17-08-2025

0999DJM262103250004 JM

PART-1 : PHYSICS

SECTION-I

1) For a particle moving on circle at constant angular speed which is incorrect :-

(A) The acceleration vector points towards centre of circle

(B) Velocity vector is tangent to circle
(C) The velocity and acceleration are perpendicular to each other
(D) The acceleration vector is along tangent line

2) A particle moves along circle of radius with constant angular acceleration. If velocity of
particle at end of second revolution after motion has begun is 80 m/s the tangential acceleration is :-

(A) 40π m/s2

(B) 40 m/s2
(C) 640π m/s2
(D) 160π m/s2

3) A grinding wheel attained a angular velocity of 20 rad/sec in 5 sec starting from rest. Find the
number of revolutions made by the wheel :-

(A)
revolution

(B)
revolution

(C)
revolution

(D)
revolution

4) A particle is kept fixed on a turn table rotating uniformly. As seen from the ground the particle
goes in a circle, its speed is 20 cm/s and acceleration is 20 cm/s2. The particle is now shiffted to a
new position to make the radius half the original value. The new values of speed and acceleration
will be:-

(A) 10 cm/s, 10 cm/s2

(B) 10 cm/s, 80 cm/s2
(C) 40 cm/s, 10 cm/s2
(D) 40 cm/s, 40 cm/s2
5) A car is travelling with linear velocity v on ‘a’ circular road of radius r. If it is increasing its speed
at the rate of 'a' metre/sec2, then the resultant acceleration will be :-

(A)

(B)

(C)

(D)

6) A conical pendulum is moving in a circle with angular velocity ω as shown. If tension in the string

is T, which of following equations are correct ?

(A) T = mω2ℓ
(B) T sinθ = mω2ℓ
(C) T = mg cosθ
(D) T = mω2ℓ sinθ

7) A pendulum bob is swinging in a vertical plane such that its angular amplitude is less than 90°. At
its highest point, the string is cut. Which trajectory is possible for the bob afterwards :-

(A)

(B)

(C)
(D)

8) A ball of mass (m) 0.5 kg is attached to the end of a string having length (L) 0.5 m. The ball is
rotated on a horizontal circular path about vertical axis. The maximum tension that the string can
bear is 324 N. The maximum possible value of angular velocity of ball (in radian/s) is :-

(A) 32
(B) 36
(C) 38
(D) 40

9) A particle is moving along a circular path with a constant speed of 10 ms–1. What is the magnitude
of the change in velocity of the particle, when it moves through an angle of 60° around the centre of
the circle in (m/s) is ?

(A) 10
(B) 20
(C) 30
(D) 40

10) A car travelling on a smooth road passes through a curved portion of the road in form of an arc
of circle of radius 10 m. If the mass of car is 500 kg, the reaction on car at lowest point P where its

speed is 20 m/s is x × 103 N then find x ?

(A) 15
(B) 20
(C) 25
(D) 30

11) In the circuit element given here, if the potential at point B, VB = 0, then the potentials of A and

D are given as :-
(A) VA = –1.5 V, VD = +2 V
(B) VA = +1.5 V, VD = +2 V
(C) VA = +1.5 V, VD = +0.5 V
(D) VA = +1.5 V, VD = –0.5 V

12) A battery of internal resistance 4Ω is connected to the network of resistance as shown. In order
that maximum power can be delivered to the network, the value of R in ohm should be :-

(A)

(B) 2

(C)

(D) 18

13) Three bulbs A, B & C are connected as shown in fig. The bulbs B & C are identical. If the bulb C

is fused:-

(A) both A & B will glow more brightly

(B) both A & B will glow less brightly
(C) A will glow less brightly & B will glow more brightly
(D) A will glow more brightly & B will glow less brightly

14)

The current in the adjoining circuit will be

(A)
ampere

(B)
ampere

(C)
ampere

(D)
ampere

15) In the circuit shown in figure reading of voltmeter is V1 when only S1 is closed, reading of
voltmeter is V2 when only S2 is closed and reading of voltmeter is V3 when both S1 and S2 are closed.

