25-05-2025

1721CJA101029250007 JM

PHYSICS

SECTION-I

1) A charge Q is uniformly distributed over a large plastic plate. The electric field at a point P close
to the centre of the plate is 10 V/m. if the plastic plate is replaced by a copper plate of the same
geometrical dimension and carrying the same charge Q, the electric field at the point P will become-

(A) Zero
(B) 5 V/m
(C) 10 V/m
(D) 20 V/m

2) A number of spherical conductors of different radii are charged to some potential. The surface
charge density of each conductor is related with its radius us

(A)

(B)

(C)
(D) None of these

3) A point negative charge -Q is placed at a distance r from a dipole with dipole moment P as shown
in figure. The x component of force acting on the charge -Q is

(A)

(B)

(C)

(D)

4) The speed of a projectile at its maximum height is times its initial speed. If the range of the
projectile is P times the maximum height attained by it, P is equal to:
(A)

(B)
(C)

(D)

5) At time t = 0, a fighter plane enters enemy territory with an initial velocity v0 =250 m/s and moves
horizontally with a constant acceleration a = 20 m/s2 (as shown in the figure). An enemy tank at the
border sports the plane and fires a shot at an angle with the horizontal and a velocity u =
600 m/s. At what altitude H can the plane be hit by the shot? (Approximately)

(A) 1473 m
(B) 2017 m
(C) 2473 m
(D) 3473 m

6) A particle having a velocity at time t =0 is decelerated at a rate of , where

positive constant. After what time will the particle comes to rest?

(A)

(B)

(C)

(D)

7) A projectile is thrown with a velocity of 20 m/s, at an angle of 60o with the horizontal. After how
much time the velocity vector will make an angle of 45o with the horizontal (in upward direction) is
(take g = 10 m/s2)

(A) sec
(B) sec

(C)
sec
(D) None of these

8) If T be the total time of flight of a current of water and H be the maximum height attained by it
from the point of projection, then H/T will be-
(u = projection velocity, projection angle)

(A) (1/2)u
(B) (1/4) u
(C) u
(D) 2u

9) A particle moves in the x-y plane with velocity and . If it passes through the point
(14,4)m at t = 2s, the equation of the path is

(A)
(B)
(C)
(D)

10) A block can slide down the incline plane with constant velocity. If it is projected with a velocity

'u' up the inclined plane at t = 0. The displacement of particle after a time from O will be

(A)

(B)

(C) Zero

(D)

11) What will be the ratio of electric field at the axis and at equatorial line of a dipole:-

(A) 1 : 2
(B) 2 : 1
(C) 4 : 1
(D) 1 : 4

12)

In space of horizontal EF (E = (mg)/q) exist as shown in figure and a mass m attached at the end of a
light rod. If mass m is released from the position shown in figure, the angular velocity of the rod
when it passes through the bottom most position is . Find . (Given )

(A) 3
(B) 4
(C) 5
(D) 6

13) Figures shows four situations in which charged particles are at equal distances from the origin,
If and be the magnitude of the net electric fields at the origin in four situations,
(i),(ii),(iii) and (iv) respectively, then

(A)
(B)
(C)
(D)

14) Point charge q, -q, 2Q and Q are placed in order at the corners A, B, C, D, of a square of side 2b.

If the field at the midpoint of CD is zero, then is-

(A) 1
(B) 2

(C)
(D)

15) An infinitely long line charge with a linear charge density of C/m is positioned along the line x
= 0, z = 2 m. Determine the electric field at the point (1,1,1) m.

(A)

(B)

(C)

(D)

16) Two identical charged spheres suspended from a common point by two massless strings of
length are initially a distance d(d << ) apart because of their mutual repulsion. The charge
begins to leak from both the spheres at a constant rate. As a result the charges approach each other
with a velocity v. Then as a function of distance x between them

(A)
(B)
(C)
(D)

17) The linear charge density on upper half of a segment of ring is and at lower half it is . The
direction of electric field at centre O of ring is:

(A) along OA
(B) along OB
(C) along OC
(D) along OD

18) A point charge is located in the XY plane at the point of position vector . What
is the electric field at the point of position vector .

