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CHAPTER 12
ATOMS
> What is the fegangennint 4 the postive chasge & the
alecthons inaide the atom 2 ‘
> (or) What is the AbAuctuae 4 the atom 2
Finst model ; atom — 2-3. Thomson [igaay
= The posttive chasge q the atom is una foseny
diataibuted throughout the” VoLume p te alm ond
the neganvely changed electrons ore embedded in atv
fixe Aseds in a Watermtlon. ’
= Plum pucldeng Moclse
«Each olemene is assowatecl with a chrracborcsie Apectn
wy pointer: Raompse Hydacgen qias 0 201 Jens ustth
fired sulative position jo the Lines.
22 TT Balmea — empinical yonnnka
— wavelen ya Mi
aettellog tee Ghee
. Ruthertondl [Research stuclenr § 3-3: Thomsen]
=? P Lane model 9 atom lor Nucheah model
the me y )
27 The enting Posirive Charge and moar % The
mass 4 the alom conuntnared in a small volume
Called Nuckevs wih electaons favolving OAound the
Nucheus j= as plone acvolve round fhe Aun:
= coop net expLan wy afens emit Light 9
only discrete wwavaling ths :ALPHA PARTICLE SCATTERING! 2 RUTHERFORD NUCLEAR Mope.
‘SOuRCE OF
ALPHA PARTIES
2
> A bean 4 5-5 Mev Particles 2mitted [rem a Bi
3
Aaclioackve Aouste At a thin motol joi! made % gold.
SCHEMATIC DIAGRAM *
Source , qf Je
oF a~ a : ve
PARITCLES| ean Z Geis ws inc Sulphide Scheer
Backs 7 Fore. Ss
MiceoscoPE /DETECTOR
wy @- pmticdes emi nad bya 2m
pi fadioachve Aout
+ CoMtimaiod into o narrate” beam by thet Pab thy
rad brie ns a f F at ugh
= The beam — jolt 0 a. thia fre geld 4 thickness 91x10 I
oy The vcattecd alpha ponticle ~Staine the scsten— Dhoduce
Deghe splashes Gr sung Mate ns
> Flashes — viewed thscugh 0 michoALope
=2 Distalbution % the number 4) Aca ttwed particles
expaussed Intoams % angle pate.Ks - al
ann
posticles
Rowts 2
> Many 9, he a panicles pass rouge te pp
> Only 14 the dndoline ae eae seatten by
more than 1°.
& : [o-c125%] difleet by mone then 90°.
> To dite ex ponticle backwards , Jt mouse experitny
oo xepulaive jen. => Posside when grunt.
POnt 9 mnss 4 Blom &
i ye Chis ge wre
Conunrhated pt onthe.
> Ruthjonc’s nuchon eodul 4, the Atom:
. x
+ The onthe tve charge 3 mods go ihe mad
% the Alor pag Conunthated in ihe nucleus
with os Some cltstance Arode
+ Es wound be moving in pnbite about we
nucleus [ Joke Pat around [he Sun]
+ Size 4} the nuchas 16° m to 16m,
‘ + TM ize 4 TR atoon Predicted dy Knitic
s+ MOE this 7
an o
atom &
i J ize :
Lopi ale. ime Anger Han size % the cuclus
"ro. 2. ato is yo* pig+ Sing ttm is opty space, o— prrticles penetAnlis
hanigh the thie metal feu
» Whine pontice is clown to nicl, ir
ys acnttuud b{ intense electric fis poclced
by acne.
“The magus 4 fore > Repulsion
ce DLpha Paaticle
Az
Aarne blu ok pwrhile
: 2 ruclns.
Alpha- Ponricle thapectony :
AU pahticles in
A beam Aave me
KE.
L
6-5
[Head on collision) tics
en ct pahameter : (b)
Tt is the Lr distance ts doinind valocis
vector fp the oe pee en the Centre the ouch,
% Smo impact parameter —> Close tothe nucbeng
| oy LARGE Acattining . (O=1)
% page lonpa ck parameter —> nent ONDEV/ATED
“COs0)
x Very onnntl 10.9 o¢-pantiths under po
Mad pn -tollicts,.Ehorson onbits:
« Elections ane fei in tein droning
Ato le onbit- .
