20-07-2025

1001CJA101021250018 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Consider a long heavy object of linear mass density λ in free space. A small particle of mass m is
orbiting this long object at a distance r from its axis as shown. The time period of revolution and

kinetic energy of the particle will be:-

(A)
, λGm

(B)
, λGm

(C)
, λG/m

(D)
, λG/m

2) A small block of mass m, having charge q is placed on frictionless inclined plane making an angle
θ with the horizontal. There exists a uniform magnetic field B parallel to the inclined plane but
perpendicular to the length of spring. If m is slightly pulled on the inclined in downward direction
and released, the time period of oscillation will be (assume that the block does not leave contact

with the plane)

(A)

(B)

(C)

(D)
3) A wooden stick of length 3ℓ is rotated about an end with constant angular velocity ω in a uniform
magnetic field B perpendicular to the plane of motion. If upper one third of it's length is coated with

copper then induced emf in part of copper coating of the stick is

(A)

(B)

(C)

(D)

4) initially, switch S is connected to position 1 for a long time shown in figure. The net amount of

heat generated in the circuit after it is shifted to position 2 is :

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) Charge is sprayed onto a large non conducting belt above the left hand roller. The belt carries
charge with a uniform surface charge density σ, as it moves with a speed v between the rollers as
shown. The charge is removed by a wiper at right hand roller. For a point just above the sheet mark

the correct option.

(A)
magnetic field is , out of the plane of the page, parallel to axis of roller.
(B) magnetic field is , out of the plane of the page, perpendicular to axis

(C)
electric field is perpendicular to the plane of sheet
If an electron moves parallel to V just above the sheet it will experience an upward magnetic
(D)
force.

2) A particle of mass m and charge q, moving with velocity v enters region II normal to the boundary
as shown in the figure. Region II has a uniform magnetic field B perpendicular to the plane of the
paper. The length of the Region II is . Choose the correct choice (s).

(A)
The particle enters Region III only if its velocity v >

(B)
The particle enters Region III only if its velocity v <
Path length of the particle in Region II is max. when velocity v =
(C)

(D) Time spent in Region II is same for any velocity v as long as the particle returns to Region I

3) A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in
equilibrium at temperature T. Assuming the gases are ideal, the correct statement(s) is (are) :-

(A) The average energy per mole of the gas mixture is 2RT.
(B) The average energy per mole of the gas mixture is 3RT
(C) The ratio of the rms speed of helium atoms to that of hydrogen molecules is 1/2.
(D) The ratio of the rms speed of helium atoms to that of hydrogen molecules is .

4) In the circuit shown below, the key is pressed at time t = 0. Which of the following statement(s)

is(are) true?
(A) The voltmeter displays –5V as soon as the key is pressed, and displays +5V after a long time.
(B) The voltmeter will display 0 V at time t = ln 2 seconds.
(C) The current in the ammeter becomes 1/e of the initial value after 1 second.
(D) The current in the ammeter becomes zero after a long time.

SECTION-II

1) An infinitely long straight wire carries a current i1 = 1 amp. A rectangular current loop placed in
the same plane of shown dimensions carries a current i2 = 1amp anticlockwise. Magnitude of net

force on the loop is found to be . Find value of β.

2) The magnetic field in a certain cylindrical region is changing with time according to the law B =
[16 – 4t2]Tesla. The magnitude of induced electric field (Volt/meter) at point P at time t = 2 sec is

3) A shown 'L' shaped frame is rotating with constant angular velocity 2 rad/sec about O inside

uniform magnetic field 1T. Find magnitude of VB – VA (in Volt).

4) A parallel paraxial beam of light is incident on the arrangement as shown. µA = 3/2, µB = 4/3, the
two spherical surfaces are very close and each has a radius of curvature 10 cm. The distance of point
where the rays are focussed from plane surface PQ is n cm. Then find the value of n.
5) Two charge particles are fixed at P1 and P2 separated by a distance 9 m. Find position (in meter)
on the line P1P2 from P1 where electric field is zero (null point).

