(a) Fe(OH), (b) Fea[Fe (CN)o)s (c) NayFe (CN)¢ (d) NaCNS_ [Ans. (by: Fern -ferrocyanide (Fea(Fe(CN).}) show the [Prussian blue color inthe test of Nitrogen, 12, Match the following- Colour (i) Dirty Green (i) Prussian blue (ii) Purple color (iv) Black PPF Compound Fed[Fe(CN)dls Pbs (© Fe(OH), () NaslFeO = N-S- Na) (CN)s] (@) ()-A,(i)-B, Gi) -C, Gy)-D () ()-C.Gi)-A, Gil), Gv) -B (©) ()-B, (il). Gii)- A iy)-D cd) Gi) =D. i) B. Gil) Gv) -C Ans. () : FeSO, + 2NaOH > a) (B) Fe(OH)» + Na:SO, Ferrous hydroxide (itty green) Detection of the following functional groups- Hydroxyl (alcoholic and phenolic) 14, Which of the following solvent is also used in the test for unsataration in place of CCl (a) CH;Cl (b) CHCl; (c) CHCl (d) None of these (Ans. (b) : In the test for unsaturation, in place of CCL lany other solvent such as CHCh/dioxane and even water can be used to dissolve the organic compound, 15. Which of the following color is obtained on reaction of alcoholic compound with ceri ammonium nitrate? (a) Blue (b) Green (©) Red (@ Violet [Ans. (c) : The reaction of alcoholic compound with] ceric ammonium nitrate give a re coloration due tothe formation ofa complex. |(NH.); [Ce(NO,),] + 3ROH > [Ce(NO}), (ROH) \Cerie ammonium Red complex nitrate +2NH,NOs ‘Which of the following reagent is used for fest of solid alcohol? (@) Acetyl chloride (b) Benzoyl chloride (6) Both(a) and(b) _(@) NaSOx [Ams (c) : When dry solid alcohol reacts with acetyl of lbenzoyl chloride, the effervescence with evolution o IHCI gas is noted IROH + CICOCH, > ROCOCH, + HCI IROH + CICOC\Hs > ROCOGHs + HC t 1. 16 Primary, Secondary and tertiary alcohols ean be classify on the basis of which test? [3NayFe(CN), * 4Feck; > Fes[Fe(CN)ghs + 12Nacl Fert -ferroeyanide (Prussian blue) |Na:S + Nas[Fe(NO) (CN)s] -> Nas(Fe(O = N - S-Na) (CNs] Sodium nitropusside Purple coloured complex INas$ + (CHsCOO): Pb -> POS + 2CH\COONa Black ppt 13, When sodium extract is treated with lead acetate the obtained compound is - (a) Nas (b) NaxSOx (c) PbS: (a) NaNOs Ans. (¢) : Black ppt, of lead sulphide is produced after] the reaction of sodium extract with ead acetate INasS + (CH,COO), Pb —» PbS + 2CH,COONa Black ppt (2) Lucas test (b) Molisch’s test (©) Lieberman's test (@) Mulliken Barken test [Ans. (a) + Lucas reagent contains zine chloride and] [concentrated hydrochloric acid, This reagent reacts with primary, secondary and tertiary alcohols, IRCH, - OH + HCl —“2-» No reaction/slow reaction Io CHOH + HCI #4 R,CHCI + H:0 RCO 25 R:CC1+ HO 18. _ Which of the following color is observed when FeCl, reset with alcoholic or aqueous solution of phenol? (@) Blue () Red (©) Green (4) Violet [Ams. (d) : 6 C.H.OH + FeCl —> 3H" + [Fe(OC.Hs),) +] SHci voilet, \Voilet color is observed when any phenol compound is reacted with feCls, 19. All phenols in which pa respond to which test? (a) Lucas test (b) Liebermann’ test (©) Fenton's test (4) Lassaigne's test [Ans. (b) + All phenols in which para position is fee] respond to Libermann’s test. Take a small amount to] |phenol and add few crystals of sodium nitrite in dry test tube then add half ml of H:SO, gives a green or blue |colour and for these on dilution the solution turns red. |Now adding NaOH in the solution it again becomes| lereen or blue. position is free, Experimental Skis 113 YcTOO -O- Indophenol anion (blue) [Ans. (b) : Aldehyde give a wine-ted or purple color lwith Schiff reagent 23, When an aldehydic group react with Tollen’s reagent? (a) Formation of silver mirror (b) Red precipitate (©) Formation of erystalline solid (Q) Violet precipitate [Ans. (a) : When an aldehydic group react with Tollen’| reagent, formation of silver mirror or blackish precipitate is observed. 