05-05-2025

6901CJA10153625CT001SB JA

PHYSICS

SECTION-I(i)

1) A beam of diameter ‘d’ is incident on a glass hemisphere as shown. If the radius of curvature of
the hemisphere is very large in comparison to d, then the diameter of the beam at the base of the
hemisphere will be :-

(A)

(B) d

(C)

(D)

2) Two particles A and B start from the same point and move in the positive x-direction. In a time
interval of 2.00 s after they start, their velocities v vary with time t as shown in the following figures.
What is the maxi-mum separation between the particles during this time interval?

(A) 1.00 m
(B) 1.25 m
(C) 1.50 m
(D) 2.00 m

3) A system consists of a small block of mass m connected with a massless spring. The system is kept
on smooth horizontal surface infront of a concave mirror of radius R as shown in figure. When spring
is at its natural length the particle is given a velocity . The image of the particle coincides
with it when elongation in spring is maximum. Find the distance of image of particle from pole of

concave mirror when compression in spring is maximum [spring constant k = ]:

(A)

(B) R
(C) 2R

(D)

4) A convex lens of focal length f and a plane mirror are y distance apart. An object O is kept on the
principal axis of the lens at a distance x from the lens. The value of x and y for the image of O to not

coincide with O is

(A) x = f, y = f
(B) x = f, y = 2f
(C) x = 2f, y = f
(D) x = 2f, y = 2f

SECTION-I(ii)

1) A wide slab consisting of two media of refractive indices n1 and n2 is placed in air as shown in the
figure. A ray of light is incident from medium n1 to n2 at an angle θ, where sin θ is slightly larger
than 1/n1. Take refractive index of air as 1. Which of the following statement(s) is(are) incorrect?

(A) The light ray enters air if n2 = n1.

(B) The light ray is finally reflected back into the medium of refractive index n1 if n2 < n1.
(C) The light ray is finally reflected back into the medium of refractive index n1 if n2 > n1.
(D) The light ray is reflected back into the medium of refractive index n1 if n2 = 1.

2) A particle is projected into the air over an inclined plane of inclination 20o, Angle of projection of
initial velocity vector above incline is . The particle hits the incline at P with velocity . Neglect
air resistance. Assume line of greatest slope lies in the plane of projection and mark the correct
statements

(A) For a given value of , OP will be maximum for

For a given value of , OP will be maximum for

(B)

(C) For a given value of , OP will be maximum for

(D) vector points vertically upwards

3) Consider an equilateral prism of refractive index . It is found that when light is incident at an
angle 60°, angle of emergence is 'e', while when light is incident at an angle 50°, it undergoes TIR
on the 2nd refracting surface. Choose the CORRECT options:

(A) A ray incident at an angle 65° will surely emerge from other surface.
(B) A ray incident at an angle of 40° will surely suffer TIR on other surface.
(C) A ray incident at an angle of 50.7°, will surely suffers TIR on other surface.
(D) A ray incident at an angle 59o, may suffer TIR on the other surface.

SECTION-I(iii)

1) ABC is a right-angled prism kept in air. A ray (1) is incident on the face AB along the normal.
Refractive index of the material of prism is the minimum value that will be required so that ray (1)
undergoes total internal reflection at the face AC. Another ray (2) is incident on the face AB such
that it emerges from face AC along the normal to AC. A third ray (3) falls on the face BC and
emerges from face AC such that its angle of emergence is the same as that of incidence. Assuming

light (1), (2) and (3) have the same wavelength, match the following.

List-I List-II

(I) Refractive index of the material of prism is (P) 120

 (II) Angle of incidence in degree of ray (2) is (Q) 90

(III) Deviation in degree suffered by ray (2) is (R) 2

(IV) Deviation in degree suffered by ray (3) is (S) 60

(T) 1.5

(U)

(A) I → U;II → Q;III → S;IV → P

(B) I → R;II → P;III → S;IV → P
(C) I → T;II → S;III → P;IV → Q
(D) I → R;II → Q;III → S;IV → P

2)

Match the list :

List-I List-II

If swimmer can swim at 5m/sec in still water and

if velocity of water flow is 4m/sec then angle
(I) (P) 53°
between direction of swimming and direction of river
flow to minimize drift.

