13-04-2025

1803CJA101029250018 JA

PART-1 : PHYSICS

SECTION-I (i)

1) The uniform solid cylinder rolls without slipping in the system shown. If the maximum
compression in spring is 15cm, the possible friction force acting on the cylinder during its motion is

(A) 4N
(B) 10N
(C) 12N
(D) 15N

2) A particle of charge q and mass m moves rectilinearly under the action of an electric field E = α –
βx. Here, α and β are positive constants and x is the distance from the point where the particle was
initially at rest. Then :-

(A) the motion of the particle is oscillatory.

(B)
the amplitude of the particle is .

(C)
the mean position of the particle is at .

(D)
the maximum acceleration of the particle is .

3) An electron is placed just in the middle between two long fixed line charges of charge density +λ

each. The wires are in the xy plane (Do not consider gravity)

(A) The equilibrium of the electron will be unstable along x-direction.

(B) The equilibrium of the electron will be neutral along y-direction.
(C) The equilibrium of the electron will be stable along z-direction.
(D) The equilibrium of the electron will be stable along y-direction.

4) For the arrangement shown below, the two point charges are in equilibrium. The infinite wire is
fixed in the horizontal plane and the two point charges are placed one above and the other below the
wire. Considering the gravitational effect of the earth, then nature of q1 and q2 can be :-

(A) q1 → +ve, q2 → +ve

(B) q1 → +ve, q2 → –ve
(C) q1 → –ve, q2 → –ve
(D) q1 → –ve, q2 → +ve

5) An object of length 1 cm is placed on a principle axis of an equiconvex lens of radii 5 cm.

Distance between the lens and object is 20 cm. Space between the lens and object is filled with
medium of two different refractive index 2 and 1, lens being placed in the medium of refractive index
1. Boundary of both medium is mid-way between the object and lens as shown in figure.

(A) The image will be formed at distance of 7.5 cm from the optical centre
(B) The image will be formed at distance of 20/3 cm from the optical centre
(C) The size of the image is 0.5 cm
(D) The size of the image is 0.4 cm

6) There is a spherical glass ball of refractive index μ1 and another glass ball of refractive index μ2
inside it as shown in figure. The radius of the outer ball is R1 and that of inner ball is R2. A ray is
incident on the outer surface of the ball at an angle i1. Mark the correct options.
(A)
The value of r1 is

(B)
The value of r2 is

(C)
The value of r1 is

(D)
The value of r2 is

SECTION-I (ii)

1)

Match List I with List II and select the correct answer using the codes given below the lists :

List I List II
(Position of the object) (Magnification)

An object is placed at a distance f

(I) (P) Magnification is ∞
before a convex mirror

An object is placed at centre of

(II) (Q) Magnification is 0.5
curvature before a concave mirror

An object is placed at focus before a

(III) (R) Magnification is +1
concave mirror

An object is placed at a distance R

(IV) (S) Magnification is –1
before a convex mirror

(T) Magnification is 0.33

Codes :
(A) I → Q;II → S;III → P;IV → T
(B) I → P;II → S;III → R;IV → Q
(C) I → R;II → Q;III → P;IV → T
(D) I → Q;II → T;III → S;IV → R

2) A circular non-conducting ring has charge density λ = λ0 sinθ as shown in figure.

(Where θ is taken from positive x-axis in anticlockwise sense)

List-I (Point) List-II (Direction of electric field)

(I) A1 (P) Positive x-direction

(II) A2 (Q) Negative x-direction

(III) B3 (R) Positive y-direction

(IV) B4 (S) Negative y-direction

(T) Positive z-direction

(A) I → S;II → P;III → P;IV → Q
(B) I → R;II → T;III → R;IV → Q
(C) I → S;II → Q;III → P;IV → T
(D) I → S;II → S;III → R;IV → R

3)

A particle is suspended from a string of length R. It is given a velocity u = 3 at the lowest point.

