24-08-2025

1001CJA103091250004 JA

PART-1 : PHYSICS

SECTION-I

1) A spherical shell of radius R is rolling down an incline of inclination θ without slipping. Find

minimum value of coefficient of friction :-

(A)
tan θ

(B)
tan θ

(C)
tan θ
(D) none

2) A simple pendulum is suspended in a car. The car starts moving on a horizontal road according to

equation . Find the time period of oscillation of the pendulum.

(A)

(B)

(C)

(D)

3) Statement–1 : The motion of a simple pendulum is simple harmonic only for a ≈ ℓ.

 Statement–2 : Motion of a simple pendulum is SHM for small angular
displacement.

Statement–1 is True, Statement–2 is True ; Statement–2 is a correct explanation for

(A)
Statement–1.
Statement–1 is True, Statement–2 is True ; Statement–2 is NOT a correct explanation for
(B)
Statement–1.
(C) Statement–1 is True, Statement–2 is False.
(D) Statement–1 is False, Statement–2 is True.

4) A solid sphere, a hollow sphere and a disc, all having same mass and radius, are placed at the top
of an incline and released. The friction coefficients between the objects and the incline are same but
not sufficient to allow pure rolling in any of three cases. Then which of the following options is
correct when objects reach bottom of incline ?

(A) Solid sphere will take least time and hollow sphere will have least kinetic energy.
(B) All will take same time and hollow sphere will have least kinetic energy.
(C) All will take same time and all will have same kinetic energy.
(D) Disc will take least time and will have least kinetic energy.

5) A massive sphere is fitted onto a light rod at a distance x from ground end and it is placed
vertically. Assume the end of rod on the ground does not slip. For which of the following values of x

the rod will fall faster ?

(A) x = ℓ
(B) x = ℓ/2
(C) x = ℓ/4
(D) rate of falling of rod is indpendent of x.

6)
A particle of mass m = 1 kg moves in a circle of radius R = 2m with uniform speed v = 3π m/s. The
magnitude of impulse given by centripetal force to the particle in one second is :-

(A)
(B)
(C)
(D)

7) A particle collides elastically with two moving walls one by one as shown on a horizontal plane.

Find the final speed of the particle after two collisions :-

(A) 11 m/s
(B) 19 m/s
(C) 21 m/s
(D) 5 m/s

8) A cube of side a and mass m is to be tilted at point A by applying a force F on rough horizontal
surface as shown in figure. The minimum force required is : (Friction is sufficient to prevent

slipping)

(A) mg

(B)

(C)

(D)

9) A uniform solid cylinder is placed on a rough horizontal surface. Two forces and

are applied simultaneously on the cylinder at the given points in the same direction. Given
C is the centre of mass and AB = DO = R/2. Match the List-I mentioning the force applied at given

points with List-II mentioning the direction of frictional force at that instant.
 List-I List-II

(P) F2 at A and F1 at C (1) Forward

(Q) F1 at B and F2 at D (2) Backward

(R) F1 at A and F2 at D (3) Zero

(S) F2 at A and F1 at D (4) Cannot be determind

(A) (P) - (2) ; (Q) - (1) ; (R) - (4) ; (S) - (3)
(B) (P) - (4) ; (Q) - (2) ; (R) - (3) ; (S) - (1)
(C) (P) - (1) ; (Q) - (2) ; (R) - (2) ; (S) - (3)
(D) (P) - (3) ; (Q) - (2) ; (R) - (2) ; (S) - (1)

10) The ratio of period of periodic motion of the conical pendulum to that of the simple pendulum is :
(Assume the strings are of the same length in the two cases and θ is the angle made by the string
with the vertical in case of conical pendulum)

(A) cos θ
(B)
(C) 1
(D) None of these

11) A horizontal spring mass system is executing SHM with time period of 4 sec.At time t = 0, it is at
mean position. Find the minimum time after which its potential energy becomes three times its
kinetic energy :-

(A) 1 sec
(B) 1/2 sec
(C) 1/3 sec
(D) 2/3 sec

12) The potential energy for a force field is given by U (x, y) = cos (x + y). The force acting on a

particle at position given by coordination is :-

(A)

(B)

(C)

(D)

13) A small ball of mass m is suspended from a light rod as shown. The ball is given a horizontal
velocity at A equal to twice the minimum velocity required by the ball to complete the loop. Find the
tension in the rod when the ball passes through the topmost point:-

(A) 15 mg
(B) mg
(C) 11 mg
(D) 12 mg

14) A rod of mass 20 kg & length 10m is hinged at A & hanging vertically. A bullet of mass 5kg
moving with velocity 10 m/s sticks to one end of rod. Find angular velocity of rod just after the

collision particle sticks to it :-

(A)

(B)

(C)

(D) 3 rad/sec

15) Statement–1 : SHM is not a periodic motion.

and
Statement–2 : Periodic motion repeat its position after certain interval of time.

