10-08-2025

2401CJA101029250022 JA

PART-1 : PHYSICS

SECTION - I (i)

1) In the given figure a uniform magnetic field B0 exist in outward direction and the wire CD of
resistance R is fixed and wire OA and OB rotating with angular speed ω as shown in figure both are
conducting wire, if at any instant OA = OB = ℓ and making an angle of 30o with y-axis each then find

the current in wire AB?

(A)

(B)

(C)

(D) Zero

2) A particle having mass m, charge q enters a cylinder region having uniform magnetic field B in
the inward direction as shown. If the particle is deviated by 60° as it emerges out of the field then

what is the time spent by it in the field.

(A)

(B)

(C)

(D) It depends on the speed of particle.

3) In the figure, there is a conducting wire having current i and which has a shape of half ellipse
 is kept in a uniform magnetic field B as shown. If the mass of wire is m, the

acceleration of wire will be:

(A)

(B)

(C)

(D)

4) A rod of length L is pivoted at one end and is rotated with a uniform angular velocity in horizontal
plane. Let T1 and T2 be the tensions at the points L/4 and 3L/4 away from the pivoted ends.

(A) T1 > T2
(B) T2 > T1
(C) T1 = T2
(D) The relation between T1 and T2 depends on whether the rod rotates clockwise or anticlockwise

SECTION - I (ii)

1) A particle of charge +q and mass m moving under the influence of a uniform electric field E and
uniform magnetic field B follows a trajectory from P to Q as shown in figure. The velocities at P and

Q are and , Which of the following statement(s) is/are correct ?

(A)
E=

(B)
Rate of work done by the electric field at P is
(C) Rate of work done by the electric field at P is zero
(D) Rate of work done by both the fields at Q is zero
2) A particle of mass m and charge q, moving with velocity v enters region II normal to the boundary
as shown in the figure. Region II has a uniform magnetic field B perpendicular to the plane of the
paper. The length of the Region II is ℓ. Choose the correct choice (s).

(A)
The particle enters Region III only if its velocity v >

(B)
The particle enters Region III only if its velocity v <

(C) Time spent by particle in Region II is when

(D) Time spent in Region II is same for any velocity v as long as the particle returns to Region I

3)

One end of massless inextensible string of length is fixed and other end is tied to a small ball of
mass m. The ball is performing a circular motion in vertical plane. At the lowest position, speed of
ball is . Neglect any other forces on the ball except tension and gravitational force.
Acceleration due to gravity is g.

(A) At the highest position of ball, tangential acceleration of ball is 0

(B) At the highest position of ball, tangential acceleration of ball is g
(C) During circular motion, minimum value of tension in the string is 15 mg
(D) During circular motion, minimum value of tension in the string is 21 mg

SECTION - I (iii)

Common Content for Question No. 1 to 2

A conducting rod of negligible resistance can slide on smooth U shaped rail as shown. At t = 0
conducting rod is given a velocity of 10 m/s towards right. A uniform magnetic field B = 1 T exists in

the region. [Mass of conducting rod is 1 kg and ℓ = 1 m]

1)

The distance travelled by the conducting rod when its speed is 5 m/s is :
(A)

(B) 5m
(C) 10 m
(D) 20 m

2) Heat loss in the resistor during the time interval t = 0 to time t when the speed of the conducting
rod is 6 m/s is :

(A) 64 J
(B) 36 J
(C) 32 J
(D) 50 J

Common Content for Question No. 3 to 4

A non-relativistic positively charge particle of mass 'm' and charge 'Q' is released from height 'h'
from earth surface. There is constant horizontal magnetic field of intensity 'B'. The acceleration due
to gravity is 'g'. The magnitude of magnetic field is selected in such a way it does not collide with

earth surface.

3) For what magnitude of magnetic field, condition of no colliding with earth surface is fulfilled.

(A)

(B)

(C)

(D)

4) If magnitude of magnetic field is increased to new value and particle does not collide with surface.
Then, which of following will increase ?

