulae of their oxides.
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Potassium (K) is a member of group IA. Its valency is 1. Therefore , the formula of its
oxide is K2O .
Carbon (C) is a member of group IVA. Its valency is 4. Therefore, the formula of its oxide is
C2O4 or CO2.
Aluminium (Al) belongs to groups IIIA and its valency is 3. The formula of the oxide of the
element is Al2O3.
Silicon (Si) is present in group IVA after carbon. Its valency is also 4. The formula of its
oxide is Si2O4 or SiO2.
Barium (Ba) belongs to group IIA and the valency of the element is 2. The formula of the
oxide of the element is Ba2O2 or BaO.
Q2. Besides gallium, which other elements have since been discovered that were left by
Mendeléev in his Periodic Table? (any two) Ans:
Scandium and germanium are the two elements that had been left by Mendeleef.
Q3. What were the criteria used by Mendeléev in creating his Periodic Table?
Ans:
The criteria used by Mendeleef were
Physical and chemical properties of the elements.
Atomic masses in increasing order.
Q4. Why do you think the noble gases are placed in a separate group?
Ans:
Noble gases are also called inert gases because they have a complete octet and hence, are very
stable. They do not react with other elements due to their stability. Since they all are unreactive,
have complete octet and similar behaviour so they are placed in a separate group .
THE MODERN PERIODIC TABLE
Based on the modern periodic law, a number of forms of periodic table have been proposed
from time to time but general plan of the table remained the same as proposed by Mendeleev.
The table which is most commonly used and which is based upon the electronic configuration
of elements is called the long form of the periodic table. This is called the modern periodic
table.
Long form of the periodic table is a chart of elements in which the elements have been arranged
in the increasing order of their atomic numbers. This table consists of horizontal rows called
periods and vertical columns called groups.
The modern periodic table has also been divided into four blocks known as s,p,d and
f blocks.
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STUDY OF PERIODS
The horizontal rows are called periods. There are seven horizontal rows in the periodic table.
First period (Atomic number 1 and 2): This is the shortest period. It contains only two
elements (hydrogen and helium).
Second period (Atomic number 3 to 10): This is a short period. It contains eight elements
(lithium to neon).
Third period (Atomic number 11 to 18): This is also a short period. It contains eight
elements (sodium to argon).
Fourth period (Atomic number 19 to 36): This is a long period. It contains eighteen
elements (potassium to krypton). This includes 8 normal elements and 10 transition
elements.
Fifth period (Atomic number 37 to 54): This is also a long period. It contains 18 elements
(rubidium to xenon). This includes 8 normal elements and 10 transition elements.
Sixth period (Atomic number 55 to 86): This is the longest period. It contains 32 elements
(ceasium to radon). This includes 8 normal elements, 10 transition elements and 14 inner
transition elements (lanthanides).
Seventh period(Atomic number 87 to 118): As like the sixth period, this period also can
accomodate 32 elements. Till now only 26 elements have been authenticated by IUPAC.
STUDY OF GROUPS
Vertical columns in the periodic table starting from top to bottom are called groups. There
are 18 groups in the periodic table.
First group elements are called alkali metals.
Second group elements are called alkaline earth metals.
Groups three to twelve are called transition elements .
Group 1, 2 and 13 - 18 are called normal elements or main group elements or
representative elements .
Group 16 elements are called chalcogen family (except polonium).
Group 17 elements are called halogen family.
Group 18 elements are called noble gases or inert gases.
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The lanthanides and actinides which form part of the group 3 are called inner
transition elements.
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CHARACTERISTICS OF MODERN PERIODIC TABLE
CHARACTERISTICS OF PERIODS
In a period, the electrons are filled in the same valence shell of all elements.
As the electronic configuration changes along the period, the chemical properties of
the elements also change.
Atomic size of the elements in a period decreases from left to the right.
In a period, the metallic character of the element decreases while their non-metallic
character increases.
CHARACTERISTICS OF GROUPS
The elements present in 2 and 18 groups differ in atomic number by 8,8,18,18,32.
The elements present in 13 – 17 groups differ in atomic number by 8,18,18,32.
The elements present in 4 – 12 groups differ in atomic number by 18,32,32.
The elements present in a group have the same number of electrons in the valence shell
of their atoms.
The elements present in a group have the same valency.
The elements present in a group have identical chemical properties.
The physical properties of the elements in group such as melting point, boiling
point, density vary
gradually.
