Target DPP Test Contact Number: 8527521718

1. The IUPAC name for the following compound is: 5. What is the correct order of acidic strength for the
following acids?
HCOOH, CH3 COOH, CH3 CH2 COOH,

CH3 CH2 CH2 COOH

HCOOH < CH3 COOH < CH3 CH2 COOH <

1.
CH3 CH2 CH2 COOH

HCOOH > CH3 CH2 CH2 COOH > CH3 COOH >
1. 2,5-Dimethyl-6-carboxy-hex-3-enal 2.
CH3 CH2 COOH
2. 6-Formyl-2-methyl-hex-3-enoic acid
HCOOH > CH3 COOH > CH3 CH2 COOH >
3. 2,5-Dimethyl-5-carboxy-hex-3-enal 3.
4. 2,5-Dimethyl-6-oxo-hex-3-enoic acid CH3 CH2 CH2 COOH

CH3 COOH > HCOOH > CH3 CH2 CH2 COOH >
4.
CH3 CH2 COOH

2. The IUPAC name of the below given compound is:

6. The number of heteroatoms present in the following
compound is/are :

1. Ethyl 2-methylprop-2-enoate
2. Ethyl 2-methylprop-1-enoate
3. 1-Ethoxy 2-methylprop-2-enoate
4. 1-Ethoxy 2-methylprop-2-enal
1. 2
3. Incorrect match amongst the following is/are: 2. 3
3,4,7- 3. 1
(a) 4. 4
Trimethyloctane
5-Ethyl-3-
(b)
methylheptane

2,3,4-
(c)
Trimethylheptane

1. a, c 2. a, b
3. b, c 4. Only b

4. The total number of pi-bond electrons in the following

structure are:

1. 4 2. 8
3. 12 4. 16

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 Target DPP Test Contact Number: 8527521718

7. Incorrect match among the following is: 9. Which of the following is a heterocyclic aromatic
compound?
Structure IUPAC name
1. 2.

4-Chloro-1,3-
1.
dinitrobenzene
3. 4.

10. How many hydrogens are involved in

2-Chloro-4- hyperconjugation in the given organic compound A?
2.
methylanisole

2,3-Dibromo-1-
3.
phenylpentane
1. 12 2. 13
3. 15 4. 16

11. The given compound is classified as:

4-Ethyl-2-
4.
methylaniline

1. Alicyclic
2. Aromatic
8. What is the correct order of stability for the given
3. Antiaromatic
carbocations?
4. Acyclic

1. II > IV > I > III

2. I > II > III > IV
3. II > I > IV > III
4. I > III > II > IV

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 Target DPP Test Contact Number: 8527521718

12. Which of the following pairs of compounds are not 13. What is the correct order of increasing stability for
isomers? the following carbanions?

I. II.
1.

2.
III. IV.

3. 1. III > IV > I > II

2. I > III > IV > II
3. I > II > III > IV
4. I > IV > III > II

14. What is the correct order of bond dissociation

energies for the bonds indicated by arrows in the given
4. compound?

1. 1 < 2 < 3 2. 3 < 2 < 1

3. 2 < 3 < 1 4. 3 < 1 < 2

15. What is the IUPAC name of this compound?

1. 2–Bromo-3–methylbutanoic acid
2. 2-Methyl-3-bromobutanoic acid
3. 3-Bromo-2-methylbutanoic acid
4. 3-Bromo-2,3-dimethylpropanoic acid.