(A) Magnitude of acceleration at an instant when particle has maximum speed

(B) The minimum separation between particle and earth surface
(C) Radius of curvature at an instant when particle has maximum speed
(D) Maximum speed
 SECTION - II

1) Loop A of radius r(r << R) moves towards a stationary constant current carrying loop B with a
constant velocity v in such a way that their planes are parallel and coaxial. The distance between the
loops when the induced emf in loop A is maximum is x. Fill x (in m) in OMR sheet. (Take : R = 6 m)

2) A uniform magnetic field of 0.06 T is inside plane of the figure. The resistance of rod is 25Ω, mass
is 36 gm and it can slide freely on smooth parallel rails which are perfectly conducting. The whole
system is in horizontal plane. The rod starts from rest. If terminal velocity of the rod (in m/s) is v

then find .

3) Consider a metallic ring of radius 1 m, mass 1 kg and carrying a current of 1A in a gravity free
space in the x-y plane with its centre O at the origin as shown in the figure. If a uniform magnetic
field T is applied, then the instantaneous acceleration of the point P (which is on the y-axis at

the moment) will be C × π m/s2. Find the value of C.

4) A string with one end fixed on a rigid wall passing over a fixed frictionless pulley at a distance of
4m from the wall has a point mass M = 2 kg attached to it at a distance of 3m, from the wall. A mass
m = 0.5 kg attached at the free end is held at rest so that the string is horizontal between the wall
and the pulley, and vertical beyond the pulley. What will be the speed (in m/sec) with which the mass
M will hit the wall when mass m is released?

5) A block of mass 1 kg is slowly pulled along the curve path ACB by a tangential force as shown in
figure. The work done (in joule) by the frictional force when the block moves from A to B is (take g =

10 m/s2)

6) A collar B of mass 2kg is constrained to move along a vertical smooth and fixed circular track of
radius 5m as shown in figure. The spring is in plane of the track and has a spring constant of 200
N/m. It is un-deformed when collar is at A. It starts from rest at B. What is the normal force (in N)
exerted by the track on the collar when it passes through A ?

PART-2 : CHEMISTRY

SECTION - I (i)

1) Difference in wavelength of two extreme spectral lines of H-atom in Balmer region is: (Where RH
is Rydberg constant)

(A) 7.2 / RH
(B) 0.25 / RH
(C) 4 / RH
(D) 3.2 / RH

2)

Major product (C) is :

(A)

(B)

(C)

(D)

3)

Which of the following ligand is ambidentate

–
(A) NO3
(B) SeCN–
2–
(C) SO4
2–
(D) CO3

4)

Find the number of nodal planes in δ* (ABMO)

(A) 1
(B) 3
(C) 2
(D) Zero

SECTION - I (ii)

1) Select the correct statement(s).

(A) In a reversible process, ΔG is always zero in a closed system.

(B) In a reversible process, ΔSuniv is always zero in a closed system.
(C) In a reversible process, ΔSsys is always zero in a closed system.
(D) In a reversible process, ΔSsys is always zero in an isolated system.

2) Which combination of reagents will not bring about the following conversion ?

⊕
(A) MeMgBr/H , H2SO4/Δ, HBr/H2O2, hv
⊕
(B) MeMgBr/H , H2SO4/Δ, HBr
⊕
(C) MeMgBr/H , HBr/CCl4
(D) MeMgBr, NH4Br

3) Which statement(s) is/are correct ?

(A) Polarising power refers to cation.

(B) Polarisability refers to anion.
(C) Small cation is more efficient to polarise anion.
(D) Molecules in which cation having pseudo inert gas configuration are more covalent.

SECTION - I (iii)

Common Content for Question No. 1 to 2

Entropy is a state function and its value depends on two or three variables temperature (T), Pressure
(P) and volume (V). Entropy change for an ideal gas having number of moles (n) can be determined
by the following equation.

ΔS = 2.303 nCV log + 2.303 nR log

ΔS = 2.303 nCp log + 2.303 nR log

Since free energy change for a process or a chemical equation is a deciding factor of spontaneity,
which can be obtained by using entropy change (ΔS) according to the expression, ΔG = ΔH – TΔS at
a temperature T.

