UNIT: STRUCTURE OF ATOM

ASSIGNMENT -1
1. How many total electrons are present in nitrate ion? 32
2. Complete the following table:

21
3. Find (a) the total number and (b) the total mass of neutrons in 7 mg of 14C 2.409 × 10 neutrons
.
-6
4.035 ×10 kg.
4. Yellow light emitted from a sodium lamp has a wavelength (λ) of 580 nm. Calculate the frequency
(v) and wave number (¯v) of the yellow light.
5. Calculate the ratio of specific charge (e/m) of a proton and that of an -particle 1:2
−16
6. A certain particle carries 2.5 × 10 C of static electric charge. Calculate the number of electrons 1560 C
present in it.
7. (i) Calculate the number of electrons which will together weigh one gram.
(ii) Calculate the mass and charge of one mole of electrons. 4
9.65 × 10 coulombs
8. An element with mass number 81 contains 31.7% more neutrons as compared to protons. Find
number of protons and Assign the atomic symbol 35 &
9. What is the number of photons of light with wavelength 4000 pm which provide 1 Joule of
energy ?
10. A 100 watt bulb emits monochromatic light of wavelength 400 nm. Calculate the number of
photons emitted per second by the bulb
11. Arrange the following type of radiations in increasing order of wavelength : (a) radiation from Cosmic rays < X -rays <
microwave oven (b) amber light from traffic signal (c) radiation from FM radio (d) cosmic rays radiation from
from outer space and (e) X -rays microwave ovens <
amber light < radiation
of FM radio
12. Electromagnetic radiation of wavelength 242 nm is just sufficient
-1
to ionise the sodium
atom. Calculate the ionisation energy of sodium in kJ mol
6
13. Nitrogen laser produces a radiation at a wavelength of 337.1 nm. If the number of photons 3.33 × 10 J
emitted is 5.6 × 1024, calculate the power of this laser
14. Wavelengths of different radiations are given below : λ (A) = 300 nm λ (B) = 30 µm λ (C) = B < A < D<C
0
300 pm λ(D) = 30 A Arrange these radiations in the increasing order of their energies
-7
15. A photon of wave length 4 × 10 m strikes on metal surface, the work function of the metal being
2.13 eV. Calculate &
(i) the energy of the photon (eV) (ii) the kinetic energy of the photoelectron
16. The increasing order (lowest first) for the values of e/m (charge/mass) for e, p, n, α n, α, p, e
17. Electrons are emitted with zero velocity from a metal surface when it is exposed to
radiation of wavelength 6800 A. Calculate threshold frequency (v0) and work function (W0)
of the metal.

18. A near ultraviolet photon of 300 nm is absorbed by a gas and then re-emitted as two photons. 496 nm
One photon is red with wavelength 760 nm. What would be the wavelength of the second
photon?
o o
19. The ratio of the energy of a photon of 2000 A wavelength radiation to that of 4000 A radiation is 2./1
20. The work function for caesium atom is 1.9 eV . Calculate (a) the threshold wavelength and
(b) the threshold frequency of the radiation. If the caesium element is irradiated with a
wavelength 500 nm, calculate the kinetic energy and the velocity of the ejected
photoelectron
21. 1.6 NA.
+
22. Find the following for He ion : rd
-13.6ev and -
-18
energy of electron in second orbit ( in ev and in joules) , velocity of electon in 3 orbit (in msec- 2.18X10 j
6
)and radius of fourh orbit (in picometer ) 2.9X10 msec-1
424pm
−19
23. Energy of electron of hydrogen atom in second Bohr orbit is −5.42 × 10 J.
24. Calculate the ratio of K.E and P.E of an electron in an orbit? K.E 1
=-
P.E 2