Atomic radii of the elements present in a group increases downwards.
ADVANTAGES OF THE MODERN PERIODIC TABLE
The table is based on a more fundamental property ie., atomic number.
It correlates the position of the element with its electronic configuration more clearly. The
completion of each period is more logical. In a period as the atomic number increases,
the energy shells are gradually filled up until an inert gas configuration is reached.
It is easy to remember and reproduce.
Each group is an independent group and the idea of sub-groups has been discarded.
One position for all isotopes of an element is justified, since the isotopes have the same
atomic number.
The position of eighth group (in Mendeleev’s table) is also justified in this table. All
transition elements have been brought in the middle as the properties of transition elements
are intermediate between left portion and right portion elements of the periodic table.
The table completely separates metals from non-metals. The nonmetals are present in upper
right corners of the periodic table.
The positions of certain elements which were earlier misfit (interchanged) in the
Mendeleev’s periodic table are now justified because it is based on atomic number of
the elements.
Justification has been offered for placing lanthanides and actinides at the bottom of the
periodic table.
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DEFECTS IN THE MODERN PERIODIC TABLE
Position of hydrogen is not fixed till now.
Position of lanthanides and actinides has not been given inside the main body of periodic
table.
It does not reflect the exact distribution of electrons of some of transition and inner
transition elements.
INTEXT QUESTIONS PAGE NO. 90
Q1. How could the Modern Periodic Table remove various anomalies of Mendeléev’s
Periodic Table?
Ans:
The fundamental basis for Modern Periodic Table is atomic number and not atomic mass
and hence, it is more accurate.
Properties of elements could be well explained when they were arranged according to their
increasing atomic number in the Modern Periodic Table.
A separate group for noble gases could be created when noble gases were discovered.
Hydrogen has been given a unique position in the Modern Periodic Table at the top left
corner because of its unique properties.
Q2. Name two elements you would expect to show chemical reactions similar to
magnesium. What is the basis for your choice? Ans:
Magnesium (Mg) belongs to group 2 of Modern Periodic Table, known as alkaline earth
metal family. The two other elements belonging to the same group are beryllium (Be) and
calcium (Ca).
Calcium and magnesium; Beryllium and magnesium - This is because both of them have electronic
configuration similar to Mg
Mg K L M
2 8 2
Ca K L M N
2 8 8 2
Be K L
2
These elements belong to the same group and hence, will show similar properties.
Q3. Name
three elements that have a single electron in their outermost shells.
two elements that have two electrons in their outermost shells.
three elements with filled outermost shells.
Ans:
(a) Li Na K
2, 1 2,8,1 2, 8, 8,1
(b) Mg Ca
2,8,2 2,8,8,2
(c) He Ar Ne
2 2,8 2,8,8
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Q4. (a) Lithium, sodium, potassium are all metals that react with water to liberate
hydrogen gas. Is there any similarity in the atoms of these elements?
Helium is an unreactive gas and neon is a gas of extremely low reactivity. What, if
anything, do their atoms have in common?
Ans:
Li, Na, and K have one electron in their outermost shell.
Li 2,1 (Atomic number 3)
Na 2,8, 1 (Atomic number 11)
2, 8, 8, 1 (Atomic number 19)
They both have completely filled outer shell.
K L
He 2 8 (Atomic number 2)
Ne 2 (Atomic number 10)
Q5. In the Modern Periodic Table, which are the metals among the first ten elements?
Ans:
Metals among the first ten elements are lithium and beryllium.
Q6. By considering their position in the Periodic Table, which one of the following
elements would you expect to have maximum metallic characteristic?
Ga Ge As Se Be
Ans:
The position of the given elements in the Periodic Table is as.
Ga Ge As Se Br (Most metallic) → (Least
metallic)
On moving from left to right in a period, size decreases due to increase in effective nuclear
charge and hence, tendency to lose electron, i.e., metallic character decreases. Thus Ga has
maximum metallic characteristic or metallic nature.
EXERCISE QUESTIONS PAGE NO. 91 and 92
Q1. Which of the following statements is not a correct statement about the trends when
going from left to right across the periods of periodic Table.
The elements become less metallic in nature.
The number of valence electrons increases.
The atoms lose their electrons more easily.
The oxides become more acidic.
On moving from left to right, the atomic number increases and hence, the nuclear charge
increases. With the increase of nuclear charge, the force binding the electron increases so the
atom lose the electrons with more difficulty, not easily.