List-I List-II
(I) Velocity at B (P) 7 mg
(II) Velocity at C (Q)
(III) Tension in string at B (R)
 (IV) Tension in string at C (S) 4 mg
(T) 5 mg
(A) I → R;II → P;III → Q;IV → S
(B) I → R;II → Q;III → P;IV → S
(C) I → S;II → Q;III → P;IV → R
(D) I → P;II → S;III → Q;IV → R

4) Pulleys, spring and string are ideal. Friction is absent every where then
(T = Time period of small oscillation of m)

List-I List-II

(I) (P)

(II) (Q)

(III) (R)
Solid cylinder of mass m & radius R no
slipping

(IV) (S)

(T)

(A) I → P;II → Q;III → R;IV → S

(B) I → Q;II → S;III → P;IV → R
(C) I → Q;II → S;III → R;IV → P
(D) I → P;II → Q;III → T;IV → S

SECTION-II

1) A small frictionless block slides with velocity on the horizontal surface as shown in the
figure. The block leaves the surface at point C. The angle then find x :

2) A massless spring is suspended from a hook at the top. A small mass of 180 gm is suspended from
the bottom of the hook. At the equilibrium it is at 20 cm from ground. It is pulled down to distance
15 cm from ground and released. Find the time (in sec) at which it is first at 25 cm from the ground.

[Take π2 = 10, g = 10 m/s2]

3) Two simple pendulum made of small masses m each are pulled to side as shown and released. The
collision is elastic. After what time (in sec) from the release will the left mass first reach point from

where it was released ? Length of both strings is 1m, take g = π2 m/s2.

4) Figure shows an irregular block of material of refractive index . A ray of light strikes the face
AB as shown in the figure. After refraction it is incident on a spherical surface CD of radius of
curvature 0.4m and enters a medium of refractive index 1.514 to meet PQ at E. Find the distance OE

upto two places of decimal.

5) A finite wire of charge density C/m is placed in gravity free space as shown in figure. A
particle of charge 10 nC and mass 3 gm is released from point P. The magnitude of initial
acceleration of particle is a × 10b m/s2 then is ....... :-

6) Two rays are incident on a spherical mirror of radius of R = 5 cm parallel to its optical axis at the
distance h1 = 0.5cm and h2 = 3cm. Determine the distance Δx(in cm) between the points at which
these rays intersect the optical axis after being reflected at the mirror.

7) What can be the maximum amplitude (in m) of the system so that there is no slipping between any

of the blocks

8) An object of mass 0.2 kg executes simple harmonic oscillational along the x-axis with a frequency
of (25/π) Hz. At the position x = 0.04, the object has kinetic energy of 0.5 J and potential energy 0.4
J. The amplitude of oscillations is_____ m. (Assume mean position to be at x = 0)

PART-2 : CHEMISTRY

SECTION-I (i)

1) For Fe4[Fe(CN)6]3 which option is correct.

(A) IUPAC name is Iron(III) hexacyanidoferrate(II)

(B) It has total 12 π bonds
(C) It has coordination number is 6
(D) Ionisation sphere has Fe3+ & coordination sphere has Fe2+ ions are present.

2) Study the following given figure (consider closed container) and pick out the correct option(s) of
the following :

(A) A white precipitate of AgCl is formed on AgNO3 side.

(B) A white precipitate of AgCl is formed on BaCl2 side.
(C) No precipitate is formed on either side.
(D) BaCl2 solution rises and that of AgNO3 solution falls in due course of time.

3) Correct statement among the following are :

2+
(A) [Co(NH3)5(SeCN)] shows linkage isomerism
(B) Tris(2,2'-bipyradine) ruthenium (II) ion is a diamagnetic complex
(C) IUPAC name of 'turnbulls blue' is iron (II) hexacyanoferrate (II)
(D) Hexachloridociprate (II) ion does not have equal bond length

4)

Identify correct statement/s.

