OO -O- Indophenol anion (blue) [Ans. (b) : Aldehyde give a wine-ted or purple color lwith Schiff reagent 23, When an aldehydic group react with Tollen’s reagent? (a) Formation of silver mirror (b) Red precipitate (©) Formation of erystalline solid (Q) Violet precipitate [Ans. (a) : When an aldehydic group react with Tollen’| reagent, formation of silver mirror or blackish precipitate is observed. 2H WREh compound ive preen color with FeCh, [line presence of cone H:S0, 10 give phenolphitalen aa OC lwhich gives a dark pink color with NaOH solution. Carbonyl (Aldehyde & Ketones group) 22. Which of the functional group give a wine-red |[Ans. (@) : Aromatic aldehyde give positive test wih] or purple color with Sehiff's reagent? tolten’s test and do not give positive test with fehlings| (a) Aleohol (b) Aldehyde test and Bendict test because they lack a-Hydrogen| (6) Ketone (d) Amide letom fAns. (€) : Resorcinol, o-, mand p - eresol give violel jor blue color where as catechol give green color with] Fecl, 21, Which color shown by the phenol in phthalein dye test? (a) Blue (b) Green (© Red (@) Dark Pink [Ans. (d) : Phenols condense with phthalic anhydride in 28. Benedict's solution is a mixture of - (a) Copper sulphate and sodium citrate (b) Alkaline solution of silver cation complex with NHs (©) Alkaline solution of Roche's salt (2) None of these [Ans. (a) : Benedict's solution is more stable than] fchling’s reagent and can be stored for a long time. It is Jalkaline solution containing a mixture of copper] sulphate and sodium citrate (2NasCsHsO>. L1H) 24, Tollen’s reagent is propare by the mixture of (a) NaOH and AgCl (by NaOH and AgNO; (c) NaNOy and AgBr _(d) NaNOs and AgCl 29. Ketone do not respond the positive test with- a) Tollen's reagent (b) 2,4 DNP test (c) Schif?'s reagent test_(d) Reagent [Ans. (b) = Tollen’s reagent is prepared by adding, di INSOH to AgNO; solution the white precipitate is produced which is dissolved by adding a few drops of lammonium hydroxide 25. Which of the following reagent is used to distinguish the aldehydic and ketonic group? (a) Lucas test (b) Mulliken Barker test (c) 24 DNP test___(d) Tate's test [Ans. (€) : These distinetion can be made by using @] Ieagent 24 DNP. |On reaction 2.4 Dinitrophenylhydrazine is converted to] 12.4 dinitropheylhydrazones these two carbonyl group is liso distinguished on the basis of test using oxidising| lagent like tollen’s reagent and fehling reagent. 26. What is fehling’s solution B? (2) Aqueous solution of copper sulphate (b) Aqueous solution of silver cation complex with NH; (©) Aqueous solution of NH.OH (@) Alkaline solution of sodium potassium tartarate [Ans. (d): Fehling’s solution B is an alkaline solution o lsodium potassium tartarate (Rochells salt), The reagent [contains Cu" ion complex with tartrate ion. 27. Aromatic aldehydes give positive test with- (2) Fehling’s test (b) Benedict test () Tollen's test (d) Allof these [Ans. (c) : Ketone do not respond the positive test with] ISchiff’s reagent. Aldehyde give a pink color with Schifts reagent. 30. Which test confirms the presence of Ketone group? (a) 24 DND test (b) Sciff's test (©) Luca's test (@) None of these [Ans. (a) : 2,4 dinitrophenylhydrazine solution (Brady's reagent) or 2.4 DNP test confirms the presence of ketonic group. [A red yellow or orange colored precipitate indicates the| |presence of carbonyl group. persed adopts 24-Dropeynee ‘What will be observed when Aldehyde test with fehling’s solution. (a) Appearance of Pink color (b) Formation of silver mirror (©) Formation of Crystalline solid (@) Formation of brick red precipitate [Ans. (d) : Formation of Brick red precipitate of copper (oxide indicates the presence of an aldehyde. a. Experimental Skills r 4 vor32. Which of the following reagent is used for test of carboxylic acid? (a) NasCOx (b) NaHCO; (c) SOCh + NaHCO _(d) HCI+ Na,CO; [Ams. (b) : Add a few drop (if liquid) or few gram (i lsolid) of the substance to a standard solution o INaHCOs, there will be effervescence due to evolution| lof CO, gas indicates the presence of carboxyl group. RCOOH + NaHCO; ~» RCOONa + H.0 + COs 33. Which product obtain when a carboxylic acid react with Alcohol? (a) Ether (b) Amide (c) Ester (d) Acid chloride [Ans. (c) : Carboxylic acid react with aleohols in the] lacidic medium to produce esters. RCOOH + ROH —°%#5% "5 RCOOR'+H;0 \Carboxylic Alcohol Ester acid. 4 Which of the following test is given by the primary amine? (a) Bayer’ test, (0) Lieberman's test (c) Molisch’stest__(d) Carbylamine test [Ans. (d): Aliphatic as well as aromatic primary amines lgve carbylamine test in which an amine is heated with chloroform. Ik - NH + CHCl + 3KOH —* > RNC + 3KCI+ 31,0 Catbylamines 35. Which of the following compound give azo dye (6) Tertiary amine __(d) All ofthese test? [Ans. (b) Secondary amine react with nitrous acid to] (a) Primary amine leive a nitroso amine. In Liebermann's nitroso reaction, () Aromatic primary amine |dissolve 0.Sgm of the given compound in 2 mi of dil (©) Secondary amine HCI, coal and add sodium nitrite solution gradually with] (a) Aromatic secondary amine shaking until yellow oil is obtained, Now place 2 drops| ns. (b) + Aromatic primary amines can be confirmed] | the oily miteso compound ina dy test tube and add a Jphenol and warm gently. A greenish blue color is sae lobtained which changes to red Preparation organic compounds i) A (©) CHsCOCH, (@) Allof these 38 Which of the following is Acetanilide? [Ans. (a) = Acetic anhydride is usually used to carry ou lacetylation, Acetyl chloride may also be used for the @ Cs foros fatto 40. Which of the following compound is used for preparation of acetanilide? © C)coon wnat Due a Ac aye (b) Aniline + Acetic acid + Acetic anhydride ‘NH, (c) Aniline + Acetic acid + Pyridine © (@) Aniline + Acetic acid + Oxalic acid ‘cocH, [Ans. (b) : For the preparation of acetanilide aniline] lacetc anhydride and acetic acid is used. (@ (O)—nucoc, (CH,CO),0/ [Ans. (a= _CHCOCL Cnt NHCOCH, -NHCOCH, is structure of acetanilide “Prine 3. Which ofthe ollowingisusedfor aceplation? || Aniline Acetic acid Acetanilide (a) Acetic anhydride (b) CH;COOH [Aniline react with nitrous acid at 0 - 5°C to produce a] {diazonium salt, This couple with B- naphthol to give a| fojave KO) Nano, © . Benzene Diazonium Chloride B-Naphibo 36, Which of the following functional group does not give carbylamine test? (a) Primary amine (b) Secondary amine (c) Tertiary amine __(d) Both (b) and (c) [Ans. (d) : Secondary amine and tertiary amine do noi] lgive carbylamine test 37. Lieberman's nitroso reaction testis given by = (a) Primary amine (b) Secondary amine Experimental Skills T 15 vor