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 Target DPP Test Contact Number: 8527521718

16. The set that contains only electrophiles is: 20. The IUPAC name of the following compound is :
i. BF , N H , H O
3 3 2

⊕
ii. AlCl3 , SO3 , NO2

⊕ ⊕ ⊕
iii. NO2 , C H3 , CH3 − C= O

⊕
iv. C2 H
⊖
, Ċ2 H5 , C2 H5
5

1. (i), (iii)
2. (ii), (iii) 1. 5-Bromo-3-methylcyclopentanoic acid
3. (i), (iv) 2. 4-Bromo-2-methylcyclopentane carboxylic acid
4. (iii), (iv) 3. 3-Bromo-5-methylcyclopentanoic acid
4. 3-Bromo-5-methylcyclopentane carboxylic acid
17. The correct IUPAC name of the compound
21. The shortest C-C bond distance is found in
1. Diamond
2. Ethane
3. Benzene
is 4. Acetylene
1. 3-ethyl-4-ethenylheptane
2. 3-ethyl-4-propylhex-5-ene 22. IUPAC name of some compounds is given. The
3. 3-(1-ethyl propyl) hex-1-ene incorrect name is:
4. 4-ethyl-3-propylhex-1-ene

18. Br Cl
1.
| |

The IUPAC name ofCH3 — CH2— C −CH — : 3-Methyl-4-

| ethylheptane
OH

CH2 - Cl is:
(1) 3-Bromo-4, 5-dichloropentan-3-ol 2.
(2) 3-Bromo-1, 2-dichloro-3-hydroxypentane : 3-Methyl-2-butanol
(3) 3-Bromo-1, 2-dichloropentan-3-ol
(4) 3-Bromo-4, 5-dichloro-3-hydroxypentane
3.
19. What is the IUPAC name of the following : 2-Ethyl-3-methylbut-1-ene
compound? 4. CH − C ≡ C − CH(CH ) : 4-Methyl-2-pentyne
3 3 2

1. 2-Ethyl-1, 1-dimethlcyclopentane
2. 1-Ethyl-2, 2-dimethlcyclopentane
3. 1,1-Dimethyl-2-ethylcyclopentane
4. 2,2-Dimethyl-1- ethylcyclopentane

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 Target DPP Test Contact Number: 8527521718

23. In which species, delocalization of positive charge is 25. In which pair is the second ion more stable than the
possible? first?

(i)
1. 2.

(ii)

3. 4.
(iii)

(iv)

24. For which of the following molecules is the dipole

moment (μ) significantly non-zero?
1. (i) and (ii)
2. (ii) and (iii)
3. (ii) and (iv)
4. (iii) and (iv)
(i) (ii)

26. How many different functional groups are present in

the given compound?

(iii) (iv)

1. 3
2. 4
1. Only (i) 2. (i) and (ii) 3. 1
3. Only (iii) 4. (iii) and (iv) 4. 5

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 Target DPP Test Contact Number: 8527521718

27. Incorrect statement among the following is: 31.

Organic reactions, which proceed by homolytic
1.
fission are called homopolar or nonpolar reactions.
The resonance structures (canonical structures or
2. contributing structures) are hypothetical and
individually do not represent any real molecule.
In the –E effect, the π - electrons of the multiple bond
3. are transferred to that atom to which the reagent gets The IUPAC name of the above mentioned compound is -
attached.
Hyperconjugation may also be known as, no bond 1. 1,2,3-Tricyanopropane
4. 2. Propane-1,2,3-tricarbonitrile
resonance.
3. 1,2,3-Cyanopropane
4. Propane Tricarbylamine
28. The IUPAC name for the following compound is :
32. The IUPAC name of the compound

1. 3,5-Dimethyl-4-propylhept-1-en-6-yne 1. 3,3-diethyl-4-methyl-5 (methylethyl)octane

2. 3-Methyl-4-(3-methylprop-1-enyl)-1-heptyne 2. 3,3-diethyl-5-isopropyl-4-methyloctane
3. 3-Methyl-4-(1-methylprop-2-enyl)-1-heptene 3. 4-isopropyl-5-methyl-6,6-diethyloctane
4. 3,5-Dimethyl-4-propylhept-6-en-1-yne 4. 6,6-diethyl-4-isopropyl-5-methyloctane

29. Electrophiles are electron-seeking species. Which of 33. The IUPAC name of the compound,
the following groups contain only electrophiles?
(a) BF , NH , H O
3 3 2

(b) AlCl , SO , NO
3 3
+

(c) NO , CH , CH − C =O
+

2
+

3 3
+

(d) C H , H C − ĊH , C H
2
−

5 3 2 2
+

5 is:
Choose the correct option: 1. 1,2-Dimethyl-2-butenol
1. (a, b) 2. (b, c) 2. 3-Methylpent-3-en-2-ol
3. (c, d) 4. (a, d) 3. 3,4-Dimethyl-2-buten-4-ol
4. 2,3-Dimethyl-3-pentenol

30. Which of the following statements is the most 34. The correct stability order of following species is :
accurate for the given compound?