(A) 1200 V/m

(B) 0.04 V/m
(C) 900 V/m
(D) 4500 V/m

19) In figure shown below, a particle of charge +e is initially at coordinate 16 nm on the dipole axis.
The origin of y is at the dipole centre. The particle is then moved along a circular path around the
dipole centre until it is at coordinate y = -16 nm. The work done by the external force in moving the

particle slowly is J. Find dipole moment

(A) C-m
(B) C-m
(C) C-m
(D) C-m

20) Six charges are placed at the corner of a regular hexagon as shown. If an electron is placed at its
centre O, force on it will be

(A) Zero
(B) along OF
(C) along OC
(D) None of these

SECTION-II

1) A large sheet carries uniform surface charge density . A rod of length has a linear charge
density on one half and on the second half. The rod in hinged at mid point O and makes an
angle with the normal to the sheet. The torque experienced by the rod is . Find .

2) Two particles A and B are separated from each other by a distance . At time t = 0, particle A
starts moving with uniform acceleration a along a line perpendicular to initial line joining A and B.
At the same moment, particle B starts moving with acceleration of constant magnitude b such that
particle B always points towards the instantaneous position of A. (b > a). Find the distance (in m)
travelled by B till the moment B converges with A. (Take b = 3 m/s2, a=1m/s2 and )

3) A particle is projected with a speed v at an angle to the horizontal from the point x = 0, y = 0.
Here, the x-axis is horizontal and the y-axis is vertically upwards. The point of projection is the
lowest point on the inner surface of a bowl formed by rotating the curve x2=4ay, where a is a
positive constant. The particle strikes the bowl at a horizontal
distance Find ?

4) A man moves along the x-axis such that its velocity is . If he is initially at x = 2m, find the
time (in sec) when he reaches x = 4 m.

5) In a certain region of space, the potential is given by . The electric field at the
point (1,1,1) has magnitude is Find ?

CHEMISTRY

SECTION-I

1) Which of the following pair of species have identical shapes ?

+ –
(A) NO2 and NO2
(B) PCl5 and BrF5
–
(C) XeF4 and ICl4
(D) TeCl4 and XeO4

2) Which of the following order is incorrect :-

(A) SbH3 > NH3 > AsH3 > PH3 (Mpt)
(B) HF > HI > HBr > HCl (Bpt)
(C) H2O < H2S < H2Se (Acidic strength)
(D) NH3 > SbH3 > AsH3 > PH3 (Bond polarity)

3) Which set of compound in the following pair of ionic compound has the higher lattice energy ?
(i) KCl or MgO (ii) LiF or LiBr
(iii) Mg3N2 or NaCl

(A) KCl, LiBr, Mg3N2

(B) MgO, LiBr, Mg3N2
(C) MgO, LiF, NaCl
(D) MgO, LiF, Mg3N2

4) Which order of dipole moment is correct ?

(A) CCl4 < CH3Cl < CH2Cl2 < CHCl3

(B) CH3Cl > CH3F > CH3Br > CH3I
(C) BF3 > NH3 > NF3
(D) o-dichlorobenzene < m-dichlorobenzene < p-dichloro benzene

5) Which of the following statement is wrong ?

(A) d-orbital taking part in dsp2 is

3
(B) d-orbital taking part in sp d is dxy.

(C) d-orbitals taking part in sp3d2 are and

(D) d-orbitals taking part in sp3d3 are and

6) Select the not incorrect for dipole moment order ?

(A) NH3 > NCl3

(B) XeF2 = XeF4 < SO2
(C) P(CH3)2 (CF3)3 < P (CF3)2(CH3)3
(D) A & B both are correct

7) Which of the following statements is incorrect ?

