Smart Guess & Test Papers

Student Name ______________________ Father Name ______________________ Roll Number _______

Class: 1st /year - Chemistry Marks : 39 Exam Format : Chapter Wise MCQs
Time : notespk.com_Nauman Sadaf | Date _________________ Examiner Sig __________ Chapter#: 7

MCQ's S/Q L/Q Total

Objective Type

‫تس‬
1. Encircle the Correct Option. (1 x 31 = 31) ‫وجاب ےک رگد دارئہ اگلںیئ۔‬ ‫در‬ .1
1) The number of fundamental ways of transferring energy into or out of system is
a) One b) Two c) Three d) Four

2) _______ is not state function.

a) Pressure b) Volume c) Temperature d) Heat

3) If an endothermic reaction is allowed to take place very rapidly in the air , the temperature of the surrounding air .
a) First increases then decreases b) Decrease c) Increases d) Remains unchanged

4) The condition of standard state of a substance can be represented as

a) 700 mm of Hg and 00C b) 1 atm and 00C c) 2 atm and 00C d) 1 atm and 298 K

5) The internal energy of a system is equal to

a) P.E. of the particles b) Kinetic energy of the particles c) Enthalpy d) Sum of K.E and P.E

6) Which of the following statement is contray to the first law of thermodynamics ?

a) Energy can neither be created b) One from of energy can be c) Continuous production of d) In an adiabatic process , the
nor be destroyed transferred into an equivalent mechanical work without work done is independent of its
amount of other kind of energy supplying an equivalent amount of path
heat is possible

7) Which of the following is the mathematical expression of First Law of Thermodynamics ?

a) q = m.S. T b) E = q - PVV c) H= E+P V d) H= E

8) Which of the following is the application of Law of conservation of energy ?

a) 1st Law of Thermodynamics b) Born Haber cycle c) Hess's Law d) All of the above

9) The measurement of enthalpy change at standard condition means that we should manage the measurement at.
a) 240C at 1 atm b) 250C at 1 atm c) 00C at 1 atm d) 1000C at 1 atm

10) The amount of heat absorbed when one mole of gaseous atoms are formed from the element is called enthalpy of
a) Formation b) Reaction c) Combustion d) Atomization

11) The change in heat energy of a chemical reaction at constant temperature and pressure is called
a) Enthalpy change b) Heat of sublimation c) Bond energy d) Internal energy change

12) For the reaction NaOH + HCl NaCl + H2O , the change in enthalpy is called
a) Heat of reaction b) Heat of neutralizaion c) Heat of formation d) Heat of combustion

13) Heat of combustion can be determined by

a) Glass calorimeter b) Copper calorimeter c) Bomb calorimeter d) Heat calorimeter

14) In bomb calorimeter the reactions are carried out at

a) Constant pressure b) Constant temperature c) Constant volume d) Constant enthalpy

15) Which of the following formulas is used to calculate the amount of heat change in a chemical reaction .
a) H= E+P V b) E= H+W c) q = m.S . T d) H= E

16) For a given reaction which description is correct ?

CH4 + 2O2 CO2 + 2H2O
a) Heat of oxidation b) Heat of combustion of CH4 c) Endothermic reaction d) Heat of Atomization

17) The heat of neutralization for a strong acid and a strong base is 57.kJ / mole . The heat of neutralization for the reaction of NaOH and CH3COOH
is
a) 5.7.kJ / mole b) Less than 57.kJ / mole c) 57.kJ / mole d) More than 57.kJ / mole

18) Standard enthalpies are measured at

a) 2730C b) 3730C c) 00C d) 298K

19) The Born-Haber cycle is the best application of law

a) Boyle's law b) Hess's law c) Dalton's law d) Graham law

20) The net heat change in a chemical reaction is same whether it is brought about in two or more different ways in one or several steps . It is known as
a) Henry's Law b) Joule's Principle c) Hess's Law d) Law of conservation of energy

21) The subject matter of thermochemistry is based upon

 a) Hess's Law b) Law of sonseervation of energy c) Born Haber's cycle d) Law of mass action

22) Born Haber cycle is used to calculate the

a) Lattice energy b) Heat of reaction c) Enthalpy change d) Heat of Atomization

23) If an endothermic reaction is allowed to take place very rapidly in the air, the temperature of the surrounding air
a) Remains constant b) Decreases c) Increases d) Remains unchanged

24) In endothermic reactions, the heat content of the

a) Products is more than that of b) Reactants is more than that of c) Both (a) and (b) d) Reactants and products are equal
reactants products

25) Calorie is equivalent to

a) 0.4184J b) 41.84J c) 4.184J d) 418.4J

26) The change in heat energy of a chemical reaction at constant temperature and pressure is called
a) Enthalpy change b) Bond energy c) Heat of sublimation d) Internal energy change

27) Which of the following statements is contrary to the first law of thermodynamics?
a) Energy can neither be created b) One form of energy can be c) In an adiabatic process, the work d) Continuous production of
nor destroyed. transferred into an equivalent done is independent of its path. mechanical work without
amount of other kinds of energy. supplying an equivalent amount of
heat is possible.

28) For a given process, the heat changes at constant pressure (qp) and at constant volume (qv ) are related to each other as
a) qp = qv b) qp < qv c) qp > qv d) qp =qv / 2

29) For the reaction: NaOH+HCl NaCl+H2 O the change in enthalpy is called
a) Heat of reaction b) Heat of neutralization c) Heat of formation d) Heat of combustion

30) The net heat change in a chemical reaction is same,whether it is brought about in two or more different ways in one or several steps. It is known as
a) Henry’s law b) Hess’s law c) Joule’s principle d) Law of conservation of energy

31) Enthalpy of neutralization of all the strong acids and strong bases has the same value because
a) Neutralization leads to the b) Strong acids and bases are ionic c) Acids always give rise to d) The net chemical change
formation of salt and water. substances. H+ ions and bases always involve the combination of H+ and
furnish OH- ions. OH- ions to form water
2. Write "T" for a true statement and "F" for a false statement (1 x 4 = 4)
‫تس‬
‫) اک اشنن اگلںیئ۔‬X( ‫) اشنن اگلںیئ اور طلغ ےک اسےنم‬ ( ‫وجاب ےک اسےنم‬ ‫در‬ .2
32) Amount of heat absorbed at constant volume is internal energy change.
✅ True ☐ False

33) The work done by the system is given the positive sign.
☐ True ✅ False

34) Enthalpy is a state function but internal energy is not.

☐ True ✅ False

35) Total heat content of a system is called enthalpy of the system.

✅ True ☐ False

3. Fill in the blanks. (1 x 4 = 4) ‫اخیل ہگج رُپ رکںی۔‬ .3

36) The substance undergoing a physical or a chemical change forms a chemical .
System

37) The change in internal energy__________ be measured.

Can

38) Solids which have more than one crystalline forms possess_______ values of heats of formation.
Different

39) A________ is a macroscopic property of a system which is__________ of the path adopted to bring about that
change.
State function ; Independent