« Fone 9 aAltnaction
bho avokvig = Cnthiparal pora
2 ‘nuchus (te Kaep thann in katt.
Onpits)
FE z ak :
Los 0 _@m yt FoA } Atom
Aliso (92 T oy —n
Ruation b/w ohbit nadine 2 2” yaloci
oo ;
ATSyme*
(29
The KE 2 PE 4 2” in H- alm pae
=> Ke y mo ==)
= ym ot
hor ani2> 4 an] —@
ae es —— (2
tox, (E)
2 ee
ie ae (3)
ATEQh
(A app dedicales that ihe Bis in 4 dine ction)
(07) 2" & bound to nucleus 2 Work must be obo
oe oe idole
aie et a aAtomic Spoctha:
(lin aR pl rg tn
Atomic ss it & excited 2 emits hadiaton
wilh Apiu pie wwavebing ths ee
tdinw an
eee background J,
> Stucly 4 Omission Apsethum is gn poe ;
que Calon 4
[Mba white ght ) poasus songl gus 4
we annlyse the taanamitted Hight basing Apeetnoms 1
he an ind ee.
te aiden ghee Close to
amassion Line, Apecthum 4
(hagasSpectral Svries: @
Observations: Fi
iq 125
Hy drogen specthum > Spaing b)0 Sines within
; CUtMin 4 % He Apactau,
x olechenres un raguden wag,
> Aw the wavs de chsases,
the Lines Appear closer
b 2 Waker tn intonsig
Balmer jound a Almple fnpinical permet:
i } )
= Rp - 4] D2 34h5 ete.
A 2 n
-1
_ 2S Rydlbog Constant = 1-097 x10" a,
_Lyrono sein: => (dtraviokr )
oe Ray) oe D = 2,3,4-.
A ns .
Prachen sore’ —> (TR)
rae eee i I _ ee
meio RULE tee eects n= 4,5,
A Stile
Bracket serine: => (IR)
re a n= 5,6,7+°-+
A ERs
P-fancl Seales *
i. feet 26,1,8 \
5 ryt | neé,In toys 5 {ra Balen jonrmule,
D= Re Fs | “2 1G= DA
n MY
de
A
Why Rathufond model falls? [cbussical] (0D De
(n An Acetharated) changed Particle as
hadinkon in the pm 4 2m waves.
(2) /. The Any 4 an aecebaratny «?
Continuous. clecrense .
About, 4
(> The ew” would Spiral inwand & fall
into ouclns => alorm Cannot be stable
[AD As the 2° spinal srwanls,
wr 2 f > ch comsinuol
vo Prep nened amined Lahr
4 re d f°
st NR Can Anpeeh A
CNH Ou OMA.
re Rutherpoadd model
\ confi Ape etrum"
B nok Auffictent Io Cornuons Apes
v
2x plain Otomic AbAuctory.
But we obsvaved
tine apeetnum 4
H - atom6
Nials Bohr Atom model.’ E Gaasotuon: reach ics]
3 postulate:
Co An 2” ay an atom could valve in contnip
AtpuaLe onbits without — the amiasion 4 Aadiont
> "siptto, Arotes” . “a
(29 Edecthon prevelves around the nucleus only in those
onbits sn which the nen momentum 6 inte
mutt ple 4 yg * > Angulas eromuntum ¢% Guontined
wl be bbe ss
Plancks conse
(> An 2” maf thansi & jtem one 4 1b nen-fadiaki
onbits to anon Lowsr emitting a
Photon with erik epnal fo he city bho
initial 2 font tales +
hn? = jE A oo
To fod rhe oneiay % di bpeane ange Atos fen
\}- atom ,
pisces
81%» we have ind
Aanding ta @”
Onbit -To eateutate ‘a’, use
“% Bohnis postulate :
Allowscl values »
Bohis
eat Quantisa no n
nd)
2 poshulate
argalin moman tune
WldA momentum
pe dntepral multiple 4 Nar
Ly =
n
mea, = Me
ug ar
n> integer T Paarl quantum wore]
Ain Radiws 0" onbir
W-> Aptecl 4 moving: 2” an the 0" onbie.
