Homework 5
CHE1401
Name___________________________________
MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.
1) Objects can possess energy as ________. 1)
(a) endothermic energy
(b) potential energy
(c) kinetic energy
A) a only B) b only C) c only D) a and c E) b and c
2) When a system ________, E is always negative. 2)
A) gives off heat and does work
B) absorbs heat and does work
C) gives off heat and has work done on it
D) absorbs heat and has work done on it
E) None of the above is always negative.
3) Which one of the following is an endothermic process? 3)
A) boiling soup
B) water freezing
C) ice melting
D) Hydrochloric acid and barium hydroxide are mixed at 25 °C: the temperature increases.
E) Both A and C
4) Which one of the following is an exothermic process? 4)
A) boiling soup
B) condensation of water vapor
C) ice melting
D) water evaporating
E) Ammonium thiocyanate and barium hydroxide are mixed at 25 °C: the temperature drops.
5) Of the following, which one is a state function? 5)
A) q
B) H
C) heat
D) w
E) none of the above
6) Which of the following is a statement of the first law of thermodynamics? 6)
A) E = Efinal - Einitial
B) Energy lost by the system must be gained by the surroundings.
C) 1 cal = 4.184 J (exactly)
1
D) Ek = mv2
2
E) A negative H corresponds to an exothermic process.
1
7) H for an endothermic process is ________ while H for an exothermic process is ________. 7)
A) positive, zero
B) positive, negative
C) zero, positive
D) negative, positive
E) zero, negative
8) The reaction 8)
4Al (s) + 3O2 (g) 2 Al2 O3 (s) H° = -3351 kJ
is ________, and therefore heat is ________ by the reaction.
A) endothermic, absorbed
B) exothermic, absorbed
C) endothermic, released
D) exothermic, released
E) thermoneutral, neither released nor absorbed
9) When ________ is constant, the enthalpy change of a process equal to the amount of heat 9)
transferred into or out of the system?
A) temperature
B) volume
C) temperature and volume
D) pressure and volume
E) pressure
10) The units of heat capacity are ________. 10)
A) J/mol
B) K/J or °C/J
C) J/g-K or J/g-°C
D) g-K/J or g-°C/J
E) J/K or J/°C
11) The units of specific heat are ________. 11)
A) J/mol
B) g-K/J or g-°C/J
C) J/K or J/°C
D) K/J or °C/J
E) J/g-K or J/g-°C
12) Which of the following is a statement of Hess's law? 12)
A) If a reaction is carried out in a series of steps, the H for the reaction will equal the product of
the enthalpy changes for the individual steps.
B) If a reaction is carried out in a series of steps, the H for the reaction will equal the sum of the
enthalpy changes for the individual steps.
C) The H of a reaction depends on the physical states of the reactants and products.
D) The H for a process in the forward direction is equal to the H for the process in the reverse
direction.
E) The H for a process in the forward direction is equal in magnitude and opposite in sign to
the H for the process in the reverse direction.
2
13) For which one of the following reactions is H°rxn equal to the heat of formation of the product? 13)
A) N2 (g) + 3H2 (g) 2NH 3 (g)
B) 12C (g) + 11H 2 (g) + 11O (g) C6 H22O11 (g)
C) P (g) + 4H (g) + Br (g) PH4 Br (l)
D) 6C (s) + 6H (g) C6 H6 (l)
E) (1/2)N2 (g) + O2 (g) NO2 (g)
14) Consider the following two reactions: 14)
A 2B H°rxn = 456.7 kJ/mol
A C H°rxn = -22.1 kJ/mol
Determine the enthalpy change for the process:
2B C
A) -434.6 kJ/mol
B) -478.8 kJ/mol
C) 478.8 kJ/mol
D) 434.6 kJ/mol
E) More information is needed to solve the problem.
15) In the reaction below, H°f is zero for ________. 15)
Ni (s) + 2CO (g) + 2PF3 (g) Ni(CO)2 (PF3 )2 (l)
A) Ni (s)
B) Ni(CO)2 (PF3 )2 (l)
C) PF3 (g)
D) CO (g)
E) both CO (g) and PF3 (g)
16) For the combustion reaction of methane, H°f is zero for ________. 16)
CH4 (g) + O2 (g) 2H2O(g) + CO2 (g)
A) CH4 (g)
B) H2 O (g)
C) O2 (g)
D) CO2 (g)
E) Both O2 (g) and CH4 (g)
17) The internal energy of a system is always increased by ________. 17)
A) adding heat to the system
B) withdrawing heat from the system
C) adding heat to the system and having the system do work on the surroundings
D) a volume decompression
E) having the system do work on the surroundings
3
18) The internal energy of a system ________. 18)
A) refers only to the energies of the nuclei of the atoms of the component molecules
B) is the sum of the rotational, vibrational, and translational energies of all of its components
C) is the sum of the kinetic energy of all of its components
D) is the sum of the potential and kinetic energies of the components
E) none of the above
19) The internal energy can be increased by ________. 19)
(a) transferring heat from the surroundings to the system
(b) transferring heat from the system to the surroundings
(c) doing work on the system
A) a only B) b only C) c only D) b and c E) a and c
20) A ________ H corresponds to an ________ process. 20)
A) negative, endothermic
B) negative, exothermic
C) positive, exothermic
D) zero, exothermic
E) zero, endothermic
4
Answer Key
Testname: UNTITLED1
1) E
2) A
3) E
4) B
5) B
6) B
7) B
8) D
9) E
10) E
11) E
12) B
13) E
14) B
15) A
16) C
17) A
18) D
19) E
20) B
