VAD_12_MD_TT_CJR_Sir_Atomic structure 25-07-2025

CHEMISTRY MARKS : 180

5 The correct order of energy of following spectral
lines is -
1 Difference in wavelength of two extreme
spectral lines of H-atom in Balmer region is:
(Where RH is Rydberg constant)
(1) 7.2 / RH (2) 0.25 / RH
(3) 4 / RH (4) 3.2 / RH
2 Iodine molecules dissociates into atoms after
absorbing light of wavelength 4500Å. If one
quantum of radiation is absorbed by each (1) 1 > 3 > 2 > 5 > 4 (2) 3 > 1 > 2 > 4 > 5
molecule what will be the approximate kinetic
Energy of iodine atom (3) 3 > 2 > 1 > 4 > 5 (4) 5 > 4 > 3 > 2 > 1
[Given B.E. of I2 = 241.2 kJ/mol], [NA = 6 × 1023]
[1eV/atom = 96.48 kJ/mole].
6 Which of the following is not the possible path of
cathode rays ejecting from the surface of cathode?
(1) 8.6 × 10 – 36 J (2)
(1)
(2) 2.0 × 10 – 20 J
(3) 433 kJ
(4) 4.3 J
3 Find the radius ratio of 2nd orbit of H atom to 2nd
orbit of He+
(3) (4)
(1) 1 : 4 (2) 2 : 1
(3) 4 : 1 (4) 1 : 2
4 Find the wavelength of 2nd line of Balmer series
of Li2+. [Given : RH = Rydberg constant]

7
(1) 16RH (2) 16
27 9RH During Millikan's oil drop experiment, which is
16 not a possible charge on oil droplet?
(3) 27RH (4)
16 27RH (1) 1.6 × 10 – 19 C (2) 2.4 × 10 – 19 C
(3) 3.2 × 10 – 19 C (4) 4.8 × 10 – 19 C

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 VAD_12_MD_TT_CJR_Sir_Atomic structure 25-07-2025
8 13 Bohr orbits are called stationary orbits because :
(1) Electron is stationary in them.
(2) Electrons in them have fixed energy.
(3) Electron is continuously loosing energy in
For above transition in hydrogen like atoms.
them.
Select the correct relation :
(4) Nucleus is stationary in atom.

(1) λ 3 = λ 1 + λ 2 (2) λ 3 = λ 1 λ 2
λ1 + λ2
14 Calculate wavelength of 3rd line of breacket series
in hydrogen spectrum :
(3) v3 = v1 × v2 (4) v3 = v1 v2 (1) 784 (2) 33
v1 + v2
33R 784R
9 In a collection of H-atoms, electrons make (3) 33R (4) 784R
transition from 4th excited state to ground state , 784 33
then maximum no. of different lines observed in
emission spectrum are
15 Light of wavelength ' λ ' falls on metal having work
hc
function . Photoelectric effect will take place
(1) 6 (2) 4 (3) 12 (4) 10 λ0
10 Three energy levels P, Q, R of a certain atom are
only if:
(1) λ ≥ λ 0 (2) λ ≥ 2 λ 0
such that EP < EQ < ER. If λ 1, λ 2 and γ 3 are the
wave length of radiation corresponding to (3) λ ≤ λ 0 (4) λ ≤ λ 0/2
transition R → Q; Q → P and R → P respectively.
The correct relationship between λ 1, λ 2 and λ 3 is 16 1st excitation energy for the hypothetical H-like
sample is 24 eV, then which one is incorrect
(2) 1 1 1
(1) λ 1 + λ 2 = λ 3 = +
(1) Ionisation energy of sample is 36 eV
λ3 λ1 λ2
(4) 2 1 1 (2) Ionisation energy of sample is 32 eV
(3) λ 2 = √
λ1 λ2 = +
λ3 λ1 λ2
11 The increasing order for the value of e/m (charge
(3) Binding energy of 3rd excited stepe is 2 eV
magnitude/mass) is : (4) Second excitation energy of the sample is
28.44 eV
(1) electron < proton < neutron < α -particle
(2) neutron < proton < electron < α -particle
17 In an atom, two electrons move around the
nucleus in circular orbits of radii R and 4R, the
(3) neutron < α -particle < proton < electron ratio of the time taken by them to complete one
revolution is (Considering Bohr's atomic theory is
(4) electron < neutron < proton < α - particle applicable)
12 The angular momentum of electron in a H-like (1) 1 : 4 (2) 4 : 1 (3) 1 : 8 (4) 8 : 1
species can not be :
(1) h (2) 1.5h (3) 2h (4) 3.5h
π π π 2π

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 VAD_12_MD_TT_CJR_Sir_Atomic structure 25-07-2025
18 1st excitation energy for the hypothetical H-like 23 The ratio of the difference between 1st and 2nd
sample is 24 eV, No. of statements which correct. Bohr’s orbit energy to that between 2nd and 3rd
(i)Ionisation energy of sample is 36 eV. orbit energy is (z = 1)
(ii) Ionisation energy of sample is 32 eV.
(1) 1 (2) 1 (3) 27 (4) 5
(iii) Binding energy of 3rd excited step is 2 eV. 2 3 5 27
(iv) Second excitation energy of the sample is
28.44 eV.
24 Photoelectric emission is observed from a surface
for frequencies ν 1 and ν 2 of incident radiations
(1) Ionisation energy of sample is 36 eV. ( ν 1 > ν 2 ). if the maximum kinetic energy of photo

(2) Ionisation energy of sample is 32 eV. electrons in the two cases are in the ratio of 2 : 1
then threshold frequency ν 0 is given by
(3) 1
(1) ν 2 − ν 1 (2) 2 ν 1 − ν 2
(4) 2 2−1 2−1

