Module 12 Limiting and Excess Reagent
Module 12 Limiting and Excess Reagent
GENERAL CHEMISTRY 1
Module 12, Quarter 1, Week 4
General Chemistry 1
Grade 11/12 Module 12 Quarter 1, Week 4
First Edition, 2020
Copyright © 2020
La Union Schools Division
Region I
All rights reserved. No part of this module may be reproduced in any form without
written permission from the copyright owners.
Management Team:
Before going on, check how much you know about this topic. Answer the
pretest on the next page in a separate sheet of paper.
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Limiting Reactant Excess Reactant Product Produced
In the previous module, you have learned about theoretical yield. In this
module, you will learn how to calculate for the limiting reactant using the value of
the computed theoretical yield, which can help in identifying the excess reactant.
For you to understand the lesson well, do the following activities. Have fun
and good luck!
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Jumpstart
Activity 1
Before we start our lesson, let’s play first! Let’s call this game “Look at the Word!”
DIRECTIONS: Search up, down, forward, backward, and diagonally to find the
hidden words. Encircle the words that you can find. The hidden words are the
following:
W R T A S B K N N T H L Y K N I N G S
C H E M I C A L E Q U A T I O N W A A
O I D O S A S G F U A E H S S H S S G
N N O L H S U T R E S X E D E R E L R
C L E E E T L A O O T P O F G M R I E
E T R C B L F I M I O E R G R K U Q A
N K X U O M U F P T C R E O I I I U C
T E B L R I E J R A [ H T L D N L I T
R D N A O K R K O R L F I K M U P D A
A Z M R N N F L R S K R C O O E C W N
T X L M A S L E D Y E E A E M S A T T
I Y I A T C A A C T U A L Y I E L D P
O M N S U C S L E A S N Y O K G T U P
N R K S T R D W I B W Y I W G V N R L
S O A A J E N Q S M H U E S D C T S Y
T A N C K A M I B N I D L A S U E O F
I T S H M C V O N I R T D M A T E L R
L E T E O T P P K G E K I R C A S I E
M O O M L S S D A H D S A N H D K D E
N A R H S B I N K W R W I H G J H K L
Have you been able to find all the words? If it is, that's
great! Words in the activity were meant to remind you of some
of the terms you've learned from previous lessons, and the
others are terms that you will encounter in the new lesson.
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Activity 2: Which is which? A Warm-up Activity
Directions: Read the description about limiting and excess reagent/reactant in a
chemical reaction. Understand what you are reading.
Limiting Reactant- Reactant in a chemical reaction that limits the amount of the
product that can be produced. The reaction stops when all the limiting reactants
are consumed.
Directions: Analyze the picture, then answer the questions that follow. Choose the
letter of the correct answer and write it on a sheet of paper.
+ → +
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Q3. From the above illustration what is the limiting reactant?
A. bun C. hot dog in bun
B. hotdog D. left over hotdog
Q5. What conclusion can you make about the above illustration?
A. More buns are needed to make more products.
B. More buns are needed to make more reactants.
C. More hotdogs are needed to make more products.
D. More hotdogs are needed to make more reactants.
Discover
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To illustrate this just like a chemical equation, the balanced equation is as follow:
Reactants Product
The balanced equation shows the ratio of the reactants and products.
What is the highest number of pack lunch you can make with the available
resources that you have? If your answer is 105, you are right. But what makes you
say so? Remember that in every pack it must consist of 3 slices of pork adobo
that’s why you have to divide 315 slices into 3 which will give you the answer 105
which is lower than the number of the available rice and eggplant.
Therefore, we could say the pork adobo stops you to make more pack lunch.
It doesn't matter if you've got a greater number of rice and eggplant omelet, you
can't make pack lunch any more when you're out of pork adobo already. And, if
this is a chemical reaction, we 'd say the pork adobo is the limiting reactant while
the rice and eggplant omelet are the excess reactant.
Excess Reagents are the reactants that are not used up when the reaction is
finished. It is what remains after the reaction stops because the limiting reagent
has all been used up.
