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K P /P P 760 MMHG Y K X The Higher and Lower Bubble Points of Components (351.3-373 K)

The document discusses phase equilibrium in a ternary system containing ethanol, benzene, and water. Specifically, it discusses how adding benzene as a separation agent eliminates the azeotrope that forms in an ethanol/water mixture. It provides the mole percentages of each component in the ternary system and gives equations to calculate the vapor pressure of each component as a function of temperature. It asks to find the bubble point of this ternary system using the information provided.

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54 views1 page

K P /P P 760 MMHG Y K X The Higher and Lower Bubble Points of Components (351.3-373 K)

The document discusses phase equilibrium in a ternary system containing ethanol, benzene, and water. Specifically, it discusses how adding benzene as a separation agent eliminates the azeotrope that forms in an ethanol/water mixture. It provides the mole percentages of each component in the ternary system and gives equations to calculate the vapor pressure of each component as a function of temperature. It asks to find the bubble point of this ternary system using the information provided.

Uploaded by

MahmoudAli
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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Phase Equilibrium

Q- Addition of a Material Separation Agent, such as benzene to an


ethanol/water mixture, changes the molecular interactions and eliminates the
: azeotrope. The ternary system (Azeotropic) Contain

Ethanol = 50% by mole


Benzene = 35% by mole
Water = 15 % by mole
: The Vapor pressure for three components are calculated by
Ethanol P*e= exp(18.5242-3578.91/(T-
50.5))
Benzene P*b= exp(15.9008-2788.51/(T-
52.36))
Water P*w= exp(18.3036-3816.44/(T-
46.13))

: Where
Ki = P*/Ptotal
Ptotal= 760 mmHg
yi =Ki*xi
The higher and Lower Bubble points of components (351.3-373 k)

.Required : Find The bubble point of ternary system

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