If swimmer can swim at 5m/sec in still water

and velocity of flow is 3m/sec then angle between
(II) direction of velocity of swimmer with respect to river (Q) 127°
and the direction of river flow if swimmer crosses the
river in minimum time.

If swimmer can swim at 4 m/sec and velocity of flow is

3m/sec then angle of resultant velocity (w.r.t. ground)
(III) (R) 143°
with the direction of river flow if swimmer swims
perpendicular to flow of river.

Angle between direction of fluttering of flag and north

if wind blows towards south west direction with a
(IV) (S) 90°
velocity m/sec. Man moves with a velocity 7m/sec
along west, holding flag in his hand.

(T) 37°
(A) I → R;II → S;III → P;IV → Q
(B) I → R;II → S;III → Q;IV → P
(C) I → S;II → R;III → P;IV → Q
(D) I → P;II → S;III → Q;IV → R

3) List I contains four combinations of two lenses (1 and 2) whose focal lengths (in cm) are indicated
in the figures. In all cases, the object is placed 20 cm from the first lens on the left, and the distance
between the two lenses is 5 cm. List II contains the positions of the final images.

List-I List-II
 Final image is formed at 7.5 cm on
(I) (P)
the right side of lens 2.

Final image is formed at 60.0 cm on

(II) (Q)
the right side of lens 2.

Final image is formed at 30.0 cm on

(III) (R)
the left side of lens 2.

Final image is formed at 6.0 cm on

(IV) (S)
the right side of lens 2.

Final image is formed at 30.0 cm on

(T)
the right side of lens 2.
Which one of the following options is correct ?
(A) I → P;II → R;III → Q;IV → T
(B) I → Q;II → P;III → T;IV → S
(C) I → P;II → T;III → R;IV → Q
(D) I → T;II → S;III → Q;IV → R

4) A bird in air is diving vertically over a tank with speed 6 cm/s. Base of tank is silvered. A fish in

the tank is rising upward along the same line with speed 4 cm/s. (Take: µ water )
 List-I List-II

Speed of the image of fish as seen by the

(P) (1) 12
bird directly (Apparent)

Speed of the image of fish formed after

(Q) (2) 4
reflection from the mirror as seen by the bird.

Speed of image of bird relative

(R) (3) 9
to the fish if it is looking upwards

Speed of image of bird relative to the fish

(S) (4) 3
looking downwards in the mirror
(A) P → 3;Q → 2;R → 4;S → 1
(B) P → 3;Q → 4;R → 1;S → 2
(C) P → 1;Q → 2;R → 4;S → 1
(D) P → 4;Q → 3;R → 1;S → 2

SECTION-II

1) Point B is the image of point A due to reflection from mirror (which is either spherical concave
mirror, or spherical convex mirror or plane mirror), whose principle axis is x-axis. One square on x-
axis represents 5cm and one square on y-axis represents 1mm. The coordinate of centre of curvature
of mirror is (x1, 0) and coordinate of pole of mirror is (x2, 0) respectively. If |x1| + |x2| = K cm, then

find the value of K.

2) A person P is standing at a distance of 250 cm from a flat mirror, at the instant shown in the
figure. A converging lens of focal length 50 cm is stationary and is placed between the mirror and P.
The mirror now starts moving towards right with constant velocity of 18 cm/s. What will be the
magnitude of velocity (in cm/s) of his image as seen by the person, at the moment when the mirror

just starts moving (Assume paraxial ray approximation)?