19 Find out ratio of following for photon

(3) 2 ν 2 − ν 1
2−1
(4) ν 2 − ν 1
2
( ν max.)Lyman : ( ν max)Brakett
25 In a Bohr’s model of atom when an electron jumps
(1) 1 : 16 (2) 16 : 1 from n = 1 to n = 3, how much energy will be
(3) 4 : 1 (4) 1 : 4 emitted or absorbed. (Z × 1)

20 The radius of the an orbit of Be+3 ion is 0.529 Å.

(1) 2.15 × 10 – 11 erg (2) 0.1911 × 10 – 10 erg
The velocity of electron in this orbit will be (3) 2.389 × 10 – 12 erg (4) 0.239 × 10 – 10 erg
(1) 0.545 × 106 m/s (2) 2.18 × 106 m/s 26 The energy required to ionise a helium atom is equal
(3) 4.36 × 106 m/s (4) 1.09 × 106 m/s to 24.6 ev. The energy required to remove both the
electrons from the helium atom would be :-
21 The de Broglie wavelength ( λ ) associated with a
(1) 59 ev (2) 81 ev
photoelectron varies with the frequency (v) of the
incident radiation as, [v0 is thershold frequency] : (3) 79 ev (4) 40 ev
(1) λ ∝ 1
3
(2) λ ∝ 1
1
27 A 100 W bulb emits light of wavelength 400 nm
(v − v0 ) 2 (v − v0 ) 2 number of photons emitted per second by the bulb is :
(3) λ ∝ 1 1 (1) 2.0 × 1020 (2) 4.0 × 1019
1
(4) λ ∝
(v − v0 ) (v − v0 )
(4) 8.0 × 10 – 20
4
(3) 6.0 × 1020
22 The ratio of the radii of first three Bohr of Be3+
28 The nucleus of an atom can be assumed to be
ion orbits is
spherical. The radius of the nucleus of mass
(1) 1 : 05 : 033 (2) 1 : 2 : 3 number A is given by 1.25 × 10 – 13 × A1/3 cm.
Radius of atom is one Å. If the mass number is 64,
(3) 1 : 4 : 9 (4) 1 : 8 : 27
then the fraction of the atomic volume that is
occupied by the nucleus is
(1) 1.0 × 10 – 3 (2) 5.0 × 10 – 5
(3) 2.5 × 10 – 2 (4) 1.25 × 10 – 13

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 VAD_12_MD_TT_CJR_Sir_Atomic structure 25-07-2025
29 In gold foil experiment if number deflected of α - 34 If λ 0 and λ be the threshold wavelength and the
particle with respect to 120° are 12 then calculate wavelength of incident light, the speed of photo-
number of deflected α -particle with respect to electrons ejected from the metal surface is :
60°- (1) 2h (2) 2hc
√
(λ0 − λ) √
(λ0 − λ)
(1) 36 (2) 108 m m

(3) 24 (4) None of these (3) 2hc λ 0 − λ (4) 2hc 1 1

√
( ) √
( − )
λ λ0 m λ0 λ
30
m
Electron of an excited hydrogen atom jumps to the
ground state and emits a photon of wavelength λ .
35 The λ of H α line of the Balmer series is 6500Å.
The quantum number n of initial excited state in What is the λ of H β line of the Balmer series.
terms of λ and R is :- (1) 5814.8 Å (2) 4814.8 Å
(1) R (1 – λ ) (2) λ (1 – R) (3) 3814.8 Å (4) 2814.8 Å
(3)
√
λ (1 − R) (4)
√
λR 36 An electron in a hydrogen atom in its ground state
R ( λ R − 1) absorbs 1.5 times much energy as the minimum
31 Given graphical representation is possible for ---- required for it to escape from the atom. What is
the velocity of the emitted electron?
orbital. and calculate number of radial nodes also
(1) 1.54 × 106 m/s (2) 1.54 × 108 m/s
(3) 1.54 × 103 m/s (4) 1.54 × 104 m/s
37 An α -particle having kinetic energy 5 MeV falls
(1) 3s,2 (2) 3p,3 (3) 3d,2 (4) 4s,2 on a Cu-foil. The shortest distance from the

32 Angular momentum for g subshell is:

nucleus of Cu to which a-particle reaches is
(Atomic no, of Cu-29, K-9x10 Nm /C")
(1) 2.236h/5.28 (2) 0.236h/6.28 (1) 2.35 × 10−13 m (2) 2.35 × 10−14 m
(3) 1.236h/6.28 (4) 4.47h/6.28 (3) 5.98 × 10−15 m (4) None of these
33 For the Balmer series in the spectrum of H atom, 38 Assume that Bohr's quantisation rule is applicable
1 1 for orbital motion of earth than find total energy of
ν¯ = RH { − } , the correct statements among
n21 n22 earth in its orbit (M = mass of sun, m = mass of
(I) and (IV) are : earth)
(I) As wavelength decreases, the lines in the series (1) −n2 h2 (2) −4 π 2 G2 M 2 m3
converge 4 π 2 GM m2 n2 h2
(II) The integer n1 is equal to 2
(III) The lines of longest wavelength corresponds (3) − π GMm2 2
(4) − 2 π G2 M 2 m2
2

nh
2 2 2 2 nh
to n2 = 3
(IV) The ionization energy of hydrogen can be 39 Which electronic transition in a hydrogen atom,
calculated from wave number of these lines starting from the orbit n = 7, will produce infrared
light of wavelength 2170 nm? (Given : RH =
(1) (II), (III), (IV) (2) (I), (II), (III)
1.09677 × 107 m – 1)
(3) (I), (III), (IV) (4) (I), (II), (IV) (1) n = 7 to n = 6 (2) n = 7 to n = 5
(3) n = 7 to n = 4 (4) n = 7 to n = 3

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