For us to be able to determine the Limiting and Excess reagent, the amount of the
product formed and the amount of the excess reactant, the following steps should
be followed:
2. Convert all given information into moles (most likely, through the use of
molar mass as a conversion factor).
3. Calculate the mole ratio from the given information. Calculate the product
produced by the reactants. (Compute for the theoretical yield of each
reactant).
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4. Identify the limiting and excess reactant, the reactant that produces a lesser
amount of product is the limiting reagent while the reactant that produces a
larger amount of product is the excess reagent.
5. Identify the amount product produced in the chemical reaction. Use the
calculated amount of product produced by the limiting reactant.
6. To find the amount of remaining excess reactant, calculate how much of the
excess reactant will be consumed once the limiting reactant is consumed.
Then, subtract the mass of excess reagent consumed from the total mass of
excess reagent given.
Sample Problem 1:
SOLUTION
for O2:
Molar mass of O2 = 2 x 16.00 = 32.00 g/mol
4.5 g
There are 0.18 moles of NH
1 mole of O2
x3 and 0.14 moles of O=
2. Now,
0.14 using
molesthis information
of O 2
we can now, identify which of 32.00 g Othe
them is 2 limiting. We just need to answer the
following questions using step 3:
a. How much product (NO) is produced if the given amount of NH3 is consumed?
b. How much product (NO) is produced if the given amount of O2 is consumed?
Step 3: Calculate the mole ratio from the given information. Calculate the
product produced by the reactants. (Compute for the theoretical yield of each
reactant).
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Question a: How much product (NO) is produced if the given amount of NH3
is consumed?
4 mol NO 30.01g NO
0.18 mol NH3 × × = 5.40g NO
4 mol NH3 1 mol NO
*This means that 0.18 mol NH3 will produce 5.40 g of the product NO.
Step 4: Identify the limiting and excess reactant, the reactant that produces a
lesser amount of product is the limiting reagent while the reactant that
produces a larger amount of product is the excess reagent.
* Since O2 produces the lesser amount of product which is 3.36g NO it is
considered to be the limiting reactant while NH 3 is the excess reactant for it
produces larger amount of the product which is 5.40g NO.
Step 5: Identify the amount product produced in the chemical reaction. Use
the calculated amount of product produced by the limiting reactant.
*Since the limiting reactant O2 produced 3.36g NO, therefore this is
also the amount of product produced in the chemical reaction because the
limiting reactant determines the amount of product produced.
Step 6: To find the amount of remaining excess reactant, calculate how much
of the excess reactant will be consumed once the limiting reactant is
consumed. Then, subtract the mass of excess reagent consumed from the
total mass of excess reagent given.
4 mol NH3 17.03g NH3
0.14mol O2 × × = 1.90g NH3
5 mol O2 1 mol NH3
*This means that 0.14 mol Al will used 1.90 g of NH3 to be totally
consumed.
Sample Problem 2:
Using the chemical equation:
Which is the limiting reactant in 86.25 grams of Al and 105.56 grams of Cl2?
And what is the greatest amount of ALC3 (in grams) can be made? Which of
the reactant is excess? How many grams are left on the excess reactant?
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Solution
- we have two Al atoms and six Cl atoms on both sides of the arrow, so we
are good to go!
for Al:
86.25 g 1 mole of Al
x = 3.20 moles of Al
Al 26.98 g Al
for Cl2:
Molar mass of Cl2 = 2 x 35.45 = 70.90 g/mol
105.56 g 1 mole of Cl2
x = 1.49 moles of Cl2
Cl 70.90 g Cl2
There are 3.20 moles of Al and 1.49 moles of Cl2. Now, using this information we
can now, identify which of them is the limiting. We just need to answer the
following questions using step 3:
a. How much product (AlCl3) is produced if the given amount of Al is
consumed?
b. How much product (AlCl3) is produced if the given amount of Cl2 is
consumed?
