Thermodynamics 1 Module 7
Thermodynamics 1 Module 7
College: Engineering
Campus: Bambang
1. Introduction
2. Review on the Different Laws of Thermodynamics
3. Carnot Cycle
4. Three Process cycle
5. Introduction to Gas and Vapor Cycles
6. Real Gases
This lesson provides the students an in-depth understanding of the Carnot and Three process cycle.
.
IV. DESIRED LEARNING OUTCOMES
V. LESSON CONTENT
1. Introduction:
Thermodynamics is the study of heat and energy. At its heart are laws that describe how
energy moves around within a system, whether an atom, a hurricane, or a black hole. The first law
describes how energy cannot be created or destroyed, merely transformed from one kind to another.
The second law, however, is probably better known and even more profound because it describes
the limits of what the universe can do. This law is about inefficiency, degeneration, and decay. It tells
us all we do is inherently wasteful and that there are irreversible processes in the universe. It gives
us an arrow for time and tells us that our universe has an inescapably bleak, desolate fate.
Despite these somewhat deflating ideas, the ideas of thermodynamics were formulated in a time of
great technological optimism – the Industrial Revolution. In the mid-19th century, physicists and
engineers were building steam engines to mechanize work and transport and were trying to work out
how to make them more powerful and efficient.
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Many scientists and engineers – including Rudolf Clausius, James Joule, and Lord Kelvin –
contributed to the development of thermodynamics, but the father of the discipline was the French
physicist Sadi Carnot. In 1824 he published Reflections on the Motive Power of Fire, which laid down
the basic principles, gleaned from observations of how energy moved around engines and how
wasted heat and useful work were related.
The second law can be expressed in several ways, the simplest being that heat will naturally
flow from a hotter to a colder body. At its heart is a property of thermodynamic systems called entropy
– in the equations above it is represented by "S" – in loose terms, a measure of the amount of disorder
within a system. This can be represented in many ways, for example in the arrangement of the
molecules – water molecules in an ice cube are more ordered than the same molecules after they
have been heated into a gas. Whereas the water molecules were in a well-defined lattice in the ice
cube, they float unpredictably in the gas. The entropy of the ice cube is, therefore, lower than that of
the gas. Similarly, the entropy of a plate is higher when it is in pieces on the floor compared with when
it is in one piece in the sink.
A more formal definition for entropy as heat moves around a system is given in the first of the
equations. The infinitesimal change in entropy of a system (dS) is calculated by measuring how much
heat has entered a closed system (δQ) divided by the common temperature (T) at the point where
the heat transfer took place.
The second equation is a way to express the second law of thermodynamics in terms of
entropy. The formula says that the entropy of an isolated natural system will always tend to stay the
same or increase – in other words, the energy in the universe is gradually moving towards disorder.
Our original statement of the second law emerges from this equation: heat cannot spontaneously flow
from a cold object (low entropy) to a hot object (high entropy) in a closed system because it would
violate the equation. (Refrigerators seemingly break this rule since they can freeze things too much
lower temperatures than the air around them. But they don't violate the second law because they are
not isolated systems, requiring a continual input of electrical energy to pump heat out of their interior.
The fridge heats the room around it and, if unplugged, would naturally return to thermal equilibrium
with the room.)
This formula also imposes a direction on time; whereas every other physical law we know of
would work the same whether time was going forwards or backward, this is not true for the second
law of thermodynamics. However long you leave it, a boiling pan of water is unlikely to ever become
a block of ice. A smashed plate could never reassemble itself, as this would reduce the entropy of
the system in defiance of the second law of thermodynamics. Some processes, Carnot observed, are
irreversible.
Carnot examined steam engines, which work by burning fuel to heat a cylinder containing
steam, which expands and pushes on a piston to then do something useful. The portion of the fuel's
energy that is extracted and made to do something useful is called work, while the remainder is the
wasted (and disordered) energy we call heat. Carnot showed that you could predict the theoretical
maximum efficiency of a steam engine by measuring the difference in temperatures of the steam
inside the cylinder and that of the air around it, known in thermodynamic terms as the hot and cold
reservoirs of a system respectively.
Heat engines work because heat naturally flows from hot to cold places. If there was no cold
reservoir towards which it could move there would be no heat flow and the engine would not work.