Statement–1 is True, Statement–2 is True ; Statement–2 is a correct explanation for

(A)
Statement–1
Statement–1 is True, Statement–2 is True ; Statement–2 is NOT a correct explanation for
(B)
Statement–1
(C) Statement–1 is True, Statement–2 is False.
(D) Statement–1 is False, Statement–2 is True.

16) Time period of a particle executing SHM is 8 sec. At t = 0 it is at the mean position. The ratio of
the distance covered by the particle in the 1st second to the 2nd second is :
(A)

(B)

(C)

(D)

17)

A light string is wrapped around a solid cylinder of mass 'm' and radius 'R'. The string is pulled
vertically upward to prevent the centre of mass from falling as the cylinder unwinds the string. Then
length of the string unwound when, the cylinder has reached a speed ω will be :

(A)

(B)

(C)

(D)

18) From the fixed pulley, masses 2kg, 1kg and 3kg are suspended as shown in the figure. Find the
extension in the spring if k = 100 N/m. (Neglect oscillations due to spring) :- (When magnitude of

acceleration for all blocks is same.)

(A) 0.1 m
(B) 0.2 m
(C) 0.3 m
(D) 0

19) A small block at rest is attached to a source supplying constant power to it. If its displacement
at t = 4 sec is 16 m on a horizontal smooth surface then its displacement at t = 9 sec will be :-

(A) 36 m
(B) 48 m
(C) 64 m
(D) 54 m

20) What will be the velocity of block "C" ?

(A) 4 m/s down

(B) 4 m/s up
(C) 2 m/s up
(D) 2 m/s down

SECTION-II

1) A ladder is resting on two mutually perpendicular walls. If ladder starts to slide and velocity of
point B at a certain point when θ is 37°, is 3 m/sec then velocity (in m/s) of point A at this moment is

2) A uniform cubical block of side 8m is at rest on an inclined plane. Find distance (in meter) of

normal reaction from the centre of block.

3) Two uniform identical rods of same mass are tied together with the help of a string and balanced
as shown in the figure. If minimum coefficient of friction for which the system will remain in
equilibrium in the position is 'µ' then find value of 6µ.

4) Two particles perform SHM of same frequency and about same mean position. Their amplitude is

same A, and time period T. At t = 0, their separation is maximum and is A. Their separation at t =

is . Find n.

5) A spring (spring constant k) having one end attached to rigid wall & other end attached to a block
of mass m kept on a smooth surface as shown in figure. Initially spring is in its natural length at x =

0, now spring is compressed to x = –a and released. (Coefficient of restitution (e) = ). If velocity of

block just after first collision is , find the value of n.

PART-2 : CHEMISTRY

SECTION-I

1) 2A(g) → 3B(g) + C(g)

Concentration of reactant (mol/litre) 1

Time (minute) 10 17 20 25 40
Order of reaction will be :
(A) 0
(B) 1
(C) 2
(D) 3

2) 1 mole of monoatomic ideal gas was subjected to a change of state from (2L,300K) to (4L, 500K)
against a constant external pressure of 1bar. Identify correct option(s) for the process : (Given: R=
25/3 J mol–1 K–1)
(1 litre bar = 100 J)

(A) ΔU = 2500 J
(B) W = 200 J
(C) q = +2000 J
(D) ΔH = 4000 J

3) For the following reaction : 2X + 3Y P

the rate of reaction is . Two moles of X are mixed with three mole of Y to make 1.0 L of
solution. At 50 s, 1.5 mole of Y is left in the reaction mixture. The correct statement(s) about the
reaction is/are :
(Use : ln 2 = 0.693)

(A) The rate constant, k, of the reaction is 1.848 × 10–2 s–1

(B) Half-life of Y is 50 s.

(C)
At 50 s, = 13.86 × 10–3 mol L–1 s–1

(D)
At 100 s, = 6.93 × 10–3 mol L–1 s–1

4) Boiling point of an aqueous solution is 100.52°C when 6 g of non volatile, monobasic acid 'Hx' was
dissolved in 100 g water. Then calculate molecular weight of 'Hx', if 20% of acid is ionised.
[Kb(H2O) = 0.52 K kg mol–1/2, normal boiling point of H2O = 100°C]

(A) 120 g/mol

(B) 100 g/mol
(C) 342 g/mol
(D) 72 g/mol

5)

The only INCORRECT option among the following is :

(A) In isothermal expansion of an ideal gas, internal energy of the gas remains unchanged.
(B) In adiabatic free expansion of an ideal gas, the internal energy of gas remains unchanged.
In adiabatic free expansion of an ideal gas, the initial and final temperature of the gas remains
(C)
same.
(D) In adiabatic expansion of an ideal gas, the internal energy of gas increases.