3) A tank of water is full upto 80cm above the hole. The radius of tank is 1m and radius of hole is
1mm. A circular light beam of radius 1mm which covers the hole completely is incident on the hole
from inside water. It is seen that the beam is travelling along the water stream like in an optical
fibre. The level of water y (in mm) at which the light beam begin to emerge from the curved surface

of water stream is , then find the value of x.

4) A bird flies for 4 s with a velocity of |t – 3| m/s in a straight line, where t = time in seconds. It
covers a distance of x meter. Find x.

5) A ray of light travelling in the direction is incident on a plane mirror. After reflection,

it travels along the direction . Find the angle of incidence (in degree):

6) James Bond is standing on a bridge above the road and his pursuers are getting too close. He
spots a flat bed truck loaded with mattresses approaching at 30 m/s which he measures by knowing
that the telephones poles the truck is passing are 20 m apart in this country. The bed of truck is 20
m below the bridge and Bond quickly calculates how many poles away the truck should be when he
jumps down the bridge onto the truck making his get away. Assume that nearest pole is just below
the bridge. How many poles is it?

CHEMISTRY

SECTION-I(i)

1) Consider the following statements in the elimination reaction of the given reaction

(1) The reaction is stereospecific reaction

(2) Of the various stereoisomers of the reactant, only stereoisomers of proper geometry, i.e.,
antiperiplanar conformer will undergo this elimination.
(3) Reaction take place by E2 mechanism
(4) Reaction take place by E1 mechanism
Of these statements

(A) 1, 2 and 4 are correct

(B) 1, 2 and 3 are correct
(C) 2, 3 and 4 are correct
(D) 1, 3 and 4 are correct
2)

Which of the above structures is a diastereomer of

(A) 3
(B) 1 and 4
(C) 4
(D) 5

3) The relative rate of acid catalysed dehydration of following alcohols would be

(A) III > I > IV > II
(B) III > IV > I > II
(C) I > III > IV > II
(D) IV > III > I > II

4) Dehydrohalogenation by strong base is slowest in

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Which of the following reactions give diastereomeric products?

(A)

(B)

(C)

(D)

2) Which of the following compounds are optically inactive but exhibit geometrical isomerism?

(A)

(B)

(C)

(D)

3) An unsaturated hydrocarbon A (C6H10) readily gives B on treatment with NaNH2 in liquid NH3.
When B is allowed to react with 1-chloropropane a compound C is obtained. On partial
Hydrogenation in the presence of Lindlar catalyst, compound C gives D (C9H18). On ozonolysis D
gives 2, 2-dimethyl propanal and 1-butanal. Which of the following is/are true

(A)
(B)

(C)

(D)

SECTION-I(iii)

1) Match the Column

Column (I) Column (II)

Reaction Product

(P) (1)

(Q) (2)

(R) (3)
 (S) (4)

The correct option is :

(A) P → 1;Q → 4;R → 2;S → 3
(B) P → 4;Q → 1;R → 3;S → 2
(C) P → 3;Q → 2;R → 1;S → 4
(D) P → 2;Q → 4;R → 1;S → 3

2)

Column (I) Column (II)

Molecules Property

(P) (1) Meso compound

(Q) (2) Achiral

(R) (3) Chiral compound

 Compound will show
(S) (4) geometrical
isomerism

The correct option is :

(A) P → 3,4;Q → 2,4;R → 1,2;S → 3
(B) P → 1,4;Q → 2,3;R → 1,2;S → 1,4
(C) P → 2;Q → 2,4;R → 1,2,4;S → 2,4
(D) P → 1,2;Q → 2,3;R → 3,4;S → 2,4

3)

Column-II
Column-I
(Total geometrical isomers)
(Structural formula)
(Ignore enantiomers)

(P) (1) 8

(Q) (2) 6

(R) (3) 4

(S) (4) 2

The correct option is :

(A) P → 4;Q → 1;R → 2;S → 3

(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 1;Q → 2;R → 3;S → 4
(D) P → 4;Q → 3;R → 2;S → 1

4)