Then :-

(A) V3 > V2 > V1

(B) V2 > V1 > V3
(C) V3 > V1 > V2
(D) V1 > V2 > V3

16) What is the equivalent resistance between the points A and B of the network :-

(A)

(B) 8 Ω
(C) 6 Ω

(D)

17) Masses of three wires of copper are in the ratio of 1 : 3 : 5 & their lengths are in the ratio 5 : 3 :
1. The ratio of their electrical resistance are :-
(A) 1 : 3 : 5
(B) 5 : 3 : 1
(C) 1 : 15 : 125
(D) 125 : 15 : 1

18) A battery of e.m.f. 10 V is connected to resistance as shown in figure. The potential difference

VA–VB between the points A and B is

(A) –2V
(B) 2V
(C) 5V

(D)

19) The potential difference between points A and B of adjoining figure is

(A)

(B)

(C)

(D) 2V

20) A wire of resistor R is bent into a circular ring of radius r. Equivalent resistance between two
points X and Y on its circumference, when angle XOY is α, can be given by :-
(A)

(B)

(C) R(2π – α)

(D)

SECTION-II

1) A particle of mass 1 kg is tied to a string of length 1 m and whirled along horizontal circle of
radius 1 m keeping the particle on a smooth horizontal table at speed 10 m/s. The tension in string in
(N) is :-

2) A motor car is travelling at 60 m/s on a circular road of radius 1200 m. It is increasing its speed at
the rate of 4 m/s2. Find the acceleration of the car is (in m/s2).

3) The resistance of bulb filament is 100 Ω at a temperature of 100°C. If its temperature coefficient
of resistance be 0.005 per °C, its resistance will become 200 Ω at a temperature of-

4) The effective resistance (in Ω) across the points A and I is :-

5) In the above circuit the current in each resistance is:-

PART-2 : CHEMISTRY
 SECTION-I

1) In the reaction
CrO5 + H2SO4 → Cr2(SO4)3 + H2O + O2 one mole of CrO5 will liberate how many moles of O2 :-

(A) 5/2
(B) 5/4
(C) 9/2
(D) 7/4

2) Match the column :-

Column I Column II
(Reduction Process) (Charge Required)

(a) 1 mol of MnO to Mn2+ (p) 193000C

(b) 1 mole of Cr2O to Cr3+ (q) 289500C

(c) 1 mole of Sn4+ to Sn2+ (r) 482500C

3+
(d) 1 mole of to (s) 579000C
(A) a → p, b → r, c → q, d → s
(B) a → r, b → s, c → q, d → p
(C) a → s, b → q, c → p, d → r
(D) a → r, b → s, c → p, d → q

3) When CrI3 oxidies to Cr2O72– and IO4– equivalent mass of CrI3 will be

(A)

(B)

(C)

(D)

4) Which is correct statement regarding CrO5

a : Oxidation number of Cr is +6.
b : Four oxygen-atoms of molecule are involved
in peroxide linkage.
c : Only one oxygen-atom has O.N. = –2

(A) All are correct

(B) b, c are correct
(C) a,c are correct
(D) Only b is correct
5) Ratio of number of oxygen atoms which show –1 and –2 oxidation states in the compound H2S2O8
is

(A) 1 : 1
(B) 1 : 3
(C) 3 : 1
(D) None of these

6) The oxidation state of molybdenum in its complex, [Mo2O4(C2H4)2(H2O)2]2– is –

(A) +2
(B) +3
(C) +4
(D) +5

7) In the reaction ; As2S3 + HNO3 → H3AsO4 + H2SO4 + NO, the element oxidised is/are :-

(A) As only
(B) S only
(C) N only
(D) As and S both

8) In the redox reaction

xMnO + yPbO2 + zHNO3
→ HMnO4 + Pb(NO3)2 + H2O

(A) x = 2, y = 5, z = 10
(B) x = 2, y = 7, z = 8
(C) x = 2, y = 5, z = 8
(D) x = 2, y = 5, z = 5

9) Which of the following has been arranged in order of increasing oxidation number of nitrogen ?

