29-06-2025

7501CJA101021250043 JA

PHYSICS

SECTION-I(i)

1) In the figure, a line of electric field created by two point charges q1 and q2 is shown. If it is known

that q1 = 1 μC, the charge q2 is closest to

(A) – 2 μC
(B) – 4 μC
(C) – 6 μC
(D) – 8 μC

2) A cube made of an insulating material has uniform charge distribution throughout its volume.
Assuming electric potential due to this charged cube at infinitely distant places to be zero, potential
at the centre is found to be V0. What is electric potential at one of its corners?

(A) V0
(B) V0/2
(C) V0/4
(D) V0/8

3) Satellite A is following a circular path of radius a around the earth while another
identical satellite B follows an elliptical path around the earth. The two satellites have same
mechanical energy and their orbits intersect. Find the speed of satellite B at the point where its
path intersects with the circular orbit of A. Take mass of earth to be M.

(A)

(B)
(C)

(D) None of these

4) An infinite line charge of uniform electric charge density λ lies along the axis of an electrically
conducting infinite cylindrical shell of radius R. At time t = 0, the space inside the cylinder is filled
with a material of permittivity ε and electrical conductivity σ. The electrical conduction in the
material follows Ohm's law. Which one of the following graphs best describes the subsequent
variation of the magnitude of current density j(t) at any point in the material?

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Each of the following figures shows electric field vectors at two points A and B in an electric field.
In which figure or figures can the illustrated field be created by a single point charge?
(A)

(B)

(C)

(D)

2) Three particles A, B and C of charges q, q and 2q and masses m, 2m and 5m respectively are held
in free space in a straight line at separation r0 between two adjacent particles as shown in the figure.
All the three particles are released simultaneously. Find velocities of all the three particles when
they reach so far from each other that electrostatic interactions between them can be neglected.

(A)

(B)

(C)

(D) None of these

3) A non-viscous liquid of constant density 1000 kg/m3 flows in a streamline motion along a tube of
variable cross section. The tube is kept inclined in the vertical plane as shown in the figure. The area
of cross section of the tube at two points P and Q at heights of 2 meters and 5 meters are
respectively 4 × 10–3 m2 and 8 × 10–3 m2. The velocity of the liquid at point P is 1 m/s and fluid flow
from P to Q, then

(A) the work done per unit volume by the pressure is + 29625 J/m3.
(B) the work done per unit volume by gravity forces is – 30000 J/m3.
(C) Net work done per unit volume is zero
(D) velocity of liquid at point Q is 0.5 m/s

4) Consider a situation in which there is a Newtonian fluid between two long coaxial uniformly

moving cylinders of radius R and 2R.

(A) Force per unit length required to keep the inner cylinder moving is 4 πηv0

(B)
Force per unit length required to keep the inner cylinder moving is
(C) Distance of the point from the axis at which speed of fluid is zero is 21/3R.
Distance of the point from the axis at which speed of fluid is zero is
(D)

SECTION-II

1) Figure shows a binary star system revolving about their COM. The masses of star A & B are 15 ×
1030 kg and 45 × 1030 kg respectively . Find the ratio of area swept by star A to area swept by star B

about their common COM in a common time interval.

2) A planet is made of two materials of density ρ1 and ρ2 as shown in figure.

The acceleration due to gravity at surface of planet is same as a depth

‘R’. The ratio of is . Find the value of x.

3) The volume charge density as a function of distance X from one face inside a unit cube is varying
as shown in the figure. Then the total flux (in S.I. units) through the cube if ρ0 = 8.85×10–12 C/m3 is

______.

4) Figure shows two configuration of system of dipoles. Initialy all the dipoles are arranged along the
+X axis. The orientation of two of the dipoles is changed leading to a final configuration as shown in

the figure. The work done by external agent to slowly do this process is given by . Fill the
value of α + β in OMR sheet.