6) Statement 1 : Activation energy and pre-exponential factors of reactions are temperature

independent for large temperature range.
Statement 2 : As the temperature increases, the number of reactant molecules which can cross the
potential energy barrier increases sharply.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation
(B)
for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

7) Match the list-I with List–II and select the correct answer using the codes given below with the
lists.
 List–I List-II
(Compounds) (Shape)
(P) XeF4 (1) Tetrahedral
(Q) XeO3 (2) Square planar
(R) XeO4 (3) Trigonal bipyramidal
(S) XeO3F2 (4) Pyramidal

(A) P – 4, Q – 3, R – 1, S – 2
(B) P – 2, Q – 4, R – 1, S – 3
(C) P – 1, Q – 4, R – 2, S – 3
(D) P – 2, Q – 1, R – 3, S – 4

8) The correct order of strength of H-bond in the following compound:

(A)
(B)
(C)
(D)

9) The INCORRECT order of match for the energy distance function for following interaction.

(A) Debye force : r–6

(B) Ion-dipole : r–4
(C) London force : r–6
(D) Ion-induced dipole : r–4

10)

Which is true for the following isomeric forms I & II respectively :

Dipole Melting
Boiling point Stability
moment point

(A) I > II I > II II > I I > II

(B) II > I II > I II > I II > I

(C) I > II I > II I > II I > II

(D) II > I II > I I > II I > II

(A) A
(B) B
(C) C
(D) D

11) Which of the following can not show geometrical isomerism :

(A)

(B)

(C)

(D)

12) Statement-1 : According to CIP sequence rule the priority of the groups is
–CH = CH2 < – C ≡ CH < – C ≡ N < –CH = O
and
Statement-2 : Priority of the given groups are based on molecular mass of groups.

(A) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1
Statement-1 is True, Statement-2 is True ; Statement-2 is not a correct explanation for
(B)
Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

13) Which of the following doesn't represent meso compound -

(A)

(B)

(C)
(D)

14) The two projection formulae that represent a pair of enantiomers are :-

(A) I and II
(B) III and IV
(C) I and III
(D) II and IV

15) In which of the following compound have plane of symmetry?

(A)

(B)

(C)
(D)

16) Which of the following represent correct stability of

(A) II > I > IV > III

(B) II > III > IV > I
(C) II > IV > III > I
(D) II > IV > I > III

17) In which of the following molecule C—C bond length will be highest ?

(A) CF3 – CF3

(B) F2CH – CHF2
(C) FCH2 – CH2F
(D) CH3–CF3

18) Which of the following compounds contain(s) no covalent bond(s) ?

KCl, PH3, O2, B2H6, H2SO4

(A) KCl, H2SO4

(B) KCl
(C) KCl, B2H6
(D) KCl, B2H6, PH3

19) Which of the following conversions involves change in both shape and hybridisation ?

–
(A) BF3 → BF4
+
(B) H2O → H3O
(C) CH4 → C2H6
+
(D) NH3 → NH4

20) Which of the following has been arranged in order of decreasing dipole moment ?

(A) CH3Cl > CH3F > CH3Br > CH3I

(B) CH3F > CH3Cl > CH3Br > CH3I
(C) CH3Cl > CH3Br > CH3I > CH3F
(D) CH3F > CH3Cl > CH3I > CH3Br

SECTION-II

1) Mr. Viru Sahastra Budhhe has lost the secret code of his bag which consists of lots of chocolates.
From the information given below help Mr. Viru Sahastra Budhhe to recall his code. The code
consists of four digits a b c d . [Molar masses (gm/mole) of K = 39, S = 32, N = 14, Cl = 35.5, O =
16, H = 1]
(a) = represents moles of hydrogen gas formed by converting all the hydrogen in 6 moles of NH3
(b) = Ratio of densities of SO2(g) and O2(g) at same temperature and pressure.
(c) = % by moles of NH3 in a mixture of NH3 & H2S having an average molecular weight of 33.15.
(d) = represents % yield of reaction if 1.68 of O2 is produced at 1 atm & 273 K from 122.5 gm of
KClO3.
(KClO3 → KCl + O2)

The value of will be :

2)

Standard molar enthalpy of combustion of glucose is –2880 kJ. If only 25% of energy of combustion
is available for muscular work and 1km walk consumes 90 kJ of energy. What maximum distance (in
km) can a person walk after eating 90g glucose?

