29-06-2025

9610ZJA801897250005 JA

PART 1 : PHYSICS

SECTION-I (i)

1)

In the figure shown current will flow through branch A–B if

(A) both S1 and S2 are open.

(B) S1 is open and S2 is closed.
(C) S1 is closed and S2 is open.
(D) S1 and S2 both are closed.

2)

In the circuit shown the cell will deliver maximum power to the network if the value of ‘R’ is :-

(A)

(B)

(C)

(D)

3) In figure, a resistance coil, wired to an external battery, is placed inside a thermally insulated
cylinder fitted with a frictionless piston and containing an ideal diatomic gas. A current i = 200 mA
exists in the coil, which has a resistance R = 350 Ω. If the pressure of the gas remains constant,
what should be the speed v (in cm/s) of the piston, of mass m = 10 kg ? (Take patm = 105Pa, A = 10

cm2)

(A) 1
(B) 2
(C) 3
(D) 4

4)

To establish an instantaneous current of 2A through a 1µF capacitor; the potential difference across
the capacitor plates should be changed at the rate of :

(A) 2 × 104 V/s

(B) 4 × 106 V/s
(C) 2 × 106 V/s
(D) 4 × 104 V/s

SECTION-I (ii)

1)

In the figure shown

(A) currents in R4 and R5 are equal
(B) currents in R2 and R3 are equal
(C) current in R1 is equal to the sum of currents in R3, R4 and R5
(D) current in R1 is equal to the sum of currents in R2, R4 and R5

2) Current flowing in a RC charging circuit is given by I = a(1 – ) (I = current, t = time, R =

resistance, C = capacitance, P = I2R, P is power)

(A) SI unit of a is ampere

(B) Unit of RC is hertz

(C)
is dimensionless
(D) Dimension formula of resistance is M1L2T3I2

3) The entire x = 0 plane of a cartesian coordinate system is a thin insulating sheet of uniform
surface charge density σ. A thin insulating spherical shell of radius ‘a’ and uniform surface charge
density 2σ is centred at the point A(+2a, 0, 0). The electric potential at A is arbitrarily fixed as zero.

(A)
The electric field at the point B(+2a, +a/2, 0) is
(B) The electric potential at the point C (+a/2, 0, 0) is
The electric potential at the point D(–2a, 0, 0) is
(C)

(D)
The electric field at the point B(+2a, , 0) is

4) In terms of potential difference V, electric current I, permittivity , permeability and speed of

light c, the dimensionally correct equation (s) is (are)
(A)
(B)
(C)
(D)

5) An elastic string of force constant k and negligible length is attached to a point on a smooth
horizontal table. A particle of charge Q, mass m is attached to the other end. A vertical magnetic
field B is present. The particle is pulled out so that length of string becomes ℓ. It is now projected
with a velocity v0 so that the particle moves in a circular path about the other end. What is possible
value of ? Take ℓ = 1m, m = 0.2kg, q = 1C, k = 30 N/m, B = 1T.

(A) 15 m/s
(B) 5 m/s
(C) –10 m/s
(D) –20 m/s

6) An elastic spring of force constant k and natural length 3 ℓ0 is cut into two parts so that their
natural lengths are 2ℓ0 and ℓ0 respectively. One end of these springs are attached to points P and Q,

on a fixed vertical wall and tied with a block of mass m.

(A) In equilibrium the distance of block from the vertical wall is 4ℓ0/3.
(B) In equilibrium the distance of block from the vertical wall is 5ℓ0/3.
(C) The force constant of shorter part of the spring is 3k.
(D) The force constant of larger part of the spring is 2k/3.

7)

On the basis of dimensions, decide which of the following relations cannot give displacement of
particle undergoing simple harmonic motion. y represent displacement; [a] = L; [t] = [T] = T

(A)

(B)

(C)
(D) y = a sin (2πt)

8) If vectors and represent two sides of a triangle,

then the third side can have length equal to :

(A) 3m
(B) 5m
(C) 6m
(D) 2m

SECTION-II

1) The equivalent resistance between A and B for the given circuit is 20x ohm where
. Write value of x in OMR sheet.