2H WREh compound ive preen color with FeCh, [line presence of cone H:S0, 10 give phenolphitalen aa OC lwhich gives a dark pink color with NaOH solution. Carbonyl (Aldehyde & Ketones group) 22. Which of the functional group give a wine-red |[Ans. (@) : Aromatic aldehyde give positive test wih] or purple color with Sehiff's reagent? tolten’s test and do not give positive test with fehlings| (a) Aleohol (b) Aldehyde test and Bendict test because they lack a-Hydrogen| (6) Ketone (d) Amide letom fAns. (€) : Resorcinol, o-, mand p - eresol give violel jor blue color where as catechol give green color with] Fecl, 21, Which color shown by the phenol in phthalein dye test? (a) Blue (b) Green (© Red (@) Dark Pink [Ans. (d) : Phenols condense with phthalic anhydride in 28. Benedict's solution is a mixture of - (a) Copper sulphate and sodium citrate (b) Alkaline solution of silver cation complex with NHs (©) Alkaline solution of Roche's salt (2) None of these [Ans. (a) : Benedict's solution is more stable than] fchling’s reagent and can be stored for a long time. It is Jalkaline solution containing a mixture of copper] sulphate and sodium citrate (2NasCsHsO>. L1H) 24, Tollen’s reagent is propare by the mixture of (a) NaOH and AgCl (by NaOH and AgNO; (c) NaNOy and AgBr _(d) NaNOs and AgCl 29. Ketone do not respond the positive test with- a) Tollen's reagent (b) 2,4 DNP test (c) Schif?'s reagent test_(d) Reagent [Ans. (b) = Tollen’s reagent is prepared by adding, di INSOH to AgNO; solution the white precipitate is produced which is dissolved by adding a few drops of lammonium hydroxide 25. Which of the following reagent is used to distinguish the aldehydic and ketonic group? (a) Lucas test (b) Mulliken Barker test (c) 24 DNP test___(d) Tate's test [Ans. (€) : These distinetion can be made by using @] Ieagent 24 DNP. |On reaction 2.4 Dinitrophenylhydrazine is converted to] 12.4 dinitropheylhydrazones these two carbonyl group is liso distinguished on the basis of test using oxidising| lagent like tollen’s reagent and fehling reagent. 26. What is fehling’s solution B? (2) Aqueous solution of copper sulphate (b) Aqueous solution of silver cation complex with NH; (©) Aqueous solution of NH.OH (@) Alkaline solution of sodium potassium tartarate [Ans. (d): Fehling’s solution B is an alkaline solution o lsodium potassium tartarate (Rochells salt), The reagent [contains Cu" ion complex with tartrate ion. 27. Aromatic aldehydes give positive test with- (2) Fehling’s test (b) Benedict test () Tollen's test (d) Allof these [Ans. (c) : Ketone do not respond the positive test with] ISchiff’s reagent. Aldehyde give a pink color with Schifts reagent. 30. Which test confirms the presence of Ketone group? (a) 24 DND test (b) Sciff's test (©) Luca's test (@) None of these [Ans. (a) : 2,4 dinitrophenylhydrazine solution (Brady's reagent) or 2.4 DNP test confirms the presence of ketonic group. [A red yellow or orange colored precipitate indicates the| |presence of carbonyl group. persed adopts 24-Dropeynee ‘What will be observed when Aldehyde test with fehling’s solution. (a) Appearance of Pink color (b) Formation of silver mirror (©) Formation of Crystalline solid (@) Formation of brick red precipitate [Ans. (d) : Formation of Brick red precipitate of copper (oxide indicates the presence of an aldehyde. a. Experimental Skills r 4 vor