08-06-2025

4001CJA101021250014 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A particle starts from point 'A' reaches to B in a uniform circular motion. Find angular
displacement of the particle (during which it reaches from A to B ) as seen from centre:- (if AC line

is diameter)

(A)

(B)

(C)

(D)

2) A particle is attached at one end of massless rod whose other end is fixed at O as shown in figure.
A particle is given minimum velocity at lower most point to complete vertical circular motion about

O. Find net force on the particle when it is at position P. Length of rod is ℓ. .

(A)

(B)

(C)

(D) None of these

3) Two conducting shells of radii r and 5r are arranged as shown in figure. If charge –Q is given to
outer shell then charge on inner shell which is grounded is

(A)

(B)

(C) +Q
(D) -Q

4) Two short electric dipoles are placed as shown. The energy of electric interaction between these

dipoles will be

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) In the figure shown ground is smooth, whereas surface between 10 kg block and 5 kg block is
rough. A force of magnitude 30 N is applied on 10 kg block, horizontally. If net work done by friction
on the system (on 10 kg and 5 kg blocks) in any time frame is zero, then cofficient of friction

between 10 kg and 5 kg can be :

(A) 0.1
(B) 0.3
(C) 0.4
(D) 0.6
2) A cylinder with radius R spins about its horizontal axis with angular speed ω. There is a small
block lying on the inner surface of the cylinder. The coefficient of friction between the block and the
cylinder is µ. Find the possible values of ω for which the block remains at rest with respect to the

cylinder. Take R = 1 m, µ = 0.2.

(A) 5 rad/s
(B) 8 rad/s
(C) 12 rad/s
(D) 3 rad/s

3) A cavity is taken out from a uniform conducting sphere. Inside the cavity a dipole is placed as
shown in the figure. Find which of the following is/are true ? (Given : q = 10–1C, ℓ = 0.1 mm, θ = 30°,

d = 10 cm, R = 12 cm)

(A) Potential at points A and B are same

(B) Potential at points A and B are different
(C) Potential at point P is 0 volt.
(D) Potential at point P is 2 volt.

4) A charged particle q is placed at a distance d from the centre of conducting sphere of radius R
(<d), then in static condition at the centre of sphere :

(A)
magnitude of electric field due to induced charge is

(B)
magnitude of electric field due to induced charge is
(C) magnitude of electric field due to induced charge is zero.

(D)
magnitude of electric field due to charge q is (where )
5) A bead of charge +q and mass m is threaded on a smooth fixed horizontal circular frame of radius

R. An infinite vertical line charge of charge/length λ passes through its plane at a distance from
the center. The bead is slightly displaced and it moves on the circular path. Choose the correct

statement(s) :-

(A)
The maximum speed of the bead is

(B)
The maximum speed of the bead is

(C)
The initial normal force on bead is
The normal force in radial direction at maximum speed is
(D)

6) A graph between x-y coordinates is given for a particle moving in x-y plane from point A to point

B. Which of the following option(s) are INCORRECT?

(A) This graph represents path of the particle.

(B) Particle does not change it's direction during the motion.
(C) Average velocity from A to B is zero.
(D) Particle travels in a straight line.

SECTION-II

1) A car starts with constant acceleration a = 2 m/s2 at t = 0. Two coins are released from the car at
t = 3 & t = 4 seconds. Each coin takes 1 second to fall on ground. Then the distance between the
two coins (in metre) will be : (Assume coin sticks to the ground)
2) A block and wedge released from rest from given situation, All surfaces are smooth. It is observed
that acceleration of wedge is 5 m/s2 along horizontal direction with respect to ground and
acceleration of block P, m/s2 with respect to ground. Find n. (g = 10 m/s2)

3) A particle is thrown horizontally with an initial speed of 5 m/s at t = 0. If the angular velocity of its

velocity vector at time t = 2 is , then find the value of 'n'. [Take : g = 10 m/s2 & neglect air drag]

4) A long uniformly charged wire with linear charge density coulomb/m is placed in the form
of a spiral of outer radius R = 1m and having a total N = 160 turns as shown in figure. A dipole of
dipole moment is placed along x-axis at point (a, 0, 0). Find the magnitude of

force (in N) experienced by dipole (in nearest integer)..

5) In the given figure a charge ‘q’ is placed at Then electric flux through the given

triangular face is then (n + m) is :

6)

A particle is given a certain veloicty v at point P as shown on a hemispherical smooth surface. The
value of v in m/s, such that particle when reaches Q the normal reaction of surface is equal to
particle's weight, is [R = 1.6 m, g = 10 m/s2]

7) A charged non conducting ring has quadrants with different charges uniformly distributed as

shown. If is net dipole moment of this system then find the value of α.

