2113 Ws
2113 Ws
1.2
Drying
1.2.1 General aspects In addition, the heat transfer is influenced by the sur-
face area, the moisture distribution on the surface and
Drying is the most common process for preservation the shape of the product to be dried.
of agricultural products. Various methods are applied, After the moisture on the surface evaporates, the liq-
depending on the properties and requirements of the uid water and the vapor migrate from the interior of the
product. product to the surface due to temperature, moisture and
Sun drying and in-field drying are still applied in pressure gradients until equilibrium is reached. This in-
developing countries using sun and wind as the only ternal heat and mass transfer is influenced by the prop-
energy sources. In countries with highly mechanized erties of the product such as:
agricultural production, automated high capacity – Morphological structure
high-temperature dryers are applied for drying almost Shape and size of the product
all agricultural products. Fossil fuels are used to heat the Length of the diffusion path
drying air; the fans are driven with electric motors. Only Chemical composition
a few products with low moisture content are dried by – Moisture content and moisture distribution
in-storage low-temperature dryers using mainly the dry- – Density
ing potential of the ambient air as energy source. – Specific heat capacity
The temperature of the drying air and the initial – Thermal conductivity
moisture content of the product are the major parame- – Thermal diffusivity
ters influencing drying time and product quality. During
the drying process, the properties of the product and In the following paragraphs, the drying parameters,
of the drying air show spatial and temporal variations. which mainly influence the drying process of agricul-
Therefore, the heat and mass transfer phenomena occur- tural commodities, are described. The properties of the
ring simultaneously during the drying process are rather drying air can be found in related engineering hand-
complex. In addition, chemical and biochemical reac- books [1, 2].
tions occur during the drying process, which influence
the quality of the dried product.
During the drying process, moisture evaporates on 1.2.2 Drying parameters
the surface and is absorbed and removed by the drying
air due to partial water pressure differences between 1.2.2.1 Morphological characteristics
the surface and the surrounding air. The heat and mass
The morphological characteristics of agricultural com-
transfer processes at the surface mainly depend on the
modities such as structure, dimensions, weight shape
properties of the drying air:
and chemical composition of the different components,
– Temperature have a significant impact on the drying process [3, 4].
– Relative humidity/absolute moisture content Besides fruits and vegetables, which are also consumed
– Air velocity in fresh condition, almost all other agricultural products
– Thermal conductivity have to be processed prior to consumption. This is done
– Specific heat capacity mostly by drying. The drying process is greatly affected
– Density by the plant organ being dried (Table 1.2.1).
TABLE 1.2.1 Plant organs of different commodities used for The inedible peel of these products has to be re-
drying. moved before cutting and drying. Only products with
Plant organ Commodity edible skin like tomato, paprika or apple can be sliced
or diced and dried without peeling. Grapes, plums, chili
Seed Cereals, grain legumes, oil seeds, cocoa, coffee
or paprika have a waxy skin, which is a barrier for the
Leave Medicinal plants, herbs moisture migration from the interior to the surface. To
Herbage Medicinal plants, fodder plants accelerate the drying process those products are either
blanched or immersed into a chemical solution prior to
Flower Medicinal plants
drying to increase the water permeability of the skin.
Root/tuber Cassava, potato, carrot, valerian Mashing the flesh of fruit like mango, banana or apricot
Fruit Apricot, apple, plum, grape, banana, tomato, and drying the puree in a thin layer to a product called fruit
paprika, chili, coconut etc. leather is an alternative to utilize over-mature fruits, small
fruits and fruits with irregular size as cheap raw material.