6) A solid sphere of mass m = 1kg and radius R = 10 cm is being wrapped by N turns of a massless
wire, is kept on a rough inclined plane. If the wire carries a current i, the sphere remains in
equilibrium in a horizontal magnetic field . If is suddenly reversed, find the angular acceleration
of the sphere. If answer is n × 100 rad/s2. Write the value of n. (Given θ = 37°)

7) A diatomic gas is undergoing a process such that 9 dQ = 14 dW where dQ is heat absorbed by gas
and dw is work done by gas. Find x if its molar heat capacity is xR.

8) Consider a circuit shown in the figure. The rod is free to slide over the resistanceless vertical
rails. Maximum charge on the capacitor C is given by q × 10–5 coulomb. Fill the value of q . (Given :
m = 0.1 kg, R = 10 Ω, C = 24 µF, B = 1T & ℓ = 8m, g = 10 m/s2)

PART-2 : CHEMISTRY

SECTION-I (i)

1) The heat of combustion of solid benzoic acid at constant volume is –321 kJ/mole at 27°C. The heat
of combustion (kJ/mole) at constant pressure is :

(A) –321 – 300 R

(B) –321 + 300 R
(C) –321 – 150 R
(D) –321 + 900 R

2) Given : ΔfG° of CO(g) = – 250 kJ/mole

ΔfG° of CO2(g) = – 380 kJ/mole
ΔfG° of Al2O3(s) = – 11250 kJ/mole
ΔfG° of PbO(s) = – 60 kJ/mole
Select the correct combination of reaction and its spontaneity under standard condition.

(A) 2Al2O3(s) + 3C(s) → 4Al(s) + 3CO2(g), spontaneous reaction

(B) 2Al2O3(s) + 6C(s) → 4Al(s) + 6CO(g), non spontaneous reaction
(C) 2PbO(s) + C(s) → 2Pb(s) + CO2g), non spontaneous reaction
(D) 2PbO(s) + 2C(s) → 2Pb(s) + CO2(g), non spontaneous reaction

3) The correct reaction/reaction sequence that would produce a dicarboxylic acid as the major
product is-

(A)

(B)

(C)
(D)

4) Roasting is not used as one of the metallurgical process in the ore :

(A) Casseterite(SnO2)
(B) Silver glance (Ag2S)
(C) Copper pyrites (CuFeS2)
(D) Galena (PbS)

SECTION-I (ii)

1) 100 ml 0.5 N H2SO4 (strong acid ) is neutralised with 200 ml 0.2M NH4OH in a constant pressure
calorimeter which results in temperature rise of 1.4°C. If heat capacity of calorimeter content is 1.5
kJ/°C. Which statement is /are correct
Given: HCl(aq.) + NaOH(aq.) → NaCl(aq.) + H2O(ℓ) + 57 kJ
CH3COOH(aq.) + NH4OH(aq.) → CH3COONH4(aq.) + H2O(ℓ) + 48.1 kJ

(A) Enthalpy of neutralisation of HCl v/s NH4OH is –52.5 kJ /mol

(B) Enthalpy of dissociation (ionization) of NH4OH is 4.5 kJ/mol
(C) Enthalpy of dissociation of CH3COOH is 4.6 kJ/mol
+ –
(D) ΔH for 2H2O(ℓ) → 2H (aq.) + 2OH (aq.) is 114 kJ

2) Select the correct statement(s) (Assuming all gases involved to behave ideally) ?

H2O(ℓ) → H2O(g)
(A) 1atm, 373K 1atm, 373K
For this ΔH = PΔV as ΔU = 0
For the reaction H2(g) + I2(g) → 2HI(g) occurring in a closed rigid container ΔH = qv (where qv is
(B)
the heat absorbed at constant volume).
(C) For irreversible isothermal expansion of an ideal gas ΔSsystem > ΔSsurrounding
If during any process entropy of a closed system is increasing, then the process must be
(D) spontaneous because according to second law of thermodynamics entropy of a system must
increase during spontaneous process.

