Thanks to visit codestin.com
Credit goes to www.scribd.com

0% found this document useful (0 votes)
56 views40 pages

Solution

Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
56 views40 pages

Solution

Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 40

06-10-2024

1701CJA101038240014 JA

PART-1 : PHYSICS

SECTION-I

1) Radii of curvature of surfaces of a biconvex lens are 10 cm and 20 cm and refractive index of its
material is µ = 1.5. If the refractive indices of the medium on the two sides of the lens are µ1 and µ2,
then the parallel rays incident on the lens from left will focus at a distance of f2 (distance being

measured from the optical centre of the lens) where f2 is equal to :-

(A)

(B)

(C)

(D)

2) Figure shows, a glass prism ABC (refractive index 1.5) immersed in water (refractive index 4/3). A
ray of light incident normally on face AB. If it is totally reflected at face AC, then :-

(A)
sinθ ≥
(B)
sinθ ≥

(C)
sinθ =

(D) < sin θ <

3) When a thin convergent glass lens (µg = 1.5) and has power of +5 D is immersed in a liquid of
refractive index µℓ it acts as a divergent lens of focal length 100 cm. Then µℓ is :

(A) 4/3
(B) 5/3
(C) 5/4
(D) 6/5

4) An object is moving at some angle with respect to the principal axis of a concave mirror as shown
in figure. Then which of the following diagrams is possible corresponding to the motion of image :-

(A)

(B)

(C)
(D)

5) A thin prism P1 with angle 4° made of glass of refrative index 1.54 is combined with another thin
prism P2 made of glass of refractive index 1.72 to produce no deviation . The angle of prism P2 is.

(A) 3°
(B) 2.6°
(C) 4°
(D) 5.33°

6) A man is 2m tall and can see his image in a plane mirror fixed on a wall. The minimum length of
the mirror to see his full image is:

(A) 2m
(B) 1.5m
(C) 4m
(D) 1m

7) A point object O is placed at a distance of 50cm from the curved surface as shown in figure. The
radius of curvature of the curved surface is 40cm. After refraction from the curved surface the

distance of image from point P will be :

(A) 200cm
(B) 300cm
(C) 400cm
(D) 500cm

8) A slab of thickness 3 cm and refractive index is placed infront of a plane mirror as shown in
figure. A point object O is placed at a distance of 4 cm from the slab. After all possible reflections
and refractions, the distance of final image of point object O from plane mirror will be :
(A) 30 cm
(B) 31 cm
(C) 29 cm
(D) 32 cm

9) A system consists of a small block of mass m connected with a massless spring. The system is kept
on smooth horizontal surface infront of a concave mirror of radius R as shown in figure. When spring
is at its natural length the particle is given a velocity . The image of the particle coincides
with it when elongation in spring is maximum. Find the distance of image of particle from pole of

concave mirror when compression in spring is maximum [spring constant k = ]:

(A)

(B) R
(C) 2R

(D)

10) Find location of final image of O after all posssible refraction & reflection :-

(A) At 60 cm right from lens.


(B) At 40 cm left from lens.
(C) At 30 cm right from lens.
(D) On object.

11) The carriage of mass M has constant initial velocity u along a straight horizontal track when at t
= 0, it starts raining. The rain drops have a vertical velocity u' and result into addition of mass m per
second to the carriage. The velocity of car after T second of start of rain is (Assume frictionless

surface) :

(A)
(B)

(C)

(D)

12) A ball is dropped from a height of 1 m. If coefficient of restitution between the surface and the
ball is 0.6, the ball rebounds to a height of :-

(A) 0.6 m
(B) 0.4 m
(C) 1 m
(D) 0.36 m

13) A 5000 kg rocket is set of vertical firing. The relative speed of burnt gas is 800 ms–1. To give an
initial upwards acceleration of 20 ms–2, the amount of gas ejected per second to supply the needed
thrust will be

(A) 127.5 kg s–1


(B) 187.5 kg s–1
(C) 185.5 kg s–1
(D) 137.5 kg s–1

14) For the given system initially at rest as shown in figure, a bullet strikes the block inelastically
and sticks to it then the amplitude of the system will be – (Neglect the thickness of the block)

(A)

(B)

(C)

(D)