In addition to the size, the shape of the product pro-
vides important information of the diffusion path and the
The size of the commodity influences the drying pro- direction of the moisture migration. Both are major crite-
cess considerably. Small-sized products such as cereals, ria for the drying process. The drying rate of commodities
oil seeds or leaves dry much faster than larger commod- with regular shapes such as grapes, litchi, longan, banana
ities like fruits and root crops. Agricultural products like etc. mainly depends on the diameter of the fruit. For prod-
most biological materials are inhomogeneous in size de- ucts with an irregular shape like cereals, knowledge about
pending for instance on cultivar, fertilization or weather the longitudinal and cross section is required to determine
conditions during cultivation. the diffusion path. In the literature, composition and cel-
Cereals, oil seeds, grain legumes, chili and grapes are lular structure are illustrated for almost all products.
dried after pre-cleaning without any other pre-treatment. However, for the analysis of the drying process the cel-
Consequently, small and large kernels have to be dried in lular structure of a commodity is of minor importance. To
the same batch. Drying the product to moisture content ac- analyze and simulate the moisture migration from the in-
cording to the requirements of the quality standards small terior to the surface of a product, shape and structure of
kernels are over-dried while large kernels still have higher the different components are the most important criteria. In
moisture content than required. Due to their hygroscopic contrast to the detailed structure of agricultural products as
characteristics, the moisture content of cereals, oil seeds described in literature, in the specific chapters of this book
and medicinal plants equalizes during storage. simplified cross sections in the three spatial axes are illus-
Fruit like grape, fig, apricot and plum are different in size trated as shown exemplarily for a maize kernel (Fig. 1.2.1).
and are dried without sorting by size. Therefore, the dried
fruits have different moisture contents after drying. To pre-
vent spoilage during storage those products have to be con-
ditioned after drying to equalize the moisture content. Only
a few fruits like litchi or longan are graded by size prior to
drying in order to get the desired uniform drying.
Products with extended size and irregular shape are
cut into slices, stripes or cubes to reduce the drying path
and, hence, to accelerate the drying process. To achieve
the desired uniform moisture content after drying the
crops have to be cut into products of regular shape and
constant size (Table 1.2.2).
Spices Onion, garlic 2–4 FIG. 1.2.1 Simplified cross section of front, side and top view of a
maize kernel with direction (arrow) and quantity (length of arrow) of
Fruits Banana, papaya, pineapple, 4–10
the expected moisture migration during drying.
mango
are also relevant for the drying process. These compo- 1.2.2.3 Moisture content [6,8–10]
nents have a different chemical composition and there- Agricultural commodities contain moisture as liquid
fore also have different hygroscopic properties, which water or water vapor. The water can be located on the
affect the diffusion rate and also the direction of the surface of the product as free moisture and/or in the in-
moisture migration. For example, the embryo of cereals terior in form of osmotic or capillary moisture.
has a higher fat and protein content compared to the en- The moisture content of agricultural commodities can
dosperm and therefore has higher moisture content be- be expressed either on wet basis (w.b.) or on dry basis
fore and after drying. Consequently, part of the moisture (d.b.). The moisture content on wet basis MCwb is de-
migrates during the drying process from the interior to fined as the ratio of the mass of water mW and the total
the surface of the product; the other part migrates from mass of the product and is expressed as % w.b.:
the endosperm to the embryo to protect the germ from
over-drying and damage. mW
MC wb = 100 (1.2.1)
m W + m dm
1.2.2.2 Diffusion path The moisture content on dry basis MCdb is the ratio
During the second phase of the drying process, the of the mass of water mW and the dry matter content mdm
moisture has to migrate from the interior to the surface and is expressed as a dimensionless value:
of the product by osmotic or capillary forces. The diffu-
mW
sion rate mainly depends on: MCdb = (1.2.2)
mdm
– Diffusion path
– Chemical composition The moisture content on wet basis is used by farmers
– Morphological structure and traders, while the moisture content on dry basis is
used for scientific analysis of drying processes since the
The diffusion path is the shortest distance from the in-
relation between the moisture content on dry basis and
terior to the surface. The diffusion path mainly depends
the mass of water is a linear function.