Q2. Element X forms a chloride with the formula XCl2, which is a solid with a high
melting point. X would most likely be in the same group of the Periodic Table as
Na (b) Mg (c) AI (d) Si
Ans:
The formula of chloride is XCl2 that means the valency of the element X is 2. The element
having valency 2 will present in group 2. Out of given choices magnesium (Mg) belongs to
group 2.
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Q3. Which element has
two shells, both of which are completely filled with electrons?
the electronic configuration 2, 8, 2?
a total of three shells, with four electrons in its valence shell?
a total of two shells, with three electrons in its valence shell?
twice as many electrons in its second shell as in its first shell?
Ans:
Noble gases are the elements which have completely filled shells. The noble gas with two
shells is Ne having atomic number 10 and electronic configuration 2, 8 both of which are
completely filled.
Electronic configuration 2, 8, 2 suggests that atomic number is 12 (2 + 8 + 2), magnesium (Mg)
has atomic number 12.
The element with three shells and form electrons in the valence shell will have electronic
configuration 2, 8, 4. The atomic number of this element is 14 (2 + 8 + 4) so it will belong to
group 14 hence, it is silicon (Si).
Element with two shells with 3 electrons in the valence shell will exist in second period and
will have the electronic configuration 2,3. The atomic number of this element will be 5 (2 + 3).
So, it will be bron (B).
The element has two shells. we know that first shell can have only 2 electrons, so according to
the question there will be 4 electrons (double the number of electrons in first shell). The
electronic configuration will be 2, 4 , so the atomic number is 6. Hence, the element is carbon
(C).
Q4. (a) What property do all elements in the same column of the Periodic Table as
boron have in common?
What property do all elements in the same column of the Periodic Table as fluorine
have in common?
Ans:
All elements of 13th group, in which boron is present, have 3 electrons in their valence
shell (2, 8, 3).
Fluorine belongs to 17th group. All elements of this group have 7 electrons in their valence
shell (2, 8, 7). They all show a valency of 1 in their compounds.
Q5. An atom has electronic configuration 2, 8, 7.
What is the atomic number of this element?
To which of the following elements would it be chemically similar? (Atomic numbers
are given in parentheses.) N(7) F(9) P(15) Ar(18)
Ans:
Atomic number of atom = 2 + 8 + 7 =17
It will be similar to fluorine which is also having 7 electrons in its valence shell [F (2, 7)].
Q6. The position of three elements A, B and C in the Periodic Table are shown below –
Group 16 Group 17
--- ---
A
---
C
State whether A is a metal or non-metal.
State whether C is more reactive or less reactive than A.
Will C be larger or smaller in size than B?
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Which type of ion, cation or anion, will be formed by element A?
Ans:
Since, A belongs to group 1 valence electrons so it is a non-metal because it will gain
electron to complete its octet.
C lies below A and in the same group. As we move down in a group, the size increases and
electronegative character decreases. With the increase in electronegative character, the
electron adapting tendency and hence the reactivities decrease so, C is less reactive than A.
C is smaller than B in size because as we move left to right in a period atomic size
decreases.
As discussed in part (a) that element A has a tendency to gain electron to complete its octet. It
−
needs to take up one electron, so it will form anion (A ).
Q7. Nitrogen (atomic number 7) and phosphorus (atomic number 15) belong to group 15
of the Periodic Table. Write the electronic configuration of these two elements. Which of
these will be more electronegative? Why?
Ans:
(a) Electronic configuration of nitrogen and phosphorus:
N K L M
2, 5
P 2, 8, 5
N will be more electronegative than P as electronegativity decreases on going down a group in
case of non-metals.
Q8. How does the electronic configuration of an atom relate to its position in the Modern
Periodic Table?
Ans:
The number of valence electrons in an atom of an element tells us the group number. e.g., Na
has atomic number 11 K L M
Electronic configuration of Na (11) =
2 8 1
It has one electron in its last shell, thus it belongs to group I of the Periodic Table.
The number of shells in its electronic configuration tells the period number e.g., Na shows
3 shells K, L, M so it belongs to 3rd period of the Periodic Table.
Q9. In the Modern Periodic Table, calcium (atomic number 20) is surrounded by
elements with atomic numbers 12, 19, 21 and 38. Which of these have physical and
chemical properties resembling calcium?
Ans:
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From the electronic configuration written above we can see that element with atomic
number 12 and 38 have 2 electrons in their last shell like calcium. So, they will resemble Ca
in their physical and chemical properties.