Because the cold reservoir is always above absolute zero, no heat engine can be 100% efficient.
The best-designed engines, therefore, heat steam (or other gas) to the highest possible temperature
then release the exhaust at the lowest possible temperature. The most modern steam engines can
get to around 60% efficiency and diesel engines in cars can get to around 50% efficiency. Petrol-
based internal combustion engines are much more wasteful of their fuel's energy.
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The inefficiencies are built into any system using energy and can be described
thermodynamically. This wasted energy means that the overall disorder of the universe – its entropy
– will increase over time but at some point, reach a maximum. At this moment in some unimaginably
distant future, the energy in the universe will be evenly distributed and so, for all macroscopic
purposes, will be useless. Cosmologists call this the "heat death" of the universe, an inevitable
consequence of the unstoppable march of entropy.
There are several rules and processes in thermodynamics, hence, to simplify all the rules or
regulations, laws of thermodynamics are introduced. There is a total of four thermodynamics laws.
The zeroth law of thermodynamics states that if two thermodynamic systems are in thermal
equilibrium with another thermodynamic system, then they all are in thermal equilibrium with each other.
Let’s consider, any three systems,
• System A
• System B
• System C
Now, if System A and System B are in thermal equilibrium and also system A and system C also
in thermal equilibrium, then system A, system B, and system C will be in thermal equilibrium.
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these laws can create a lot of confusion. Thus he was forced to adopt the number” zero” for his law. And
finally, this law was named” Zeroth Law of Thermodynamics”.
Application:
1. To measure human body temperature.
This first law is related to the conservation of energy. It states that energy can never be created
or destroyed, but it can be changed from one form of energy to another form of energy.
• To understand, let us take some water in a container. There will not be any change when the
water in a normal condition. We will heat the water and we will see after heating, water
changed into vapor. Here, water is changed into vapor due to heat input.
• If we put coal in the furnace of the power plant, then only we get electricity through the
process. Coal has stored thermal energy which is used to get heat energy. So, energy is the
same, but it is changed into different forms.
Heat Engine that violates the Kevin Heat Engine satisfying First Law and
Planck’s statement of Second Law. Kevin Planck’s statement of Second Law.
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“It is impossible to construct a device (operating in a cycle) that can transfer heat from
cold body to the hot body without absorbing any work”
Or
It is very easy to understand, just see the above picture, Heat Q 1 is at a lower temperature body and it
is saying that it will not travel to a higher temperature body without absorbing any heat.
Consider a heat pump as shown in the picture below. This heat pump absorbs heat from the lower
temperature body and rejects heat to the higher temperature body without a supply of any work. This
phenomenon is possible according to the First Law of thermodynamics. But it does not obey the second law
of thermodynamics. Thus, such a device can not transfer heat from a lower temperature body to a higher
temperature body without any supply of work to it. So according to Clausius’s statement of the second law of
thermodynamics, this type of heat pump is not possible.
Now see the image below. This type of heat pump is possible according to the statement/definition of the
second law of thermodynamics because it is consuming some work to transfer heat from a lower temperature
body to a higher temperature body. Thus, this heat pump obeys the 1st Law as well as the 2nd Law of
Thermodynamics.
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“In all the spontaneous processes, the entropy of the universe increases”
Spontaneous processes are those processes that occur on their own. For example, gas spreads
in the entire room on its own, Hot coffee cools down automatically on its own, ice kept on the table will
melt on its own, etc.
Now, what is entropy? You all know about solids, liquids, and gases.
Solids have closed arrangements of molecules. Liquids show more movement of molecules
compared to that solid, and gases show the maximum movement of molecules as shown in the above
picture.
Now, this movement of molecules is known as disorder or randomness. And the measurement of
this disorder is known as entropy. Thus, entropy is the measurement of the disorder of a system. The
statement of the second law of thermodynamics simply says that- “If the process is occurring on its own,
then the disorder of the universe always increases.”
This law is related to entropy. As per this law, entropy is always increased in an isolated system.
• It means, there should be an external energy source to transfer heat energy from a lower
temperature region to a high-temperature region.
• For example, if you switched ON the air conditioner, then only it will cool the room. Hence,
external power is required to run the air conditioner or to transfer heat from room to outside.