on size and shape of the product as well as on the me-
To convert the moisture content on wet basis into dry
chanical pre-treatment. To reduce the diffusion path root
basis and vice versa, the following equations can be used:
crops, vegetables and some fruits are cut in slices or are
diced. Stone fruits are halved or pitted (Table 1.2.3). MCdb
MC wb = 100 (1.2.3)
1 + MCdb
The mass of water ∆ mW, which has to be removed during The final moisture content MC2 at which the product
the drying process, can be calculated as follows: is safe for storage is influenced by:
– Chemical composition of the commodity
MC1 − MC 2 (1.2.5) – Nutrient distribution
∆m W = m1
100 − MC1 – Hygroscopic properties
– Storage conditions (temperature, humidity)
MC1 − MC 2 – Packaging materials
∆m W = m 2 (1.2.6)
100 − MC 2 According to their hygroscopicity, products with a high
fat and protein content have to be dried to a lower moisture
where m1 is the mass of the wet product and m2 is the content, while products with a high content of carbohy-
mass of the dried product. drates can be stored at higher moisture contents (Table 1.2.5).
The initial moisture content greatly affects the mass
of water, which has to be removed during the drying
process and therefore, also influences drying time and TABLE 1.2.5 Final moisture content MC2 of agricultural
energy consumption significantly. For most agricul- products.
tural products, the moisture content at harvest is iden- Commodity Moisture content MC2 (% w.b.)
tical with the moisture content at the beginning of the
drying process. Only a few products such as some cere- Cereals 12–14
als or some medicinal plants are pre-dried in the field Oil crops 7–9
after harvest. In addition, after osmotic dehydration of Root crops and tubers 12–14
fruits and vegetables the initial moisture content is re-
duced compared to the moisture content after harvest Vegetables 5–10
due to the diffusion of water from the product into the Spices 5–10
osmotic solution. The initial moisture content MC1 is
Stimulants 7–10
mainly influenced by:
Fruits 16–20
– Commodity and cultivar
Medicinal plants 8–12
– Weather condition before and during harvest
– Stage of maturity
– Pre-drying
– Osmotic dehydration The amount of water, which has to be removed during
the drying process, depends on the initial and the final
and therefore shows great variation (Table 1.2.4).
moisture content of the product. Per 100 kg of dried
product the amount of water in kg, which has to be re-
moved during the drying process is listed in Table 1.2.6.
TABLE 1.2.4 Initial moisture content MC1 of agricultural
products.
Commodity Moisture content MC1 (% w.b.)
TABLE 1.2.6 Mass of water ∆ mW to be removed during drying of
Cereals agricultural commodities.
Small grains 12–30 Commodity Water removed ∆ mW (% w.b.)
Maize 20–35 Cereals
Root crops 70–85 Small grains 0–22
Oil crops 8–55 Maize 14–32
Vegetables 85–95 Root crops 8–100
Spices 70–85 Oil crops 200–350
Stimulants 50–60 Vegetables 500–1700
Fruits 65–80 Spices 350–375
Medicinal plants 65–80 Stimulants 86–125
Fruits 128–300
Q = m P ⋅ c P ⋅ ( TP 2 − TP1 ) (1.2.8)
During drying, heat is transferred from the drying air to Water 4.18
the surface of the product by natural or by forced convection. Carbohydrates 1.71
Inside the product, the heat is transferred by conduction.
The thermal conductivity k of agricultural commod- Protein 1.71
ities, expressed in W/m K, is a measure of its ability to Fat 1.93
transmit heat during the drying process from the surface Fiber 1.84
to the interior of the product. For a product particle, the
one-dimensional heat flow dQ/dt depends on the ther- Ash 0.84
mal conductivity k, the cross sectional area A and the Air 1.0
temperature gradient dT/dx:
dQ dT (1.2.7)
= − k⋅A The specific heat capacity of agricultural commodities
dt dx
is also greatly influenced by the moisture content and
The thermal conductivity is widely independent of the ranges from 1.5 to 4.0 kJ/kg K and only slightly increases
temperature and is mainly influenced by the structure and with temperature.
the chemical composition of the product (Table 1.2.7).