Q10. Compare and contrast the arrangement of elements in Mendeléev’s Periodic Table
and the Modern Periodic Table.
Ans:
Mendeleev’s periodic table Modern periodic table
1. Elements are arranged in the increasing 1. Elements are arranged in the increasing
order of their atomic masses. order of their atomic numbers.
2. There are a total of 7 groups (columns) 2. There are a total of 18 groups
and 6 periods (rows). (columns) and 7 periods (rows).
3. Elements having similar properties 3. Elements having the same valence shell
were placed directly under one another. are present in the same period while
elements having the same number of
valence electrons are present in the
same group.
4. The position of hydrogen could not be 4. Hydrogen is placed above alkali metals.
explained.
5. No distinguishing positions for metals 5. Metals are present at the left hand side
and non-metals. of the periodic table whereas non-
metals are present at the right hand
side.
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ASSIGNMENT QUESTIONS SET – 1
CHAPTER – 5
PERIODIC CLASSIFICATION OF ELEMENTS
The property of an element in the periodic table depends on its, ________.
atomic size
atomic mass
electronic configuration
number of protons
An element has configuration 2, 8, 1. It belongs to, _________.
. 1 group and 3rd period
. 3 group and 1st period
. 1 group and 8th period
. 17 group and 3rd period
The number of electrons in the valence shell is equal to its ________.
. atomic mass
. group number
. period number
. atomic volume
The non-metallic element present in the third period other than sulphur and chlorine is
. oxygen
. fluorine
. nitrogen
. phosphorus
At the end of each period the valence shell is __________.
. incomplete
. half filled
. singly occupied
. completely filled
The family of elements having seven electrons in the outermost shell is ______.
. alkali metals
. alkaline earth metals
. halogens
. noble gases
Which of the following factors does not affect the metallic character of an element?
. Atomic size
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 175 -
ii). Ionisation potential
iii). Electronegativity
iv). Atomic radius
The family of elements to which potassium belongs is _________.
i). alkali metals
ii). alkaline earth
metals iii). halogens
iv). noble gases
The modern periodic table is given by ________
i). Mendeleev
ii). Einstein
iii). Bohr iv).
Mosley
Elements belonging to groups 1 to 17 are called __________. i).
noble gases
ii). normal elements
iii). transition elements
iv). inner transition elements
A liquid non-metal is ___________. i).
phosphorous
ii). mercury
iii). bromine
iv). nitrogen
The first alkali metal is _________. i).
hydrogen
ii). lithium
iii). sodium
iv). francium
A purple coloured solid halogen is ________. i).
chlorine
ii). bromine
iii). iodine
iv). astatine
Lanthanides and actinides are also called ___________. i).
normal elements
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 176 -
ii). transition elements
iii). noble gases
iv). inner transition elements
The family of elements to which calcium belongs is __________.
i). alkali metals
ii). alkaline earth
metals iii). halogens
iv). noble gases
The least reactive element in group 17 is ___________. i).
fluorine
ii). chlorine
iii). bromine
iv). iodine
The valency of chlorine with respect to oxygen is __________. i).
1
ii). 3
iii). 5
iv). 7
The number of shells in the elements of 3rd period is __________. i).
1
ii). 2
iii). 3
iv). 0
Four elements along a period have atomic number (11, 13, 16 and 17). The most metallic
among these has an atomic number of __________.
i). 11
ii). 12
iii). 16
iv). 17
Six elements A, B, C, D, E and F have the following atomic numbers (A = 12, B = 17, C = 18,
D = 7, E = 9 and F = 11). Among these elements, the element, which belongs to the 3rd
period and has the highest ionisation potential, is __________.
i). A
ii). B
iii). C
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iv). F
A factor that affects the ionisation potential of an element is __________. i).
atomic size
ii). electron affinity
iii). electro-negativity
iv). neutrons
The element, which has the highest electron affinity in the 3rd period is _________. i).
Na
ii). Mg
iii). Si
iv). Cl
The element, which has zero electron affinity in the 3rd period is __________. i).
Al
ii). P
iii). Ar
iv). S
The statement that is not true about electron affinity is i).
It causes energy to be released
ii). It causes energy to be absorbed
iii). It is expressed in electron volts
iv). It involves formation of an anion
Down a group, the electron affinity __________. i).
increases
ii). decreases
iii). remains same
iv). increases and then decreases
Name an element with five electrons in the outer shell.