Based on this third law of thermodynamics, when the temperature of a state approaches
absolute zero, entropy approaches a constant value.
• The entropy of a pure crystal, as per the third law of thermodynamics, is zero, at absolute zero
temperature.
• The entropy of any system is the measurement of the disorder.
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3. CARNOT CYCLE
Carnot cycle is an ideal cycle as adopted for an ideal heat engine. It consists of two isothermal
processes (expansion and compression) and two adiabatic processes (expansion and compression). The
cylinder and piston of the engine are considered as perfect non-conductor of heat but the cylinder cover
head is a good conductor of heat. The hot body at a higher temperature is brought in contact with the
bottom 'B' of the cylinder. The cylinder is fitted with a weightless and frictionless piston.
The French engineer Nicolas Leonard Sadi Carnot was the first scientist who realizes the problem
of the efficiency of heat engines and invented the Carnot cycle. The pressure-volume (p-v) and
temperature-entropy (T-S) graph are shown in fig.
From the above two p-V and T-S graphs, the horizontal axis represents volume 'v' and entropy 'S'
and the vertical axis represents pressure 'p' and temperature 'T'.Let, engine cylinder contains m kg of air
at its original condition represented by point 1 on the p-v and T-S diagrams. At this point, let p1,v1 , and
T1 be the pressure, temperature, and volume.
A Carnot heat engine is a theoretical engine that operates on the Carnot cycle. The basic model
for this engine was developed by Nicolas Léonard Sadi Carnot in 1824. The Carnot engine model was
graphically expanded by Benoît Paul Émile Clapeyron in 1834 and mathematically explored by Rudolf
Clausius in 1857, work that led to the fundamental thermodynamic concept of entropy.
Every thermodynamic system exists in a particular state. A thermodynamic cycle occurs when
a system is taken through a series of different states and finally returned to its initial state. In the process
of going through this cycle, the system may perform work on its surroundings, thereby acting as a heat
engine.
A heat engine acts by transferring energy from a warm region to a cool region of space and, in
the process, converting some of that energy to mechanical work. The cycle may also be reversed. The
system may be worked upon by an external force, and in the process, it can transfer thermal energy from
a cooler system to a warmer one, thereby acting as a refrigerator or heat pump rather than a heat engine.
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In 1824, Sadi Carnot gave the exact theoretical explanation of the engine. He explained the
different parts of the engine and the processes involved in the working of the engine. During this theory
on the Carnot engine, he made an assumption, so this engine is an ideal engine (hypothetical engine)
and designed to be 100% efficient.
Note: Carnot Engine is just an ideal engine (or hypothetical engine). No engine has 100 percent
efficiency according to the Second Law of Thermodynamics.
Let, the unit mass of perfect gas is admitted into the cylinder at the beginning of the outward
moment of the piston, and the pressure, temperature, volume of the gas at a point 1 is p 1,v1, and
T1 respectively. The bottom 'B' of the cylinder can be covered by an insulating cap. During the movement
of the piston, the heat Q1 is supplied to the perfect gas and the gas expands isothermally keeping
temperature T1 constant until the volume v2 and pressure p2. The heat supplied by the hot body is fully
absorbed by the air and is utilized by doing external work. So, heat is supplied during this process is
equal to the work done during this process. This isothermal expansion is represented by the curve 1-2
on the p-v and T-S diagram.
So, work done by the air
𝑉2 𝑉2
𝑊 = 𝑝1 𝑉1 ln = 𝑚𝑅𝑇1 ln
𝑉1 𝑉1
𝑝1 𝑉1 = 𝑚𝑅𝑇1
Since there is no change of temperature from point 1 to 2, so, (T1=T2) and as per the first law of
thermodynamics, the internal energy is also zero (E=0).