(A) The second ionization energy of sulphur is greater than that of chlorine
(B) The third ionization energy of phosphorus is greater than that of magnesium
(C) The first ionization energy of aluminium is less than as that of gallium
(D) The second ionization energy for boron is greater than that of carbon

8)
Column –I Column –II
(Species) (Magnetic Moments)
(A) Ni+2 (i) B.M.
(B) O–2 (ii) 0 B.M.
(C) Co+3 (iii) B.M.

(D) Fe+3 (iv) B.M.

(A) A–iii, B–ii, C–i, D–iv
(B) A–ii, B–iii, C–iv, D–i
(C) A–iii, B–ii, C–iv, D–i
(D) A–iv, B–iii, C–ii, D–i

9) Select equation having not endothermic step :

(A) S–(g) —→ S2–(g)

(B) Na+(g) + Cl–(g) —→ NaCl(s)
(C) N(g) —→ N–(g)
(D) Al2+(g) —→ Al3+(g)

10) Which is mismatched regarding the position of the element as given below ?

(A) (Z = 89) – f block, 6th period

(B) (Z = 100) – f block, 7th period
(C) (Z = 115) – d block, 7th period
(D) Both (1) and (3)

11) Consider the following reaction :

Which of the following types of hydrogen atoms are most easily abstracted by the bromine radical to
form HBr ?

(A) Hydrogen atoms attached to a benzene ring

(B) Hydrogen atoms of the methyl group attached directly to benzene ring.
(C) Hydrogen atoms of the methylene group of the ethyl substitutent
(D) Hydrogen atoms of the methyl group of the ethyl substituent

12) What is the A product :-

(A)

(B)
(C)

(D) None

13) Which of the following dehydration product is incorrect ?

(A)

(B)

(C) CH3CH2CH2CH2OH
CH3–CH=CH–CH3

(D)

14) The main product formed in the following reaction is

(A)

(B)

(C)

(D)

15) Methyl acetate on treating with excess of C2H5MgBr produces :

(A)
(B)

(C)

(D)

16)

Which of the following will not yield a cyclic compound on heating :

(A)

(B)

(C)

(D)

17)

Which of the following reactions will not produce a racemic product ?

(A)

(B)

(C)

(D)

18)
To prepare 3-ethyl-3-pentanol, which of the following pairs of reactants should be chosen ?

(A) CH3CH2CH2COCH3 and CH3CH2MgBr

(B) CH3CH2CH2COCH2CH3 and CH3MgBr
(C) CH3CH2COCH2CH3 and CH3CH2MgBr
(D) CH3CH2COCH3 and CH3CH2CH2MgBr

19)

Consider the following sequence of reactions.

Ketone A B C

+
The ketone (A) is -

(A)

(B)

(C)

(D)

20)

The major product (Y) in the following reactions is :

(A)

(B)
(C)

(D)

SECTION-II

1)

The number of pπ-pπ bonds in XeO4 molecule is/are :-

2) Find out the number of 1-2 shift during the conversion of :-

3)
How many sigma bond present in product B

4) How many isomers obtained on the monochlorination of 3-methylpentane (Excluding

stereoisomers) :-

5) Calculate number of optical isomers in the following compound :

MATHS

SECTION-I

1) For function and it is given that and ,

then the value of b - d is.