Name an element which tends to lose two electrons.
Name an element that would tend to gain two electrons.
Name the group having a non metal liquid as well as non metal gas at room temperature.
Name the group having element with zero valency.
Name the metalloid present in group 14.
What is the name given to group of three similar elements by Dobereiner?
State "Newlands law of Octaves" for classification of elements.
Name the fundamental property used by Mendeleev as the basis of classification.
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 178 -
How many groups and periods are there in the Modern periodic table?
What was the prediction of Mendeleev regarding the gaps in his periodic table?
How is valence of an element determined?
What will be the valence of an element having atomic number 16?
How does valence vary in going down a group?
Why inert gases have zero valences?
What would be the valence of an atom containing 8 electrons in its outermost shell?
How does the electronegative character of elements vary along a period of the periodic
table?
The present classification of elements is based on which fundamental property of elements?
Among first ten elements in the modern periodic table name the metals present.
Metals are on which side of Modern periodic table?
State Mendeleev’s periodic law.
Name two elements, other than Gallium, whose existence was predicted by Mendeleev.
State Modern Periodic law.
Write the name given to the vertical columns in a periodic table.
What name is given to the horizontal rows in a periodic table?
Why does silicon is classified as Metalloid?
State two limitations of Newland's law of Octaves.
Name the scientist who proposed modern periodic law? On which fundamental property of
elements it is based?
Why could no fixed position be given to hydrogen in Mendeleev’s Periodic table?
What are metalloids? Give two examples.
In group 1 of periodic table three elements X, Y and Z have atomic radii 133 pm , 95pm and
65pm respectively giving a reason, arrange them in the increasing order of their atomic
number in the group.
In modern periodic table, the isotopes of Chlorine Cl-35 and Cl-37 having different atomic
masses will be kept in different slots or they would be assigned same position on the
basis of their chemical properties? Give reason in support of your answer.
Nitrogen (At no. 7) and Phosphorus (At no. 15) belong to group 15 of the periodic table:-
Write the electronic configuration of the two.
Predict whether they are metallic or nonmetallic in nature.
How and why does the atomic size vary as you go down a group?
Why was Dobereiner system of classification of elements into triads not found to be
useful?
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 179 -
State three merits of Modern periodic table.
What are amphoteric oxides? Choose the amphoteric oxide from among the following
oxides :– Na2O, ZnO, Al2O3, CO2, H2O
Study the variation in the atomic radii of first group elements given below and arrange
them in increasing order :–
Group I element Na Li Rb Cs K
Atomic Radii P.M 86 152 244 262 231
An element X has the electronic configuration as 2, 8, 7 :–
What is the atomic number of the element?
What will be the formula of its compound formed with Na?
What is the name given to the family of this element?
How do you calculate the valence of the element from its electronic configuration? What is
the valence of Mg with atomic number 12 and sulphur with atomic number 16? How does
the valence vary in going down in a group?
Atomic radii of the elements of the period II are as follows:–
Period II elements : Be B O N C Li
Atomic Radius : 111 88 66 74 77 152
Arrange them in decreasing order of their atomic radii.
How does the atomic size vary on moving from left to right in a period? Explain why?
How will the tendency to lose electrons will vary on moving from left to right in this
period II?
Oxygen (O, 8) and sulphur (S, 16) belong to group 16 of the periodic table:-
Write the electronic configuration and valence of these two elements?
Which among these will be more electronegative? Why?
Two elements ‘A’ and ‘B’ belong to group 1 and 2 respectively in the same period.
Compare them with respect to :–
(a) Number of valence electrons. (b) Valency
(c) Metallic character (d) Size of atom
(e) Formulae of their oxides.
What is periodicity?
Who showed for the first time that there is periodicity in properties of elements?
Are the properties of elements placed in a group same?
Give reason for the need of classification of elements.
Hydrogen can be placed in group 1 and group 7 of periodic table. Why?
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 180 -
Name two elements whose properties were correctly predicted by Mendeleev. Mention
their present day name.
State Mendeleev's periodic law. Why did he leave gaps in his periodic table?
An element Z is of second group of the periodic table. Write the formula of its oxide.
Noble gases did not find a place in Newland's Octaves. Explain.
Give formula for the following:
bromide of element X of second group.
oxide of element Y of third group.
chloride of element Z of fourth group.
How many elements are present in (i) Second period (ii) Six period
Name (i) A Non metal solid at room temperature (ii) A Metal liquid at room temperature
Arrange the following elements in the decreasing order of metallic character.