Then the heat supplied
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𝑉2 𝑉2
𝑊1−2 = 𝑄1−2 = 𝑄𝐴 = 𝑝1 𝑉1 ln = 𝑚𝑅𝑇1 ln
𝑉1 𝑉1
𝑉2
𝑟 = 𝑒𝑥𝑝𝑎𝑛𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜𝑛 =
𝑉1
𝑄1
𝑆2 − 𝑆1 =
𝑇1
𝑄1−2 = 𝑄𝐴 = 𝑇1 (𝑆2 − 𝑆1 )
As the piston moves outward, the gas expands adiabatically till the pressure p 3, volume v3, and
temperature T2 and the hot body is removed from the bottom of the cylinder 'B' and the insulating cap is
brought in contact. In this process, there is no interchange of the heat of the surrounding gasses (Q = 0)
The reversible adiabatic expansion is represented by the curve 2-3 on the PV diagram.
So, work done by the air
𝑝3 𝑉3 − 𝑝2 𝑉2
𝑊2−3 =
1−𝑘
𝑚𝑅𝑇3 − 𝑚𝑅𝑇2
𝑊2−3 =
1−𝑘
𝑚𝑅(𝑇3 − 𝑇1 )
𝑊2−3 =
1−𝑘
𝑝𝑉 = 𝑚𝑅𝑇 𝑎𝑛𝑑 𝑇1 = 𝑇2 ; 𝑇3 = 𝑇4
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Now the piston moves inward the gas and insulating cap I.C. is also removed from the bottom of
the cylinder and brings the cold body in its contact. The air pressure is compressed isothermally keeping
temperature constant T3 from v3 to v4. It means at a point 4 temperature T4 is equal to T3. That's why heat
is rejected to the cold body is equal to the work done on the air. The isothermal compression curve is
represented by 3-4 on the p-v curve.
So, work done by the air
𝑉4 𝑉4 𝑉3
𝑊3−4 = 𝑄3−4 = 𝑄𝑅 = 𝑝3 𝑉3 ln = 𝑚𝑅𝑇3 ln = −𝑚𝑅𝑇3 ln
𝑉3 𝑉3 𝑉4
(𝑝𝑉 = 𝑚𝑅𝑇)
𝑉3
𝑟 = 𝑖𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝑐𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜 =
𝑉4
𝑄3
𝑆3 − 𝑆4 =
𝑇4
𝑄𝑅 = 𝑇4 (𝑆3 − 𝑆4 )
𝑄𝑅 = 𝑇3 (𝑆2 − 𝑆1 )
(𝑆2 = 𝑆3 𝑎𝑛𝑑 𝑆1 = 𝑆4 ) ; 𝑇4 = 𝑇3
As the piston moves inwards the gas insides the cylinder is compressed adiabatically till the
pressure p1, volume v1, and temperature T1 such that the gas returns to its original condition to complete
the Carnot cycle and insulated cap I.C. is brought in contact with the bottom of the cylinder B. The
temperature of air increases from T4 to T1 and not heat is absorbed or rejected by the air. The reversible
adiabatic compression is represented by the curve 4-1 on the p-v and T-S diagram
So, work done by the air for adiabatic compression
𝑝1 𝑉1 − 𝑝4 𝑉4
𝑊4−1 =
1−𝑘
𝑚𝑅𝑇1 − 𝑚𝑅𝑇3
𝑊4−1 =
1−𝑘
𝑚𝑅 (𝑇1 − 𝑇3 )
𝑊4−1 =
1−𝑘
𝑝𝑉 = 𝑚𝑅𝑇 𝑎𝑛𝑑 𝑇3 = 𝑇4
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From the above discussion, it is seen that the total internal energy decrease in reversible adiabatic
expansion shown in curves 2-3 is equal to the increase in internal energy during reversible adiabatic
compression 4-1. So, the net effect of the whole Carnot cycle is zero.
