0

16 x
IstBohr's orbit r0= 0.529 A of hydrogen
1. (b) 9 n2
Change in kinetic energy is (i) n  2, Be3  r  r0   r0
 Z  4 Z
x 8x
x  2 2 4r
9 9 (ii) n  2, Li 2  r  r0   0
 Z  3 3 3
For Bohr model of atom 2
The kinetic energy in a state is equal to half 2
(iii) n  2, He2  r  r0   2r0
of the potential energy in magnitude.  Z  2 2
 Potential energy 3 2
(iv) n  3, Li 2  r  r0   3r0
= 2 Kinetic energy  Z  3 3
8 x 16 x
2 
9 9
7. (a)
2 a0
nh h
2. (c) n2= 9 to n1= 6 
First line in balmer series means transition 2 
from n = 3 to n = 2. Now, 9thorbit of Li2+ has n=2
same energy as third orbit of 'H' atom & 6th n2 22
r  a0   a0   2a0
orbit of Li2+ has same energy as second orbit z 2
of 'H' atom. So n = 9 to n = 6 transition in 2  2 r
Li2+ would have same wavelength as first    r   2a0
line in balmer series of
H-spectrum.
v
3. (d)486.4 nm 8. (b) 4
1 1 h h
1
 RH Z 2  2  2  x.m.v  or .m.v 
 4 4
 n1 n2  h h
1 1 1 or m.v 
  RH  12  2  2  mv 4
 2 4  v
or v 
 
1 1

3 4
 912 16
0
   4864 A 9. (b) 1.6 x 1016
  4860.4nm nhc
E

4. (b) -82kJmol-1 1240
5  103 J / s  n   1.6  1019 J
Z
2 632.8
We know that En= Elx   n  1.6  1016
n
E
Given E2  21  328kJ mol 1 10. (a)5 :9
2 We know that
E2 328
E4  2  kJ mol 1  82kJ mol 1 1 1 1  R
2 4  R   
min 4  4
5. (a) 0.55eV
4
1  1 1  5R  5
13.6 13.6 13.6  R     min  R 
En   2
eV ; E2   2 ; E4   2 eV / atom min  4 9  36 max
36 9
n 2 4
5R
E  E4  E2  2.55eV
Absorbed energy = work function of metal +
KE 11. (b) 6 x
2.55 = 2 + K.E. for Hydrogen atom, rn  n2
K.E. - 0.55 eV r1=x
r3=9x
6. (a) n = 2, Be3+ Now,  2 r3  n

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782

 2 r3 h
    x  p 
3 4
2 h
     9x  p 
3 4   x
  6 x h
v 
4 m x
3
2
6.625  1034
12. (c) -2 x 13.6 x    31 10
 5.8  105
8 9.1 10  10    3.14
The angular momentum of an electron in an
nth orbit is given by 15. (b) 0.5a0,3a0
h
me vr  n. ; n  1.2.3... For node  2 = 0 , So also  = 0
2 3
1  1 2  x

   x  1  x  8 x  12   e
h h 
n  14  n  8 So for:   2 2

2 11 16 4  a0 
[(x -1) (x -8x +12)] should be equal to zero
2
Z 2
P.E  2  13.6 2 eV
n [(x -1) (x2-8x +12)] = 0, solve the equation
2 (x-1)(x2-8x+12)
Z
Potential energy = -2 x 13.6 x   X = 1, 2, 6
n i.e.i = 0.5a ,a ,3a ; 0 0 0
2
3 2r
Potential energy = -2 x 13.6 x   x
8 a0
forLi ,Z = 3
2+
So minimum 0.5a0
maximum 3a0
13. (d)
16. (c) at the angle of 45° from the x-and y-axis
The maximum probability of finding
electron in the dxy orbital lies at the angle of
45° from the x-and y-axis.

The spectral distribution of the thermal

energy radiated by a blackbody (i.e. the
pattern of the intensity of the radiation over
a range of wavelengths or frequencies)
depends only on its temperature. As the
temperature increases wavelength of peak
emission decreases. And the graph follows
as:
17. (c)i and iii
(i) and (iii) are correct graph according to
their orbitals 1s & 3s respectively.
Graph of 2s:

14. (a) 5.8 x 105

According to uncertainty principle
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 Graph of 3p: 21. (a) 6.626 x 10-31 m
v = 3600km/hr = 1000 m/s
p = mv = (1 x 10-6kg) (1000m/s) = 10-3 kg
m/s
Use de broglie'srelation.

  h / mv 
 6.626  1034 J  s 
1103 kg 
= 6.626 x 10-31m

(i) - (iv) - As all graphs for 4 r 2 2 v/s r start 22. (c)

from origin. So it is incorrect.

h2
18. (b)
32 2 ma02
1
K.E.= mv2...(i)
2
nh This is correct graph for Is.
mvr=
2
nh
v …(ii)
2 mr
Putting (ii) and (i)
1 n2 h2 n2 h2
K.E.= m 2 2 2  2 2
2 4 m r 8 r m
Now r = 4a0 (since n = 2 ) and a0= Bohr's
radius
n2 h2 n2 h2 23. (d) A - Li2+, B - He+, C – H