SECTION-III

1) Two beads of equal mass m and unlike charges of modulus q1 and q2 can slide on a fixed
frictionless non-conducting rod, bent at right angle. Initially, the beads are held at rest at distances
d and 2d from the corner as shown and then released simultaneously. Ratio of time taken by the

bead 1 to bead 2 to reach at the corner. (treat the beads as particle)

2) Two identical particles A and B each having charge q when released in free space with initial
separation r0 between them, their separation becomes double in time t0. If charge of particle A is
made 12q, that of particle B is made 3q and they are released with initial separation r0, then time

taken to double the separation is t /n. find the value of n.

3) A grounded metallic ball of radius r is placed on the centre of a uniformly charged thin insulating
disc of radius R (R >> r). If total charge on the disc is Q, And force of electrostatic interaction
between the ball and the disc is , then find (x + y).

4) A satellite is seen after every 6 hr over the equator . It is known that it rotates opposite to that of

earth’s direction. Then the angular velocity of the satellite about the centre of earth will be
rad/h. Find the value of n.

5) A tunnel is dug along the chord of the earth at a perpendicular distance from the earth’s centre.
Walls of tunnel are frictionless. A particle of mass m is released into tunnel. Find the ratio of normal
reactions at point P & Q between tunnel and particle as shown in the figure.

6) Two charges q and –2q are placed at (–3,0) and (3,0) in x–y plane. The locus of the point in the
plane of the charges, where the field potential is zero is (x + α)2 + y2 = 4β2. Find the value of (α+β).

CHEMISTRY

SECTION-I(i)

1) Which of the following structure is non-planar and have atleast one 'Cl' as bridging atom ?

(A) Be2Cl4
(B) Al2Cl6
(C) Si2Cl6
(D) I2Cl6

2) What volume of 0.2 M NH4Cl solution should be added to 100 ml of 0.1 M NH4OH solution to
produce a buffer solution of pH = 8.7?
Given : pKb of NH4 OH = 4.7 ; log 2 = 0.3

(A) 50 ml
(B) 100 ml
(C) 200 ml
(D) None of these

3) Among the given compounds, the most succeptible to nucleophilic attack at the carbonyl group is
-

(A) MeCOCl
(B) MeCHO
(C) MeCOOMe
(D) MeCOOCOMe

4) In the chemical reaction, CH3CH2NH2 + CHCl3 + 3KOH → (A) + (B) + 3H2O, the compounds (A)
and (B) are respectively -

(A) C2H5CN and 3kcl

(B) CH3CH2 CONH2 and 3kcl
(C) C2H5NC and K2CO3
(D) C2H5NC and 3KCl

SECTION-I(ii)

1) Which of the following reactions result in an ester?

(A)

(B)

(C)
(D)

2) Which of the following will give yellow precipitate with I2/NaOH-

(A) ICH2COCH2CH3
(B) CH3COOCOCH3
(C) CH3CONH2
(D) CH3CH(OH)CH2CH3

3) An organic compound ‘A’ on treatment with ethyl alcohol gives a carboxylic acid ‘B’ and
compound ‘C’, Hydrolysis of ‘C’ under acidic conditions gives ‘B’ and ‘D’. Oxidation of ‘D’, with
KMnO4 also gives ‘B’. ‘B’ on heating with Ca(OH)2 gives ‘E’ (molecular formula C3H6O). ‘E’ does not
give Tollen’s test and does not reduce Fehling’s solution but give 2,4 DNP test. Identify true
statements.

(A) Compound 'A' is (CH3CO)2O

(B) Compound 'B' is CH3COOH
(C) Compound 'C' is CH3COCH3
(D) Compound 'D' is C2H5OH

4) A 2.5 g impure sample containing weak monoacidic base (Molecular weight = 45) is dissolved in
100 ml water and titrated with 0.5-M HCl at 25°C. When 1/5th of the base was neutralized, the pH
was found to be 9 and at equivalent point, the pH of solution is 4.5 (log 2 = 0.3).

−6
(A) Kb of base is less than 10 .
(B) Concentration of salt at equivalent point is 0.25 M.
(C) Volume of HCl used at equivalent point is 100 ml.
(D) Mass percentage of base in given sample is 80%.