3) Testosterone, which is a steroidal hormone, has the following structure.

The total number of asymmetric carbon atom/s in testosterone is ______

4) Number of molecules show optical isomerism :

(i) (ii)

(iii) (iv)

(v) (vi)

(vii) (viii)

5) If number of fully filled gerade orbitals in N2 is 'X' and number of fully filled ungerade orbitals in
O2 is 'y' then x + y is ______.

PART-3 : MATHEMATICS

SECTION-I

1) Let f : (–5, 5) → R be a differentiable function with f(1) = 1, f '(1) = –1, f(0) = –1 and f '(0) = 1.
If g(x) = ƒ(ƒ2(x)), then the value of g'(0) is

(A) 2
(B) 3
(C) 6
(D) 7

2) If ........., then the value of at x = is

(A) 2

(B)

(C) 1

(D)

3) Assertion (A) : If roots of the equation x2 – bx + c = 0 are two consecutive integers, then b2 – 4c
= 1.
Reason (R) : If a, b, c are odd integer then the roots of the equation 4b x2 + (b2 – 4ac)x – b = 0 are
real and distinct.

(A) A is True, R is True; R is a correct explanation for A.

(B) A is True, R is True; R is not a correct explanation for A.
(C) A is True, R is False.
(D) A is False, R is True.

4) Let ƒ(x) = x3 + 3x + 1 and g(x) be the inverse of ƒ(x). If , then N is equal to

(A) 4
(B) 6
(C) 8
(D) 9

5) The differentiation of with respect to is

(A)

(B)

(C)

(D)

6) If ƒ(x) is a non constant polynomial function such that ƒ'(2x) = ƒ"(3x).ƒ"'(x), then leading coefficient
of ƒ(x) is

(A)

(B)

(C)

(D)

7) For the curve 32x3y2 = (x + y)5, then value of at P(1, 1) is equal to

(A) 0
(B) 1
(C) –1

(D)
8) If , then f '(x) at is

(A) 0.5

(B)

(C) 0

(D)

9) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

If y = acost and x = a(t – sint), then

(A) (I) 0
the value at

(B) (II) –1
If , then ƒ'(0)
is

(C) If f(x) = , then ƒ'(0) is (III) 3

(D) (IV) 2
If , then 2y''(1) is
(A) (A) – II, (B) – III, (C) – IV, (D) – I
(B) (A) – II, (B) – III, (C) – I, (D) – IV
(C) (A) – IV, (B) – II, (C) – III, (D) – I
(D) (A) – IV, (B) – I, (C) – III, (D) – II

10) If is continuous at x = 0, then

(A) a + b + c = 2
(B) ab = –4
(C) a + c = 4
(D) a – b + c = 2

11) If number of points of non-derivability of ƒ(x) = (x – 1)(x – 2)|(x – 1)(x – 2)(x – 3).....(x – m)| (where
m ∈ N) in (–∞, ∞) are 9, then m is equal to -

(A) 7
(B) 8
(C) 10
(D) 11
12) Let

(A) ƒ(x) is always discontinuous at x = 0

(B) for a = b = c = 1, ƒ(x) is continuous at x = 0
(C) ƒ(x) is always continuous at x = 0
(D) ƒ(x) is continuous but not differentiable at x = 0

13) The number of points of non-differentiability for is

(A) 4
(B) 3
(C) 2
(D) 5

14) Number of points of discontinuity for ƒ(x) = sgn(sinx), x ∈ [0, 4π] is

(A) 3
(B) 4
(C) 5
(D) 7

15) Statement-1 : If 4a2 + 9b2 + 16c2 = 2(3ab + 6bc + 4ca), where a, b, c are non-zero real
numbers, then a, b, c are in GP.
Statement-2 : If (a1 – a2)2 + (a2 – a3)2 + (a3 – a1)2 = 0, then a1 = a2 = a3, ∀ a1, a2, a3 ∈ R.

(A) Both statements-1 and statement-2 are false

(B) Both statements-1 and statement-2 are true
(C) Statement-1 is true and statement-2 is false.
(D) Statement-1 is false and statement-2 is true.