3)

For the reaction sequence given below, the correct statement(s) is(are)

(A) P is optically active.

(B) S gives Bayer’s test.
(C) Q gives effervescence with aq. NaHCO3.
(D) R is an alkyne.

4) Werner, when passed excess of ammonia through cobalt(III) chloride solution, followed
by crystallisation observed 4 different colour compounds, yellow, purple, green, violet are produced
and considering that separate aqueous solution of each compound show electrical conductance then
which is/are true

(A) All four coloured compounds are ionisation isomers.

(B) In all the four compounds hybridisation of central atom is same
(C) All four compounds have same number of unpaired e–.
Addition of excess AgNO3 to the equimolar solution of separate four compound, two
(D)
solution will produce same amount of AgCl as ppt.

SECTION-II

1) Ionic compound AB has NaCl type structure. It's density is 3.6 gm/cc. When 4 gm of this

compound is dissolved in 200 gm of water, one molal solution is formed. If radius of anion is pm
and then find radius of cation (in pm). (Given : Avogadro number NA = 6 × 1023)

2) Determine the minimum weight of I2 in kg required to form at least 1 kg of each of the product
(except water) when I2 reacts with hot & concentrated NaOH [Assume 100% yield].

3) From the compounds given below, number of compounds which give positive Tollen's test is
_______.
(i) Benzaldehyde, (ii) Acetaldehyde, (iii) Acetone, (iv) Acetophenone, (v) Methanal, (vi) 4-
Nitrobenzaldehyde,
(vii) Cyclohexane carbaldehyde.

4)
Find out the value of (x–y) in given reaction.

5) How many reactions give benzaldehyde as one of the products

(a) (b)

(c) (d)

(e) (f)

(g)

6) Find total number of correct statement(s) related to the metal extraction processes (i) A mixture
of PbS and ZnS can be separated by addition of KCN as depressant in froth floatation process for
PbS.
(ii) Mond's process is used for refining of Ti, Zr and Hf.
(iii) Separation of Ag from Pb in Parke's process works on solvent extraction technique.
(iv) Retort process is used to reduce ZnO to Zn where Zn distills off and collected by rapid cooling, is
known as Zinc spelter
(v) Casseterite, white bauxite and chromite ore can be concentrated by magnetic separation.

7)

How many of the following species are planar.

[ZnCl4]2–, •CH3, •CF3, B2H6, Al2H6, CℓF3.
[Ni(CN)4]2–, [Pd Cl4]2–, ClO3, S2O82–, N2O5.

8) How many of following statement(s) is/are correct about steel? (i) Tempering : Quenched steel
becomes hard but brittleness disappears
(ii) Annealing : Quenched steel becomes soft.
(iii) Case-hardening : This gives hard coating of iron nitride on the surface.
(iv) Hardening/Quenching : Steel is heated to temperature between 500 to 575 K and then cooled
slowly. It makes hard and brittle.
(v) Mn : Imparts high hardness and increases tensile strength of steel.

PART-3 : MATHEMATICS

SECTION-I (i)

1) A ray of light travelling along the line x = 2 strikes a parabolic mirror with equation y2 – 2y – 4x +
5 = 0 and gets reflected from its surface then equation of reflected ray may be -
(A) y = 5
(B) x = –1
(C) y = –1
(D) y = 1

2) If f(x) is differentiable at x = 5 and f(5) = 1, , then value of

is

(A) 0
(B) 1

(C)

(D)

3) Let A and B be two 2 × 2 non singular skew symmetric matrices such that AB = BA. If PT denotes
transpose of P then (B2A2)2((BTA)–1)2((BA–1)T)2 is equal to

(A) A4
(B) B4
(C) A2
(D) A2B2

4) Let be three non-zero vectors which are pairwise non-collinear. If is collinear with
and is collinear with , then is :

(A)
(B)
(C)
(D)

SECTION-I (ii)

1) Consider an ellipse E :