Step 3: Calculate the mole ratio from the given information. Calculate the
product produced by the reactants. (Compute for the theoretical yield of each
reactant).
Question 2: How much product (AlCl3) is produced if the given amount of Cl2 is
consumed?
2 mol AlCl3 133.33g AlCl3
1.49mol Cl2 × × = 132.44g AlCl3
3 mol Cl2 1 mol AlCl3
*This means that 1.49 mol Al will produce 132.44 g of the product AlCl3
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Step 4: Identify the limiting and excess reactant, the reactant that produces a
lesser amount of product is the limiting reagent while the reactant that
produces a larger amount of product is the excess reagent.
* Since Cl2 produces the lesser amount of product which is 132.44g AlCl3 it is
considered to be the limiting reactant while Al is the excess reactant for it
produces larger amount of the product which is 426.66g AlCl 3.
Step 5: Identify the amount product produced in the chemical reaction. Use
the calculated amount of product produced by the limiting reactant.
*Since the limiting reactant Cl2 produced 132.44g AlCl3, therefore this
is also the amount of product produced in the chemical reaction because the
limiting reactant determines the amount of product produced.
Step 6: To find the amount of remaining excess reactant, calculate how much
of the excess reactant will be consumed once the limiting reactant is
consumed. Then, subtract the mass of excess reagent consumed from the
total mass of excess reagent given.
2 mol Al 26.98 Al
1.49mol Cl2 × × = 26.80g Al
3 mol Cl2 1 mol Al
*This means that 1.49 mol Al will used 26.80 g of Al to be totally
consumed.
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Explore
Here are some enrichment activities for you to work on to master and
strengthen the basic concepts you have learned from this lesson.
In a perfect world, you 'd have just as much of every reactant you need to
convert everything into a product. However, in real life, you are much more likely to
have non-stoichiometric amounts of reactants.
You 're working in a factory that makes Oreo cookies. This process is usually
automated, but there has been a glitch in the software that runs the cookie-
assembling machine. Now you and your colleagues need to put the Oreos together
by hand.
Two boxes are given to you: one containing stacks of chocolate wafers and
one containing stacks of creamy fillings. The shipping supervisor shows up at your
workstation and wants to know how many Oreos you can make with the contents
of these two boxes. To figure this out, you look at the boxes and see the following
information printed along the outsides of each box:
Box 1
Box 2
Taking in all this information, you think back fondly as Chemistry student and
realize that you can approach this like a chemistry problem!
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You decide to write the Oreo recipe like a chemical equation:
2. Considering ONLY the chocolate wafers you have, how many Oreos total
could you make?
A. 42 B. 54 C. 66 D. 124
4. Considering ONLY the orange fillings you have, how many Oreos total could
you make?
A. 23 B. 39 C. 46 D. 75
5. Considering all of your ingredients (both wafers and fillings), how many
Oreos could you make in total?
A. 39 B. 42 C. 84 D. 100
6. In chemistry, the reactant that runs out first is called the limiting
reagent. In this Oreo cookie scenario, what is the limiting reagent?
A. fillings C. usable oreo cookies
B. chocolate wafers D. damaged oreo cookies
7. In chemistry, the reactant that is left over after the limiting reagent runs out
is called the excess reagent. In this Oreo cookie scenario, what is the
excess reagent?
A. fillings C. usable oreo cookies
B. chocolate wafers D. damaged oreo cookies
Direction: Analyze the given equation then answer the questions that follow in a
separate sheet of paper.
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Enrichment Activity 2: Follow the Recipe!
Analyze the recipe and apply your knowledge about limiting and excess reactant
and answer the questions that follows in a separate sheet of paper.
2. One tootsie roll reacts with four gummy bears to form a tootsie bear
according to the following balanced equation:
1 Tr + 4 Gb → 1 TB
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Assessment 2: Calculate Me!
Directions: Solve the following problems in a separate sheet of paper.
Answer what is being asked and show your solution?
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Deepen
At this point, make a comics strip showing the significance of determining the
limiting and excess reactant. Relate it also with your activities of daily living. Use at
least 2-3 short bond papers in portrait layout.