15) A triangular lamina plate having side length ‘a’, ‘b’ and ‘c’ have moment of inertia I0. About the
side of length ‘a’. If another triangular lamina plate having side length ‘2a’, ‘2b’ and ‘2c’ is rotated
about side ‘2a’. Then its new moment of inertia.
(A) 2I0
(B) 4I0
(C) 8I0
(D) 16I0

16) Two identical rods each of mass M and length L are kept according to figure. The moment of
inertia of rods about an axis passing through O and perpendicular to the plane of rods, is :-

(A)
ML2

(B)
ML2
(C) 2ML2

(D)
ML2

17) Four rod each of mass m form a square length of diagonal b rotates about its diagonal. Its
moment of inertia is :-

(A)

(B)

(C)

(D) mb2

18)

System is in equilibrium. Find the hinge force (Ny) :-


(A)

(B)

(C)

(D) None

19) A block of mass m (has dimension ℓ × b × h) slides downward on fixed rough inclined plane
(whose inclination angle θ) with a constant velocity. The torque of normal contact force about the
centre of mass of the block will be : [Friction coefficient between block and inclined is µ]

(A) Zero

(B)

(C)

(D)

20) From the circular disc of radius 4R two small disc of radius R are cut off. The centre of mass of

the new structure will be:

(A)
(B)

(C)

(D) None of these

SECTION-II

1) A concave mirror has focus 20cm. It is at the bottom of a glass that has water filled up to 5 cm
(see figure). If a small particle is floating of the surface of water, its image as seen, from directly
above the glass, is at a distance d from the surface of water. The value of d (in cm) is close to :

(Refractive index of water = 1.33)

2) Three plane mirrors are kept as shown in the figure. A point object (O) is kept at the centroid of

the triangle seen in the figure. How many images will be formed ?

3) A parallel beam of light enters in glass sphere of radius 10 cm and refractive index 1.5. Distance
of final image from first surface is 5n cm. What is the value of n.

4) A point object is placed at a distance of 25 cm from a convex lens. Its focal length is 22 cm. A
glass slab of refractive index 1.5 is inserted between the lens and the object, then the image is
formed at infinity. Find the thickness of the glass slab (in cm).

5) A plane mirror is kept parallel to line y = x as shown. An object is kept at (2, – 2, 0). What is the y

coordinate of the image formed.


6) A bi-convex lens of glass (μg = 3/2) is immersed in water (μw = 4/3). The ratio of new focal length
of the lens in water to the original focal length of the lens in air is n. The value of n is :

7) If the acceleration of 3 kg block is 4 m/s2 to the left, what is the magnitude of acceleration (in

m/s2) of 8 kg block ?

8) Two bodies collide on a horizontal and frictionless surface. The velocities before the collision and
after the collision are shown in the drawing. Assume mass of body ‘A’ is twice as large as mass of
body ‘B’. The magnitude of the velocity B after the collision is α times 5 m/sec. Then α is :

9) The system shown in figure is held at rest. A horizontal force F = Mg is applied on block B
maintain equilibrium of system of blocks A, B & C. A particle of mass M is released from rest from
point P and there after falls through height ‘h’ before making a perfectly inelastic collision with
block A. The force F is removed just before collision. Then the acceleration of block C just after

collision is , find the value of N.

10) Force acting on a particle is plotted against time as shown. Calculate the impulse (in Ns) of the

force in 2 sec.
PART-2 : CHEMISTRY

SECTION-I

1) Which of the following compound can show geometrical isomerism.

(A)

(B)

(C)

(D)

2) Which of the following has aromatic character in it’s enol form.

(A)

(B)

(C)

(D)
3) In the following structure, the double bonds are marked as I, II, III and IV

Geometrical isomerism is not possible at site (s) :

(A) I
(B) III
(C) I and III
(D) I and IV

4) The 'E'-isomer is :

(A)

(B)

(C)

(D)

5) Correct order of stability of resonating structures is :

(i)

(ii)

(iii)

(iv)

(A) i > iii > ii > iv


(B) i > ii > iii > iv
(C) i > iii > iv > ii
(D) i > iv > ii > iii

6) If number of resonating structure for P1 and P2 are X & Y respectively.


Then (Y–X) has value.

(A) 6
(B) 4
(C) 3
(D) Zero

7) Correct basic strength order is :

(A) r > q > p > s


(B) r > p > q > s
(C) q > r > p > s
(D) r > q > s > p

8)
Both [X] and [Y] produce ink blue solution with H2O2 in presence of organic solvents and H2SO4, [X]
& [Y] respectively

(A)
(B)
(C)
(D)

9) Statement 1 : Permanganate titrations in presence of hydrochloric acid are unsatisfactory.