SECTION-II

1)
How many formaldehyde will be obtained in above reaction ?

2) A student is asked to select some compounds from the following.

(I) CH3CHO (II) (III) (IV) (V)
(VI) PhCHO (VII) CH3CH2CHO (VIII) PhCOCH3 (IX) EtOEt
Only those compounds can be selected which give atleast two positive test/reaction from following
list
(i) Positive Tollens test (ii) Positive 2,4-DNP test
(iii) Immediate turbidity with lucas reagent (iv) Positive iodoform test
(v) Cannizzaro reaction
How many compounds can be selected by student.

3) Number of reactions which can produce 1° amine is/are

(i) (ii)

(iii) (iv)

(v) (vi)

(vii)

4) An organic compound (P) has molecular formula, C8H11NO and it can be resolved into
enantiomers. (P) does not decolourise bromine water solution. ‘P’ on refluxing with dilute H2SO4
yields another resolvable compound Q(C8H12O3) which give effervescence with NaHCO3. ‘Q’ on
treatment with NaBH4 yields R(C8H14O3) which on heating with conc. H2SO4 yields S(C8H12O2).
Compound (P) on reduction with LiAlH4, followed by treatment of H2SO4 yields the compound which

is given below Let the sum of degree of unsaturation in P, Q, R and S be ‘x’; the sum
of the number of rings in P, Q, R and S by ‘y’ and the sum of distinct functional groups in P, Q, R and
S be ‘z’ (if the same functional group appears in two or more compounds count it once only).
Then find, the value of .

SECTION-III

1) Total how many sp3 hybrid orbitals are used in formation of a molecule of Be2H4 ?

2)

Calculate the pH of solution prepared by mixing 40 ml of 0.1M acetic acid with 20 ml of 0.1M
sodium hydroxide. Given Ka(ACETIC ACID) = 10-5

3) P (no. of products)

Q (no. of products)

R (no. of products)

S (no. of products)
In all reactions the sum of product is.
How will you bring about the following transformation:

4)

Identify value of 'Y' where Y =

5) Find out the total number of compounds which undergoes acetylation with excess of
and increased in molecular weight by 126.

(i) (ii) (iii)

(iv) (v) (vi)

6)
In the major product, number of 'C' atoms in the ring is X, and the number of 'C' atoms outside the
ring is Y, the value of (X – Y) is ___.

MATHEMATICS

SECTION-I(i)

1) The value of limit is equal to :

(A) e
(B) –e

(C)

(D)

2) For the function the number of points of discontinuity of

the function are (where [x], {x} represent G.I.F. and fractional part respectively).

(A) 900
(B) 960
(C) 1004
(D) 728

3) If the equation (p < q) has only one real root , then value of
is

(A)
(B)

(C)

(D) 0
4)

Least positive solution of equation is

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) If exists and is equal to zero then

(A) α + 2β = 6

(B)

(C) 3α + 2β = 0
(D) 3α – 5β = 0

2) Let and be two functions defined by f (x) = max. and

Identify which of the following statement(s) is (are) correct? ([ ]represent greatest
integer function)

(A) Number of points where f(x) is discontinous is 0.

(B) Number of points where f(x) is non-derivable is 1.
(C) Number of points where g(x) is discontinous is 8
(D) Number of points where g(x) is non-derivable is 9

3) If x1 and x2 (x1 > x2) be roots of the equation , then

(A)

(B)

(C)

(D)

4) Which of the following is true for (where {.} denotes fractional part
function)-
(A)
Domain of ƒ(x) is

(B)
Range of ƒ(x) is
(C) ƒ(x) is periodic function

(D)
Number of solutions of , in [0,100] is 100

SECTION-II

1) Let

If f(x) is continuous at x = 0, then the value of is:

2) Let a, b, c be three non-zero real numbers such that the equation

has two distinct real roots with Then, the value of is________

3) The value of the expression 128 is equal to:

4) Let be an even
function then the sum of all positive values of ‘a’ is
(where {.} denotes G.I.F and {.} fractional part functional part function)

SECTION-III

1) If α, β are two distinct real roots of the equation ax3 + x – 1 – a = 0 (a ≠ –1,0), none of which is

equal to unity and the value of is then the value of k + ℓ

2) Let and number of points where f(x) is not differentiable is 'n', then the
value of 'n' is

3) Find the number of ordered pair(s) (a, b) for which the function f(x) = sgn

is non differentiable at exactly one point (where a, b are integer).