Net work is done,
𝑉2 𝑉3
𝑊𝑛𝑒𝑡 = 𝑚𝑅𝑇1 ln − 𝑚𝑅𝑇3 ln
𝑉1 𝑉4
𝑊𝑛𝑒𝑡 = 𝑚𝑅 ln 𝑟 (𝑇1 − 𝑇3 )
Or
𝑊𝑛𝑒𝑡 = 𝑄𝐴 − 𝑄𝑅
𝑤𝑜𝑟𝑘 𝑑𝑜𝑛𝑒
𝑒=
ℎ𝑒𝑎𝑡 𝑠𝑢𝑝𝑝𝑙𝑖𝑒𝑑
𝑉2 𝑉2
𝑄𝐴 = 𝑝1 𝑉1 ln = 𝑚𝑅𝑇1 ln
𝑉1 𝑉1
𝑉4 𝑉4 𝑉3
𝑄𝑅 = 𝑝3 𝑉3 ln = 𝑚𝑅𝑇3 ln = −𝑚𝑅𝑇3 ln
𝑉3 𝑉3 𝑉4
𝑇3 𝑉2 𝑘−1
=[ ]
𝑇2 𝑉3
𝑇4 𝑉1 𝑘−1
=[ ]
𝑇1 𝑉4
But 𝑇4 = 𝑇3 𝑎𝑛𝑑 𝑇1 = 𝑇2
Therefore,
𝑉2 𝑘−1 𝑉1 𝑘−1
[ ] =[ ]
𝑉3 𝑉4
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Then,
𝑉3 𝑉2
=
𝑉4 𝑉1
𝑉3
𝑄𝑅 = −𝑚𝑅𝑇3 ln
𝑉4
𝑉2
𝑄𝑅 = −𝑚𝑅𝑇3 ln
𝑉1
𝑉2 𝑉2
𝑊𝑛𝑒𝑡 = 𝑄𝐴 − 𝑄𝑅 = 𝑚𝑅𝑇1 ln − 𝑚𝑅𝑇3 ln
𝑉1 𝑉1
𝑉2
𝑊𝑛𝑒𝑡 = (𝑇1 − 𝑇3 ) 𝑚𝑅 ln
𝑉1
𝑉2
𝑊𝑛𝑒𝑡 (𝑇1 − 𝑇3 ) 𝑚𝑅 ln 𝑉1
𝑒 = =
𝑄𝐴 𝑉
𝑚𝑅𝑇1 ln 2
𝑉1
𝑇1 − 𝑇3
𝑒 =
𝑇1
𝑇3 𝑇𝐿
𝑒 =1− =1−
𝑇1 𝑇𝐻
𝑇𝐿 = 𝑙𝑜𝑤 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒
𝑇𝐻 = ℎ𝑖𝑔ℎ 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒
From the Carnot cycle efficiency equation, T1 is greater than T3. For the smaller value of T3, the
thermal efficiency will be maximum. That’s why the Carnot cycle has the highest thermal efficiency of all
heat engines.
𝑉2 𝑝3 𝑉3 − 𝑝2 𝑉2 𝑉4 𝑝1 𝑉1 − 𝑝4 𝑉4
𝑊 = ∑ 𝑊 = 𝑝1 𝑉1 𝑙𝑛 + + 𝑝3 𝑉3 𝑙𝑛 +
𝑉1 1−𝑘 𝑉3 1−𝑘
𝑉2 𝑚𝑅(𝑇3 − 𝑇1 ) 𝑉4 𝑚𝑅 (𝑇1 − 𝑇3 )
𝑊 = ∑ 𝑊 = 𝑚𝑅𝑇1 𝑙𝑛 + + 𝑚𝑅𝑇3 𝑙𝑛 +
𝑉1 1−𝑘 𝑉3 1−𝑘
Mean effective pressure is the average constant pressure that acting through one stroke, will do
on the piston the net work of the single cycle.
A quantity of special interest in connection with reciprocating engines is the mean effective
pressure (mep), which is defined as the constant pressure acting on the engine piston for its work stroke
that would result in the network of the cycle. It is a measure of the effectiveness of utilizing the cylinder
volume. Thus, we have
𝑉2
𝐼𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝑒𝑥𝑝𝑎𝑛𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜 =
𝑉1
𝑉3
𝐼𝑠𝑒𝑛𝑡𝑟𝑜𝑝𝑖𝑐 𝑒𝑥𝑝𝑎𝑛𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜 =
𝑉2
𝑉3
𝑂𝑣𝑒𝑟𝑎𝑙𝑙 𝑒𝑥𝑝𝑎𝑛𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜 =
𝑉1
𝑉3
𝐼𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝑐𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜 =
𝑉4
𝑉4
𝐼𝑠𝑒𝑛𝑡𝑟𝑜𝑝𝑖𝑐 𝑐𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜, 𝑟𝑘 =
𝑉1
𝑉3
𝑂𝑣𝑒𝑟𝑎𝑙𝑙 𝑐𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜 =
𝑉1
The isentropic compression ratio, 𝑟𝑘 , is the compression ratio most commonly used.