2)

A 1 kg block 'B' rests as shown on a frictionless bracket 'A' of same mass. Constant force F = 3N
starts to act at time t = 0, when the distance of block B from the end of bracket is 13.5m. Find time
(in sec), when block B falls off the bracket.

3) A positively charged particle starts at rest 25 cm from a second positively charged particle which
is held stationary throughout the experiment. The first particle is released and accelerates directly
away from the second particle. When the first particle has moved 25 cm, it has reached a velocity of
. What is the maximum velocity (in m/s) that the first particle will reach ?

4) Figure shows a binary star system revolving about their COM. The masses of star A & B are 15 ×
1030 kg and 45 × 1030 kg respectively . Find the ratio of area swept by star A to area swept by star B
in a common time interval.

5) Figure shows a square loop 10 cm on each side in the x-y plane with its centre at the origin. An
infinite wire is at z = 12 cm above y-axis. What is torque (in µN-m) on loop due to magnetic force?

6) In the figure shown equal currents are flowing in the two wire. If force acting on wire AB

is ln k, then find value of k.

PART 2 : CHEMISTRY

SECTION-I (i)

1) What will be IUPAC name of compound when allyl and neopentyl joined together :

(A) 4,4-dimethyl pent-1-ene

(B) 5,5-dimethyl hex-1-ene
(C) 6-methyl hept-1-ene
(D) 5-methyl hex-1-ene
2) Iodine molecules dissociates into atoms after absorbing light of wavelength 4500Å. If one
quantum of radiation is absorbed by each molecule what will be the approximate kinetic Energy of
iodine atom
[Given B.E. of I2 = 241.2 kJ/mol], [NA = 6 × 1023][1eV/atom = 96.48 kJ/mole].

(A) 8.6 × 10–36 J

(B) 2.0 × 10–20 J
(C) 433 kJ
(D) 4.3 J

3) H2(g) is produced industrially by electrolysis of aq. NaCl using inert electrodes. How many
ampere-hours would be required for production of 20 kg hydrogen :

(A) 5.36 × 105

(B) 1.07 × 106
(C) 2.68 × 105
(D) 1.93 × 105

4) Liquid 'M' and liquid 'N' form an ideal solution. The vapour pressures of pure liquids 'M' and 'N'
are 450 and 700 mmHg, respectively, at the same temperature. Then correct statement is:
(xM = Mole fraction of 'M' in solution ;
xN = Mole fraction of 'N' in solution ;
yM = Mole fraction of 'M' in vapour phase ;
yN = Mole fraction of 'N' in vapour phase)

(A) (xM – yM) < (xN – yN)

(B)

(C)

(D)

SECTION-I (ii)

1)

1.22 gm C6H5COOH is added into 100 gm of acetone, elevation in B.P. is found to be 0.17. If Kb
(acetone) = 1.7 K - Kg mol–1 then select the incorrect options

(A) Observed molar mass of benzoic acid is 61 gm/mole.

(B) Observed molar mass of benzoic acid is 122 gm/mole
(C) Benzoic acid neither associate nor dissociate.
(D) Benzoic acid exist as dimer in acetone due to intermolecular H-bonding

2) In a bimolecular reaction, the steric factor P was experimentally determined to be 4.5. The
correct option(s) among the following is(are) :
 The value of frequency factor predicted by Arrhenius equation is higher than that
(A)
determined experimentally
(B) The activation energy of the reaction is unaffected by the value of the steric factor
(C) Since P = 4.5, the reaction will not proceed unless an effective catalyst is used.
Experimentally determined value of frequency factor is higher than that predicted by Arrhenius
(D)
equation.

3) The standard reduction potentials of some half cell reactions are given below:
;
;
;
;
Pick out the correct statement (for standard condition of all species) :

4+ 2+
(A) Ce will oxidise Pb to PbO2
(B) will oxidise Pb2+ to PbO2
(C) H2O2 will oxidise Mn2+ to
(D) PbO2 will oxidise Mn2+ to

4)

Which of the following statement is/are correct

(A) The peroxide ion has a bond order of 1 while the oxygen molecule has a bond order of 2
(B) The peroxide ion has a weaker bond than the dioxygen molecule has.
(C) The peroxide ion as well as the dioxygen molecules are paramagnetic
(D) The bond length of the peroxide ion is greater than that of the dioxygen molecule

5) How many of the following trend is "INCORRECT" ?