[Note : sgn (x) denotes signum function of x.]
4)

If f(x) = sin–1(x + 2019)–cos–1(x + 2021) and g(x) = sin–1(x + 2017) + cos–1(x + 2019) and x1, x2 lies in

domain of f(x) & g(x) respectively, then is equal to :

5) The number of integers satisfying the inequality

, is

6) If the value of is equal to ea, then a is equal to ________.

 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. D B A A

SECTION-I(ii)

Q. 5 6 7 8
A. A,C A,B,C A,B,D B,C

SECTION-II

Q. 9 10 11 12
A. 9.00 7.00 0.75 9.00

SECTION-III

Q. 13 14 15 16 17 18
A. 1 6 4 4 1 7

CHEMISTRY

SECTION-I(i)

Q. 19 20 21 22
A. B C A D

SECTION-I(ii)

Q. 23 24 25 26
A. A,B,C,D A,D A,B,D B,C

SECTION-II

Q. 27 28 29 30
A. 1.00 6.00 4.00 2.20

SECTION-III

Q. 31 32 33 34 35 36
A. 0 5 9 2 3 3

MATHEMATICS
 SECTION-I(i)

Q. 37 38 39 40
A. D B A A

SECTION-I(ii)

Q. 41 42 43 44
A. A,C A,B,C A,B,C,D A,B,C,D

SECTION-II

Q. 45 46 47 48
A. 0.80 2.00 4.00 11.66

SECTION-III

Q. 49 50 51 52 53 54
A. 2 5 6 1 3 3
 SOLUTIONS

PHYSICS

1)
q2

2)

By symmetry corner of this cube will be centre of 8 identical cube.

&

3)

At the point of intersection both the satellites have same PE. Since they have same mechanical
energy their KE will be same at the point of intersection.

4)

5)

at near point, magnitude of field will be more

(A)
point B is nearer so EB > EA

(C)
Point B is nearer so EB > EA

6)
apply conservation of linear momentum
5mvc = mvA + 2mvB
5vC = vA + 2 VB
Now apply come
ki + ui = kf + uf

7) A1 = 4 × 10–3m2
A2 = 8 × 10–3m2
v1 = 1 m/sec
ρw = 103 kg/m3
Continuity equation at P & Q
A1v1= A2v2
(4 × 10–3) (1) = (8 × 10–3) (v2)

Work done per unit volume by pressure = ΔP = pressure difference

Applying Bernoulli's theorem between P & Q
Work done per unit volume by gravity force =
So, work done/volume = ρg (h1 – h2)
= 1000 × 10 [2 – 5]
= – 30000 J/m3

8)

9) Rate of area swept

(r = distance from COM)

10) =

= M'

πR3 ρ1 + π(8R3 – R3)ρ2 =

ρ1 + 7ρ2 = 4ρ1
 =

11)

12)

WD = Uf – Ui =
∴α+β=1+8=9

13) Both reach the corner simultaneously.

Acceleration magnitudes of the beads are proportional to their distances from the corner.

14)
For simplicity, you may proceed with dimensional analysis.

15) ele. potential at centre of disc

Vc =

after earthing , pot. of ball becomes zero.

F = qE
 16)

17)

So normal at each point is same.