8) In given two cases two concentric conducting spherical shells are arranged as shown. In case-1
when switch S1 is closed energy loss is Q1. In case-2 when switch S2 is closed energy loss is Q2 then

find Q1 – Q2

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which of the following is the most appropriate set of reagents for the following conversion ?

+
(A) (i) H3O ; (ii) conc.H2SO4 ; (iii) Δ
(B) (i) O3/Zn-H2O ; (ii) LAH ; (iii) Al2O3/Δ
(C) (i) O3/H2O ; (ii) NaOH/CaO ; (iii) Δ
(D) (i) Br2/CCl4 ; (ii) alc.KOH ; (iii) LAH

2) Which of the following element of symmetry is present in cis–decalin ?

(A) C2
(B) Ci
(C) Both of these
(D) None of these

3)
Each curve is for titration of 10.0 mL of a 1.0 M acid with 1.0 M NaOH.
What is the correct order of pKa values ?

(A) pKa1 > pKa2 > pKa3 > pKa4

(B) pKa1 < pKa2 < pKa3 < pKa4
(C) pKa1 = pKa2 = pKa3 = pKa4
(D) Can't be determined

4) Find the complex which has maximum number of stereoisomers -

(A) [Ma3b3]
(B) [Ma3b2c]
(C) [Ma2b2c2]
(D) [M(AA)a2b2]

SECTION-I (ii)
1) Which of the following statements is/are correct regarding chlorination of methane?

(A) Methane and chlorine do not react in the dark at room temperature.
(B) Reaction takes place readily, however, in the dark at temperatures over 250°.
When the reaction is induced by light, many (several thousand) molecules of methyl chloride
(C)
are obtained for each photon of light that is absorbed by the system.
The presence of a small amount of oxygen slows down the reaction for a period of time, after
(D)
which the reaction proceeds normally.

2)
At low temperatures, where collision energies are small, two isomeric forms of 'G' have been isolated
by crystallization–'X' (can undergo dehalogenation & dehydrohalogenation) & 'Y' (can undergo
dehalogenation but not dehydrohalogenation).
Which of the following statement(s) is/are correct ?

(A) 'X' is optically inactive.

(B) 'Y' is optically inactive.
(C) 'X' on dehalogenation can give trans alkene.
(D) 'Y' on dehalogenation can give trans alkene.

3) Which of the following compounds is/are not resolvable ?

(A)

(B)
(C)

(D)

4) For titrating 40.00 mL of 0.1000 N NH3 with a solution of 0.1000 M HCl, which of the following
indicators is/are best suited:

(A) Phenolpthalein
(B) Methylorange
(C) An indicator with dissociation constant: 2 × 10–8
(D) An indicator with pKIn = 5

5) Correct statements regarding the complex [Co(NH3)2(H2O)2ClBr]NO3 is.

(A) It has six geometrical isomers

(B) It has four optically active isomers
(C) It has two ionisation isomers and one hydrated isomers
(D) It has linkage isomer

6) H2CO3 ionizes as :

The correct information(s) related with

solution is/are

(A) The degree of hydrolysis of is 0.02

(B) pH of solution is 2.0
(C) pOH of solution is 2.0
(D)

SECTION-II

1) The order: Methane < Ethane < Propane holds from for how many of the following properties ?
(i) Melting point (ii) Boiling point (iii) Density (iv) Heat of combustion (per
mole)
(v) Rate of halogenation (vi) Volatility

2) A certain hydrocarbon A was found to contain 87.8 percent Carbon and 12.2 present Hydrogen.
This compound consumes 1 molar equivalent of Hydrogen to give a compound B which doesn't
decolourise 5% solution (by weight) of Br2 in CCl4. But 1 g of hydrocarbon A just decolourises 39.02
g of the same solution.
How many compounds (including stereoisomers) are possible which fit the given description of
compound A and yield 1–Bromo–1–methyl cyclopentane as a major product on acid catalysed
hydrobromination ?

3) For the following compounds:

(A) (B)

(C) (D)
'X' = π–bonds with 'E' configuration.
'Y' = Number of chiral centres with 'R' configuration.
Find the value of X × Y.

4) The polarimeter reading in an experiment to measure the rate of inversion of can sugar (1st order
reaction) were as follows.