Si, Be, Mg, Na, P
B, Al, Mg, K
How in modern periodic table position of elements in groups and periods is decided?
Why metallic character decreases across a period and increases down a group?
Among the elements of second period ‘Li’ to ‘Ne’ pick out the element.
with the largest atomic radius
that is the most reactive non metal
that is the most reactive metal
which is a metalloid.
Elements A, B, C, D, E have following electronic configurations-A:
2,3
B: 2,8,3
C: 2,8,5
D: 2,8,7
E: 2,8,8,2
Which of these belong to same group?
Which of these belong to same period?
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 181 -
ASSIGNMENT QUESTIONS SET – 2
CHAPTER – 5
PERIODIC CLASSIFICATION OF ELEMENTS
Upto which element, the Law of Octaves was found to be applicable
Oxygen
Calcium
Cobalt
Potassium
According to Mendeleev's Periodic Law, the elements were arranged in the periodic table in
the order of
increasing atomic number
decreasing atomic number
increasing atomic masses
decreasing atomic masses
In Mendeleev ’s Periodic Table, gaps were left for the elements to be discovered later.
Which of the following elements found a place in the perioidc table later
Germanium
Chlorine
Oxygen
Silicon
Which of the following statement (s) about the Modern Periodic Table are incorrect
The elements in the Modern Periodic Table are arranged on the basis of their decreasing
atomic number
The elements in the Modern Periodic Table are arranged on the basis of their increasing
atomic masses
Isotopes are placed in adjoining group (s) in the Periodic Table
(iv) The elements in the Modern Periodic Table are arranged on the basis of
their increasing atomic number
(i) only (b) (i), (ii) and (iii)
(i), (ii) and (iv) (d) (iv) only
Which of the following statements about the Modern Periodic Table is correct:
It has 18 horizontal rows known as Periods
It has 7 vertical columns known as Periods
It has 18 vertical columns known as Groups
It has 7 horizontal rows known as Groups
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Which of the given elements A, B, C, D and E with atomic number 2, 3, 7, 10 and 30
respectively belong to the same period?
A,B,C
B,C,D
A,D,E
B,D,E
The elements A, B, C, D and E have atomic number 9, 11, 17, 12 and 13 respectively.
Which pair of elements belong to the same group?
A and B
B and D
A and C
D and E
Where would you locate the element with electronic configuration 2,8 in the Modern
Periodic Table?
Group 8
Group 2
Group 18
Group 10
An element which is an essential constituent of all organic compounds belongs to
group 1
group 14
group 15
group 16
Which of the following is the outermost shell for elements of period 2?
K shell
L shell
M shell
N shell
Which one of the following elements exhibit maximum number of valence electrons?
(a) Na (b) Al
(c) Si (d) P
Which of the following gives the correct increasing order of the atomic radii of O, F and N
?
(a) O, F, N (b) N, F, O
(c) O, N, F (d) F, O, N
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 183 -
Which among the following elements has the largest atomic radii?
Na
Mg
K
Ca
Which of the following elements would lose an electron easily?
Mg
Na
K
Ca
Which of the following elements does not lose an electron easily?
(a) Na (b) F
(c) Mg (d) Al
Which of the following are the characteristics of isotopes of an element?
Isotopes of an element have same atomic masses
Isotopes of an element have same atomic number
Isotopes of an element show same physical properties
Isotopes of an element show same chemical properties
(i), (iii) and (iv) (b) (ii), (iii) and (iv)
(ii) and (iii) (d) (ii) and (iv)
Arrange the following elements in the order of their decreasing metallic character
Na, Si, Cl, Mg, Al
Cl > Si >Al > Mg >Na
Na >Mg >Al >Si > Cl
Na > Al > Mg > Cl > Si
Al > Na> Si > Ca> Mg
Arrange the following elements in the order of their increasing nonmetallic character
Li, O, C, Be, F
F < O < C < Be < Li
Li < Be < C < O< F
F < O < C < Be < Li
F < O < Be < C < Li
What type of oxide would Eka– aluminium form?
(a) EO3 (b) E3O2
(c) E2O3 (d) EO
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Three elements B, Si and Ge are
(a) metals (b) non-metals
(c) metalloids (d) metal, non-metal and metalloid respectively
Which of the following elements will form an acidic oxide?