25. The radius of first Bohr's orbit for hydrogen is X pm . The radius of third Bohr's orbit 9Xnpm
would be …..xpm
26. The value of the energy for the first excited state of hydrogen atom will be ............. eV -3,4ev
0 14 −1 −19
27. The threshold frequency v for a metal is 7.0 × 10 s . Calculate the kinetic energy of an 1.988 × 10 J
15 −1
electron emitted when radiation of frequency v = 1.0 × 10 s hits the metal
+
28. Calculate the energy associated with the first orbit of He What is the radius of this orbit?
26.45 pm
29. The energy of second Bohr orbit of the hydrogen atom is −328 kJ mol −1 , hence the energy of −82 kJ/mol
−1
fourth Bohr orbit would be .............. kJ mol
30. If change in energy during transition of electron is then wavelength of the light
emitted is
31. In a H atom If electron falls from n = 3 to n = 2, then emitted energy is ........... eV 1.9 eV
14
32. The corresponding frequency emitted in transition of electron from n = 2 to n = 1 in 24.66 × 10 Hz
hydrogen atom is
−18 2 −19
33. The electron energy in hydrogen atom is given by En = ( −2.18 × 10 ) /n J Calculate the 5.45 × 10 J
0
energy required to remove an electron completely from the n = 2 orbit. What is the longest 3647 A
0
wavelength of light inA that can be used to cause this transition?
34. The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity to 91 nm
7 −1
stationary state 1, would be ............... nm (Rydberg constant = 1.097 × 10 m )
15 −1
35. The frequency of radiation emitted when the electron falls from n = 4 to n = 1 in a = 3.08 × 10 s .
hydrogen atom will be
th
36. Find the wavelength of a spectral line produced when an electron in the H-atoms jumps from 4 0
nd 4863 A
level to 2 level.
37. Calculate the minimum and maximum values of wavelength in Balmer series of a H atom. 3647 and 6564 nm
38. True and False 1F,2T,3T,4T,5T,6F,7
F
1 All electromagnetic radiations have same energy.
2 Bohr’s model is applicable for H-atom only.
3 Specific charge of cathode rays remains same irrespective of the gas used in the discharge
tube.
4 Atoms with same atomic number but different number of neutrons are called isotopes. Chemistry By:
5 Energies and angular momentum of electron in orbits are quantized Mukesh Sharma
6 The number of electrons ejected in the photoelectric effect is proportional to frequency of of
light used DPS JODHPUR
7 Threshold wavelength is the minimum wavelength required to cause photo electric emission
from a particular metal.
39. The wavelength of the first spectral line in Paschen series for H-atom is____________. 16410 Å
40. What is the maximum number of lines obtained when the excited electrons of a hydrogen atom in 15
n=6
drops to the ground state.
−18
41. Calculate the energy required for the process 8.72 × 10 J
if The ionization energy for the
−18
H atom in the ground state is 52.18 × 10 J atom−1
42. An electron in a hydrogen atom in its ground state absorbs 1.50 times as much energy as 4.7 Å
the Minimum required for its escape from the atom. What is the wavelength of the emitted
–31
electron? (me = 9.11  10 kg)
43. Calculate the uncertainty in the velocity of a cricket ball of mass 130g, if the uncertainty in its
position is of the order of 1.2 A°.
-7
44. A moving electron has a de Broglie wavelength of 7 x 10 m. Calculate its kinetic energy. (Plank’s
-34 -31
constant = 6.626 x 10 Js, Mass of an electron = 9.1 x 10 kg).
6 -1
45. An electron is moving with a velocity of 2.5 x 10 ms . If the uncertainty in its velocity is 0.1%,
-34
calculate the uncertainty in its position. (Planck’s constant, h = 6.826 x 10 Js, Mass of the
-31
electron = 9.1 x 10 kg)
46. Show that the circumference of the Bohr orbit for the hydrogen atom is an integral
multiple of the de Broglie wavelength associated with the electron revolving in orbit.
−33
47. The de-Broglie wavelength of a particle with mass 1 gm and velocity 100 m/ sec is 6.63 × 10 m
−23 −8
48. An electron has kinetic energy 2.8 × 10 J. de-Broglie wavelength will be nearly(me = 9.1 9.28 × 10 meter
−31
x10 kg)
−5 −29
49. Uncertainty in position of a 0.25 g particle is 10 . Uncertainty of velocity is (h = 6.6 × 10−34 Js) 2.1 × 10 m/s
50. A series of lines in the spectrum of atomic hydrogen lies at wavelengths 656.46, 482.7, 397.2 nm
434.17, 410. 29 nm. What is the wavelength of next line in this series?
 Structure of atom ( assignment 2)
1. (a) If the quantum number ‘l’ has value of 2, what are the permitted values of m =–2, –1, 0, + 1, + 2
the quantum number ml ? l = 0, 1, 2
m= –3,–2, –1, 0, + 1, +
(b) A shell has n = 3, what are the possible values of l ? 2, + 3.
(c) for 3d subshell, what are the possible values of ml ?
2. Write the name of subshell with the following quantum numbers: (a) 7s (b) 3d (c) 4f (d)
(a) n = 7, l = 0 (b) n = 3, l = 2 (c) n = 4, l = 3 (d) n = 5, l = 1 5p-subshells