(1) x > Y > w > z

(2) y > x > w > z
(3) x > w > z > y
1. It contains three lone pairs of electrons. (4) z > x > y > w
2. It contains 19 sigma and 3 pi bonds.
3. It contains sp3, sp2 and sp hybridized carbon atoms.
4. It contains only sp3 and sp2 hybridized carbon atoms.

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 Target DPP Test Contact Number: 8527521718

35. The most contributing structure in nitroethene 38. The least stable resonance structure among the
among the following is- following is:

1.
1.

2.
2.

3.

3.

4.

39. consider the following compounds

4.

36. The stability of 2,3-dimethyl but-2-ene is more than

2-butene. This can be explained in terms of:
1. resonance
2. hyperconjugation
3. electromeric effect
4. inductive effect

37. Which of the following resonating structures of 1- hyperconjugation occurs in

methoxy-1,3-butadiene is least stable? 1. I only
⊖ ⊕

1. C H − CH = CH − CH =O −CH
2 3
2. II only
⊖ ⊕
3. III only
2. CH = CH − C H − CH =O −CH
2 2 3
4. I and III
⊖ ⊕

3. C H − C H − CH = CH − O − CH
2 3
⊖ ⊕

4. CH 2 = CH− C H− C H − O − CH3

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 Target DPP Test Contact Number: 8527521718

40. Hyperconjugation is possible in which of the 42. The isobutyl group among the following is:
following compound(s)?
1.

i. ii. 2. CH3–CH2–CH2–CH2–

3.

iii. iv.

4.

1. i and ii
2. i, ii, and iii
3. Only ii
4. In all compounds, hyperconjugation takes place
43. The correct IUPAC name for

41. The most stable carbocation among the following is:

is _____.
1. 2-Ethyl-3-methylpentane
2. 3,4-Dimethylhexane
1. 2. 3. 2-sec-Butylbutane
4. 2,3-Dimethylbutane

44. The IUPAC name of the given compound is:

`

3. 4.

1. 3-(Bromomethyl)-2-methyl butanoyl chloride

2. 3-(Bromomethyl)-2-methyl propionyl chloride
3. 2-(Bromomethyl)-3-methyl butanoyl chloride
4. None of the above

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 Target DPP Test Contact Number: 8527521718

45. Which of the following molecules/intermediates/ 48. The increasing reactivity of the sites (a-d) in the
species is/are electrophile(s)? following compound in S 1 reaction is
N

A. BH3 B. SiH4
C. PCl3 D. :CH2
E. NH3
1. A, B, C, and D only
2. A, B, and C only
3. A only
4. A and D only

46. The electrophile species among the following is/are: 1. d>b>c>a

1. CO 2 2. d>c>a>b
2. N O
+

2
3. d>c>b>a
3. AlCl 3
4. c>d>b>a
4. All of the above.
49. Three structures out of the given four are resonating
47. Arrange the following carbanions in correct order of structures of each other. Which one is not?
stability:

1. 2.

I. II.

3. 4.

III. IV.
50. The compound that does not have sp2 hybridized
carbon among the following is:
1. Acetone
1. I > II > III> IV 2. Acetic acid
2. II > III > I > IV 3. Acetonitrile
3. III > II > IV > I 4. Acetamide
4. III > I > II > IV
51.