Statement 2 : Hydrochloric acid is oxidised to chlorine by paramagnate ion.
Statement–1 is true, statement–2 is true and statement–2 is correct explanation for
(A)
statement–1.
Statement–1 is true, statement–2 is true and statement–2 is NOT the correct explanation for
(B)
statement–1.
(C) Statement–1 is true, statement–2 is false
(D) Statement–1 is false, statement–2 is true.

10) Which of the following statement(s) is/are correct regarding complex ion [Co(en)2(NH3)2]3+
(I) Central metal is sp3d2 hybridised
(II) Complex ion shows geometrical as well as optical isomerism.
(III) It has two N–Co–N bond angles.

(A) I & II
(B) II & III
(C) Only II
(D) Only III

11) Select the correct statements?


(i) [Zn(gly)2] is optically active compound
(ii) [PdClBr(gly)]Θ exhibits geometrical isomerism
(iii) [IrBr4(en)]Θ exhibits cis trans isomerism
(iv) [RhCl2(NH3)4]+ number of stereo isomers is equal to number of geometrical isomers

(A) (i), (ii), (iv)


(B) (ii), (iii), (iv)
(C) (ii), (iii)
(D) (i), (iii), (iv)

12) At 373 K, a gaseous reaction


A(g) → 2B(g) + C(g) is found to be of first order. Starting with pure A, the total pressure at the end
of 10 min was 176 mm Hg and after a long time when A was completely dissociated, it was 270 mm
Hg. Then pressure of A at the end of 10 minutes was :

(A) 94 mm
(B) 47 mm
(C) 43 mm
(D) 90 mm

13) A certain reaction has rate constant(k) = 0.025 Ms–1 for the disappearance of A. What will be the
concentration of A after 15 sec. if the initial concentration is 0.50 M?

(A) 0.50 M
(B) 0.375 M
(C) 0.125 M
(D) 0.060 M

14) How many isomeric forms are possible for the octahedral complex,
[Rh(en)2(NO2)(SCN)]+ ?

(A) 8
(B) 10
(C) 12
(D) 14

15) Which of the following pair of complex/complex-ion is correct against to their indicated
properties-

–2 –4
(A) [Ni(CN)4] > [NiF6] – CFSE
(B) [Ni(CO)4] < [Fe(CO)5] – valence shell electrons on central metal ion.
–3 –3
(C) [Fe(CN)6] > [FeF6] – Number of unpaired electrons of central metal ion
–3 3–
(D) [Co(ox)3] > [Co(CN)6] – stability

16) The only incorrect information is

(A) In isothermal expansion of an ideal gas, internal energy of the gas remains unchanged.
(B) In adiabatic free expansion of a Vanderwaal gas, the internal energy of gas remains unchanged.
In adiabatic free expansion of an ideal gas, the initial and final temperature of the gas remains
(C)
same.
In adiabatic free expansion of a Vanderwaal gas, the initial and final temperature of gas will
(D)
remains same.

17) Rate constant k varies with temperature by equation , log k(min–1) = 5 – . We can conclude:

(A) pre–exponential factor A is 5 min–1


(B) Ea is 2000 kcal
(C) pre–exponential factor A is 105 min–1
(D) Ea is 9.212 cal

18) 10 mole of ideal gas expand isothermally and reversibly from a pressure of 10 atm to 1 atm at
300K. What is the largest mass which can be lifted through a height of 100 m (Take g = 10 m/s2, R
= 8 J mol–1K–1)

(A) 318.42 kg
(B) 55.2 kg
(C) 342.58 kg
(D) 58.55 kg

19) In a certain polytropic process the volume of argon was increased 4 times. Simultaneously, the
pressure is decreased 8 times. The molar heat capacity of argon in this process, assuming the gas to
be ideal, is :

(A) –1 cal/K-mol
(B) –1.5 cal/K-mol
(C) +2 cal/K-mol
(D) 1 cal/K-mol

20) For 2 moles of He(ideal gas), find the work done in a process where it is heated from 200 K to
400 K such that the enthalpy of the gas varies as : H = 10 V2 :-

(A) – 100 R
(B) – 200 R
(C) – 300 R
(D) – 400 R

SECTION-II

1) How many of the following compounds can exhibit tautomerism ?