3. Write the value of PQN and AQN for the orbitals of following subshell (a) n = 6, l =1 (b) n = 5,
a) 6p, b) 5f, c) 4d, d) 3p, e) 2s l = 3 (c) n = 4, l = 2 (d)
n = 3, l = 1, (e) n=2,l=0
4. Write the following for N shell only 1) 4
1) Value of PQN 2) 0,1,2,3
3) Four
2) possible values of l 4) Four
3) number of values of l 5) 4s,4p,4d,4f
4) number of subshell present 6) For s m= 0,
5) name of subshells present for p m= -1,0,+1
for d,m=2, –1, 0, +
6) values of m for each subshell present in it 1, + 2
7) total number of values of m for f ,m== –3,–2, –
8) number of orientations possible for subshell with l=3 1, 0, + 1, + 2, + 3.
9) total number of orbitals 7) 16
10) name of orientations of orbital in subshell with l=2 8) 7
9) 16
11) maximum number of orbitals with n+l=7 10) 5
12) maximum number of of electrons possible withs=+1/2 11) 7
13) maximum number of electron with l=2 12) 16
14) maximum number of electron with n+l=5 13) 10
14) 6
5. Explain giving reasons, which of the following sets of quantum numbers are (a) possible
not possible and explain reason (b) Possible
(c) Not possible
(a) n = 1, l = 0, ml = 0, ms = + 1/2 (b) n = 3, l = 2, ml = +1, ms = + 1/2 (d) Possible
(c) n = 2, l = 1, ml = -2 ms = + 1/2 (d) n = 2, l = 1, ml = 0, ms = – 1/2 (e) Not possible
(e) n = 3, l = 3, ml = –3, ms = + ½ (f) n = 3, l = 2, ml = 1, ms = +1 (f) not Possible
6. How many electrons in a given atom can have the following quantum (a) 6 (b) 2 (c) 1 (d) 18
numbers ? (a) n = 3, l = 1 (b) n = 3, l = 2, ml = 0 (c) n = 3, l = 2, ml = + 2, ms = + 1 2
(d) n = 3
7. Which of the following orbital are possible ? 1p, 2s, 2p and 3f and explain 2s, 2p

8. Which quantum number does not follow from the solutions of Schrodinger Spin quantum number
wave equation
9. Which of the four qunatum numbers (n, l, ml , ms) determine (a) the energy of (a) both n and l (b) n
an electon in a hydrogen atom and multi electron atoms (b) the size of an (c) l (d) ml
orbital (c) the shape of an orbital (d) the orientation of an orbital in space ?
10. Which shell would be the first to have a g-subshell ? 5th energy level