The double bond in the above-mentioned compound that

accepts proton (H ) fastest is:
+

1. A 2. B
3. C 4. D

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 Target DPP Test Contact Number: 8527521718

52. The most stable resonating structure of HCOOH is: 55. The correct order with respect to –I effect of the
substituents is:
(R = alkyl)
1. 2. 1. –NH2 > –OR < –F
2. –NR2 < –OR < –F
3. –NH2 > –OR > –F
4. –NR2 > –OR > –F

3. 4. 56. The correct decreasing order of priority for the

functional groups of organic compounds in the IUPAC
system of nomenclature is:
1. –SO3H, –COOH, –CONH2, –CHO
2. –CHO, –COOH, –SO3H, –CONH2
53. The correct stability order of the resonating structure 3. –CONH2, –CHO, –SO3H, –COOH
of the given compound is: 4. –COOH, –SO3H, –CONH2, –CHO

57. The number of σ bonds, π bonds and lone pair of

electrons in pyridine respectively are:
1. 12, 2, 1
2. 11, 2, 0
3. 12, 3, 0
4. 11, 3, 1
A.
58. Hyperconjugation involves the delocalization of:
1. σ electron
2. π-electron
B. 3. Both σ and π electrons
4. Proton

59. In which of the followig molecules all the effects

namely inductive, mesomeric and hyperconjugation
C. operate ?

1. A > B > C 2. B > A > C

3. C > A > B 4. B > C > A
(1) (2) (3)

54. The strongest acid, among the compounds given

below, is:
1. HC≡CH 2. C6H6
3. C2H6 4. CH3OH (4)

60. In hyperconjugation, the atom involved is:

1. βΗ atom
2. α-H atom
3. γ-H atom
4. All of these

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 Target DPP Test Contact Number: 8527521718

61. The shifting of electrons of multiple bonds under 66. What is the correct order of basicity for the given
the influence of a reagent is called: compounds?
1. I-effect
2. E-effect
3. M-effect A. B.
4. None of the above.

62. Which of the following is more basic than

aniline?
1. Diphenylamine
2. Triphenylamine C. D.
3. p-nitroaniline
4. Benzylamine

63. which one of the following has the most acidic

nature?
1. C>A>B>D
2. D>B>A>C
3. B>A>C>D
1. 2.
4. D>C>A>B

67. Given below are two statements:

3. 4. Cycloheptatrienyl cation is an aromatic
Statement I:
species.
Cycloheptatrienyl cation contains 6π
Statement II:
electrons in conjugation.
In the light of the above statements, choose the correct
answer from the options given below:
64. The order of stability of the following carbocations 1. Statement I is incorrect and Statement II is correct.
is:
2. Both Statement I and Statement II are correct.
3. Both Statement I and Statement II are incorrect.
4. Statement I is correct and Statement II is incorrect.

(I) (II) (III)

1. I > II > III

2. III > I > II
3. III > II > I
4. II > III > I

65. Which of the following orders of acid strength is

correct:
1. RCOOH > ROH > HOH > HC ≡ CH
2. RCOOH > HOH > ROH > HC ≡ CH
3. RCOOH > HOH > HC ≡ CH > ROH
4. RCOOH > HC ≡ CH > HOH > ROH

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 Target DPP Test Contact Number: 8527521718

68. Which hydrogen is the most acidic in the molecule 71. The structure of cis-bis (propenyl) ethene is:
shown?

1.

2.
1. Ha
2. Hb
3. Hc
3.
4. Hd

69. The basic strength of the following anions, ordered

from most to least, is: 4.
¯
¯¯¯
− − −
OH , H COO , CH3 COO , OR

(I ) (I I ) (I I I ) (I V )
72. Fisher projection indicates:
1. II > III > I > IV 1. horizontal substituents above the plane
2. IV > I > III > II 2. vertical substituents above the plane
3. III > IV > I > II 3. both horizontal and vertical substituents below the
4. I > IV > II > III plane
4. both horizontal and vertical substituents above the
70. The number of sigma and pi bonds, respectively, in plane
the given organic compound are:

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