(A) Electron affinity : Se > S > Br > Cℓ

(B) Ionic radii : Ba2+ > Rb+ > K+ > Sr2+
(C) Atomic radii : S > Cℓ > O > F
(D) I.E2 (Be) > I.E2 (Li)

6) When photons of energy 4.25 eV strike the surface of a metal A, the ejected photoelectrons have
maximum kinetic energy, TA (expressed in eV) and de–Broglie wavelength λA. The maximum kinetic
energy of photoelectrons liberated from another metal B by photons of energy 4.20 V is TB = TA –1.50
eV. If the de–Broglie wavelength of these photoelectrons is λB = 2λA then :

(A) the work function of A is 2.25 eV

(B) the work function of B is 3.70 eV
(C) TA = 2.00 eV
(D) TB = 2.75 eV
7) An electron in hydrogen atom makes a transition from n = n1 to n = n2. The ratio of time period of
the revolution of the electron in the initial state is eight times that in the final state. The possible
values of n1 and n2 are:

(A) n1 = 4, n2 = 2
(B) n1 = 8, n2 = 2
(C) n1 = 8, n2 = 1
(D) n1 = 6, n2 = 3

8) 8.7 g of pure MnO2 is heated with an excess of HCl and the chlorine gas evolved is passed into a
solution of KI. Calculate the amount of the iodine liberated. (I = 127) (Mn = 55)

(A) 0.1 mol

(B) 25.4 g
(C) 15.4 g
(D) 7.7 g

SECTION-II

1) In the reaction : N2H4 (ℓ) + ClO3– (aq.) → NO(g) + Cl– (aq.) number of moles of electrons gained by
1.5 moles of ClO3– (aq.) will be :-

2)

19 gm mixture of Na2CO3(s) and NaHCO3(s) on heating gives 2.2 gm CO2 gas.

Find % NaHCO3 (by mass) in mixture.

3) The decomposition reaction 2N2O5(g) 2N2O4(g) + O2(g) is started in a closed cylinder under
isothermal isochoric condition at an initial pressure of 1 atm. After Y × 103 s, the pressure inside the
cylinder is found to be 1.45 atm. If the rate constant of the reaction is 5 × 10–4 s–1, assuming ideal
gas behavior, the value of Y is ___

4) A current of 9.65 micro-amperes is passed through AuCl3 solution for 30 minutes using Pt-
electrodes causing deposition of a uniform single atom thick layer of total area 600 cm2. Then
average surface area covered by a single gold atom is 1.66 × 10–b cm2 then find the value of b.
(NA = 6 × 1023).

5) An aqueous solution containing 28% by mass of liquid (mol. mass = 140) has a vapour pressure of
160 mm at 30 °C. Find the vapour pressure of the pure liquid A. (The vapour pressure of water at 30
°C is 150 mm)

6) The bond length in HCl molecule is 0.127 nm. The observed dipole moment of HCl is 1.08 D. The
percentage ionic character in HCl molecule is_________.
 PART 3 : MATHEMATICS

SECTION-I (i)

1) The absolute value of difference of roots of is

(A) 350
(B) 2.350
(C) 2
(D) 0

2) If 2, h1, h2, h3 ... h20, 5 are in H.P., 2, a1, a2, a3 ... a20, 5 are in A.P. and 2, g1, g2, g3 ... g20,5 are in G.P.

and , then is equal to

(A) 3
(B) 4
(C) 5
(D) 7

3) is equal to

(A)

(B) 1
(C)
(D) 0

4) Let ƒ : [0, ∞) → [0, 3] be a function defined by Then which

of the following is true?