An element with atomic number 7
An element with atomic number 3
An element with atomic number 12
An element with atomic number 19
The element with atomic number 14 is hard and forms acidic oxide and a covalent halide.
To which of the following categories does the element belong?
(a) Metal (b) Metalloid
(c) Non-metal (d) Left-hand side element
Which one of the following does not increase while moving down the group of the periodic
table?
Atomic radius
Metallic character
Valence
Number of shells in an element
On moving from left to right in a period in the periodic table, the size of the atom.
(a) increases (b) decreases
(c) does not change appreciably (d) first decreases and then increases
Which of the following set of elements is written in order of their increasing
metallic character?
(a) Be Mg Ca
(b) Na Li K
(c) Mg Al Si
(d) C O N
The three elements A, B and C with similar properties have atomic masses X, Y and Z
respectively. The mass of Y is approximately equal to the average mass of X and Z. What is
such an arrangement of elements called as? Give one example of such a set of elements.
Elements have been arranged in the following sequence on the basis of their increasing
atomic masses.
F, Na, Mg, Al, Si, P, S, Cl, Ar, K
Pick two sets of elements which have similar properties.
The given sequence represents which law of classification of elements?
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Can the following groups of elements be classified as Dobereiner's triad ?
In Mendeleev ’s Periodic Table the elements were arranged in the increasing order of their
atomic masses. However, cobalt with atomic mass of 58.93 amu was placed before
nickel having an atomic mass of 58.71 amu. Give reason for the same.
“Hydrogen occupies a unique position in Modern Periodic Table”. Justify the statement.
Write the formulae of chlorides of Eka-silicon and Eka-aluminium, the elements predicted
by Mendeleev.
Three elements A, B and C have 3, 4 and 2 electrons respectively in their outermost shell.
Give the group number to which they belong in the Modern Periodic Table. Also, give
their valencies.
If an element X is placed in group 14, what will be the formula and the nature of bonding of
its chloride?
Compare the radii of two species X and Y. Give reasons for your answer.
X has 12 protons and 12 electrons
Y has 12 protons and 10 electrons
Arrange the following elements in increasing order of their atomic radii.
Identify and name the metals out of the following elements whose electronic configurations
are given below.
(a) 2, 8, 2 (b) 2, 8, 1
(c) 2, 8, 7 (d) 2, 1
Write the formula of the product formed when the element A (atomic number 19) combines
with the element B (atomic number 17). Draw its electronic dot structure. What is the
nature of the bond formed?
Arrange the following elements in the increasing order of their metallic character
Mg, Ca, K, Ge, Ga
Identify the elements with the following property and arrange them in increasing order of
their reactivity
An element which is a soft and reactive metal
The metal which is an important constituent of limestone
The metal which exists in liquid state at room temperature
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Properties of the elements are given below. Where would you locate the following
elements in the periodic table?
A soft metal stored under kerosene
An element with variable (more than one) valency stored under water.
An element which is tetravalent and forms the basis of organic chemistry
An element which is an inert gas with atomic number 2
An element whose thin oxide layer is used to make other elements corrosion resistant by
the process of “ anodising”
An element is placed in 2nd Group and 3rd Period of the Periodic Table, burns in presence of
oxygen to form a basic oxide.
Identify the element
Write the electronic configuration
Write the balanced equation when it burns in the presence of air
Write a balanced equation when this oxide is dissolved in water
Draw the electron dot structure for the formation of this oxide
An element X (atomic number 17) reacts with an element Y (atomic number 20) to form a
divalent halide.
Where in the periodic table are elements X and Y placed?
Classify X and Y as metal (s), non-metal (s) or metalloid (s)
What will be the nature of oxide of element Y? Identify the nature of bonding in the
compound formed
Draw the electron dot structure of the divalent halide
Atomic number of a few elements are given below 10, 20, 7, 14
Identify the elements
Identify the Group number of these elements in the Periodic Table
Identify the Periods of these elements in the Periodic Table
What would be the electronic configuration for each of these elements?
Determine the valency of these elements
In which form matter is present around us?
At present, how many elements are known to us?
The earliest attempt in classifying elements resulted in the formation of two groups of
elements. What are they?
Who made the first attempt of classifying elements?
On what basis Dobereiner classified elements?
Dobereiner classified elements into how many groups?
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What name was given to Dobereiner groups?
What is the total number of elements in Dobereiner groups?
How did John Newlands classify elements?
Name the first element of Newland’s octaves.
Name the last element of Newland’s octaves.