(a) CH2 = CH – OH (b)

(c) (d)

(e) (f)

(g) (h)

(i) (j)

2) In how many options given below the value of Keq > 1


(i)

(ii)

(iii) CH≡CH + NaNH2

(iv)

(v)

(vi)

(vii)

(viii)

3) How many of the given compound can exhibit geometrical isomerism :

(1) (2)

(3) (4)

(5) (6)

(7)
(8)
(9) HOOC–CH=CH–COOH

(10)

4) Find the number of electrons in the non-axial d-orbitals of [NiCl4]2– .

5) How many of the following compound can be optically active ?


(a) [Co(en)2CIBr] (b) [Co(en)(NH3)2Cl2]+
(c) [Cr(NH3)4Cl2]+ (d) [Co(NH3)3Cl3]
(e) [Co(en)3]3+ (f) [Ni(dmg)2]
2–
(g) [Pb(EDTA)] (h) [Cr(ox)2(NH3)2]–
(i) [Cr(gly)3]

6) Consider the following first order decomposition reaction:


A4(g) → 4A(g)
The T1/2 of the above reaction based on following graph is
(log2 = 0.3)

7)
Give the answer of the following questions for the reaction product [X].
P. Maximum number of M–O bonds, the bond length are equal [M = Metal]
Q. What is the number of orbitals of each central metal involved in hybridisation by X.
R. What is the magnetic moment of the central metal ion.
S. How many peroxide linkage are there in the product formed by the reaction of [X] with H2O2 in
acidic medium.

8) For reaction A → B, the rate constant k1 = A1 and for the reaction X → Y, the rate
constant k2 = A2 . If A1 = 109, A2 = 1010 , = 1200 cal/mol and = 1800 cal/mol, then

the temperature at which k1 = k2 is . Find .


(Given; R = 2 cal/K-mol )

9) 200 L of a certain liquid is confined in insulated walls at the pressure of 100 atm. The pressure is
suddenly released and maintained to 5 atm by which the liquid expanded by 1 % against this

external pressure. For the process, the absolute value of in L-atm is.

10) 10 moles of an ideal gas is subjected to an isochoric process and a graph of log P (y–axis) vs log
T (x–axis) is plotted where P is in “atm” and T is in “Kelvin”. If volume of the container is 82.1 litre
then calculate sum of a, b and c.
[a = slope of curve, b = intercept on x–axis, c = intercept on y–axis]

PART-3 : MATHEMATICS

SECTION-I

1) y = tan–1 and then k is

(A) a
(B) 1
(C) –1
(D) 5a

2) If yx = xy, then is :

(A)

(B)

(C)

(D)

3) The function f(x) = maximum {1 – x, 1 + x, 2} is

(A) continuous at all point except x = ±1


(B) differentiable at all points
(C) differentiable at all point except x = ±1
(D) None

4) If xsinx + ycosx + xy – 4x = 0, then at x = 0 is-

(A) –4
(B) 4
(C) 8
(D) –8

5) If the function is differentiable, then the value of a2 + b2 is -

(A) 5
(B) 2
(C) 1
(D) 13

6) If f(x) = 2x3 + 7x – 5 and g(x) = f–1(x), then g′ (4) is equal to

(A)

(B)

(C)

(D) non existent

7) Let f(x) = 5 sgn (ex) – 4(x – 2)2/3. Then


[Note: sgn k denotes signum function of k.]

(A) f(x) is increasing in (2, ∞)


(B) f(x) is decreasing in (–∞, 2)
(C) f(x) has minima at x = 2
(D) f(x) has maxima at x = 2

8) The minimum distance of a variable point on the curve y = x2 – 4 from origin is :

(A)

(B)

(C)

(D)
9) Distance between points on the curve where tangents to the curve y2 – 2x3 – 4y + 8 = 0 pass
through (1, 2) is :

(A)

(B)

(C)

(D)

10) The slope of normal to the curve x = t2 + 3 t – 8, y = 2t2 – 2t – 5 at the point (2, –1) is :

(A)

(B)

(C)

(D)

11) Tangent from to y2 = x3 ; y > 0 touches at (a, b) then value of a + b is :

(A) 1

(B)

(C) –1
(D) 2

12) If f : , f(x) = sinx – cosx + kx + b increases in its domain then set of values of k is :

(A)
(B)
(C)
(D)

13) A light ray emanates from the point (1, 1) and upon reaching the point (λ, 0) on x-axis it gets
reflected and the reflected ray passes through (3, 2), then λ is equal to -

(A) 5

(B)

(C)

(D)
14) Value of λ for which the lines 3x–4y – 13 = 0, 8x – 11 y – 33 = 0 and 2x – 3y + λ = 0 are
concurrent is :

(A) –1
(B) –7
(C) 1/7
(D) 9

15) A variable line L passes through point of intersection of lines x + y – 3 = 0 and 2x + 3y – 1 = 0.