(A) ƒ is continuous everywhere but not differentiable exactly at one point in (0, ∞)
(B) ƒ is differentiable everywhere in (0, ∞)
(C) ƒ is not continuous exactly at two points in (0, ∞)
(D) ƒ is continuous everywhere but not differentiable exactly at two points in (0, ∞)

SECTION-I (ii)

1) Consider the equation (x2 – 4x + 6)2 – (k + 2)(x2 – 4x + 6) + k + 5 = 0 (k ∈ R). Which of following

are correct ?
(A) There is no integral value of k for which given equation has exactly 4 real solutions.
(B) There is only one integral value of k for which given equation has exactly 3 real solutions.
(C) There is only one integral value of k for which given equation has exactly one real solution.
(D) The number of positive integral values of k for which given equation has no real solution are 3.

2) Let A = N × N be the Cartesian product of N and N. Let

S = {((m, n), (p, q)) ∈ A × A : m + q = n + p}
Consider the following statements :
I. If ((m, n), (p, q)) ∈ S and ((p, q), (r, s)) ∈ S then ((r, s), (m, n)) ∈ S
II. There exists at least one element ((m, n), (p, q)) ∈ S such that ((p , q), (m, n)) ∉ S
Then which of the following options is/are incorrect ?

(A) I is correct
(B) II is correct
(C) Both I and II are correct
(D) Neither I nor II is correct

3) If and , then which of the following is/are not correct ?

(A)

(B)

(C)

(D)

4) Consider ƒ(x) = sinx + 2sin2x + 3sin3x + 4sin4x+......... ∞ ; , then

(A)
Range of ƒ(x) is
(B) Range of ƒ(x) is (–∞,∞)

(C)
is equal to

(D)
is equal to 2

5) If , then which of the following is/are

correct ?

(A)
(wherever defined)
value of N when x = 2 is 2
(B)
(C) value of N when x = 2 is 22008
(D) Number of solutions of |N| = 1 is one

6) The value of 3 is less than:

(A) 1
(B) 2
(C) 3
(D) 4

7) Which of the following statement(s) is True?

(A) P(n): n2 – n + 41 is prime for every n ∈ N.

(B)
is rational.

(C)
simplifies to an integer.
5 –6 10
(D) Coefficient of x in (1 – x) is C6

8) Let a, b ∈ and ƒ : → be defined by ƒ(x) = acos(|x3 – x|) + b|x|sin(|x3 + x|). Then ƒ is

(A) differentiable at x = 0 if a = 0 and b = 1

(B) differentiable at x = 1 if a = 1 and b = 0
(C) NOT differentiable at x = 0 if a = 1 and b = 0
(D) differentiable at x = 1 only if a = 1 and b = 1

SECTION-II

1) Consider function . If range of function is [a,b), then value

of is equal to

2)

is equal to then the value of K is

3) The sequence is defined by . Then

 , where denotes greatest integer function, is equal to

4) Find the coefficient of x4 in the expansion (1 + x + x2 + x3)11

5) Let The value of is equal to

6) Let
(where [.] denotes the greatest integer less than or equal to x). Then the number of points, where
f(x) is discontinuous is
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. D A B C

SECTION-I (ii)

Q. 5 6 7 8 9 10 11 12
A. A,B,C,D A,C A,B,C A,C A,C A,C B,D A,B

SECTION-II

Q. 13 14 15 16 17 18
A. 5.00 3.00 20.00 9.00 72.00 4.00

PART 2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22
A. B B A C

SECTION-I (ii)

Q. 23 24 25 26 27 28 29 30
A. A,D B,D A,B,C A,B,D A,B,D A,B,C A,D A,B

SECTION-II

Q. 31 32 33 34 35 36
A. 9.00 44.21 2.30 to 2.31 14.00 360.15 17.69 to 17.71

PART 3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40
A. C A D B

SECTION-I (ii)

Q. 41 42 43 44 45 46 47 48
A. A,B,D B,C,D B,C,D A,D A,B,D B,C,D B,C A,B
 SECTION-II

Q. 49 50 51 52 53 54
A. 3.00 6.00 1.00 990.00 6.00 3.00
 SOLUTIONS

PART 1 : PHYSICS

1)

When both switch are closed then only there will be current in branch AB

2) The cell will deliver maximum power to the network if Req = r

3) i2R =

CP = & PV = nRT ⇒ PAv =

4)

5) Use rules of combination of resistances and distribution of currents.