8  16a0 m 128 a0 m
2 2 2 2 Radial nodes for 2s orbital is at distance
Now n = 2  2a0 
 Z 
4h 2
h 2  
K .E.  
128 ma0 32 ma0
2 2 2 2  2a 
For (a)  0  is least Z = 3 for Li2+
 Z 
 2a 
6h  4 For (b)  0  is intermediate Z = 2 for He+
 Z 
19. (a) 2
 2a 
 321 : n= 1,1 = 2,m= 1 For (c)  0  is maximum Z = 1 for H.
 Z 
h 6h
Angular momentum = 11  1  A - Li ,B - He+, C - H.
2+
2 2
Spherical nodes = 3 -2 - 1 = 0; Angular node
=2
n2
6h 6h  4 rn   0.529A
Sum of all the above = 2 Z
2 2 24. (a)
3 3
r3 for Li 2   0.529
20. (b)2,0 3
Number of radial nodes = (n -1 -l)  1.587A o
For 3s, n = 3,1 = 0 (Number of radial node =
3-0-1 = 2) 25. (c)According to Heisenberg’s uncertainty principle
For2p,
h
n = 2,1 = 1 Number of radial node =2-1-1 = x  p 
0 4

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782

x  m 
h
(as x  2P )
3 108
  3.5 109
4 1
so x  2  m   10.5 101  1.05m
h
2  m  
2

4 mur 
nh
v
nh
1 h 2 2 mr
    2 31. (c)
2

2m 4 distance 2 r 4 2mr 2
Time   
1 h velocity nh / 2 mr nh
v 
2m 2 32. (d) JEE Main 2019

As we know that,
26. (b)Series limit is the last line of the series, i.e. n2  
̅ ( ) (where, )
1 1  1 1
v R 2  2 R 2   After putting the values, we get
 n1 n 2   n1  
R 109677 ̅ ( )
v  2  6854.8 
n1 n12
̅
109677
n12   16 Comparing to , we get
6854.8
Thus, n1  4 means Brackett series. and (slope)

1 1 1 33. (d) JEE Main 2019

 RH  2  2 
  n1 n 2  According to de-Broglie wavelength equation,
27. (c)
For longest wavelength n1  2 n 2  3 (Balmer series)
1 1 1 5 According to photoelectric effect,
 R H     R H  15233
  4 9  36
1
  6.56 105 cm  656nm
15233
Assertion‐Reason Type questions
( )

  A   3 107 m
28. (c)
( )
  B  3 104 m
  C   3 109 m 34. (c) JEE Main 2019

  D   3 109 m
1
E

Thus, increasing order of energy 
CDAB

29. (d)II is not correct.

1 1 According to photoelectric effect,

frequency  
30. (b)
time period 3.5 109
c c
v   Work function ( )
 v
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 For determined shortest wavelength,
Lyman series ̅ *( )
+
35. (d) JEE Main 2019
Paschen series ̅ *( +
Given )
̅
… (i)
̅
Radii of stationary states ( ) is expressed as :
… (ii) 40. (b) JEE Main 2019
From equation (i) and (ii)
Phosphorus has atomic number 15. Its group
number is 15, number of valence electrons is 5
and valency is 3.

41. (a)JEE Main 2020

Self-Explanatory

36. (c) JEE Main 2019

42. (b): Higher the value of  n  l  for an orbital, higher is its
(I) 6 energy. However, if two different types of orbitals have same
(II) 5
value of  n  l  , the orbital with lower value of n has
(III) 5
lower energy. Therefore, decreasing order of energy of the
(IV) 4
given orbitals is 5 f  6 p  5 p  4d .
The energy of an atomic orbital increases with
increasing . For identical values of ,
energy increases with increasing . Therefore the 43. (c) : Number of spherical/radial nodes in any orbital
correct order of energy is :  n  l 1
Number of planar/angular nodes in orbital l 3
IV II III I Total number of nodes in any orbital  n  1  3
n  4
37. (d) JEE Main 2019 Thus, the orbital is 4 f .
In photoelectric effect,
44. (c) : According to Hund’s rule of maximum
multiplicity, the correct configuration of ‘N’ is
Given that KE of ejected photoelectron is very 1s 2 2s 2 2 p1y
2 p1x 2 p1Z
high in comparison to work function .
    

New wavelength 45. (a): For n  3 and l  1 , the subshell is 3p and a

( ) particular 3p orbital can accommodate only 2
electrons.

38. (a) JEE Main 2019 46. (c) : d x2  y 2 and d z2 orbitals have electron density
Atomic numbers of N, O, F and Na are 7, 8, 9 along the axes while d xy , d yz and d xz orbitals have
and 11 respectively. Therefore, total number of electron density inbetween the axes.
electrons in each of and are 10
and hence they are isoelectronic. 47. (b): For the two electrons occupying the same
orbital values of n, l and ml are same but ms is
39. (a) JEE Main 2019
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
 different, i.e.,  1 and‐ 1 .
2 2

(d): Number of d ‐electrons in Fe2  6

48.
Number of p ‐electrons in Cl  11

49. 3 pZ has following set of

(a): Only one orbital,
quantum numbers, n  3, l  1 and ml  0.

50. (c): Rb (37): 1s 2 2s 2 2 p6 3s 2 3 p6 4s 2 3d 10 4 p6 5s1

For 5s, n  5, l  0, m  0, s  1/ 2 or 1/ 2

H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782