(A) NH3 < N2O5 < NO < N2

(B)
(C)
(D) NO2 < NaN3 < < N2O

10) Equivalent mass of Na2S2O3 during conversion into Na2S4O6 is same as :-

(Atomic masses : K = 39, Mn = 55, Na = 23)

(A) Equivalent mass of KMnO4 as oxidant in acidic medium

(B) Equivalent mass of KMnO4 as oxidant in basic medium
(C) Equivalent mass of KMnO4 as oxidant in neutral medium
(D) None of these
11) Which of the following has an optical isomer ?

2+
(A) [Co(en)(NH3)2]
3+
(B) [Co(H2O)4(en)]
3+
(C) [Co(en)2(NH3)2]
+
(D) [Co(NH3)3Cl]

12) The IUPAC name of the complex [CrCl2(H2O)4]NO3 is:-

(A) Dichlorotetraaquachromium (III) nitrate

(B) Tetraaquadichlorochromium (III) nitrate
(C) Chromium tetra aqua dichloro nitrate
(D) Dichlorotetraaquachromium nitrate

13) Give the correct order of electrical conductivity of aquous solution of following complexes :-
(a) [Pt(NH3)6]Cl4 (b) [Cr(NH3)6]Cl3
(c) [Co(NH3)4Cl2] Cl (d) K2[PtCl6]

(A) a < b < c < d

(B) a > b > d > c
(C) a < b < d < c
(D) a > b < c < d

14) Which is the pair of ambidentate ligand ?

(A)
(B)
(C)
(D)

15) One unknown complex has the spin only magnetic moment is of 1.73 BM. Predict the correct
situation of it -

(A) d7, Oh-field, with SFL

(B) d5, sq.planar-field, with SFL
(C) d9, Td, field with WFL
(D) All of these

16) One mole of the complex compound Co(NH3)5Cl3 gives 3 moles of ion on dissolution in water. One
mole of the same complex reacts with two moles of AgNO3 solution to yield two moles of AgCl(s). The
structure of the complex is-

(A) [Co(NH3)4Cl]Cl2.NH3
(B) [Co(NH3)5Cl].Cl2
(C) [Co(NH3)3Cl].2NH3
(D) [Co(NH3)4Cl2]Cl.NH3

17) The donor sites of [EDTA]–4 are

(A) O atoms only

(B) N atoms only
(C) Two N atoms and four O atoms
(D) Three N atoms and Three O atoms

18) The value of n in the carbonyl is

(CO)n — Co – Co — (CO)n

(A) 4
(B) 5
(C) 6
(D) 8

19) Among and

species, the hybridization state of Ni atoms are respectively :

(A)
(B)
(C)
(D)

20) Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong ?

The complex involves d2sp3 hybridisation and

(A)
is octahedral in shape.
(B) The complex is paramagnetic.
(C) The complex is an outer orbital complex.
(D) The complex gives white precipitate with AgNO3 solution.

SECTION-II

1) 6 × 10–3 mole K2Cr2O7 reacts completely with 9 × 10–3 mole X+n to give XO3– and Cr+3. The value of
n is :-

2) How many moles of hydrazine (N2H4) can be oxidized into N2 using 2/3 mole of bromate ions
:-

3) 25 ml of N/10 caustic soda solution exactly neutralise 20 ml of an acid solution contained 7.875
gm of acid per litre. What will be Equivalent mass of acid ?
4) Find sum of number of unpaired electron in
[CoCl6]–3, [Cr(NH3)6]+3 and [Zn(NH3)4]+2 :-

5)

The CFSE for [CoCl6]4– complex is 18000 cm–1. The Δ for [CoCl4]2– will be :