11. What is the value of orbital angular momentum for an electron in 3s-orbital zero

12. Write the minimum 3 similarities and 3 differences between a 1s and a 2s

orbital.
13. For an atom , What will be the maximum number of subshell having n + l = 7 4
? 16
What will be the maximum number of orbital having n + l = 7 ?
14. Which of the following are is soelectronic species : Na+, K+, Mg2+, Ca2+, S2–, Na+,Mg2+ (ii)K+,Ca2+
Ar ? S2–Ar
15. For each of the following pair of orbitals of Rn atom , indicate which is higher (i) 2s (ii) 3p (iii) same
in energy : (i) 1s, 2s (ii) 2p, 3p (iii) 3dxy, 3dyz (iv) 4s, 3d (v) 4f, 6s. (i) 4s (v) 6s.
(iii) same
(b) Which of the above orbital pairs are degenerate
16. (a) Based on Bohr Bury’s rules arrange the following orbitals in the increasing i) 3s < 3p < 4s < 4d
order of energy. (i) 4s, 3s, 3p, 4d (ii) 5p, 4d, 5d, 4f, 6s (iii) 5f, 6d, 7s, 7p (ii) 4d < 5p < 6s < 4f <
5d (iii) 7s < 5f < 6d <7p
17. What is the correct sequence of energies of 4s, 4p, 4d and 4f-orbitals in (i) 4s = 4p = 4d = 4f
(i) a hydrogen atom and (ii) a zinc atom? (ii) 4s < 4p < 4d < 4f

18. Write the electronic configuration of elements of atomic numbers 10, 15,18,
24, 27, 29, and 36,42,54,65, 86, 112
19. How many electrons in Zn atom may have the following quantum number ? (i) 1 (ii) 2 (iii)10
(i) n = 4, ms = +½ (ii) n = 3 , l = 0 (III) l=2 (iv) m=0 (v)n+l=4 (iv)14 (v)8

20. (i)How many unpaired e- are present in (i) As (Z = 33) (ii) Ni2+ (Z = 26), 3 2,4
Co+3(Z=27) (ii) also find which one is paramagnetic all paramagnetic
21. An atom has 2 electrons in the first (K) shell, 8 electrons in the second (L) shell and 2 Conf : 1s2 2s2 2p6 3s2
electrons in the third (M) shell. Give its electronic configuration and find out the (a) Atomic no = 12
following : (a) Atomic number (b) Total number of principal quantum numbers (c) (b) PQN= 3 (c) 4 (d) 3
Total number of sublevels (d) Total number of s-orbitals (e) Total number of p- (e) 6
electrons.
22. Write the electronic configuration of chromium (Z = 24) and predict in it (i) 7 (ii) 7 (iii) 8 (iv) 1
(i) number of subshells (ii) number of electrons in subshell having l = 0
(iii) number of electrons having n + l value equal to 3 Chemistry by:
(iv) number of electrons in highest value of n Mukesh Sharma
23. The 4f subshell of an atom contains 12 electrons. What is the maximum 7
number number of electrons having same spin in it ?
24. In which atom, the outermost electron can have the following set of quantum Na
numbers ? n = 3, l = 0, ml = 0 ms = – ½
25. True or false (1) (r) is a radial wave function describing the electron 1) T
(2)2 (r) give radial probability density at a particular direction over a spherical 2) F
3) T
surface
4) F
(3) Radial distribution function (2·4r2dr) give probability in a small volume dV 5) T
(4) '2p' orbital with. n = 2,l = 1, m = 0, do not show angular dependence
5)for 3p orbital Number of maxima when a curve is plotted between 4r 2R2' (r) vs r
are 2
26. Calculate the number of (a) angular nodes (b) radial nodes and (c)total nodes 3d= 2,0,2 4p= 1,2,3
present in: (i) 3d orbital.(ii) 4p orbital (iii)5s (iv)3s orbital 5s = 0,4,4, 3s= 0,2,2

27. (a) The Schrodinger wave equation for For node at r = r0 ,  2

hydrogen atom isWhere a0 is Bohr's =0
r = 2a0
radius. Let the radial node in 2s be at r0.
Then find r0 in terms of a0.
28. Which of the following is correct graph for the popery given below (more than once correct)
if (i)R(r) is radial wave function:(r) (ii)R2 is radial probability density: 2 (r) (iii) (4r2R2 (r) is Radial
distribution function (RDF): (2·4r2dr)

(A) (b)

(c) (d) all

29. (i) Which of the above graph explain penetration power of 3 shell orbitals 28-All
(29) -d 3s> 3p>3d
(ii) 3d)max < (3p)max
<3s)max