(A) 64
(B) 93
(C) 0
(D) Data insufficient

2) The expression

(A) p
(B) q
(C) r
(D) 3

3) If a, b are co-prime numbers and satisfying

then (a + b) can be equal to

(A) 13
(B) 5
(C) 7
(D) 8

4) If x & y are positive integers such that log2(xy) = 4 + ƒ1 & log2(x/y) = 2 + ƒ2, where ƒ1, ƒ2 ∈ [0, 1),
then number of integers for x is -

(A) 8
(B) 9
(C) 10
(D) 11

5) If the smallest integer satisfying the equation,

be 'a', then log2(a) equals,

(A) 0
(B) 1
(C) 2
(D) None of these

6) A ball of diameter 26cm is floating so that top of the ball is 8cm above the surface of water. The
circumference (in cm) of the circle formed by the contact of water surface with the ball is-

(A) 10π
(B) 20π
(C) 24π
(D) 36π

7) is equal to -

(A)

(B) 2a
(C) 3a1/2

(D)

8)

If ƒ(x) = x11 + sin3(35x) + 111x, then the value of

is equal to -

(A) ƒ(π11)

(B)

(C)

(D) f(0)

9) ƒ : R → R+, ƒ(x) = ex, g : R → R, g(x) = 30–2x and , then number of

solution(s) of equation ƒn(g(x)) = ƒn–1(–x) is

(A) 0
(B) 1
(C) 2
(D) infinite

10) The sum of all possible solutions(s) of the equation

is.

(A) 0
(B) -8
(C) -10
(D) None of these

11)
For , let f(x) = , g(x) = tanx and . If ϕ(x) = ((hof)og)(x), then is
equal to :

(A)

(B)

(C)

(D)

12) Which of the following is the solution set of the equation

(A) (0, 1)
(B) (–1, 1) – {0}
(C) (–1, 0)
(D) [–1, 1]

13) The value of is equal to

sec
(A)

(B)
sec
(C) 1
(D) -1

14) The value of is ( )

(A)
(B)

(C)

(D)

15) Let and g(x) = 2tan–1(ex) – for all x ∈ , then which of the
following is wrong ?
(where sgn(x) denotes signum function of x)

(A) ƒ(x) is an even function

(B) goƒ(x) is an even function
(C) g(x) is an odd function
(D) ƒoƒ(x) is an odd function

16) is equal to -

(A)

(B)

(C)

–
(D)

17) is equal to

(A)

(B) 1
(C)
(D) 0

18) is equal to _____

(A) 9
(B) 18
(C) 15
(D) 24

19) If α > β > 0 are the roots of the equation ax2 + bx + 1 = 0, and

,
then k is equal to

(A) 2β
(B) 2α
(C) α
(D) β

20) where [ ] denotes the greatest integer functions :

(A) 0
(B) 1/2
(C) 2/3
(D) 1/4

SECTION-II

1) The number of one-one function such that

is.

2) If real numbers a, b, c, d, e satisfy a + 2 = b + 5 = c + 6 = d + 7 = e + 1 = a + b+ c + d + e + 5

then find sum of digits of (a2 + b2 + c2 + d2 + e2).

3) Number of integral values x can take if

4) If ; a, b ∈ N. Find value of a + b

5) Let f(x) = a + a1x + a2x2 + a3x3 + a4x4 where ai ∈ R and , then is

equal to
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B C C C B C B A D B A A D D A C D D D

SECTION-II

Q. 21 22 23 24 25
A. 4 9 6 6 6

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A D B B D B C B D C A B B B A A C B D

SECTION-II

Q. 46 47 48 49 50
A. 0 3 12 4 3

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C C A A C A D A D C A D D D A D B B B

SECTION-II

Q. 71 72 73 74 75
A. 31 9 3 7 8
 SOLUTIONS

PHYSICS

1)
For conducting plate of cooper

2)

3)

4)
5)

2473 m

6)

7) sec

8) (1/4) u

9)

10)

11)

12) 3

13)

14)

15)
 16)

17) along OC

18) 4500 V/m

19) C-m

20) None of these

21) 4

22) 9

23) 6

24) 6

25)

CHEMISTRY

26)

Shape
Linear
V-shape
PCl5 TBP
BrF5 Square pyramidal

XeF4, Square planar XeO4 Tetrahedral

TeCl4 Bent T-shape

27) M.Pt → NH3 > SbH3 > AsH3 > PH3

28)

Lattice energy
29)

Correct order of dipole moment : CCl4 < CHCl3 < CH2Cl2 < CH3Cl
BF3 < NF3 < NH3
O-dichlorobenzene > m-dichlorobenzene > p-dichlorobenzene

30)

In sp3d hybridisation, participates.