1) What would be the entropy change involved in thermodynamic expansion of 2 moles of a gas from
a volume of 5 L to a volume of 50 L at 25°C [Given R = 8.3 J/mole – K]

(A) 38.23 J/K

(B) 26.76 J/K
(C) 20 J/K
(D) 28.23 J/K

2) An isobaric process having one mole of ideal gas has entropy change 23.03 J/K for the
temperature range 27°C to 327°C. What would be the molar specific heat capacity (CV) ?

(A)
J/K mol

(B)
– 8.3 J/ K mol
(C) 10 × log2 J/K mol
(D) 10 log2 + 8.3 J/K mol

Common Content for Question No. 3 to 4

Generally acid derivatives gives SNAE type of reaction with Grignard reagent.

Carbonyl compound further react with Grignard reagent and give alcohol as product by Nucleophilic
addition reaction.

3)
Product can be :

(A)

(B) CH3–CH2–OH

(C)

(D)

4)
Which of the following reaction gives only 2° alcohol as organic product :

(A)

(B)

(C)

(D)

SECTION - II

1) What is the magnitude of work performed by one mole of an ideal gas in cal, when its volume
increases eight times in reversible adiabatic expansion if the initial temperature of the gas is 300 K?
CV for the gas is 1.5 R. (R = 2 cal/mol/K)

2) 18gm of ice is converted into water at 0°C and 1 atm. The entropies of H2O(s) and H2O(l) are 38.2
and 60 J/mol K respectively. The enthalpy change for this coversion is (in kJ/mol)

3) How many of the following compounds can be reduced by NaBH4/H⊕ ?

4) The number of chiral centres present in [B] is _______.

5) The number of chelate rings in Nickel dimethylglyoximate is

6) The number of bidentate ligands from the following are-

PART-3 : MATHEMATICS

SECTION - I (i)

1) Area bounded by the curve y = ex, tangent to curve y = ex at x = 0 and ordinate x = 1 is-

(A)

(B)

(C)

(D)

2)

Area of the region is equal to

(A)

(B)

(C)

(D)

3) Let f be a real valued continuous function on [0,1] and Then which of the
following points (x,y) lies on the curve y = f (x)?

(A) (2, 4)
(B) (1, 2)
(C) (4, 17)
(D) (6, 8)

4) If , then is -
(A)

(B)

(C)

(D)

SECTION - I (ii)

1) If PQ is a chord of parabola x2 = 4y which subtends right angle at vertex. Then locus of centroid of
triangle PSQ (S is focus) is a parabola whose -

(A) vertex is (0, 3)

(B)
length of LR is
(C) axis is x = 0
(D) tangent at the vertex is x = 3

2) If latus rectum of an ellipse {0< b < 4}, subtend angle 2θ at farthest vertex such
that cosecθ = , then -

e=
(A)

(B) no such ellipse exist

b=
(C)

(D) area of Δ formed by LR and nearest vertex is 6 sq. units

3) If a hyperbola passes through the foci of the ellipse and its transverse and conjugate
axis coincides with the major and minor axis of the ellipse and product of their eccentricities is 1,
then -

equation of hyperbola
(A)

equation of hyperbola
(B)

(C) focus of hyperbola (5, 0)

focus of hyperbola
(D)

SECTION - I (iii)
Common Content for Question No. 1 to 2
For j = 0, 1, 2, .... n let Sj be the area of region bounded by the x-axis and the curve yex = sin x for
.

1) The value of equals to

(A)

(B)

(C)

(D)

2) The value of S0 is

(A)

(B)

(C)

(D)

Common Content for Question No. 3 to 4

Let y = ƒ(x) be a curve given by the solution of differential equation

and y = ƒ(x) cuts x-axis at atleast one point.