PART-3 : MATHEMATICS

SECTION-I

1) dx (where a, b ∈ R+) is equal to

(A) 2x 3x
a b ℓn +k

(B)
ℓn +k

(C)
ℓn (a2xb3x e) + k

(D)
– ℓn (a2xb3x e) + k

2) If = f(x) · log(x+1)+g(x) · x2+Ax+ C, then

(A) f(x) = x2
(B) g(x) = log x
(C) A = 1
(D) None of these

3) is equal to

(A)

(B)

(C)

(D)
4) is equal to -
(where C is constant of integration)

(A)

(B)

(C)

(D)

5) If = ln(f(x)) + g(x) + C where C is the constant of integration and

f (x) is positive, then f (x) + g (x) has the value equal to

(A) ex + sin x + 2x
(B) ex + sin x
(C) ex – sin x
(D) ex + sin x + x

6) dx equals -

(A)

(B)

(C)

(D)

7) If , where C is a constant of integration, then

the ordered pair (A(x), B(x)) can be

(A)
(B)
(C)
(D)
8) The integral is equal to (where C is a constant of integration)

(A)

(B)

(C)

(D)

9) If

, where c is a constant of integration, then

g(0) is equal to

(A) 2
(B) e2
(C) e
(D) 1

10) If = ƒ(x) + C and

ƒ , then ƒ(–1) is equal to -

(A) 0

(B)

(C)

(D)

11) The integral

is equal to (where C is constant of integration)

(A)

(B)

(C)
(D)

12) equal:

(A)

(B)

(C)

(D)

13) If A = (1 + tan1º).(1 + tan11º).(1 + tan20º). and

B = (1 + tan25º).(1 + tan34º).(1 + tan44º), then simplified value of AB is :

(A) 2
(B) 4
(C) 8
(D) 16

14) If α and β are solutions of sin2x + a sin x + b = 0 as well that of cos2x + c cos x + d = 0, then
sin(α + β) is equal to

(A)

(B)

(C)

(D)

15)

The value of

is

(A)

(B)

(C)

(D) None
16) If tan α is equal the integral solution of inequality 4x2–16x + 15 < 0 and cos β equal to slope of
the bisector of the first quadrant, then sin (β + α) sin (α – β) is :-

(A) 3/5
(B) –3/5
(C) 4/5
(D) –4/5

17) If cosx + cosy = and , then cosx cosy is -

(A)

(B)

(C)

(D)

18)

If the maximum value of is λ then the value of is

(A) 0
(B) 6
(C) 8
(D) 1

19) If r > 0, –π ≤ θ ≤ π and r , θ satisfy r sinθ = 3 and r = 4 (1 + sinθ) then no. of possible solutions
of the pair (r, θ) is -

(A) 2
(B) 3
(C) 4
(D) 1

20) Let x = sin 1°, then the value of the expression

is equal to

(A) x

(B)
(C)

(D)

SECTION-II

1)

where , then ƒ(0) + 10K is equal to

(where C is constant of integration)

2) If

= then the value of 'a' is :

3) Let , then the value of a + b is :

4) Maximum value of is :-

5) Let α and β be two real roots of the equation

(k + 1) tan2x – . λ tanx = (1 – k),
where k(≠ –1) and λ are real numbers.
If tan2 (α + β) = 50, then value of |λ| is ;
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B C A B A C B A C D B C C B B D B C A

SECTION-II

Q. 21 22 23 24 25
A. 100 5 300 1 0

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D D B A B B D A C B C B B A D B C A B C

SECTION-II

Q. 46 47 48 49 50
A. 1 1 63 7 8000

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D D D C B D C C A C B A C D B C D B A B

SECTION-II

Q. 71 72 73 74 75
A. 20 1 4 4 10
 SOLUTIONS

PART-1 : PHYSICS

1)

The Correct Answer is D

2)

3) ω = ω0 + αt
20 = 0 + α(5)
α = 4 rad/s2
(20)2 = 0 + 2(4)Δθ

4) Angular speed of table =

v=10 cm/s2
rω2 = 20

∴
ac = 10cm/s2

5)

ar =
at = a

anet =

6)
Tcosθ = mg ⇒ T = mg/cosθ
Tsinθ = mω2r
⇒ Tsinθ = mω2ℓsinθ
⇒ T = mω2ℓ

7)

8)
Tsinθ=mω2 (Lsinθ) ⇒ T = mω2L

9) ΔV =

10)

N – 5000 = 500 ×
⇒ N = 25000
⇒ N = 25K

11) Potential difference between A and B

Potential difference between B and C

⇒
Potential difference between C and D
12) For max power transfer, r = Req.