(A) Vapour pressure is a colligative property

Freezing point of a solution containing non-volatile solute in liquid solvent is always lower than
(B)
that of the pure solvent
Acetic acid undergoes association in benzene. The molar mass of acetic acid, determined by
(C) elevation of boiling point of solution of acetic acid in benzene is always higher than its normal
molar mass
(D) Osmotic pressure measurements can be used for determination of molar mass of polymers

5)

Which of the following complexes NOT follow Sidgwick EAN rule ?

5
(A) [Fe(η -C5H5)2]
2
(B) K[PtCl3(η -C2H4)]
(C) [V(CO)6]
(D) [Mn(CO)6]
6) Which of the following is a halide ore?

(A) Cryolite
(B) Fluorspar
(C) Horn silver
(D) Limonite

SECTION-I (ii)

1) Match the ores listed in column I with the type of ores listed in column II and select the correct
alternate.

Column I Column II

(1) Bauxite. (p) Carbonate ore.

(2) Argentite. (q) Halide ore.

(3) Carnallite (r) Sulphide ore.

(4) Azurite. (s) Oxide ore.

(A) 1 → s;2 → r;3 → q;4 → p
(B) 1 → p;2 → s;3 → q;4 → r
(C) 1 → p;2 → q;3 → r;4 → s
(D) 1 → s;2 → r;3 → p;4 → q

2) Match the solution in Column I with its nature in Column II.

Column I Column II
P Benzene + Toluene 1 Non-ideal solution
Q Ethanol + Water 2 Ideal solution
R Benzene + Ethanol 3 ΔHmix > 0
S Acetone + Chloroform 4 ΔHmix < 0
(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 2;Q → 1;R → 3;S → 2
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 2;Q → 1;R → 3;S → 4

3) Match the column :

List-II
List-I
(Metals associated with the
(Metals)
given process)

(P) Sn (1) Liquation

(Q) Al (2) Self reduction

(R) Zn (3) Electrolytic refining

 (S) Pb (4) Poling

(5) Cupellation
(A) P → 1;Q → 3;R → 2;S → 1
(B) P → 3;Q → 4;R → 2;S → 2
(C) P → 1;Q → 3;R → 1;S → 4
(D) P → 4;Q → 3;R → 3;S → 1

4)

List-II
List-I
(Effective atomic
(Coordination Compound)
number)
(P) [Ni(CO)4] (1) 84
(Q) K3[Fe(ox)3] (2) 36
(R) [PtCl2(NH3)2] (3) 30
1 3
(S) [Ti(η -C3H5)2(η -C3H5)2] (4) 38
(5) 35
(A) P → 4;Q → 1;R → 5;S → 3
(B) P → 3;Q → 1;R → 5;S → 3
(C) P → 2;Q → 5;R → 1;S → 3
(D) P → 5;Q → 1;R → 2;S → 4

SECTION-II

1) Among the following X is the number of polar protic solvent and Y is the number of polar aprotic

solvent report your answer as .

(i) DMSO (ii) H2O (iii) DMF (iv) CH3COOH (v) HMPA
(vi) Acetone (vii) ROH (viii) DMA (ix) CCl4

2) Among the following, total number of metals are extracted by self reduction method ?
Pb, Zn, Cu, Mg, Hg, Fe, Al, Au

3) The observed and normal masses of compound MX2 are 65.6 and 164 respectively. The percent
degree of ionisation of MX2 is _________%. (Nearest integer)

4) The Vent Hoff factor (i) for a dilute solution of K3[Fe(CN)6 is (Asuming 100% ionisation):

5) Ratio of the total number of isomers of Benzene hexachloride to that of K[Co(NH3)2(F)2(Cl)2] is:

6) How many of the following compounds written as R-(l.g) are considered having good leaving
groups in nucleophilic alkyl substitution reactions ?
7) EDTA4– is ethylenediaminetetraacetate ion. The total number of N–Co–O bond angles in
[Co(EDTA)]–1 complex ion is