Column-II
Column-I value of 'x' per
mole of reactant
 (P) (1) 1

Major product + CH4

(Q) (2) 3
Major product

(R) (3) 4

(S) (4) 5

The correct option is (DBE: Double bond equivalent)

(A) P → 4;Q → 2;R → 3;S → 1
(B) P → 3;Q → 2;R → 1;S → 4
(C) P → 3;Q → 1;R → 2;S → 4
(D) P → 4;Q → 2;R → 1;S → 3

SECTION-II

1)
on monochlorination give X number of isomeric products which on fractional distillation give Y
number of isomeric products. Find the value of |X – 2Y|?

2) Find the number of incorrect statements

3) An organic compound (A) of molecular formula C5H8 when treated with sodium in liquid ammonia
followed by reaction with n-propyl iodide yields (B), C8H14. (A) gives a ketone (C). C5H10O, when
treated with dilute H2SO4 and HgSO4. (B) on oxidation with alkaline KMnO4 gives two isomeric acids
(D) and (E), C4H8O2. Calculate the no of tertiary carbon atom(s) in one molecule of compound 'A'

4) Compound (A) with M.W. 108 contained 88.89% C and 11.11% H. It gave a white precipitate with
ammoniacal silver nitrate. Complete hydrogenation of (A) gave another compound (B) with
molecular weight 112. Oxidation of (A) gave an acid (C) and other side product. Decarboxylation of
this acid gave cyclohexane.

major product alkene (D). Number of α – H (alpha hydrogens)

present in one molecule of compound (D) is:

5)

Given:-
A is a substituted product (Salt)
Compound E is a homocyclic hydrocarbon
Find the molecular mass of compound E.
6) How many structures of 2o amines are possible by C5H13N (without counting stereoisomers)?

MATHEMATICS

SECTION-I(i)

1) Let P be a square matrix such that P2 = I – P. For α, β, γ, δ ∈ Ν, if Pα + Pβ = γΙ – 29P and Pα – Pβ =

δΙ – 13P, then α + β + γ – δ is equal to (Where I denotes identity matrix)

(A) 18
(B) 40
(C) 24
(D) 22

2) Let be a polynomial such that and

.

If and constant term in is where p and then

is

(A) 89
(B) 91
(C) 90
(D) 88

3) If a,b,c are unequal real numbers in G.P. and 'a' is their harmonic mean then is
(where [.] denotes greatest integer function)

(A) 7
(B) 11
(C) None of these
(D) 3

4) If A is a non-singular square matrix of order less than 4 such that and B = adjA, then

is-

(A) A
(B) B
(C) |A|A
(D) |B|B

SECTION-I(ii)
1) Let A and B be two invertible matrices of order n such that I – AB is invertible, then which of the
following is (are) CORRECT?

(A) I – BA is singular
(B) I – BA is non-singular
(C)
(D)

2) If A and B are two non-singular matrices such that and (where

I represents the identity matrix of order 4). If tr(X) represents sum of diagonal elements of matrix X,
then

(A)

(B)

(C)

(D) tr(3A3 – A2) = 4

3) If a, b and c are three terms of an A.P. such that a ≠ b, then may be equal to :

(A)
(B) 2
(C) 1
(D) 3

SECTION-I(iii)

1) Match the following List-I with List-II

List-I List-II

(P) (1) singular

If and , then A is

(Q) (2) skew-symmetric

and , then A is

(R) (3) symmetric

and , then A is

(S) (4) idempotent

, then A is

(5) Involutary
(A) P → 3;Q → 1;R → 1;S → 2
(B) P → 3;Q → 2;R → 1;S → 1
(C) P → 1;Q → 2;R → 3;S → 4
(D) P → 3;Q → 1;R → 2;S → 1

2) Let A, B, C, D be non singular matrices of order 3 × 3 such that (AAT) BC2 = BT and C2 = I and D is
an orthogonal matrix such that AT and D commute with each other and DTATD = A–1. Then (Where I
denotes identity matrix)