4= ⇒ R = 2Ω

13) When C is fused R , hence I↓ Thus brightness of A will decrease. Also as now entire
current I will pass through B, hence brightness of B will increase.

14)

15) In series : Potential difference ∝ R

When only S1 is closed

When only S2 is closed

and when both S1 and S2 are closed combined
resistance of 6R and 3R is 2R

∴ ⇒

16)
Rnet = 8Ω

17) R = =

R1 : R2: R3 = : :

= : : = : :
= 25 × 5 : 15 : 1
= 125 : 15 : 1

18) Req = 5Ω, Current and current in each branch = 1A

Potential difference between C and A,
.......(i)
Potential difference between C and B,
......(ii)
On solving (i) and (ii)

Short Trick :

19) I= ........(1)

I1= I2 = .......(2)

=
VA–VB = I1 × 10

= × 10

20) λ =
Rxwy= λrα
Rxzy = λr(2π – α)

21) T =

22) aT = 4 m/s2
v = 60 m/s
r = 1200 m
 aR = 3

aT = 4 ⇒ a = a = 5.

23)

R100 = …(1)
RT = ….(2)

T=

T = 200 + 100 = 300ºC

24) Use symmetry method 1Ω

25) Current in each resistor is 3ℓr0. (Ans. 0)

PART-2 : CHEMISTRY

26)

The Correct Answer is D

27)

Equivalents = Mole × (n-factor) = Faraday

; 1 mole × 5 = 5F = 482500 C
; 1 mole × 6 = 6F = 579000C
+4 +2
Sn → Sn ; 1 mole × 2 = 2F = 193000 C

Al+3 → Al ; 1 mole × 3 = 3F = 289500 C

28)
n-factor ⇒ Cr = (+ 3 to + 6) = 3e– loss
I = (– 1 to + 7) × 3 = 24 e– loss
n-factor = 27 ∴ E =

29) The structure of CrO5 is

30)
According to structure,
Oxidation state of 2"O" atom = –1
(due to peroxide)
Oxidation state of 6"O" atom = –2
∴ Ratio of atoms = 2 : 6 = 1 : 3

31)

[Mo2O4(C2H4) (H2O)]–2
2x + 4(–2) = –2
x = +3

32) As2S3 → H3AsO4 + H2SO4 (+3) (–2) (+5) (+6)

33) x = 2, y = 5, z = 10

34)

The Correct Answer is C

35)
n-factor (e– transfer per mole)
= (+ 2 to + 2.5) × 2 "S atom = 1

n-factor = (+ 7 to + 6) × 1 "Mn" atom

36)
The Correct Answer is C

37)

The Correct Answer is B

38)

The Correct Answer is B

39) CN–, are ambidentate

40) μs = 1.73BM
no. of unpaired e–1 = 1
(a) d7 (SFL)

t2g
(b) d (SFL) dsp2
5

(c) d9 (WFL) sp3

41) [CO(NH3)5 Cl]Cl2 ⇒ give 3 mole ion

42)

The Correct Answer is C

43)
Co = Z → 27
Number of co-ordinate bond → 4
Number of delta bond → 1
So value of 'n' in (Co)n – Co – Co – (Co)n = 4

44) [Ni(CO)4], [Ni(CN)4]–2, [NiCl4]–2

 sp3 dsp2 sp3

45) [Cr+3(NH3)6]Cl3 + AgNO3 → AgCl↓

white
+3 0 3
Cr = [Ar]4s 3d

46)