8) How many of the following solutions show negative deviation from Raoult's Law?
Liquid A + Liquid B
(i) (CH3)2CO + CS2
(ii) CCl4 + C 6 H6
(iii) CCl4 + CHCl3
(iv) H2O + C2H5OH
(v) (C2H5)2O + (CH3)2CO
(vi) CH3COOH + C5H5N (pyridine)
(vii) C6H5NH2 + (CH3)2CO
(viii) C6H5Cl + C6H5Br
(ix) Cyclohexane + Ethanol

PART-3 : MATHEMATICS

SECTION-I (i)

1) f(x) = sin–1x + cos–1x + cot–1x and g(x) = sec–1x + cos–1x + tan–1x, then

(A)
Range of f(x) is

(B)
Range of f(x) is

(C)
Range of g(x) is

(D)
Range of g(x) is

2)
where a, b, c, ℓ ∈ R then

(A)
a=
 b=
(B)

(C)
c=

(D)

3) If cos–1x + sin–12x = and

sin–1y + cos–12y = then

(A)

(B)

(C)

(D)

4) Let , (where [x] denotes Greatest Integer function), then

(A)

(B)

(C)

(D)

5) f(x) = x2 – 2x + 3, f:A→ [2, ∞) where f is bijective function. If g(x) is inverse of f(x) then

(A)
(B)
(C)
(D)

6) If then

(A)

(B)

(C)
(D)

SECTION-I (ii)

1)

List-I List-II

Number of integral solution(s) for which

(I) (P) 0
sin(x) > in [0, 2π], is/are

Number of integral solution(s) for which

(II) (Q) 1
log2(cosx) < in [–π, π], is/are

Number of integral solution(s) for which

(III) (R) 2
tan(x) > in [0, 2π], is/are

Number of integral solution(s) for which

(IV) (S) 3
cosec2(x) < 2 in [π, 2π], is/are

(T) 4
(A) I → R;II → Q;III → P;IV → R
(B) I → R;II → T;III → P;IV → Q
(C) I → R;II → Q;III → R;IV → T
(D) I → S;II → Q;III → P;IV → R

2)

List-I List-II

(I) Value of (P) 0

(Where [.] denotes G.I.F.)

Maximum value of 32cosθ.642sinθ is (4)2k,

(II) (Q) 1
then is

If cot = , where
(III) (R) 2
a < b < c < d then value of a + d – b – c
is

(IV) (S) 3
Value of is

(T) 4
(A) I → P;II → S;III → Q;IV → T
(B) I → P;II → S;III → Q;IV → R
(C) I → Q;II → T;III → P;IV → R
(D) I → P;II → R;III → T;IV → S

3) List-I contains function and List-II contains their points of discontinuity. Match the List-I and List-
II. (where [.] denotes Greatest integer function and {.} denotes Fractional part function)

List-I List-II

(I) f(x) = [x2] (P)

(II) g(x) = [ex] (Q) x=

(III) (R)

(IV) h(x) = [x] + {2x} (S) x = ℓn2

(T)

(A) I → P;II → Q;III → R;IV → S

(B) I → Q;II → S;III → T;IV → P
(C) I → P;II → T;III → Q;IV → S
(D) I → R;II → S;III → P;IV → Q

4) Match the List-I and List-II. (where [.] = Greatest integer function and {.} = Fractional part
function.)