Normal is drawn at a point P on E to intersect x and y axis at A and B respectively then locus of
(A)
circumcentre of ΔOAB is 4x2 + y2 = 9 (where O is the origin)
Normal is drawn at a point P on E to intersect x and y axis at A and B respectively then locus of
(B)
circumcentre of ΔOAB is x2 + 9y2 = 4 (where O is the origin)
Area of quadrilateral formed by foci and end points of minor axes of the given ellipse is sq.
(C)
units
If a tangent is drawn at P on E to intersect the x-axis and y-axis at L and M respectively then
(D)
minimum value of LM is 6 units
2) If k ∈ N and , where [.] denotes greatest integer function, then

(A) I20 = –80

(B) I20 = –60

(C)

(D)

3) If a function f : R → (0, ∞) satisfies relation ∀ x ∈ R and

f(0) = f ′ (0) = 1 then which of following statement is/are correct ?

(A)

(B) f(x) has local minimum value at x = 0

(C) f(x) = ex has two solutions
(D) f(x) = ex has one solutions

4) Let A = [aij] be a matrix of order 3 such that AP = 2I where I is an identity matrix of order 3 and

, then which of the following hold(s) ?

[Note : adj(M) denotes adjoint of matrix M and Tr(M) denotes trace of matrix M]

(A) Tr(adj(adjA)) = 48
(B) Tr(adj(adj A)) = 12
(C) det(adjA. adj(adjA)) = 218
(D) det(adjA. adj(adjA)) = 224

SECTION-II

1) If from a point on the line x – y + 2 = 0, tangent are drawn to the hyperbola such that

the chord of contact passes through fixed point (α, β) then equals

2) The solution of is where c is constant then, find the

value of p + q ?
3) The area bounded by the curves y = 6x – x2 and y = x2 – 2x is A, then value of is

4) A and B are square matrices of order 3, where |A| = –2 and |B| = 1, then the absolute value of

is

5) Let B be a skew symmetric matrix of order 3 × 3 with real entries.

Given I – B and I + B are non-singular matrices.
If A = (I + B)(I – B)–1 where det(A) > 0, then the value of det (2A) – det (adj A) is
[here det (P) denotes determinant of square matrix P and det(adj P) denotes determinant of adjoint
of square matrix P respectively]

6) Let is a symmetric matrix, and

, then projection of on is

7) A function y = f(x) satisfies the differential equation f(x) sin2x – cosx + (1 + sin2x) f'(x) = 0 with
initial condition y(0) = 0. The value of f(π/6) is equal to

8) Let f be a function defined on R (set of all real numbers) such that f ′ (x) = 2018(x – 2019)3(x –
2020)4(x – 2021)5(x – 2022)6 for all x ∈ R. If g is a positive valued function defined on R such that f(x)
= ℓn(g(x)), for all x ∈ R. Then the number of points in R at which g(x) has a local minima, is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A A C C

SECTION-I (ii)

Q. 5 6 7 8
A. A,C,D A,C,D A,D A,B,C,D

SECTION-II

Q. 9 10 11 12 13 14 15 16
A. 1.00 8.00 9.00 3.00 3.00 3.00 7.00 3.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. C B C B

SECTION-I (ii)

Q. 21 22 23 24
A. A,B,D B,C B,C B,C,D

SECTION-II

Q. 25 26 27 28 29 30 31 32
A. 66.00 3.85 5.00 4.00 6.00 3.00 5.00 3.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 33 34 35 36
A. C B B A

SECTION-I (ii)

Q. 37 38 39 40
A. A,C,D A,C A,D A,C
 SECTION-II

Q. 41 42 43 44 45 46 47 48
A. 3.00 4.00 8.00 8.00 7.00 0.85 or 0.86 0.40 1.00
 SOLUTIONS

PART-1 : PHYSICS

1) By analogy with Gauss Theorem; in gravitation, we have

mrω2 or ... (1)

also from equation (1)

2) When block is pulled and then release. Block having some speed along up incline then

to incline plane. so, this magnetic force

will not affect time period of spring block system.

