Time : 35 mins Max.

Marks : 100

1. A sample of oxygen gas and a sample of an unknown gas are weighed separately in the
same evacuated flask. Use the data given below to find the molar mass of the unknown
gas (assume experiments are carried out at the same pressure and temperature).

Mass of evacuated flask 124.46 g

Mass of flask + oxygen 125.10 g
Mass of flask + unknown gas 125.34 g

(a) 22 g/mol (b) 38 g/mol (c) 44 g/mol (d) 84 g/mol

2. Value of gas constant R is:

(a) 0.082 litre-atm (b) 0.987 cal mol–1 K–1
(c) 8.3 J mol–1 K–1 (d) 83 erg mol–1 K–1

3. Which of the following parameters would be expected to have the same values for
C₂H5OH and CH3OCH3?
(a) Heat of vaporization
(b) Vapour pressure at the same temperature
(c) Boiling points
(d) Gaseous densities at the same temperature and pressure (Assuming ideal behaviour)

4. Which of the following is not the correct set of pressure and volume at constant
temperature and constant moles of gas?
P V P V
(a) 1 atm 200 mL (b) 760 mm 0.2L
(c) 0.5 atm 100 L (d) 2 atm 100mL

5. Just below this temperature, gases would theoretically have a negative volume (which is
however not possible):
(a) absolute zero (b) -100° C (c) 100° C (d) 100 K

6. The volume of a gas increases by a factor of 2 while the pressure decreases by a factor of
3. Given that the number of moles is unaffected, the factor by which the temperature
changes is:
 3 2 1
(a) (b) 3 x 2 (c) (d)  3
2 3 2
7. If V0 is the volume of a given mass of gas at 273 K at constant pressure, then according
to Charle's law, the volume at 10° C will be:
2 10 283
(a) 10 V0 (b) ( V0 +10 ) (c) V0 + (d) V0
273 273 273
8. On a ship sailing in pacific ocean, where temperature is 22° C, a balloon is filled with 2L
air. What will be the volume of balloon when the ship reaches Indian ocean, where
temperature is 27° C? The atmospheric pressure is same over pacific ocean and Indian
ocean.
600 54 590
(a) 2L (b) L (c) L (d) L
295 22 300

9. At constant volume, the temperature (in °C) of certain mass of a gas is increased by 20%.
The pressure of gas:
(a) will increase by 20%
2000
(b) will increase by %
373
20 t
(c) will increase by % , where t° C is the initial temperature of gas
273 + t
20 t
(d) will increase by % , where t° C is the final temperature of gas
273 + t

10. 0.1 mole of argon has pressure P and temperature T K in the vessel. On keeping the
vessel at 50° C higher temperature, 0.8 g of argon was given out to maintain same
pressure. The original temperature was: [Ar = 40]
(a) 273 K (b) 200 K (c) 100 K (d) 300 K

11. A weather balloon filled with hydrogen at 1 atm and 300 K has volume equal to 12000
liters. On ascending it reaches a place where temperature is 250 K and pressure is 0.5
atm. The volume of the balloon is:
(a) 24000 liters (b) 20000 liters (c) 10000 liters (d) 12000 liters

12. Four one litre flasks are separately filled with the gases, O2, F2, CH4 and CO2 under the
same conditions. The ratio of number of molecules in these gases:
(a) 2:2:4:3 (b) 1:1:1:1 (c) 1:2:3:4 (d) 2:2:3:4

13. At 0.821 atm and at 177° C, gas SO3 occupies 45 L. Moles of neutrons present in SO3
are: (Take NA = 6 x 1023)
(a) 40 (b) 24 x 1024 (c) 24 x 1023 (d) 6 x 1024
14. A gas sample in a flexible container is maintained at constant pressure while its
temperature is increased from 25° C to 75° C. If the initial volume of the gas is 4.2 L,
what is the change in volume due to the temperature increase?
(a) 0.7 L (b) 4.9 L (c) 8.4 L (d) 12.6 L

15. A sample of an ideal gas has a volume of 0.500 L at 25° C and 1.20 atm pressure. What is
its volume at 75° C and 3.60 atm?
(a) 0.143 L (b) 0.195 L (c) 0.500 L (d) 1.75 L

16. A sample of gas occupies a volume of 9.23 L at 345 K and 1.40 atm. What is its volume
at 525 K and 3.20 atm?
(a) 2.65 L (b) 6.14 L (c) 13.9 L (d) 32.1 L

17. When 0.25 L of liquid nitrogen (d = 0.807 g/mL) is vaporized, what volume does the
resulting gas occupy at 25° C and 5.00 atm?
(a) 71 L (b) 54 L (c) 35 L (d) 32 L

18. A sample of He gas in a flexible container at room temperature exhibits a certain

pressure. What will be the new pressure when the absolute temperature and volume of the
container are both halved? The pressure of the He will be:
(a) the same (b) doubled (c) halved (d) quadrupled

19. A 3.0 L sample of helium gas is stored in a rigid, sealed container at 25° C and 1.0 atm
pressure. The temperature is increased to 125°C. What is the new pressure of the gas?
(a) 0.20 atm (b) 0.75 atm (c) 1.33 atm (d) 5.0 atm

20. There are three closed containers in which equal moles of gas is filled if the containers
are placed atthe same temperature, then which of the following is correct?
I-Cube II-Cylinder III-Sphere

(a) Pressure in I is the maximum. (b) Pressure in II is the maximum.

(c) Pressure in III is the maximum. (d) All the vessels have equal pressure.
21. Value of absolute zero of temperature in degree Celsius (°C) can be determined by given
data. The density of an ideal gas at 25° C and 100° C are 1.5 and 1.2 g/L, respectively,
both at the same pressure. The value of absolute zero of temperature in degree Celsius
(°C) is:
(a) -273 C (b) -275° C (c) -200° C (d) 0° C

22. Which gas has a density of 0.71 gL-1 at 0° C and 1 atm?

(a) Ar (b) Ne (c) CO (d) CH4

23. A 2.00 L balloon at 20.0° C and 745 mm Hg floats to an altitude where the temperature is
10.0° C and the air pressure is 700 mm Hg. What is the new volume of the balloon?
(a) 0.94 L (b) 1.06 L (c) 2.06 L (d) 2.20 L

24. A sample of gas at 273 K has a pressure of P1 and a volume of V₁. When the pressure is
changed to P2, what is the volume V2? (Assume the temperature remains constant.)
PP PV PV P
(a) 1 2 (b) 1 1 (c) 2 1 (d) 2
V1 P2 P1 P1V1

25. A gas in a closed, flexible container is slowly cooled from 50° C to 25° C. What is the
ratio of the final volume of the gas to its initial volume? (Assume ideal behaviour).
2 1.08 0.923 0.5
(a) (b) (c) (d)
1 1 1 1