List-I List-II

(I) (P) 0

(II) (Q) 1

(III) (R) 2

(IV) (S) –2

(T) 3
(A) I → R;II → R;III → P;IV → S
(B) I → P;II → Q;III → R;IV → S
(C) I → T;II → S;III → P;IV → R
(D) I → S;II → P;III → Q;IV → T

SECTION-II

1) The number of solutions of sin2x + (2 + 2x – x2)sinx – 3(x – 1)2 = 0, where –π ≤ x ≤ π, is

2) If f(x) = [3 sinx] , f : [0, π] → R and g(x) = {2x} , g : [0, 3] → R

then sum of number of points of discontinuity of f(x) and g(x) is equal to ______
(where [.] = Greatest integer function , {.} = Fractional part function)

3)

4) If , where , then number of

values of 'x' is equal to

5) Let f(x) is an even periodic function with period = 4 and f(x) = x2, x ∈ [0, 2] then number of
solutions of f(x) = 1 for x ∈ [0, 20] is equal to

6) If [x] denotes greatest integer function of x , then value of [sin–1(sin10) + cos–1(cos10) +

tan–1(tan10)] is equal to

7) If , then the value of a2 + b2 = ______

8) Let , where f(x) is continuous at x = 0

and then value of is equal to ________

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,B A,B,C,D A,B,C B,C A,C A,B

SECTION-I (ii)

Q. 7 8 9 10
A. A D B B

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 6.00 0.50 0.66 to 0.67 6.05 to 6.07 2.00 0.60 to 0.63 1.00 0.06

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A,C,D C,D A,B,D B,C,D B,C,D A,B,C

SECTION-I (ii)

Q. 25 26 27 28
A. A D D C

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 35.00 3.00 75.00 4.00 1.50 7.00 8.00 2

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. B,D A,B,C,D A,C A,B,C A,D A,B,C

SECTION-I (ii)

Q. 43 44 45 46
A. A B B C
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 2.00 11.00 2.50 3.00 10.00 2.00 17.00 20.00
 SOLUTIONS

PART-1 : PHYSICS

1) F1 – f = 3a

fR=
F1 = 4.5a

a=

f= × 30 = 10N

Alternative : fmax = = 10N

2) ...(1)

a = 0 at
Equation (1) can be written as

v = 0 at x = 0 and

So, the particle oscillates between x = 0 and with mean position at .

Maximum acceleration of the particle is at extreme positions (at x = 0 or ) and

.
[From equation (1)]

3) Along × axis
If displaced slightly towards right
 ;
F2 > F1 ⇒ Net force towards right
⇒ Unstable equilibrium
Along y-axis :-

Along y axis it will remain in equilibrium upon displacing so neutral equilibrium.

Along z-axis :-

If electron is displaced in z direction then it will experience net force towards its initial
position.
So stable equilibrium.

4) Just draw the FBD of both charge particles and see whether force can be zero or not, on the
particles.

5)
6) μ1 sin r1 = sin i1 ⇒ r1 =

sin i2 = sin r2; = sin r2; r2 =

8)

9) For (A) – 2gR = 9gR – 2gR = 7gR ⇒

For (B) –2g(2R) = 5gR ⇒

For (C) = = 7mg

For (D) TC + mg = ⇒ TC = 4mg

11)
–ΔU = ΔK

mg r (1 – cos θ) = ....(1)

mg cos θ = ....(2)

12)

A = 5 cm
kx0 = mg
k=

T= = 1 sec.

t=

13)

= Same for both.

⇒ collision at mean position of the bobs.
⇒ velocities are exchanged
⇒ Amplitude are exchanged
Aleft bob = 6°

sec

14) Applying Snell's law on face AB

or
i.e. ray becomes parallel to AD inside the block.

Now applying, on face CD,

Solving this equation we get OE = 6.06 m

15)
 16)

17) a = ω2A
f1 = (1)ω2A ≤ 6.....(1)
f2 = 3ω2A ≤12
ω2A ≤ 4 ....(2)
2
⇒ωA=4

18) mv2 = mw2(a2–x2) = 0.5 and mω2x2 = 0.4

= 0.06 m

PART-2 : CHEMISTRY

19)

(A) IUPAC name is Iron (III) hexacyanido ferrate (II)

(B) One CN contain 2π-bonds and there are 18CN ligands total in whole molecule.
So total number of π-bonds are 36.
(C) Co-ordination number = 6. Since in complex [Fe(CN)6]4–
One Fe (central metal atom) is coordinated by 6 ligand of CN– anion.
(D) Fe4[Fe(CN)6]3
Ionization sphere
↑
Fe3+[Fe(CN)6]4
↓
Co-ordination sphere
Fe + 6X(–1) = –4
Fe = +2
Fe+2 from co-ordination sphere.
So only (B) option is incorrect.