3)

Motional emf

4)
When switch is at position-1
amax = CE1
5)
By Biot-savart Law

e– experience magnetic force

 Upwarm

6) The radius of circle of path of charged particle is R =

For particle to enter region III R > . or >

For path length of particle in region II to be maximum

= R or V =

The period of revolution of charged particle is ω =

The time spent in region II is t = , which is same for all the cases when it returns to
region II.

7)

Total energy = = 4RT

average energy /mole = 2RT

8) (A) At t = 0, capacitor acts as short-circuit

At t → ∞, capacitor acts as open circuit and no current flows through voltmeter.

(B)

=
(C) τ = 1 sec.
So, by i = i0e–t/τ current at t = 1 sec. is = i0/e
(D) After long time no current flows since both capacitor and voltmeter does not allow.

9)
Fnet = F1 – F2
= i2B1(2a) – i2(B2)(2a)

∴β=1

10)

11)

So, VB – VA = 9

12)

For Ist surface :

v = 30 cm
This will be the distance of object for second surface.
For IInd surface :

v' = + 20 cm.
For IIIrd surface :
u = 20 – 16 = 4 & R = ∞

V" = 3 cm

13)

ratio of charge at P1 and P2 is q1 : q2 = ,

so null point distance

 14)
m = 1kg, R = 10 cm

Initial
Now if we reverse direction of current

= 300

15)
dQ = dU + dw

dQ = dU +

dQ =

16)
At equilibrium mg = iℓB

qmax = CΔv =
= 3 × 10–5

PART-2 : CHEMISTRY
17) C6H5COOH(s) + 7.5 O2(g) → 7CO2(g) + 3H2O(ℓ), Δng = –0.5
ΔH = ΔU + ΔngRT
ΔH = –321 – 0.5 × R × 300 = –321 – 150R

18) (A) 2Al2O3(s) + 3C(s) → 4Al(s) + 3CO2(g) ; ΔrG° = +ve

(B) 2Al2O3(s) + 6C(s) → 4Al(s) + 6CO(g) ; ΔrG° = +ve
(C) 2PbO(s) + C(s) → 2Pb(s) + CO2(g) ; ΔrG° = –ve
(D) 2PbO(s) + 2C(s) → 2Pb(s) + CO2(g) ; ΔrG° = –ve

19)

20) (A) Casseterite ore (SnO2) : Roasting is performed to remove impurities of pyrites of
copper and iron (Cu2S and FeS)
(B) For silver glance (Ag2S) → Mac Arthur Forest cyanide process.
(C), (D) CuFeS2, PbS (sulphide ore) → Roasting.

21) H2SO4(aq.) + 2NH4OH(aq.) → (NH4)2SO4(aq.) + 2H2O(ℓ)

Initial millimoles 200 × 0.2

= 25 = 40 (limiting reagent)

ΔHneutralisation = – = –52.5 kJ/mol

ΔHneutralisation of NH4OH with strong acid = 52.5 kJ/mol
ΔHneutralisation = ΔHionisation + ΔrH (H+ + OH– → H2O )
–52.5 = x – 57
ΔHionisation (NH4OH) = x ⇒ 4.5 kJ/mol
for NH4OH and CH3COOH:
ΔHneutralisation = ΔHionisation (NH4OH) + ΔHionisation (CH3COOH) + ΔrH (H++OH– → H2O) = – 48.1 = 4.5
+ y – 57
ΔHionisation of CH3COOH = y = 4.4 kJ/mol
for 2H2O (l) → 2H+ + 2OH– ⇒ ΔH = + 2 × 57 = 114 kJ

22) (A) ΔU = 0 only for an ideal gas at constant temperature.