𝑝1 𝑝2
𝑚𝑎𝑥𝑖𝑚𝑢𝑚 𝑐𝑦𝑐𝑙𝑒 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 𝑟𝑎𝑡𝑖𝑜, 𝑟𝑝 = =
𝑝4 𝑝3
𝑉4 𝑉3
𝑟𝑘 = =
𝑉1 𝑉2
1
𝑒 = 1− 𝑘−1
𝑟𝑘
This equation shows that the Carnot cycle thermal efficiency increases as 𝒓𝒌
increases. This implies that the high thermal efficiency of a Carnot cycle is obtained at the
expense of large piston displacement, that is, large cylinder size.
1
𝑒 = 1− 𝑘−1
𝐾𝑎𝑖𝑟 = 1.4
𝑟𝑝 𝑘
This equation indicates that the high Carnot cycle efficiency is obtained at the
expense of a large rp , This would mean that a Carnot cycle must operate with high peak
cycle pressure to obtain high cycle efficiency.
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During the isothermal process, the piston should move very slowly within the cylinder. So that
insufficient time is available for the transfer of heat to the working medium within the cylinder during
expansion or from the working medium within the cylinder during isothermal compression.
But during the adiabatic process, the piston moves very fast within the cylinder. So that no time
is available for the transfer of heat.
So, a sudden change of speed (from low speed to high speed) of the piston is required to make
the cycle efficiency. But this is not possible due to the direction of the cylinder and the piston is none a
conductor of heat and the cover head of the cylinder is a good conductor. Again, there is a weightless
and frictionless piston fitted on a cylinder which is practically impossible. That’s why the Carnot cycle
cannot be used in actual practice.
https://www.mechanicaltutorial.com/4-stages-of-carnot-cycle-improving-thermal-efficiency
CARNOT CYCLE
Examples:
1. A Carnot engine receives 130 Btu of heat from a hot reservoir at 700°F and rejects 49 Btu of heat.
Calculate the temperature of the cold reservoir.
𝑇1 − 𝑇3 𝑊𝑛𝑒𝑡
𝑒 = =
𝑇1 𝑄𝐴
2. A Carnot requires 35kJ/s from the hot source. The engine produces 15 kW of power and the
temperature of the sink is 26℃ . What is the temperature of the hot source in ℃?
𝑇1 − 𝑇3 𝑊𝑛𝑒𝑡
𝑒 = =
𝑇1 𝑄𝐴
𝑇1 − (26 + 273) 15
=
𝑇1 35
3. A Carnot power cycle operates on 2 lb of air between the limits of 70°F and 500°F. The pressure
at the beginning of the Isothermal expansion is 400 psia and at the end of Isothermal expansion
is 185 psig. Determine (a) volume at the end of Isothermal compression, (b) ∆S during an
Isothermal process, (c)QA, (d) QR, € W, (f) e, (g) the ratio of expansion during Isothermal heating
and the overall ratio of expansion, and (h) the mean effective pressure.