Time(min.) 0 30

Angle (degree) 30 20 –15

(Use: log35 = 1.54, log3 = 0.48, log2 = 0.3)
Calculate the time (in second) when the mixture will become optically inactive.

5) Number of species that has involved in bonding amongst the following:

[Cu(NH3)4]SO4, K4[Fe(CN)6], [Co(C2O4)3]Cl3, [NiCl4]2–, [PtCl4]2–, [Ni(CN)4]2–, [Ni(Co)4]

6) An environmental chemist needs a carbonate buffer of pH 10.00 to study the effects of the acid
rain on limestone–rich soils. How many grams of Na2CO3 must she add to 1.5 L of freshly prepared
0.20 M NaHCO3 to make the buffer? Ka of HCO3– is 4.7 × 10–11.
Write your answer after rounding off to the closest integer.

7) Find the concentration of Ag+ ions in 0.01 M AgNO3 that is also 1.0 M NH3 ?
Kd(Ag[NH3]2+) = 5.88 × 10–8 ; Ksp(AgCl) = 1.8 × 10–10.
If [Ag+] is x × 10–10 M, mark 'x' (closest integer).

8)

Find the number of complex following sidwick EAN rule :

[Ag(CN)2]¯, [HgI4]2–, [Ti(CO)6]2–, [Ti(σ – C5H5)2 (π – C5H5)2]°, [Fe(CN)5NO]2–

PART-3 : MATHEMATICS

SECTION-I (i)

1) If f(x) = –1 + ax +a neither touches nor cuts the curve f(x) = ℓnx, then minimum value of a may lie
in :

(A)

(B) (e, e2)

(C)

(D) none of these

2) If A(z1); B(z2) and C(z3) are vertices of a triangle such

that and and then area of ΔABC is k. Let z4, z5 ∈ C such
that . If and . The value of is q. The value of 4k + q is
:

(A) 27
(B) 25
(C) 35
(D) 45
3) Let P(α, 0) be a variable point lying on the positive x-axis such that three distinct secants can be
drawn from P to the circle x2 + y2 = 1, with property that each corresponding chord is bisected by
the curve y2 = 4x. If α ∈ (a, b) then a + b is :

(A)

(B)

(C)
(D)

4) Let and If

then

(A) Number of divisors of N is 169

(B) Number of divisors of N is 256
(C) Number of divisors of N which are perfect squares is 49
(D) Number of divisors of N which are perfect cubes is 16

SECTION-I (ii)

1) Let and be two fixed points on xy plane and R(h, k) is a point such that PR :
QR = k (k ≠ 1) and locus of R for different values of k be curves S1, S2 … Further
let be circles such that Si is orthogonal of Let number of common tangents of Si and Sj (i ≠
j) is ‘m’ and number of common tangents of S i′ and Sj′ (i ≠ j) is ‘n’ then m+n may be :

(A) 2
(B) 4
(C) 6
(D) 8

2) A circle C1 touches the circle at A internally and the curve at B

and C externally. If ΔABC formed is equilateral then which of the following are true.

(A)

(B)
radius of

(C)
AB =
(D)

3) If lies inside or on the triangle ABC, where equation of AB is x+y = 3, BC is y+m1x

=0; and AC is ; then :

 for and
(A)

(B) for and

for and
(C)

(D) for and

4) If from a point P(z1) on the curve |z| = 2, pair of tangents are drawn to the curve |z| = 1 meeting
at Q(z2) , R(z3) then (where z1, z2, z3 are complex numbers)

(A)
complex number will lie on the curve |z| =1

(B)

(C) orthocentre will lie on curve |z|=1

(D)
, where n ∈ I

5) Which of the following are correct ?

(A)
If α1, α2, α3 ……, α2018 are all the 2018th roots of unity then is 7
(B) The number of common roots of and z315 = 1 is 45
If (α, β) is a point on the circle whose centre is on x-axis and which touches the line x+y = 0 at
(C)
(2, –2) then greatest value of α is
Let a circle S whose centre is (h, k); k > 0 touches a line pair 4xy – 3y2 + 12 – h = 0 at A and B.
(D)
If ‘r’ is radius of circle ‘S’ then r + k may be equal to 12

6) Consider a tetrahedron dice that has four integers 1, 2, 3, 4 written on its faces. Roll the dice
2000 times and for each j = 1, 2, 3, 4, let f(j) represents the number of times j is written on the
bottom face. Let A denotes total sum of numbers on the bottom face for these 2000 rolls. If A4 =
6144 f(1) f(2) f(3) f(4) and g(x) is a polynomial such that g(x) = 0 has all real roots. If a, b, c, d ∈ R
and i = iota, let g(x) = x4+ (f(1) – d)x3 + (f(2) – c)x2 + (f(3) – b)x + (f(4) – a). Given |g(i)|=1. Then