On the basis of above information, answer the following questions :

3) The number of value(s) of p is -

(A) 0
(B) 1
(C) 2
(D) 3

4) The sum of real roots of the equation ƒ(x) = 0 is -

(A) 2
(B) 4
(C) 6
(D) 8
 SECTION - II

1) If ; and the curve y = f(x) passes through origin and (x1, π), where 6 < x1

< 7 then is equal to :

2) If a curve y = f(x) passing through origin has slope of tangent of curve at any point (x, y) equal to
x(1+y), then number of solutions of equation f(x) = 1, is -

3) If f(x) is an even function and and

, then is

4) is equal to

5) If , then the value of 4k – 6 is equal to

6) Radius of largest circle which passes through focus of parabola y2 = 4x and contained in it, is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION - I (i)

Q. 1 2 3 4
A. A C D A

SECTION - I (ii)

Q. 5 6 7
A. A,B,D A,C,D A,C

SECTION - I (iii)

Q. 8 9 10 11
A. B C C A

SECTION - II

Q. 12 13 14 15 16 17
A. 3.00 4.00 8.00 5.87 -20.00 1480.00

PART-2 : CHEMISTRY

SECTION - I (i)

Q. 18 19 20 21
A. D C B B

SECTION - I (ii)

Q. 22 23 24
A. B,D B,C,D A,B,C,D

SECTION - I (iii)

Q. 25 26 27 28
A. A B A B

SECTION - II

Q. 29 30 31 32 33 34
A. 675.00 5.95 3.00 4.00 4.00 5.00

PART-3 : MATHEMATICS
 SECTION - I (i)

Q. 35 36 37 38
A. A B D C

SECTION - I (ii)

Q. 39 40 41
A. A,B,C A,B,C,D A,C

SECTION - I (iii)

Q. 42 43 44 45
A. B B B B

SECTION - II

Q. 46 47 48 49 50 51
A. 2.00 2.00 2.00 2.00 9.00 4.00
 SOLUTIONS

PART-1 : PHYSICS

1)

2) For complex circular motion

Since it is deflection by 60°

3) Clearly F = BIl = BI × (2b)

∴a=

4)

Ans. (A)
A is the correct answer

5)

PQ = 0

6)
 Independent of speed.

7)
No tangential force at top.
∴ tangential acceleration at top = 0

∴ v2 =

∴ mg + Tmin =

∴ Tmin =

8)

F = –iℓB

9)

Loss = ΔKE

Loss =

10) Ans. (C)

C is the correct answer

11) Ans. (B)

B is the correct answer
Hint :
Particle will not collide earth surface if maximum downward displacement is less than 'h'
Magnitude of acceleration = g
minimum seperation between particle and earth surface

→ Increases

→ Decreases

→ Decreases

12)

× 2x × r

e max ⇒ =

R2 = 4x2

x=

13)

ε = Blv = 36

v= = 1200 m/s

14)

τ = 1 × π × 12 × 5 =
α = 10π
α = rα
= (1 × sin 53)α = 8π
 15) by conservation of energy

v cos 37 =
∴ v = 5.87 m/s

16) Work done by friction

= µmgx = 20 J

17) l0 + x = = 13

x = 6m

mg × 5 + k (02 – 02) = mv2

100 + × 100 × 36 = × 2 ×v2

v2 = 3700

N= = = 1480 N

PART-2 : CHEMISTRY

18)

λ – λ' =

19)

20)

Ans. (B)
B is the correct answer

21)

Ans. (B)
B is the correct answer

22)

(B) In closed system, no matter exchange, only heat exchange occurs.

q = heat lost to surrounding in reversible way

ΔSsys =

ΔSsurr =
ΔSuniv = 0
(D) In isolated system, matter exchange = 0
Heat exchange = 0
ΔSsys = 0

23)

Ans. (B,C,D)
B,C,D is the correct answer

24) Factual according to Fajan's Rule.

25) ΔS = 2.303 x 2 x 8.3 log = 38.23 J/K

26)

ΔS = 2.303 × 1 × CP log = 23.03 CP =

CV = CP – R = – 8.3

27)

Ans. (A)
A is the correct answer

28)

Ans. (B)
B is the correct answer
 29) We have a relation in adiabatic process.

T2 = 75 K
Work done =
= 1 × 1.5 R × 225
= 1 × 1.5 × 2 × 225
w = 675 cal

30)

Question Explanation:
The question asks us to calculate the enthalpy change (ΔH) for the conversion of ice (H2O(s))
to water (H2O(l)) at 0°C and 1 atm. We are given the entropies of ice and water, which allows
us to relate the entropy change to the enthalpy change at constant temperature.