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m = 2 lb
p1 = 400 psia
T1 = 960°R
p2 = 185 psig +14.7 =199.7 psia
T3 = 530 °R
Point 1:
𝑚𝑅𝑇1 (2)(53.34)(960)
𝑉1 = = = 1.778 𝑓𝑡 3
𝑝1 (400)(144)
Point 2:
𝑚𝑅𝑇2 (2)(53.34)(960)
𝑉2 = = = 3.561 𝑓𝑡 3
𝑝2 (199.7)(144)
Point 3:
𝑘 1.4
𝑇 𝑘−1 530
𝑝3 = 𝑝2 [ 3 ] = (199.7) [ ]1.4−1 = 24.57 𝑝𝑠𝑖𝑎
𝑇2 960
𝑚𝑅𝑇3 (2)(53.34)(530)
𝑉3 = = = 15.72 𝑓𝑡 3
𝑝3 (24.97)(144)
Point 4:
𝑉1 1.778
𝑉4 = 𝑉3 [ ] = (15.72) [ ] = 7.849 𝑓𝑡 3
𝑉2 3.561
(a)
𝑽𝟒 = 𝟕. 𝟖𝟒𝟗 𝒇𝒕𝟑 − −𝑣𝑜𝑙𝑢𝑚𝑒 𝑎𝑡 𝑡ℎ𝑒 𝑒𝑛𝑑 𝑜𝑓 𝑖𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝑐𝑜𝑚𝑝𝑟𝑒𝑠𝑠𝑖𝑜𝑛
(b)
𝑉2 (2)(53.34) 3.561
∆𝑆1−2 = 𝑚𝑅𝑙𝑛 [ ] = 𝑙𝑛 [ ] = 𝟎. 𝟎𝟗𝟓𝟐 𝑩𝒕𝒖/°𝑹
𝑉1 778 1.778
1 Btu = 778 ft-lb
R = 53.34 ft-lb/lb-°R
(c)
𝑉2 𝑉2
𝑄𝐴 = 𝑝1 𝑉1 ln = 𝑚𝑅𝑇1 ln
𝑉1 𝑉1
𝑄𝐴 = 𝑇1 (𝑆2 − 𝑆1 ) = 960°R (0.0952 Btu/°R) = 𝟗𝟏. 𝟒𝟑 𝑩𝒕𝒖
(d)
𝑉4 𝑉4 𝑉3
𝑄𝑅 = 𝑝3 𝑉3 ln = 𝑚𝑅𝑇3 ln = −𝑚𝑅𝑇3 ln
𝑉3 𝑉3 𝑉4
(e)
𝑊𝑛𝑒𝑡 = 𝑄𝐴 − 𝑄𝑅 =91.43 𝐵𝑡𝑢− 50.46 𝐵𝑡𝑢 = 𝟒𝟎. 𝟔𝟕 𝑩𝒕𝒖
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(f)
𝑇1 − 𝑇3 𝑊𝑛𝑒𝑡 40.67 𝐵𝑡𝑢
𝑒 = = = 𝑥 100% = 𝟒𝟒. 𝟖𝟏 %
𝑇1 𝑄𝐴 91.43 𝐵𝑡𝑢
(g)
𝑉2 3.561
𝐼𝑠𝑜𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝑒𝑥𝑝𝑎𝑛𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜 = = =𝟐
𝑉1 1.778
𝑉3 15.72 𝑓𝑡 3
𝑂𝑣𝑒𝑟𝑎𝑙𝑙 𝑒𝑥𝑝𝑎𝑛𝑠𝑖𝑜𝑛 𝑟𝑎𝑡𝑖𝑜 = = = 𝟖. 𝟖𝟒
𝑉1 1.778 𝑓𝑡 3
(h)
778 𝑓𝑡 − 𝑙𝑏
𝑊𝑛𝑒𝑡 𝑊𝑛𝑒𝑡 40.67 𝐵𝑡𝑢 ( 1 𝐵𝑡𝑢 ) 1 𝑓𝑡 2 𝑙𝑏
Pm = = = 3 3
𝑥 2
= 15.88 2 = 𝟏𝟓. 𝟖𝟖 𝒑𝒔𝒊
𝑉𝐷 𝑉3 − 𝑉1 15.72 𝑓𝑡 − 1.778 𝑓𝑡 144 𝑖𝑛 𝑖𝑛
4. Three-Process Cycle
Example: Ten cu. ft of helium at 20 psia and 80°F are compressed isentropically 1-2 to 80 psia. The
helium is then expanded polytropically 2-3 with n=1.35 to the initial temperature. An
isothermal 3-1 returns the helium to the initial state. Find T2, V2, p2, QA, QR, W,∆S3-1, and pm
or mep.