Locus of feet of perpendicular drawn from origin to the variable line will be

(A) x2 + y2 + 8x + 5y = 0
(B) x2 + y2 + 8x – 5y = 0
(C) x2 + y2 – 8x + 5y = 0
(D) x2 + y2 – 8x – 5y = 0

16) Consider the triangle ABC having vertex A(1, 1) and its orthocentre is (2, 4). Also side AB and BC
are members of the family of lines ax + by + c = 0, where a, b, c are in AP. Length of side AC is
(where a,b,c ∈ R)

(A)
(B)
(C)
(D) None of these

17) If ax + y – 16 = 0 and x + ay – 6 = 0 represent two adjacent sides of a rhombus whose diagonals


intersect at (3,5) then sum of possible value of a is :

(A) 4
(B) 2
(C) –2

(D)

18) Water is leaking at the rate of 2m3/sec from bottom of an inverted cone of semi-vertical angle
45°. If the rate at which periphery of water surface changes when the height of the water in the cone
is 2 metres is d m/sec, then |5d| is equal to :

(A) 4
(B) 5
(C) 6
(D) 7

19) Find the minimum value of


(A)

(B)

(C)

(D)

20) If f(x) = xex(1–x) then f(x) is :

(A)
increasing on
(B) decreasing on R
(C) increasing on R

(D)
decreasing on

SECTION-II

1) Determine the value of 3ea + 6b + c for which the function is continuous


at x = 0 is

2) If the tangent at any point P (4m2, 8m3) of x3 – y2 = 0 is also a normal to the same curve, then the
value of (9m2 + 3) is :

3) The slope of the tangent to the curve represented by x = t2 + 3t – 8 and y = 2t2 – 2t – 5 at the

point M(2, –1) is , then value of λ is ?

4) Y intercept of tangent to the curve x + y = xy, where it cuts x-axis is :

5) The number of possible straight lines passing through (2, 3) and forming a triangle with co-
ordinate axes, whose area is 12 sq. units is :

6) If line 3x + 4y + c = 0 touches the circle x2 + y2 – 2x – 2y – 2 = 0 then maximum possible value of


c is :

7) Area of the parallelogram bounded by the lines


2x – 3y – 1 = 0
2x – 3y + 4 = 0
x+y–2=0
x+y–6=0
is equal to :

8) If the function f(x) = 2x2 - ln x (where x > 0) is increasing in the interval (a, ∞), then the value of

will be ________.

9) The length of perpendicular from the origin on the normal to the curve 3x2 + 4y2 – 7xy = 0 at (4,
3) is:

10) If x + 4y is a normal to the curve y2 = αx3 – β at (2, 3), then the value of α + β is :
ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A B B A D A C D D A D B B D B A C C C

SECTION-II

Q. 21 22 23 24 25 26 27 28 29 30
A. 9 12 5 9 2 4 4 6 9 9

PART-2 : CHEMISTRY

SECTION-I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. D C A D C C B B A C A B C C A D C B A B

SECTION-II

Q. 51 52 53 54 55 56 57 58 59 60
A. 7 6 8 4 6 90 6402 3 5 1

PART-3 : MATHEMATICS

SECTION-I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. D B C B B A D C B B D B B B C A D B B A

SECTION-II

Q. 81 82 83 84 85 86 87 88 89 90
A. 7 5 6 1 3 3 2 5 5 9
SOLUTIONS

PART-1 : PHYSICS

1)

2) Since TIR occurs at surface AC, thus

1.5 sin θ = ⇒ sin θ =

Therefore

3) For lst case, f = = 20 cm

∴ (µg – 1) =


For 2nd case,

5) Deviation produced by one is cancelled by the other :


Use δ = A(µ – 1)

6) Length =

7)

v = –200cm

10) For lens,


u = –30, f = 20 cm

⇒ v = 60 m
for mirror,
u = – 40 cm, f = – 20 cm
v = – 40 cm
light ray retraces it is path.