(A) a = 240
(B) a = 260
(C) d = 980
(D) g(–2) = 18
 SECTION-II

1) If a circle C0 with radius 1 unit touches both the axes as well as line L1 (L1 passing through P(0, 4)
and cutting x-axis at (x1, 0)). Again a circle C1 of same radius is drawn touching x-axis, line L1 and
another line L2 (L2 passing through P(0, 4) and cutting x-axis at (x2, 0)) and this process is repeated n

times. The x-coordinate of the center of C2 is α and is β then 4(α + β) is :

2) A square ABCD of a diagonal 2a is folded along the diagonal AC so that the planes DAC, BAC are
at right angle. The shortest distance between DC and AB is ka then [4k2 ] is : (where [ ] denotes
Greatest integer function)

3) A point D is taken on the side AC of an acute triangle ABC such that AD = 1, DC = 2 and BD is an
altitude of ΔABC. A circle of radius 2 which passes through points A & D touches the circumcircle of

ΔBDC at point D. If area of ΔABC is N then is :

4) The graphs of and intersect at

four points. The sum of distances from these four points to the point (–3, 2) is 10 k then k is equal to
:

5) The roots of the equation (where a and b are complex numbers)

are the vertices of a square, then find the value of |2b – 13a| .

6) The line x + 2y = a intersects the circle x2 + y2 = 4 at two distinct points A and B. Another
line 12x – 6y – 41 = 0 intersects the circle at two another distinct points
C and D. The value of |a| for which the points A, B, C and D are concyclic.

7) Let A(z1), B(z2), C(z3) be the affixes of ΔABC on the circle (A, B, C in anticlockwise
sense). If the internal bisectors of ∠B and ∠C meet the circle at P(z) and Q(z') respectively such that

. If be the excentres of ΔABC opposite to ∠B and ∠C respectively then

I2I3 is?

8) On the side AB and BC of a ΔABC, squares with centres D and E are made such that points C and
D lie on same side of line AB and points A and E lie on opposite sides of line BC. If A, B, C are
represented by 1, ω, ω2 respectively then the angle between AC and DE is θ, find tan2 θ
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. C C A B

SECTION-I (ii)

Q. 5 6 7 8 9 10
A. B,C,D B,C A,C A,D B,C,D B,C,D

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 9 3 17 1 9 4 4 0

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22
A. B A A C

SECTION-I (ii)

Q. 23 24 25 26 27 28
A. A,B,C,D A,D A,C,D B,D A,B A,C,D

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 3 3 18 7200 0 15 6 3

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40
A. A C D C

SECTION-I (ii)

Q. 41 42 43 44 45 46
A. A,C B,C,D A,B,C,D A,B,C,D B,C,D A
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 39 5 9 4 60 2 6 1
 SOLUTIONS

PART-1 : PHYSICS

1)

angle is measured from centre not C.

2)

mgl(1 – cos 37°) = – 4gℓ

∴ gl = – + 2gℓ

∴ v2 =

Fnet = =

3)

4)

U= –PE11

5)

acommon =
Freq to move = 5 × 2 = 10 N
µN ≥ 10
µ 50 ≥ 10

µ≥
µ ≥ 0.2

6)
N = mg cos θ = mω2R
N = mω2R + mg cos θ
fr ≥ mg sin θ
µ(mω2R + mg cos θ) ≥ mg sin θ

ω2R =

ω=

7)

Surface of conductor is equipotential.

vp = 0
Net outer surface charge is zero.

8)

⇒ Esp =

9) Ui + Ki = Uf + Kf

10) x-y graph represents path of the particle. Average velocity from A to B is not zero because
displacement of particle along x is not zero.

11)

Speed of Car at t = 3 is 6 m/s

so distance travelled by coin = 6 × 1 = 6m
speed of Car at t = 4 is 8 m/s
so distance travelled by coin = 8 × 1 = 8m
distance travelled by car during 3 to 4 sec

S=6×1+
so distance between coin
(7 + 8) – (6) = 9m

12)
a1 = g sin 37º by using wedge constant
= 6 m/s2 a2 = 5 sin 37° = 3 m/s2
So acc. of block =
=

13) at t = t

at t = 2 : tan θ =
tanθ = 4

cosθ = ⇒ sec2θ = 17

⇒ =
ω=
n = 17

14)

15)

16)

17)
 18) Case-1 :

Case-2 :

PART-2 : CHEMISTRY

19)

20) Cis–decalin has a C2 passing through common edge of 2 six–membered rings.