(B) ΔH = Δ(Δng = 0)
ΔH = ΔU = qv
(C) For any irreversible isothermal expansion
ΔSuniverse > 0
ΔSsystem + ΔSsurr > 0
ΔSsystem is +ve
ΔSsurroudning is –ve
|ΔSsystem| > |ΔSsurrounding|
(D) According to second law of thermodynamics entropy of inverse must increase during
spontaneous process.
23) gives Bayer’s test

gives effervescence with aq. NaHCO3

24)

The correct answer is (B),(C), (D)

25) Molality = 1 =
Molar mass of AB = 20 g/mole

3.6 =

a=
a = 2(r+ + r–)

r+ = 66 pm

26) 3I2 + 6NaOH → 5NaI + NaIO3 + 3H2O

To prepare atleast 1 kg of each product we must prepare 1 kg of NaIO3 so that NaI > 1 kg

Moles of NaIO3 =

Moles of I2 required = mol

Mass of I2 required = × 254 = 3848 g = 3.85 kg

27)

The correct answer is 5.00

28) The correct answer is 4.00

29) Except (C) All are

30) (i), (iii) , (iv)

 31) CH3, CℓF3, PdCl42–, N2O5 , [Ni(CN)4]2–

32) (i), (ii) and (v) is correct

PART-3 : MATHEMATICS

33)
(y – 1)2 = 4x – 4
(y – 1)2 = 4(x – 1)
y – 1 = ±2
Equation of reflected rays
y = –1 and y = 3

34)

use L hospital

35) BT = –B; AT = –A ;
(–A)–1 = –A–1; (–B)–1 = –B–1
B2A2B2A2A–1(–B)–1A–1(–B)–1(–A)–1(–B)(–A)–1(–B)
= BB.AABBAAA–1B–1A–1B–1A–1BA–1B = B4

36) ...(1)
...(2)
from (1) & (2)
from eq. (1) we get

37)
A(3cosθ, 0) B(0, –6sinθ)
2h = 3cosθ, 2k = –6sinθ

4x2 + y2 = 9

(C) ,

&
B1(0, 2) & B2(0, –2)

(D)
L = (4secθ, 0) M = (0, 2cosecθ)

LMmin = 6

38)

King :

Add :

⇒ Ik = –4k
39)

x=0 c=0

x=0 k = –1
f(x) =

40) AP = 2I ⇒ |A| = 8

P = 2A–1 ⇒
adj(adjA) = adj(4P) = 16adjP
Tr(adj(adjA)) = 48;
adjA.adj(adjA) = 16.4P.adjP
= 64 |P| I3 = 64I
∴ det(adjA.adj(adjA)) = (64)3 = 218

41) P(t + 2, t)

COC : ⇒

(α, β) = (3, 1)

42)

or
43)
point of intersection A (4, 8)

44) Required value =

∵ ; |AdjB| = |B|n – 1, where n is order

∴ Value =

45) A = (I + B)(I – B)–1

AAT = (I + B)(I – B)–1((I – B)T)–1(I + B)T
= (I + B)(I – B)–1(I + B)–1(I – B)
= (I + B)((I + B)(I – B))–1(I – B)
= (I + B)((I – B)(I + B))–1(I – B)
(∵ I + B, I – B are commutative)
∴ AAT = (I + B)(I + B)–1(I – B)–1(I – B) = I
∴ AAT = I
|AAT| = |I| = 1 ⇒ |A|2 = 1
as |A| > 0 ⇒ |A| = 1
det(2A) – det(adj (A)) = 8 det(A) – det(A)2
= 8(1) – (1)2 = 7.

46) Symmetric matrix

so x – 1 = 2x + 3 ⇒ x = –4

Projection =

47) ysin2x – cosx + (1 + sin2x) = 0 where y = f(x)

I.F. = (by putting 1 + sin2x = t)

y(1 + sin2x) =
y(1 + sin2x) = sinx + C; (y(0) = 0) ⇒ C = 0

hence,

48) ∴ g(x) = ef(x) ⇒ g ′ (x) = ef(x).f ′ (x) ∀ x ∈ R

⇒ g ′ (x) = ef(x)[2018.(x – 2019)3.(x – 2020)4.(x – 2021)5.(x – 2022)6]
∵ f ′ (x) changes its sign from negative to positive in the neighbourhood of x = 2021
⇒ f(x) has local minima at x = 2021
so, the number of local minima is one.