11) using conservation of linear momentum


Mu = (M + mt) v1

13)
Fthrust – mg = ma
m = 5000 kg
a = 20 m/s2
⇒ Fthrust = 150000 N

Fthrust = Urel × ⇒ (–800) × = 150000

⇒ ≈ –187.5 kg/s

14)

By momentum conservation
mv = (M + m)v'

x=
v'2 = ω2 (A2 – x2)

15)

I ∝ mℓ2
I ∝ (4m) (2ℓ)2
I = 8I0

16) ∵ Moment of inertia about an axis passing through an end =

∴ Igiven system = + =

17)
b → daigonal

18)

200 × 2 = N × 7

N=

19) Block slides downward ie. block is in rotational equilibrium


Torque about the centre of mass of block
(∵ constant velocity ⇒ fr = mgsinθ)

20)

22) Images formed due to multiple reflection in mirrors AB and BC will lie on a circle centred
at B. Position of images are 1, 2, 3, 4, 5. Images due to reflections in BC and CA are 1', 2', 3', 4'
and 5'. Images due to reflections in AB and AC are 1", 2", 3", 4" and 5". 1 and 1", 1' and 5" and
5 and 5' coincide.
∴ Total number of images = 12.

23)

⇒ v1 = 30 cm
v = 5cm from second surface
∴ from first surface = 25 cm
∴ 5n = 2s ⇒ n = 5

24) When object is placed at the focus of the lens, i.e. at 22 cm from the lens, image will be
formed at infinity. Shift in the position of object.

25 – 22 =

⇒3= ⇒t=

25)

26)

=4

27) acom =

⇒ a = 4 m/s2

28)

m/sec.
29)

= 3Mv

for block B,
for block C, T – Mg = Ma

30)

I = area of F-t curve

=6×1+ × 1 × 6 = 9 Ns

PART-2 : CHEMISTRY

31)

32) (A) do not tautomerize.

(B)
(C)

(D)

34) In 'E'-isomer senior groups are present on opposite side.

39) Refer. NCERT (d & f-block)

40)
Co+3 → [Ar], 3d6
Hybridisation d2sp3 in presence of strong field ligand.
Total 15 N–Co–N bond angles

42) A → 2B + C
t=0 a 0 0
t = 10 a – x 2x x
t→∞ 0 2a a
a + 2x ∝ 176
3a ∝ 270
a ∝ 90
∴ 2x ∝ 86
x ∝ 43
a – x ∝ 90 – 43
a – x ∝ 47

43) For zero order reaction, apply Ct = C0 – kt

46) q = 0 , w = 0, ΔU = 0 = f(V,T)
As volume changes, temperature must change to maintain constant internal energy.

50) H α T ⇒ TαV2 ⇒ TV–2 = constant


⇒ PV–1 = cosntant = (K)


51) (a), (c), (d), (f), (g), (h), (j)

52) (iii), (iv), (v), (vi), (vii), (viii)

55) (a) Cis-isomer is op. active

(b) is op. active


(c) optically inactive.
(d) op. inactive
(e) always optically active
(f) square planar, optically inactive
(g) EDTA complexes are optically active
(h) 3 didentate ligands are always optically active
(i) same as (h)

56) A4(g) → 4A(g)


a 0
a–x 4x
Given a – x = 4x

or

57)

58) A → B

x→y

if k1 = k2
59) ΔE = Δq–w
ΔE = –w = –P [V2 – V1]
ΔE = –5 [2L]
ΔE = –10 L -atm

PART-3 : MATHEMATICS

61)

62)
⇒ x log y = y log x

63) f(x) = maximum {1 – x, 1 + x, 2}

f(x) = maximum {1 – x, 1 + x, 2}
Sharp corner at x = 1, –1
Non diff. at x = 1, –1

64) xsinx + ycosx + xy – 4x = 0; x = 0 ⇒ y = 0


⇒ xcosx + sinx + y'cosx – ysinx + xy' + y – 4 = 0
put x = y = 0

⇒ y' – 4 = 0 ⇒

65)
⇒ b = a = a ......(1)