(A) P → 1;Q → 4;R → 2;S → 3

(B) P → 1;Q → 5;R → 1;S → 4
(C) P → 3;Q → 5;R → 1;S → 3
(D) P → 3;Q → 4;R → 2;S → 4

3) Consider , Q is 3 × 3 order skew symmetric matrix and

Consider two 3 × 3 non-singular matrices A and B satisfying A = Adj B – BT and B = Adj A –
AT (where CT denotes transpose of matrix C, I denotes identity matrix). Then

List - I List - II

(P) (1) 1

(Q) if then value of is (2) 4

(R) (3) 0

The set of values of 'a' for which the

equation
(S) has all (4) –4
its roots real is given by
Then is:

(5) –1
(A) P → 3;Q → 4;R → 2;S → 5
(B) P → 5;Q → 1;R → 3;S → 1
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 3;Q → 1;R → 5;S → 2

4)

List - I List - II

(P) if BA = A2B then (AB)4 = AλB4 then absolute value of λ–10 is (1) 0
 if AB = A + B then |AB–BA| is (Where |P| denotes
(Q) (2) 1
determinant of P)

(R) (3) 2
If then absolute value of sum of
elements of first row of A–1 is

(S) (4) 3
If then
absolute value of λ–10 is

(5) 5
(A) P → 2;Q → 1;R → 1;S → 4
(B) P → 5;Q → 1;R → 4;S → 2
(C) P → 3;Q → 3;R → 2;S → 2
(D) P → 5;Q → 4;R → 3;S → 3

SECTION-II

1) Let A and B are two non-singular matrices such that and . If the least value of m

such that is K then find the value of

2) The number of all 3 × 3 matrices A, with enteries from the set {–1,0,1} such that the sum of the
diagonal elements of AAT is 3, is

3) If α, β & γ are roots of equation x3 – 2x + 3 = 0 then value of (α + β + 2)(β + γ + 2)(γ + α + 2), is

4) If where a, b, c are

natural numbers, then the value of is equal to

5) Let {ak} and {bk}, k ∈ , be two G.P.s with common ratio r1 and r2 respectively such that a1 = b1 =

4 and r1 < r2. Let ck = ak + bk, k ∈ . If c2 = 5 and then is equal to

_______.
6) Let and then the value of is equal to
 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. D B D C

SECTION-I(ii)

Q. 5 6 7
A. A A,B A,B,D

SECTION-I(iii)

Q. 8 9 10 11
A. D A A B

SECTION-II

Q. 12 13 14 15 16 17
A. 40 4 18 5 30 3

CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21
A. B B D C

SECTION-I(ii)

Q. 22 23 24
A. B,C A,B,C A,B,C

SECTION-I(iii)

Q. 25 26 27 28
A. A C D B

SECTION-II

Q. 29 30 31 32 33 34
A. 9 1 1 7 78 5

MATHEMATICS
 SECTION-I(i)

Q. 35 36 37 38
A. C C D A

SECTION-I(ii)

Q. 39 40 41
A. B,C A,B,D B,C,D

SECTION-I(iii)

Q. 42 43 44 45
A. D B C B

SECTION-II

Q. 46 47 48 49 50 51
A. 7 672 7 3 4 600
 SOLUTIONS

PHYSICS

1)

v = 3r
Using similar triangles,

3)
at maximum compression, we get:
Using mirror formula

6)

10) (I)

u2 = +15

(II) v1 = +20
u2 = +15

(III) v1 = +20
u2 = +15
(IV)
u2 = –15

11) (I) Velocity of fish in air =

Velocity of fish w.r.t. bird = 3 + 6 = 9

(II) Velocity of image of fish after reflection from mirror in air =

w.r.t. bird = –3 + 6 = 3

(III) Velocity of bird in water =

w.r.t. fish = 8 + 4 = 12
(IV) Velocity of bird in water after reflection from mirror = 8
w.r.t. fish = 8 – 4 = 4

12)

m = +4

we get f = -20 cm

13)

For I3

v= & = 36 cm/s

=
 15)

Area =

CHEMISTRY

18)
ß – H need to be anti periplanar.