Water 5.1
Carbohydrates 2.1
Protein 2.2
Fat 4.4
Fiber 2.6
Ash 2.7
Air 0.55
– Storage during night interrupts the drying pro-cess – Mass losses due to rodents, birds and theft
– Air temperature in the bulk during storage – Non-uniform, insufficient drying and insect
corresponds to the product temperature before infestation causes losses during storage
collecting – Contamination with pathogenic germs and heavy
– Relative humidity in the bulk is in equilibrium with metals increases health risk for the consumers
the moisture content of the product and therefore – Mold growth can cause formation of mycotoxins
is significantly lower than the humidity of the air during storage
during night – High labor input for spreading, mixing and
– Product temperature and moisture content of the collecting the product
product are equalized during storage
Utilization 1.2.3.2 Solar drying [5, 21–29]
– All agricultural products The introduction of solar dryers offers a promising
alternative to reduce the tremendous postharvest losses
Drying conditions
in developing countries. Numerous natural convection
– Spreading in thin layer: 5–10 cm type solar dryers such as cabinet dryers of different de-
– Turning intervals: 2–4 h signs were developed. Due to their low capacity in rela-
– Drying air temperature: 20–35 °C tion to the investment and the high weather dependent
– Drying time: 1–6 days risk of spoilage, the use of solar cabinet dryers is very
limited.
Advantages
To overcome the main disadvantages of the cabinet
– Simple drying method dryers, solar dryers with forced convection were devel-
– Low investment for mats, foils, trays, rakes etc. oped to reduce postharvest losses and to improve prod-
– Protection from rain and dew precipitation when uct quality. Described and evaluated below are the most
storing in a shelter during night common commercially produced types.
– Low operating cost
– Fossil fuels and electricity are not required
Solar tunnel dryer [26, 27]
Disadvantages
Solar tunnel dryers (Fig. 1.2.5) consist of a solar air
– Drying behavior depends on fluctuating weather heater and a tunnel dryer, which are arranged in series.
conditions Air heater and tunnel dryer are covered with either a
– Extended drying periods during rainy season transparent foil, polycarbonate double-skin sheets or
increase risk of losses glass sheets. The transparent cover is tilted to drain
– Prevention of over drying of the top layer requires water. A black metal sheet is used as absorber. On the
turning in short intervals
FIG. 1.2.5 Solar tunnel dryer with photovoltaic driven fans (left), cross section of the dryer (right).
the bottom of the front side. The air outlet is installed – A solar greenhouse dryer with parabolic roof is
on the top of the backside. The drying air is guided by operated without additional solar air heater
air ducts, which are installed underneath the tables in – Solar radiation is absorbed and converted into heat
longitudinal direction of the dryer. To enable operation by the product spread on trays and also by the
independent of weather conditions and time of day the concrete platform inside the greenhouse
dryer can be equipped with a gas heater. – The course of the drying air temperature is following
the pattern of solar radiation.
– The lower temperature inside the greenhouse leads
to a flat moisture content curve compared to solar
dryers with air heaters
– The drying process is extended after sun set by the
thermal energy stored in the concrete platform inside
the greenhouse
– The transparent cover protects the product from
remoistening by rain or dew
– During adverse weather the supplementary heater
can be used to continue drying
Utilization
– Fruits
– Vegetables
– Spices
FIG. 1.2.7 Solar greenhouse dryer with parabolic roof, back-up
heating system and photovoltaic driven fans [5].