Given Data:

A. Mass of ice = 18 g
B. Temperature (T) = 0°C = 273.15 K (We'll use 273 for simplicity)
C. Entropy of H2O(s) (Sice) = 38.2 J/mol K
D. Entropy of H2O(l) (Swater) = 60 J/mol K

Concept:
Relationship between entropy change (ΔS), enthalpy change (ΔH) and temperature (T) for a
reversible process at constant temperature:

Solution:
ΔS = ΔH / T
We can rearrange this to solve for ΔH:
ΔH = T × ΔS
Fist, we need to calculate the number of moles of ice. Then, we calculate the change in entropy and
finally, we calculate the enthalpy change.

Mathematical Calculation:

A. Mole of ice: Molar mas of H2O = 18 g/mol Number of moles (n) = mass / molar mass = 18g /
18 g/mol = 1 mol
B. Entropy change (ΔS): ΔS = Swater – Sice = 60 J/mol K – 38.2 J/mol K = 21.8 J/mol K
C. Enthalpy change (ΔH): ΔH = T × ΔS = 273 K × 21.8 J/mol K = 5951.4 J/mol
D. Concert to kJ/mol: ΔH = 5951.4 J/mol × (1 kJ / 1000 J) = 5.9514 kJ/mol

Final Answer:
The enthalpy change for the conversion of ice to water is approximately 5.95 kJ/mol.
 31) NaBH4 is a weak reducing agent and can only reduce aldehydes, ketones and acid
chlorides.

32)

33)

Ans. (4.00)
(4.00) is the correct answer

34)

Ans. (5.00)
(5.00) is the correct answer

PART-3 : MATHEMATICS

35)
tanget is y = x + 1

∴ Area

36)

Required Area
 .

37)
f(x) = Ax – B ...(i)

...(ii)

Also

......(iii)
From (2), (3)

so f(6) = 8.

38)

Ans. (C)
C is the correct answer

39)
x2= 4y

h=

t1 + t2 =
k=
(3k – 1) = t12 + t22

(3k – 1) = (t1 + t2)2 – 2t1t2 =

⇒ (3k – 9) =

= –1
t1t2 = – 4

= 3(k – 3)

h2 =

x2 =
Vertex ≡ (0, 3)

L.R. =
axis x = 0
Option A, B and C are correct.

40)

tanθ =

=1-e

So b = 2
and Area = 6
Option (C) is correct

41) Eccentricity of ellipse =

Eccentricity of hyperbola = and it passes through (±3, 0)

⇒ its equation
where ⇒ b2 = 16

⇒ and its focii are (±5, 0)

42)

43)

44)

= px4 – 6x2 – 8x + c
⇒ y = px4 – 6x2 – 8x + 32
Let x = α be a root of y = 0
pa4 – 6α2 – 8α + 32 = 0

⇒ α4 - 6α2 - 8α + 32 0
⇒ (α2)2 – 8α2 + 2α2 – 8α + 16 + 16 0
⇒ (α2 – 4)2 + 2(α – 2)2 0
∴ α = 2, p = 1
Clealy (α – 2) is a repeated factor.
45) = px4 – 6x2 – 8x + c
⇒ y = px4 – 6x2 – 8x + 32
Let x = α be a root of y = 0
pa4 – 6α2 – 8α + 32 = 0

⇒ α4 - 6α2 - 8α + 32 0
⇒ (α2)2 – 8α2 + 2α2 – 8α + 16 + 16 0
⇒ (α2 – 4)2 + 2(α – 2)2 0
∴ α = 2, p = 1
Clealy (α – 2) is a repeated factor.

46) (tan y + y sec2y)dy = ex(sin x + cos x) dx

(0, 0) gives C = 0

47)

f(x) = 1 ⇒ ⇒ 2 solutions

48)

x + 2017 = z
49) Given limit

50) ;

=
⇒ 4k – 6 = 9

51)
(x – 1 – r)2 + y2 = r2
touches y2 = 4x
x2 + (1 + r)2 – 2x(1 + r) + 4x = r2
x2 – 2x (r – 1) + 2r + 1 = 0
D=0
r=4