31)

32) (i)

(ii)

(iii)
(size almost same due to transition contraction)
Al < Ga (IE)
(iv)

33) µ = B.M.

34) Na+(g) + Cl–(g) → NaCl(S) ΔH=–ve exothermic

35) (Z = 89) d-block, 7th period
(Z = 115) p-block, 7th period

36)

2° Benzylic free radical is most stable.

37)

38)

39)

40)

41)
42)
(No chiral centre, so no racemisation possible)

43) Asking about : To prepare 3-ethyl-3-pentanol from Reaction of carbonyl compound with
Grignard Reagent.

Concept : Reaction of carbonyl compound with Grignard reagent.

Solution/Explanation/Calculation :

3 – ethyl – 3 – pentanol.
Correct Answer: CH3CH2COCH2CH3 and CH3CH2MgBr
Hence, the correct answer is option (3).

44) Concept:
45)

46)

In XeO4, πp-dπ bonds = 4

pπ-pπ bonds = 0

47)

48) A =

B= 12 and 3

49)

Number of monochloroproducts = number of monovolent radicals

50) Number of optical isomers

= 2n–1 + 2n/2–1
=2+1=3
MATHS

51)

52)

53)
54) log2x + log2y = 4 + ƒ1
log2x – log2y = 2 + ƒ2
—————————
2log2x = 6 + ƒ1 + ƒ2 \({\log _2}x = 3 + \frac{{{f_1} + {f_2}}}{2}\) or x = 23 + ƒ
23 < x < 24 ⇒ Number of x = 8

55) Let log1/6x = t

|t – 1| + 2 = |t – 3|
case I : t < 1
–t+1+2=–t+3
3 = 3 ⇒ Hence log1/6x < 1
case II : 1 ≤ t < 3
t–1+2=–t+3
2t = 2
case III : t ≥ 3
t – 1 + 2 = t – 3 (Not possible)
So smallest integer is 1.

56)
r = 12
Circumference
= 2πr
= 24π

57)

58) ∵ 'f' is odd ƒ–1 is also odd

f–1(x) + f–1(–x) = 0
⇒ sum = 0
59)

⇒ ƒ(g(x)) = –x
⇒ e30–2x = –x ⇒ No solution

60)

61)

f(x) = , g(x) = tanx, h(x) =

fog (x) =

hofog (x) = h( )=

ϕ(x) =

62)

63)
64)

65)

Graph of f(x)

f(x) is an even function

Also, g(x) = 2tan–1(ex) –

g(–x) = 2tan–1(e–x) –

g(–x) = –g(x)
∴ g(x) is an odd function.
In composition function E0O (x) = E
E0E (x) = E
O0E (x) = E
O0O (x) = O
so option (D) is the incorrect.

66)

67)

and

68)
= 18

69) α, β are roots of ax2 + bx + 1 = 0

are roots of x2 + bx + a = 0,
(by transformation)

x2 + bx + a =
Comparing k = 2α

70)

71)

72) a + 2 = k
a=k–2
b=k–5
c=k–6
d=k–7
e=k–1
a + b + c + d + e + 5 = 5k – 16 = a + 2
5k – 16 = k
4k = 16
k=4
a = 2 c = –2
d=3
b = – 1 d = –3
a2 + b2 + c2 + d2 + e2 = 27
sum of digits = 9

73)

is a solution

Final solution x = 0,3,8

No. of integral values = 3

74)

⇒ – tan–10 – tan–1 – tan–12

⇒
∴ a = 5, b = 2

75)
⇒ f(x) = x – 2x2 + 3x3 + 6x4