18)

Potential at P = 0 =

⇒ 9-6x + x2 + y2 = 4x2 + 24 x + 36 + 4y2

⇒ 3x2 + 30x + 27 + 3y2 =0
⇒ (x+5)2 + y2 = 42 ⇒ α =5, β=2 ⇒ α + β =7

CHEMISTRY

19) Al2Cl6
(1)

(2)

(3)

(4)

20) Let V ml of NH4 Cl added into NH4 OH solution

[NH4 Cl] in resultant solution =

[NH4 OH] in resultant solution =

pOH = pKb + log

5.3 = 4.7 + log

∴4= ⇒ V = 200 ml

21) MeCOCl is most electrophilic.

22) CH3CH2–NH2 + CHCl3 + 3KOH

23)
(A) (B) (C) (D)

24) Compounds having can give positive iodoform test.

25) (A) (CH3CO)2O

(B) CH3COOH
(C) CH3COOC2H5
(D) C2H5OH
(E) CH3COCH3

26)

+ +
BOH + H B + H2 O
a mole b mole 0

0
Equivalent point =0 =0 a mole

Now, for 1/5th reaction,

or, (14 - 9) =
∴ = 5.6 ⇒ Kb = 2.5 × 10–6

At equivalent point :

or, 4.5 ⇒ - [14–5.6 – log C]

C = 0.25 M
Now, nHCl used = nB formed
+

or,
Mass % of base = moles × 45
moles of base = moles of acid = 0.5 × 0.1 = 0.05

27)

28)

(I) (II) (III) (VI) (VII) (VIII)

29) i, ii, iv, vi

30) (P) (Q)

(R) (S)

31)

(Be is sp2 hybridised in Be2H4)

32)

CH3COOH = 40 ml 0.1 M
CH3COOH = 40 x 0.1 = 4 mmol
NaOH = 20 x 0.1 = 2 mmol

CH3COOH + NaOH → CH3COONa + H2O

4 2 0
–2 –2 2
2 0 2
33)

CH3–CH = CH – COOH (Total product = 2)

Sum of all product = 9

34)

35)

Answer is 3
 36)

MATHEMATICS

37) Let

38)
[210x] is discontinuous at x = 1, 2, 3,.... 1023
{26x} is discontinuous at x = 1, 2, 3,.... 63

but is continuous at x = 1, 2, 3, .... 63

Points of discontinuity = 1023 – 63 = 960

39)

f(0) = 1, f(–1) = p – q < 0

–1 < x0 < 0
cosec x0 < – 1
 0
2 tan–1(cosec x ) =

40)

or

or

Least positive value is

41)
for existence of limit α = –3 & β = 9/2

42)

f(x) is continuous for all

g(x) is discontinuous at x3 + 1 = 1, 2, 3, 4, 5, 6, 7, 8

and non differentiable at same point

43)
⇒
, now check options

44)
obviously 'ƒ' is periodic

45)

46)

47)

48)
49) Put , then

but roots of ay3 + ay – (1 + a) = 0 are α, β

and third root will be (1)
So + + 1 = 0 ⇒ (α + = –1)

So,
⇒ k=l=1 ⇒ (k + ℓ = 2)

50)
Not differentiable at 5 sharp corner points x = 0, ±4, ±5

51) f(x) = sgn

For exactly one point of discontinuity = 0 at exactly one value

of x.
Let P(x) = x2 – ax + 1 .....(1) and Q(x) = bx2 – 2bx + 1 ......(2) b ≠ 0
and D1 and D2 are the discriminant of equation (1) and (2) respectively.
Case-I: D1 = 0 and D2 < 0
2
a –4=0 4b2 – 4b < 0
a=±2 b ∈ (0, 1) rejected because there is no integral value of b.
Case-II: D1 < 0 and D2 = 0
a ∈ (– 2, 2) b = 0, 1
a = – 1, 0, 1 b = 0 is rejected
∴ number of ordered pairs are 3.
Case-III: D1 = 0 and D2 = 0
a = – 2, 2 b = 0, 1
For b = 0, a = – 2 & 2 and for b = 1, a = 2
∴ number of ordered pairs are 3.
∴ Total number of ordered pairs are 6. Ans.
52)

Similarly

=1

53) ⇒
∴ given equation becomes

⇒ x2 ≤ 2 ⇒
No of integers = 3

54)