21) pH of equivalence point increases as acidic strength decreases.

22) Max) Stereo isomer at Ma2b2c2 are 6.

23) FR mechanism explains all the observations.

24)
25) Interconversion of enantiomers causes optically active compounds to be non–resolvable.

26) pH at equivalent point 5.27

27)

[Co(NH3)2(H2O)2ClBr]NO3
Isomerism
[Ma2b2cd]

Optically active Optically active

6 geometrical isomers
+
2 enantiomers compound
(A & B) are correct
8 stereoisomers.
(C) 3 Ionization isomers
[Co(NH3)2.(H2O)2Cl.Br] NO3
[Co(NH3)2.(H2O)2Cl.NO3]Br
[Co(NH3)2.(H2O)2NO3Br]Cl
(D) [Co(NH3)2.(H2O)2Cl.Br]NO3
It does not have linkage isomer.
So only A & B are correct.

28)

29) Density: Methane > Ethane > Propane

30)

31) X = 6 and Y = 3.

32)

= 250 × 0.48 min.

= 120 min.
= 7200 sec.

33) No species that has involved in bonding.

34) Solving for the buffer-component concentration ratio:

Calculating the amount (mol) and mass (g) of Na2CO3 that will give the needed 0.47 : 1.0 ratio:

Amount (mol) of NaHCO3 =

Amount (mol) of Na2CO3 = 0.30 mol NaHCO3 ×

= 0.14 mol Na2CO3

Mass (g) of Na2CO3 = 0.14 mol Na2CO3 × = 15 g Na2CO3

35) AgNO3 + 2NH3 → Ag(NH3)2+ ....Initial conc.

0.01M 1M 0
0 (1–0.02)=0.98M 0.01 M ....at eq.conc.

(0.01–x) x (0.98+2x)
=0.01 M 0.98 M .... at eq.conc.
Since x <<< 1
 36)

[HgI4]2–, [Ti(CO)6]2–, [Ti(σ – C5H5)2 (π – C5H5)2]°

PART-3 : MATHEMATICS

37)

y+1 = a(x+1)

–ℓn a + 1 = 1 + a
–ℓn a = a

38) (1)
(2)
Multiply 2nd equation by iota and add and subtract in Ist equation

39)
S1 < 0

T = S1
Put (a, 0)

a>4

40) Use formula of AGP in f(x)

41)

(Which is a circle for different values of k centre of S1, S2, S3 are an PQ none intersects with
other Hence common tangents are either 0 or 4)
Also are the circles passing through P and Q. Hence have two common tangents.

42)
BC = 2r cos 30°

43)

x = 5 or x = 2
A = (2, 1)
B = (5, –2)

44)

ΔPQR is equilateral

45)

HCF of (315, 360) = 45

consider this

46)
Use AM-GM in f(1), 2f(2), 3f(3) and 4f(4)
G(x) = x4

47)

Put

48)
Use distance between two skew lines.

49)

R=4
BC = 8

Area =

50) On adding and subtracting and

Let point of int be (x1, y1), (x2, y2), (x3, y2), (x4, y2)
y1 + y2 = 20 and y1, y2 > 0

51) Note that z = 0 is one root of the given

equation cancelling z we get]
.....(1)
The 3 vertices of the square other than (0 + 0i) are u, iu, u(1+i)
Now u(ui) + (iu) (1+i)u + [(1+i)u] u = 12 + 9i

3iu2 = 12 + 9i

∴ u = 2 – i or –2 + i (both values of u will be give the same result)

Again, –a = u + ui + u(1+i) = u[1 + i + 1 + i] = 2u(1 + i ) = 2(2 –i) (1+i)
= 2(3 + i) = 6 + 2i
a = –6 – 2i
Again (u) (ui) (1+i)u = –b
–b = u3(–1 + i)
b = (2 – i)3 (1 – i) = [8 – i3 –6i] (2 – i)] (1 – i) = (8 + I – 12i – 6) (1 – i) = (2 – 11 i) (1 – i)
b = 2 – 2i – 11i – 11 = – 9 – 13 i
∴ b = –9 – 13i
Hence, 2b – 13a = 2(–9 – 13i) – 13(–6 – 2i) = 60
52)

The given two lines and radical axis of two circles are 3 concurrent lines.

53)
∠A = 60°

54) Use rotation of complex numbers.