New Sol.
Current inversible proportional to magnitude of resistance. As R1 and R5 are equal current will
be equal in both. Simillarly resistance of R2 and branch containing R3 is same.

6)

⇒ [I] = [a] =
⇒ [a] = Ampere
∵ Exponential function is dimensionless

∵
⇒ [RC] = [t] = sec
∵ P = I2R

⇒R=

⇒ [R] = = ML2T–3I–2
7)

– Vdue to sphere
8)

9)

10)
(3ℓ0)k = (2ℓ0)k1 = (ℓ0)k1

k2 = 3k

2x – 2ℓ0 = 2ℓ0 – x
3x = 4ℓ0

11)

Trignometric ratios are defined only for angles, and angles should be dimensionless.

12)
Possible lengths would be or

13) From infinite series

xR + 2R2 + 2Rx = xR + x2
x2 – 2Rx – 2R2 = 0

x=

x=

Req = 100 Ω

14)

F – T = mAaa
T = mBaB

t = 3 sec.

15)
Vmax =

16)

Rate of area swept

(r = distance from COM)

17)

Side View

τnet= Torque to force couple of Fcosθ

= (Fcosθ)(10 cm)

=
 Substituting the values we get
τ = 72 µN-m

18)

PART 2 : CHEMISTRY

19)

20)

= 0.25

= 0.125 × 1.6 × 10–19J/atm

= 2.0 × 10–20J/atm

21) Cl– + H2O + e– → Cl2 + H2 + OH– + e–

22) According to Raoult's law;

PM = ; PN =
According to Dalton's law;
PM = PS.YM; PN = PS.YN
Þ = PS.YM … (1)
& = PS.YN … (2)
Divide (1) & (2);
Given; = 450 mmHg & = 700 mmHg

⇒ ; as when multiplied by a number less than 1 gives .

23)

ΔTb = i.Kb.m

0.17 = i × 1.7 ×
i = 1, so no association or dissociation take place.

24)
P = 4.5
Kactual > Ktheoreticala
Kactual = Kexp. =
Aactual > Atheorectical
Hence experimental determined value of frequency factor is higher that predicted by
Arrhenius equation.
Activation energy of reaction is unaffected by the value of the steric factor.
Since P = 4.5 P > 1 so no catalyst is required.

25)

A) thus Ce4+ will be reduced.

B) thus will be reduced.
C) thus will be reduced.
D) thus it means that will be reduced and hence Pb2+ will be oxidized
4+
to Pb .
Hence options (A), (B) and (C) are correct.

26)

Peroxide ion = ⇒ B.O. = 1

O2 molecule ⇒ B.O. = 2

B.O. ∝ B.E. ∝
Correct option is A,B,D.

27)

(B) G-1 and G-2 Ionicradii

G-1 G-2
3 1(smallest)
5 2
8 4
9 6
10(Highest) 7
(D) I.E3 (Li) > I.E2 (He)

28) TA = 4.25 – WA
TB = 4.20 – WB

TA = 2 eV, TB = 0.5 eV, WA = 2.25 eV, WB = 3.7 eV

29)

Here,
n1 = 2n2

30)

MnO2 + HCl → MnCl2 + 2H2O + Cl2 …(i)

n=2 n=2
0 –1 0 –1
Cl2 + KI → I2 + KCl …(ii)
n=2 n=2
Eq. of I2 = eq. of Cl2 reacted in equation (ii)
= eq. of Cl2 produced in equation (i)
= eq. of MnO2 reacted in equation (i)

weight of I2 = 25.4 g
31)
nf of ClO3–1 = 6
⇒ 1 mole of ClO3–1 gained → 6e–
∴ 1.5 mole of ClO3–1 gained → (6 × 1.5) e–
= 9 e–

32)

Na2 CO3 No decomposition

2NaHCO3 Na2 CO3 + CO2 + H2O

= 2 × 0.05 = 0.1
Wt. of NaHCO3 = 0.1 × 84 = 8.4 gm

% NaHCO3 in sample = × 100 = = 44.21

33) 2N2O5(g) 2N2O4(g) + O2(g) at constant V, T

t=0 1
t = y × 103 sec (1 – 2P) 2P P
PT = (1 + P) = 1.45
P = 0.45 atm

(2K)t =

(2 × 5 × 10–4) × y × 103 =
y = 2.303 = 2.30

34)
 35) For two miscible liquids,
0 0
Ptotal = Mole fraction of A × PA + Mole fraction of B × PA

Number of moles of
Liquid B is water. Its mass is (100 – 28), i.e., 72.