Relanon blw Uy # fin:
zy
Un = ah
472, MAn
From 24n. (1
27
ATS (ohn) 7
whl farm aqn (4)
ge
My =
AME, mm ih
eae
2
@
: (@
AMZ MA,
ow,
ee
n 408, (Afar)
es (a>
on bital art
ye by A facion
% n.yecies:
Suecbset n> a 2
aren 2") (Ale) (Aan)
w
2
t " wh) Be > Radius 4 the to
Onbie Uncheases with n®
The Aizt 4) the dinner moar oftbit net
a2 4 Jay
1° om (B)
- i, 408
manr “92
2
n= A’ és. . °
I aS = 8 Boba i
mee = Aadins ts
Swati crea m pry be ae
Enagy 9, ts 2" so the _Atationasy Atolis
6 in the Staronany Atle 9, ha Ay dgin cy
é eats et
Sus, h
— (6
. a
From 2, 4 B= eo? m (211) ite
Wo a2, 0? A” ae)
amen \
Ben A> —t—b)
2 7 aD:
Fenengy Aone ~
For ned, the MAaty 4 an pitom
GRooND (B= =o) => Ao when ein
ee cRaY 7 Closest to rhe nucheaes
Fon n=, 3,40 (ihe Olbsolute v wus 9 taergy is
Amol) che AY ‘s Lager Jin jhe oukta oabit-
Toni sation UvAYA"
The minimum “emp Aaguiradl rae the 2? ffm
the garund arate ie H-atom w 1BbeV- The
Called the ionisation ney 9 fhe Kogan atom .
Whi & hydhegen «lor aatbins turgy by collisions ,
the Atom quire Avg picieor nuts fatse the 2”
to Aighn any tats.@
fon ne Q, ey = —3-402V
The aunty faquitedl Io excite an 0” to i pose
txcited state =Ey-E, = — 3-40-H5-6) = 1o.gev
ly Vv
Wd Fok nea y Es = -152
E,-E, = -\5 - €13-6) = 1209eV
‘ LY :
% From the fxcied Stole, mee” Cnnay Aegus seed
me Alate 4 Lowa Fle ee
mls brew to d fhom ground stat
emit ton in (net
fd’ ; “ cee ; EO Awpncl bute
Atote-(n= 3).
the process.
The Aihar onugy stakes Naa, the &nugy = Oev,
The dine spectra 4 the Hydrogen Atom,
Wien an aiom makes A tAanitton oo
tare wlth Quantum Number a;
te igh smagy 4 q S
ae oun srasry- state [4] [ng Re h03xi0%m™
3 oer
44 ; Chose to the
Value obtained
of Ralmua.
Tana = Ly tonfiem Bohrs
Atom model.
>Nhn 0’ eae {rom
Li Athte bo
Jot “sat €, Photons
DA AMitted => semlrrion Lins,
> whin £°5 absoibs
tangy md go
gna => absorption Linn .@
De Broghie'’s expdhnation fh Behn’s Ateonel postulate
4 Quant sakion:
De Bnogve po thesis:
Material peaticts, sith as thetrons have
pn dn chculan onbil-
a wave NAWrAL. = a Can be Len ABD
particle wave.
Sihoding Waves:
oe Stenchng Wan 45 5 dehmed
WAsn nods OX
A eins (Wome or
@ tinealas opbiy yohue
4 he Broglie wore ling tha
ve toto the Cincutn fesse
4 fhe AbiFor on 2” in obit 4 hacking Dy , the
an
tom) distane the Uncun pence the oabitr,
25, =nh TM = WOR:
Exnnple ne4
An = AD
be tn
Pp me,
27 An = ak
mu,
ees co ee Qn = 4h.
mut Mn JL
as
degh |
or
-—