22)

(A) is a colligative property.

(B) Entropy of solution is more than entropy of pure solvent.
(C) Due to association molar mass increases.
(D) Larger value of osmotic pressure is easily measurable.

25)

(1) Bauxite is Al2O3.2H2O.

(2) Argentite is Ag2S.
(3) Carnallite is KCl.MgCl2.6H2O.
(4) Azurite is Cu(OH)2.2CuCO3

26) Analysis of Solutions:

A. Benzene + Toluene

A. Both are non-polar hydrocarbons with similar structures and weak van der Waals
forces.

B. They form an ideal solution.

C. (P → 2)

B. Ethanol + Water

A. Strong hydrogen bonding occurs, leading to negative enthalpy of mixing (ΔHmix <
0).

B. (Q → 4)
 C. Benzene + Ethanol

A. Ethanol is polar, whereas benzene is non-polar, leading to weaker interactions.

B. This results in positive enthalpy of mixing (ΔHmix > 0), making it a non-ideal
solution.

C. (R → 3)

D. Acetone + Chloroform

A. Strong hydrogen bonding occurs between acetone (C=O) and chloroform (CHCl₃),
releasing energy.

B. This results in ΔHmix < 0.

C. (S → 1)

Final Matching:
Column I (Solution) Column II (Nature)
P: Benzene + Toluene 2 (Ideal Solution)
Q: Ethanol + Water 4 (ΔHmix < 0)
R: Benzene + Ethanol 3 (ΔHmix > 0)
S: Acetone + Chloroform 1 (Non-ideal Solution)

Final Matching:Correct Answer:

(4) → 2 4 3 1 ✅

30) Pb, Cu, Hg Can be extracted by self-reduction

31)

MX2 → M+2 + 2X–

α = 0.75
percent dissociation = 75%
 33) Total number of isomers of B.H.C. = 9
Total number of isomers of K[Co(NH3)2(F)2(Cl)2] = 6

PART-3 : MATHEMATICS

37)

Domain of f(x) is [–1,1]

so range of f is to
Domain of g(x) is x = ±1 only

38)

then a + c – 1 = 0
a+b=0

39) ⇒

⇒ 3x2 = 1 – x2

40)
41)

y = x2 – 2x + 3
⇒ x = y2 – 2y + 3 ⇒ (y – 1)2 = x – 2

if
if

42)

45)

[x2] is discontinuous at x =
[ex] is discontinous at x = ℓn2

{2 sinx} is discontinuous at

[x] + 2{x} is discontinuous at

46)

(I) ,

(II)

(III)

(IV)

47) sin2x – (x2 – 2x – 2)sinx – 3(x – 1)2 = 0

sin2x – (x – 1)2)sinx – 3(x – 1)2 = 0

roots :
sinx = –3 (reject) or (x – 1)2
sinx = (x – 1)2
48)

0 < 3sinx < 3, for x ∈ [0,π)

Discontinuous for 3 sinx = 1,2,3
⇒ 5 points
0 < 2x < 6 for x ∈ [0,π]
Discontinuous for 6 points

49)

50)

x2 = 1 ⇒ x = ±1
solution are x = 0,1,–1

51)
two solutions in [0,4] ⇒ 10 solution

52)

[3π –10 + 4π – 10 + 10 – 3π]

= [4π – 10] = 2

53)
a = 1, –b = 4 ⇒ b = –4
a2 + 52 = 17

54)
using sandwich