What you need: Short bond paper, pencil, crayons and other drawing materials.
Rubrics
4 3 2 1
Creativity The pictures and All but 1 of the All but 2 of the More than 2 of
captions reflect pictures and pictures and the pictures
an exceptional captions reflect captions reflect and captions
degree of student an exceptional an exceptional reflect an
creativity. There degree of degree of exceptional
is great attention student student degree of
to detail. creativity creativity student
creativity
Theme All 20 panels Only 15 panels Only 10 panels Less than 10
relate to the relate to the relate to the panels relate to
theme theme. theme. the theme.
Total points=________________
Final Grade=________________
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Gauge
Directions: Read carefully each item. Use a separate sheet for your answers. Write
only the letter of the best answer for each test item.
1. What is a limiting reagent in a chemical reaction?
A. the reactant that is in excess
B. the product that you can make the most of
C. the amount of reactants that react with each other
D. the reactant that determines how much product can be made
3. What is the first step in determining the limiting reactant in a chemical reaction?
A. check the mole ratio
B. convert given mass to mole
C. balance the chemical equation
D. compute for the product produced
4. What will be your guide in determining the limiting and excess reactant?
A. amount of reactants
B. ratio of reactants and products
C. molar mass of reactants and products
D. amount of product produced of each reactants
5. How will you identify the amount of product produced in the chemical reaction?
A. Use the calculated amount of product produced by the excess reactant.
B. Use the calculated amount of product produced by the limiting reactant.
C. Convert the given mass of the reactants in the chemical reaction into
moles.
D. Convert the given mass of the products in the chemical reaction into
moles.
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8. Pretend you have a job building bicycles. If you had 120 wheels, 240 pedals, and
75 seats, which is considered to be the limiting reactant?
A. pedals B. seats C. wheels D. pedals and
wheels
9. In the problem above, how many pedals are left over after you have built the
bicycles?
A. 30 B. 60 C. 90 D. 120
10. You need 2 pieces of bread, 1 tablespoon of peanut butter and 2 tablespoons of
jelly to make a 6 sandwich. If you have 85 pieces of bread, 24 tablespoons of
peanut butter and 44 tablespoons of jelly, what is the limiting reactant?
A. bread B. jelly C. peanut butter D. sandwich
11. In the reaction, Zn + 2 HCl ZnCl2 + H2, 106.08 grams of Zn are reacted with
97.54 g of HCl. How many grams of H2 will be produced?
A. 2.71g H2 B. 3.27g H2 C. 5.18g H2 D. 7.17g H2
14. Silicon carbide, an abrasive, is made by the reaction of silicon dioxide with
graphite.
SiO2 +3C → SiC + 2CO
If 125.92g of SiO2 and 136.32 g of C are reacted, which one of the following
statements will be correct?
A. 45.66g of C will be left over. C. 23.65 g of SiO2 will be left over.
B. 60.66g of C will be left over. D. 114.33 g of SiO2 will be left over.
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References
Printed Materials:
Ilao, L., Lontoc, B., & Gayon, E. 2017. “General Chemistry 1”. Quezon City,
Philippines. Rex Publishing
Punzalan J,M, Monserrat R.C. 2016. “Science in Today’s World; Physical Science”.
pp. 65 – 80
Sostarecz, Michael C., and Audra Goach Sostarecz. 2012 "A conceptual approach to
limiting-reagent problems." Journal of Chemical Education 89, no. 9 : 1148-1151.
Website:
Bain, R., “Limiting Reagents”. Chemistry Activities. Accessed July 23, 2020.
https://wisc.pb.unizin.org/chemactivities/chapter/limiting-reagents/
Khan Academy. “Limiting reagents and percent yield”. Accessed July 22, 2020.
https://www.khanacademy.org/science/chemistry/chemical-reactions-
stoichiome/limiting-reagent-stoichiometry/a/limiting-reagents-and-percent-yield
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Key Answers
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