For complete reaction : geq of K2Cr2O7 = geq of Xth

or mole of K2Cr2O7 × = moles of
X+n × 6 × 10–3 × 6 = (5 – n) × 9 × 10–3 [n = 1]

47) ; n-factor = (+ 5 to – 1)
–
= 6 e gain
N2H4 → N2 ; n-factor = (– 2 to 0) × 2
= 4e– loss
Total loss = Total gain

n × 4e– = × 6e– n = 1 mole

48)

100 ml → 7.875

20 ml →

=
E = 63

49)

[CoCl6]–3, Co+3 ⇒ 4s23d7 = d6

[Cr(NH3)6]+3, Cr+3 ⇒ 4s23d5d3

[Zn(NH3)4]+2, Zn+2 ⇒ 4s23d10

unpaired e– = 0
Sum = 7e–
 50)

PART-3 : MATHEMATICS

51) I=

=
Let a2x b3x = t. Then t ℓn a2b3 dx = dt. Therefore,

I=

=–

=–

52)

Hence, f(x) = , g(x) = – log x and

A=

53) Let I =

If = sin p, then dx = cos p dp

I=

=2

=2

= 2(tan p – sec p) = 2

54)

55)

= ℓn(ex + sinx + x) –x + C

56)

put log x = t
⇒ dx = et dt

57) The integral

Let x = tan2θ ⇒ dx = 2 tan θ sec2 θdθ,

So, 2tanθ sec2θdθ

 tanθ sec2θdθ

By integration by parts

= θ tanθ –
= θ tan2θ – tanθ + θ + C
= xtan–1 – + tan–1 +C
–1
= (x + 1)tan – +C
–1
= A(x) tan + B(x) + C [given]
So, (A(x), B(x)) = (x + 1, – )
Hence, option (C) is correct.

58) Given integral

= x cos x + sin x – sin x = x cos x

∴
By integration by parts, we have

Hence, option (C) is correct.

59) Given integral

Let ex = t ⇒ dx =

So,

= [given]
x
∴ g(x) = 1 + e ⇒ g(0) = 1 + 1 = 2

60)

61)

62)
63) If A + B = 45º, then (1 + tanA) (1 + tanB) = 2
AB = (1 + tan1º).(1 + tan11º).(1 + tan20º).
(1 + tan25º).(1 + tan34º)(1 + tan44º)
= 2.2.2 = 8

64) According to the given condition,

sin α + sin β = –a and cos α + cos β = –c

⇒ ...(1)

and ...(2)
(1) ÷ (2)

⇒
Hence, (D) is the correct answer.

65)

66) 4x2 – 16x + 15 < 0

(2x – 5) (2x – 3) < 0

<x<
∴ tan α = 2
and cos β = 1
Now sin (α + β) sin (α – β) = sin2α – sin2β
= cos2β – cos2α

=1– =1– =

67)

Also 2cos2x – 1 + 2cos2y – 1 =

⇒ cos2x + cos2y =

⇒ (cosx + cosy)2 – 2cosx cosy =

⇒ – 2cosx cosy =

68)

y = 7 cos2x + 6 sinx cos x – sin2x

= 3sin 2x + 4 cos 2x + 3
The maximum value of y is 8

Also

69)

r = 4 (1 + sinθ), r sinθ = 3

⇒r=4
⇒ r = 6, – 2

So, sinθ =

⇒θ=

(r, θ) =
2 pairs

70)

+ (tan 3° – tan2°) + (tan4° – tan3°) + ...

+ (tan 45° – tan 44°)]
71) = f(x) + K log|x| + C,
and f(π/4) = 1

= tan x + 2log |x| + C

f(x) = tanx, K = 2 (by comparing)
Now, f(0) + 10K = tan0 + 10×2 = 0 + 20 = 20

72) Put

⇒a=1

73)

∴ a = – 5, b = 9
a+b=4

74) sin6x + cos6x = 1 – 3 sin2xcos2x

=1–

75) tanα + tanβ =

tanα. tanβ =

tan(α + β) =