What is your observation from Newland’s octaves?
What is Newland’s Law of octaves?
Besides atomic masses, on what other basis were the elements arranged in the Mendleev’s
periodic table?
Which chemical property of an element was treated as one of the basic property for classifying
elements and why?
What name is given to vertical columns in Mendleev’s periodic table?
What name is given to horizontal rows in Mendleev’s periodic table?
While developing the Periodic table, at few places Mendleev inverted the sequence of some
elements i.e. he placed an element with slightly greater atomic mass before the element of
lower atomic mass. Why did he do so?
Though the atomic mass of cobalt (58.9) is greater than nickel (58.7) yet Co is placed before Ni
in Mendleev’s periodic table. Why?
Which elements did not exist at the time of Mendleev’s periodic classification? What name was
given to these elements?
In what way hydrogen resembles alkali metals?
In what way hydrogen resembles halogens?
Why hydrogen cannot be given a fixed position in periodic table?
What is the first limitation of Mendleev’s periodic table?
How isotopes of all the elements posed a challenge to Mendleev’s periodic table?
Who proposed that atomic number is the more fundamental property for classifying elements?
In Modern periodic table, How do elements belonging to the same group resemble each other?
Write two points.
Different elements have same number of shells, in group or in period?
First period of the Modern periodic table contains only two elements. Justify.
How many elements are present in second group of the periodic table? Justify.
“The valence electrons determine the kind and number of bonds formed by an element”.
Justify.
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 188 -
An element belongs to the first group and third period of the periodic table. What conclusion
can you draw from its position ?
A metal M forms an oxide having the formula M2O3. It belongs to the third period and
thirteenth group of the Modern periodic table. Write the atomic number and valency of the
element.
What were the two major shortcomings of Mendleev’s periodic table? How have these been
removed in the modern periodic table?
Two elements X and Y have atomic numbers 12 and 16 respectively. Write the electronic
configuration for these elements. To which period of the modern periodic table do these
two elements belong? What type of bond will be formed between them and Why?
What were the two achievements of Mendleev’s periodic table? What was the basis of
classification of elements in it?
Atomic radius decreases in moving from left to right in a period. Why?
Atomic radius increases down the group. Why?
In the modern periodic table a zig-zag line separates metals from non-metals. What are these
elements called and why?
X, Y and Z are the elements of a doberniers triad. If the atomic mass of X is 7and that of z is 39,
what should be the atomic mass of Y?
A and B are the two elements having similar properties which obey Newlands law of octaves. How
many elements are there in between A and B?
Why Na is greater in atomic size than Na+ ?
Why does ionization energy generally decrease going down a group or family?
An element X (2,8,2) combines separately with NO 3- and (SO4)2 -, (PO4)3 - radicals. Write the
formulae of the three compounds so formed. To which group of the periodic table does the
element ‘X’ belong? Will it form covalent or ionic compound? Why?
A metal M forms an oxide having the formula M2O3. It belongs to 3rd period in the modern
periodic table. Write the atomic number and valency of the metal.
Which of the two elements A=2,8,1 B = 2,8,8,1 i s more electropositive?
How does the atomic size vary in going from A) Left to right in a period B) Top to Bottom in a
group
An element has atomic number 13. In which group and period it should be placed?
How many periods and groups are there in the long from of P.T?
Why does the size of the atoms progressively become smaller when we move from sodium (Na) to
chlorine (Cl) in the third period of the period table ?
Give symbols for A. A metal of group 2. B. A metal of group 13. C. Two non metals of group
16. D. Most reactive non- metal of group 17.
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 189 -
Explain Why-
All the elements of a group have similar chemical properties.
All the elements in a period have different chemical properties.
The atomic number of an element X is 17. Predict – A.
Its valency.
B. Nature of the elements.
C. Whether it is metal or non –
metal. D. Name of the element.
E. Relative size with respect to other members of its group.
The three elements predicted by mendeleev from the gaps in his periodic table were known as eka-
boron, eka- aluminum, eka- silicon. What names were given to these elements when they were
discovered later on?
The atomic numbers of Nitrogen, Oxygen and fluorine are 7, 8, and 9 respectively. Write the
electronic configuration of each element and answer the following:
Out of N, O and F which is most electronegative and which one is least electronegative?
What is the number of valence electrons of F?
What is the valency of each of N, O and F?
Prepared by: M. S. KumarSwamy, TGT(Maths) Page - 190 -
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