Number of moles of
Total number of moles = 0.2 + 4.0 = 4.2
Given, Ptotal = 160 mm
0
pB = 150 mm

So, = ;

36)

µtheoritical =q×d

µobserved = 1.08 D

% Ionic character =

PART 3 : MATHEMATICS

37)

not possible

absolute value of difference of roots = 2

38) L = (a1h1g1)(a2h2g2)....(a20h20g20) =(g1g2....g20)30 = 1030

39)

and
40) Graph of max{ sin t : } in

& graph of 2 + cos x for

So graph of

f(x) is differentiable everywhere in

41) Let
(x2 – 4x + 6) = t
f(t) = t2 – (k + 2)t + k + 5 = 0
Apply conditions of location of roots on equation f(t) = 0.
for exactly 4 real solutions k ∈ (4, 5)
for exactly 3 real solutions k = 5
for exactly one real solution k ∈ ϕ
for no real solution k ∈ (–∞, 4)

42) Given ((m,n) ,(p,q)) ∈ S

⇒m+q=n+p ...(i)
also ((p,q) , (r,s)) ∈ S
⇒p+s=r+q ...(ii)
Now if we add above equation
we get m + s = n + r
⇒ ((r,s) , (m,n)) ∈ S
Hence statement (I) is correct
If ((m,n) , (p,q)) ∈ S
⇒m+q=n+p
⇒p+n=q+m
hence ((p,q) , (m,n)) ∈ S
Hence statement (II) is incorrect

43) Let .

Note that for positive real numbers a and b. In particular, for each
fixed positive integer n with 1 ≤ n ≤ 8 choose a > b > 0 satisfying a + b = 6, ab = n then a, b
are roots of the equations x2 – 6 + n i.e.

44) ƒ(x) = sinx + 2sin2x + 3 sin3x+....∞

sinx ƒ(x) = sin2x + 2sin3x +.... ∞

45)

⇒
(A)
(B) if x = 2 ⇒ N = 2

(D)

⇒ (Solve)

46)

=
=

= =
Ans. (BCD)

47) (A) For n = 41, P(n) is not prime.

(B) We have
= (eln 2 – 1) + (eln 4 – 1) = 1 + 3 = 4
(B) is correct

(C) We have ∞

∴ Tn = = = =
(D) Coefficient of x5 in (1 – x)–6 = 10C5.
(D) is not correct

48)

If x3 – x 0 ⇒ cos|x3 – x| = cos(x3 – x)
x3 – x < 0 ⇒ cos|x3 – x| = cos(x3 – x)
Similarly b|x|sin|x3 + x| = bxsin(x3 + x) for all x ∈ R
∴ ƒ(x) = acos(x3 – x) + bxsin(x3 + x)
which is composition and sum of differentiable functions
therefore always continuous and differentiable.

49)

Dom of f(x) = [2, 4] & its range = [0, 1]

∴ range of

∴ range of

∴
50)

51)

52)

Coefficient of x4 is

53) (by putting )

54)

When cot x ∈ I, [cot x] = cot x

⇒ tan x [cot x] = 1
When cot x ∉ I
[cot x] < cot x
⇒ 0 < tan x [cot x] < 1
⇒ [tan x [cot x]] = 0

⇒
So, f(x) is discontinuous when cot x ∈ I

⇒ 0 < cot x ≤ 2 +
Hence, number of points of discontinuity

x = cot–1 3, cot–1 2 and cot–11 =

x = cot–1 3, cot–1 2 and cot–11 =

Thus three points of discontinuity.