1=a ......(2)
∴ a=1=b

66)
x=1
y=4

67) (x) = 5 – 4(x – 2)2/3

f'(x) = – 4 ×

X = 2 is point of maxima

68) Let point at minimum distance from O is


(h, h2 – 4)
∴ OP2 = h2 + (h2 – 4)2
∴ OP is min at h = ±

69) Let a tangent is drawn to the curve at point Q(α, β) on the curve which passes through P(1,
2).
Differentiating w.r.t. x,

2y – 6x2 – 4 =0

or =

Now, slope of line PQ =

or
or (β – 2)2 = 3α2(α – 1)
Also, (α, β) satisfies the equation of the curve. So,
β2 – 2α3 – 4β + 8 = 0 or (β–2)2 = 2α3–4
From equations (1) and (2), 3α2(α–1) = 2α3–4
or α3–3α2+4 = 0 or (α – 2)(α2 – α – 2) = 0
or (α – 2)2 (α + 1) = 0
When α = 2, (β – 2)2 = 12 or β = 2 ± 2
When α = –1, (β – 2)2 = –6 (not possible)
or (α, β)≡(2, 2 ± 2 )

70) For the given curve = at common t = 2, =

slope of normal is

71)

⇒ 3t3 = 2t3 + 1
⇒t=1
∴ P(1, 1)

72) f'(x) = k + cosx + sinx ≥ 0


k ≥ – (cos x + sin x)
k∈

73)
P, Q, R' are collinear

74) Point of intersection (11, 5)


2(11) – 3(5) + λ = 0
λ = –7

75)

m1m2 = –1


⇒ x2 + y2 – 8x + 5y = 0

76)
AB and BC are the family of lines
ax + by + c = 0 and a – 2b + c = 0
On comparing
⇒ (x, y) = (1, –2) = B
orthocentre of ΔAHB is C
C = (–17, 4)
altitude through H is y = 4
altitude through B is x + 3y + 5 = 0
length

77) Diagonals of rhombus are angle bisector of adjacent sides.


Equation of bisector of the sides are

⇒ ax + y – 16 = ±(x + ay – 6)
passes through (3,5)
⇒ 3a + 5 – 16 = ±(3 + 5a – 6)

∴ sum of values

78)

...(i)

Also

At r = 2,

79)

Consider two curves:


Minimum distance occurs along common normal
⇒Normal at P must pass through (0, 0)

80) We have,
f '(x) = ex(1–x) + x·ex(1–x)·(1–2x)
= ex(1 – x) [1 + x(1 – 2x)]
= ex(1–x)·(–2x2 + x + 1)
Now, the sign-scheme for –2x2 + x + 1 is

∴ f '(x) ≥ 0 if ex(1 – x) is always positive

So, f(x) is increasing on

81)
f(x) is continuous at x = 0
f(0) = b ...(1)

R.H.L. =

, c1/3 – 1 = 0 ⇒ c = 1

L.H.L. =
L.H.L. = R.H.L. = f(0)

ea = =b

3ea + 6b + c =
82) 3x2 – 2y . y' = 0

y' = = 3m
tangent : y – 8m = 3m (x – 4m2)
3

y – 3 mx + 4m3 = 0
taking intersection with curve
(m2, –m3)

slope of normal at (m2, –m3) =

= 3m
2
9m = 2

83) t2 + 3t – 8 = 2 ⇒ t = 2, –5
2t2 – 2t – 5 = –1 ⇒ t = 2, –1
So, at t = 2

84) Given curve is x + y = xy at x-axis y = 0,


0
∴x+0=x ⇒ x=1
∴ Point is A(1, 0)
Now to differentiate x + y = xy take log on both sides
⇒ log(x + y) = y logx

Putting x = 1, y = 0


Tangent y = –x + 1

85) y – 3 = m (x – 2)
x = 0, y = 3 – 2m

y = 0, x = 2 –

Δ = |3 – 2m) = 12
2
(3 – 2m) = ± 24m
4m2 – 12m + 9 = –24m
4m2 + 12m + 9 = 0
(i)
2
4m – 12m + 9 = 24m
4m2 – 36m + 9 = 0
(ii)
86) =2
c = 3 or –17

87) Area of the parallelogram formed by the lines


y = m1x + c1, y = m1x + c2
y = m2x + d1, y = m2x + d2
is given by

88) f(x) = 2x2 - ln x


For increasing f'(x) > 0

89) (x – y) (3x – 4y) = 0 ⇒ Normal is


4x + 3y = 25

90) y2 = αx3 – β

⇒ at (2, 3) = .
α = 2, β = 7

You might also like