Operating conditions
– Width: 6–10 m
– Length: 10–30 m
Drying curves (Fig. 1.2.8) – Height: 3–3.5 m
– Air velocity: 0.5 m/s
– Power requirement: 50–250 W
– Loading capacity: 500–1500 kg
– Drying air temperature: 30–60 °C
– Drying time: 2–5 days
Advantages
– High drying capacity
– Multi-purpose dryer
– Low electric energy consumption
– Dryer can be operated during adverse weather by
use of supplementary heater
– Loading, mixing and unloading is weather
independent
– Product is protected from rain, dust, insects, birds
and rodents
– Hygienic production of high quality products
Disadvantages
– High investment
– Non-uniform air distribution
– Requirement of UV-stabilized polycarbonate sheets
as cover material
Especially for drying medicinal and aromatic plants,
a solar dryer was developed, where flat-bed dryers are
FIG. 1.2.8 Characteristic drying curves and typical course of ambi- incorporated into a plastic covered greenhouse with a
ent temperature Tamb, drying temperature T and relative humidity RH
of a solar greenhouse dryer with parabolic roof. span roof and vertical sidewalls (Fig. 1.2.9). The solar air
Disadvantages Dryer
– High investment – Width: 4 m
– Non uniform drying when operated without product – Length: 6 m
mixing – Bulk depth: 0.2 m
– Access to public grid to operate the fans – Loading capacity: 4000 kg/module
– UV-resistant bubble foil as cover material is – Air velocity: 0.2–0.3 m/s
required – Power requirement: 3 kW/module
– Drying air temperature: 40–60 °C
– Drying time: 2–6 days
Solar processing center [29]
For cooperative and commercial production of co- Advantages
coa and coffee a solar processing center was developed – Modular design
(Fig. 1.2.11). The center consists of a simple substructure, – High drying capacity
which is fixed on an elevated concrete platform. The – Commercial or cooperative application
solar air heater is incorporated into the tilted roof. The – Weather independent operation
drying air is sucked by axial flow fans through the solar – Utilization of fuel wood as supplementary energy
air heater, the horizontal and vertical air ducts and is source
forced through the product, which is dried in flat-bed – Low energy cost
dryers. During periods of adverse weather conditions, – Product is protected from environment
the drying air is heated with a supplementary biomass
furnace, which reduces the drying time from 4 to 6 days Disadvantages
to 2 days. Fermentation, grading, drying and storage – High investment
can be performed simultaneously in the center. – Labor intensive mixing of the product during
drying
– Temperature difficult to adjust and to control
Drying curves
– Drying curves are similar to those of a
solar greenhouse dryer with roof integrated
collector
Utilization
– Cocoa
– Coffee
Operating conditions
Structure
FIG. 1.2.12 Structure of a low-temperature in-storage system for
– Width: 12 m grain drying [6].
– Length: 10–20 m
– Gable height: 5.5 m
FIG. 1.2.15 Schematics of the relative direction of product and air-movement in dryers for agricultural products [6].
Batch dryers
In batch type dryers, a horizontal or vertical container
is loaded with the wet product. The heated air is forced
through the product until the drying process is finished.
After cooling the batch with ambient air, the dried prod-
uct is discharged and a new batch of wet product is FIG. 1.2.16 Structure of a flat-bed dryer [6].
loaded.
FIG. 1.2.17 Characteristic drying curves of flat-bed dryers at the air inlet and air outlet together with drying air temperature T, product tem-
perature TP and relative humidity RH [6].
Utilization
Drying curves (Fig. 1.2.19)
– Fruits
– Drying air temperature and air flow rate are constant – Vegetables
during the whole drying process – Spices
– At the air inlet, the moist product is exposed to the high
Operating conditions
temperature. The moisture content is reduced rapidly
until the equilibrium moisture content is reached – Length: 1.0 – 1.5 m
– Due to the comparatively high air velocity the – Width: 1.0 – 2.5 m
temperature of the drying air is only slightly reduced – Height: 2.0 – 2.5 m
on its way through the dryer, which is caused by – Distance between trays: 50 – 100 mm
– Loading capacity: 50 – 1000 kg
– Air velocity: 0.2 – 0.3 m/s container with a rectangular or circular cross section.
– Drying air temperature: 40 – 80 °C During the drying process, the product is continuously
– Drying time: 4 –24 h discharged at the bottom of the container and conveyed
with a vertical auger or a bucket conveyor to the top of
Advantages
the dryer. The conveyors are also used for loading and
– Uniform drying unloading. The drying air is forced horizontally through
– Possibility to dry small batches the bulk. After the drying process is finished heater and
– Easy handling conveying equipment are switched off and ambient air
– Low electric energy consumption is forced through the product until it is cooled down
to almost ambient temperature. Despite the high dust
Disadvantages
emissions, in general, recirculating batch dryers are not
– High investment equipped with dust separation systems.
– Limited drying capacity
Drying curves (Fig. 1.2.21)
– Limited drying air temperature
– High labor requirement for cleaning the trays
– High thermal energy consumption when not
recirculating the exhaust air