19) Diastereomers are the stereoisomers that are not the mirror image of each other.

21) Compound (c) has all equitorial substituent, hence, it is most stable and undergo
elimination with slowest state.

22)
23)
pos present but cis & trans isomers exist

POS present but cis & trans isomers exist

POS present but cis & trans isomers exist

POS present same groups present wrt double bond so, no geometrical isomers.

24) Str (D)

Should be z-isomers

28)

P.
Q.

R.

S.

29)
X = no of isomeric product = 11
Y = no of isomeric product obtain after distillation = 10

30)
Point of symmetry present, So, optically inactive
31)

32)

33)
 34)

MATHEMATICS

35)

P2 = I – P
Pα + Pβ = γI – 29P, Pα – Pβ = δI – 13P
P4 = (I – P)2 = I – 2P + P2 = 2I – 3P
P6 = (2I – 3P)(I –P) = 5I – 8P
P8 = (2I – 3P)2 = 4I –12P + 9(I – P) = 13I – 21P
P8 + P6 = 18I – 29P
P8 – P6 = 8I – 13P
α = 8; β = 6; γ = 18, δ = 8
α + β + γ – δ = 8 + 6 +18 – 8 = 24

37) Let a,b,c are a, ar, ar2

⇒ ⇒
⇒ 3r2 + r2 + r + 1
⇒ 2r2 – r – 1 = 0

(rejected ∵ a,b,c are diff.)

⇒ a, b, c are

38) so A is 2 × 2 order matrix.

= adj B
=A
39)

Again,

= B(I – AB)–1IB–1

40)

3A – 4BBT = I
B–1 = 2AT

(RHS is symm by properties)

T
A is symm A is symm B–1 is symm B is symm BT = B

B–1 = 2AT B–1 = 2A

3A – 4BBT = I
2BT – B + 4B3 – 5BA

(A is correct)
(2A)–1 + I – 2AB + 4B3
= (B–1)–1 + I – B–1 B + 4B3

(B) is correct

(C) is wrong
 [post multiplying by A]
2
2B = 3A – A [post multiplying by A]
3A3 – A2 = I [post multiplying by A]
(D) is correct

41)

Let a be pth terms of A.P. whose first term is 'T' and common difference 'd'
∴ a = T + (P − 1) d
Similarly let 'b' be qth term and 'C' be rth term
then b = T + (q − 1) d
c = T + (r − 1) d
According to question

If a,b,c are consecutive terms then

If a, b, c are 2nd, 3rd and 6th term respectively then

and can never be an irrational so option 3 and 4 are correct.

42) (P) ⇒

(Q)
(R)
(S) |A| = 2 × (3×(–3) – (–2) ×4) – (–2)((–1)×(–3) –1×4) – 4×((–1) (–2) –1×3) = 0

43) ATD = DAT

DDT = DTD = I
⇒

(A)

(B)
⇒ k is odd
(C)

(D)

44)

from given data

45) if
(Q)

(R)

(S)

46) squaring both the sides

Again squarring

Similarly

so

47) trace (AAT) =

Hence, number of such matrices
= 9C3 × 23 = 672.00

48) x3 – 2x + 3 = (x – α) (x – β) (x – γ)
⇒ (2 – α) (2 – β) (2 – γ) = 7
(∵ α + β + γ = 0)

49)

Sum

50)

Given that
ck = ak + bk and a1 = b1 = 4
also a2 = 4r1 a3 = 4r12
b2 = 4r2 b3 = 4r22

Now c2 = a2 + b2 = 5 and c3 = a3 + b3 =

⇒ and

Hence which gives &

= 24 – 20 = 4

51)