Solution:
p1= 20 psia
T1 =540°R
V1= 10 ft3
p2 = 80psia
T3 = 540°R
𝑝1 𝑉1 (20)(144)(10)
𝑚= = = 0.1382 𝑙𝑏
𝑅𝑇1 (386.04)(540)
Point 2:
𝑘−1 1.666−1
𝑝2 𝑘 80 1.666
𝑇2 = ( ) = 540 ( ) = 𝟗𝟑𝟗. 𝟗°𝐑
𝑝1 20
1 1
𝑝1 𝑘 20 1.666
𝑉2 = 𝑉1 ( ) = 10 ( ) = 𝟒. 𝟑𝟓𝟏 𝐟𝐭 𝟑
𝑝2 80
Point 3:
𝑛 1.35
𝑇3 𝑛−1 540 1.35−1
𝑝3 = 𝑝2 ( ) = (80) ( ) = 𝟗. 𝟒𝟑𝟓 𝒑𝒔𝒊𝒂
𝑇2 939.9
1 1
𝑝2 𝑛 80 1.35
𝑉3 = 𝑉2 ( ) = (4.351) ( ) = 𝟐𝟏. 𝟐 𝐟𝐭 𝟑
𝑝3 9.435
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𝑉1 (0.1382)(386.04)(540) 10
𝑄𝑅 = 𝑚𝑅𝑇3 ln = ln = −𝟐𝟕. 𝟖𝟐 𝑩𝒕𝒖
𝑉3 778 21.2
Q R −27.82 𝐵𝑡𝑢
∆𝑆3−1 = = = −𝟎. 𝟎𝟓𝟏𝟓 𝑩𝒕𝒖/°𝐑
𝑇1 540°R
The purpose of power cycles is to convert heat into work as efficiently as possible. Recall
that areas on PV Diagrams can be interpreted as boundary or shaft work for certain types of
systems.
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What is the main difference between gas and vapor power cycles?
In vapor power cycle, the working fluid exists in vapor phase during one part of the cycle and in
liquid phase during another part whereas in a gas power cycle, the working fluid remains in the
gaseous phase throughout the entire cycle.
6. Real Gases
Real gases are non-ideal gases whose molecules occupy space and have interactions;
consequently, they do not adhere to the ideal gas law. To understand the behavior of
real gases, the following must be taken into account:
• compressibility effects;
• variable specific heat capacity;
• van der Waals forces;
• non-equilibrium thermodynamic effects;
• issues with molecular dissociation and elementary reactions with variable
composition
Real gases are any gases that do not obey the ideal gas law, they are gases with
compressibility factor Z (pV/RT) different than 1. The non-ideal properties of gases become more
important as (a) pressure increases, (b) temperature decreases, or (c) conditions approach the
critical point. The widely published compressibility chart shows how temperature and pressure
affect the compressibility factor and how every gas can become a real (non-ideal) gas under some
pressure and temperature conditions.
Any gas that exists is a real gas. Nitrogen, oxygen, carbon dioxide, carbon monoxide, helium
etc. Real gases have small attractive and repulsive forces between particles and ideal gases do
not. Real gas particles have a volume and ideal gas particles do not.
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1. Assume that we are to design an air-standard Carnot cycle according to the following
specifications:
Determine:
a. The cycle thermal efficiency
b. The isentropic compression ratio
c. The pressure ratio
d. The maximum cycle pressure in MPa
e. The mep in KPa on the basis of 1 kg of air.
2. Show that the thermal/cycle efficiency of the Carnot cycle in terms of isentropic compression
1
ratio 𝒓𝒌 is given by 𝑒 = 1 − 𝑘−1
𝑟𝑘
Brainwriting Activity
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VIII. ASSIGNMENT
Directions: Please answer the following problems neatly and accurately. Draw the PV and TS
diagrams of the different processes. Write your solutions legibly in a short bond paper
1. The working substance for a Carnot cycle is 8 lb of air. The volume at the beginning of
isothermal expansion if 9 ft3 and the pressure is 300 psia. The ratio of expansion during
the addition of heat is 2 and the temperature of the cold body is 90°F. Find (a) QA, Btu (b)
QR, Btu (c) V3, ft3 (d) p3, psia (e) V4, ft3 (f) p4, psia (g)pm, psia (h) the ratio of expansion
during the isentropic process, and (i) the overall ratio of expansion.
2. A three-process cycle of an ideal gas, for which, cp = 1.064 and cv= 0.804 kJ/kg-K, is
initiated by an isentropic compression 1-2 fro, 103.4 kPa, 27C to 608.1 kPa. A constant
volume process 2-3 and a polytropic 3-1 with n= 1.2 completes the cycle. Circulation is
steady rate of 0.905 kg/s, compute (a) QA, kJ/s (b) W, kJ/s (c) e, % (d) pm
IX. REFERENCES
A) Book/Printed Resources
Please Read!!!!!
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