16) If (where [.] & {.} denotes greatest integer & fractional
functions respectively), then

(A) ƒ(x) is discontinuous at x = 1

(B) ƒ(x) is continuous but not differentiable at x = 1
(C) ƒ(x) is differentiable at x = 1

(D)
|ƒ'(1+) – ƒ'(1–)| =

17) If and , then

(A) ƒ(x) is discontinuous at 5 points and not differentiable at 5 points

(B) ƒ(x) is discontinuous at 3 points
(C) ƒ(x) is discontinuous at 2 points
(D) ƒ(x) is continuous everywhere

18) If then ℓ is less than

(where [.] denotes greatest integer function)

(A) 6
(B) 7
(C) 8
(D) 9

19) is -

(A)
(B)
(C) e–1
(D) e

20) If , then

(A) a = 1, b = 2
(B) a = 2, b = 1
(C) a = 4, b = 2
(D) a = 2, b = 4

SECTION-II

1) If range of function is (a,b], then value of is equal to

2) If range of ƒ(x) = cos–1x + cot–1x is [a,b], then value of is equal to

3) Let ƒ be a function satisfying the functional equation , then the

value of is
[Note : [.] denotes greatest integer function]
4) If the solution set of inequality in [0,2π] is
, α, β, γ, δ ∈ I+, then the value of |β – α + δ – γ| is

5) If α, β are roots of ax2 + bx + c = 0, ac ≠ 0 and are roots of x2 – 3x + 1 = 0, then is

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B D B C D B B C B D B C B D D A B D D

SECTION-II

Q. 21 22 23 24 25
A. 4 3 4 2 3

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A C D D D B D B D C C D C A C C B A A

SECTION-II

Q. 46 47 48 49 50
A. 18 4 6 5 7

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A C B B D D A C A D D B D C D B C D C A

SECTION-II

Q. 71 72 73 74 75
A. 2 2 5 6 5
 SOLUTIONS

PART-1 : PHYSICS

1)
mg sin θ – fs = macm ...(1)
fs·R = Icmα

...(2)
Adding (1) + (2)

From (2)

2)

Accelerating of car is

∴ geff =

∴ or

3) Conceptual based.

4)

Friction will be same for all i.e. f = µmg cosθ

So ae = g(sinθ – µcosθ) is same for all
So all will take same time.
Now L = same for all

5) Let at an instant consider the intermediate position of rod where it has moved through the
angle from verticle.
No from energy conservation

mgR = mgR cos +

so for given value of , will be greater for smaller R.

R the distance of end of rod to cog of sphere

6)

The angular displacement of the particle in t = 1 sec is

∴ The magnitude of impulse by centripetal force in t = 1 second is

= change in momentum = mv = .

7)

After 1st collision, speed = (2 × 5) + 3 = 13 m/s

After 2nd collision, speed = (2 × 3) + 13 = 19 m/s
Final speed = 19 m/s
8)

9)
2F + F–f = ma ... (i)

fR + 2FR = ... (ii)

from (i) & (ii)

or friction is in forward direction

Similarly we can solve (Q, R,S)

10)

11)

Given,

or
x = A sinωt {equation of SHM}
V = Aω cosωt
Given : P.E. = 3 K.E.

A2 sin2 wt = 3 × m × A2 cos2 wt
sin2wt = 3w2 cos2wt

wt = tan–1
12)

Fx = – = sin (x + y) Fy = – = sin (x + y)

Fx = sin(x + y)](0, π/4) = Fy = sin(x + y)](0, π/4) =

∴=

13)

we know, for a rod for looping, vmin =

v = 2vmin =
By energy conservation, velocity at top most point will be

v=

⇒ Ttop =

14)

m1vℓ = + m1(Lω) L

15) Conceptual based.

16) t 0 1 2

f 0

pos. 0 A

17)

mgR =

⇒
ω2 = 2αθ

=
ℓ=

18)

kx = 20

19)

When power is constant ; displacement α t3/2

x2 = x1 × = 16 × = 54 m

20) TvA – TvB – (2T)vC = 0

(7 – 3) = 2vC
vC = 2 m/s

21) x2 + y2 = ℓ2

xvB + yvA = 0
xvB =–yvA

|vA| = 4 m/s

22) τcm = 0
 23) T the FBD of any one rod is

T = µN ....(i)
mg = N ....(ii)
Taking torque of any one rod is

= TLsin37°

24)
Phase differene = 60°

in , each turns by 30°,

∴ 1 particles is at mean position and other at

25)

Speed just before collision

Speed just after collision

PART-2 : CHEMISTRY

26) Conc.
t = 10 1

t = 20

t = 40

27)

W = – Pext ΔT
= – 1 bar × (4 – 2) litre
W = – 2 litre bar
W = – 200 J

ΔE = 1 × × R × (200 K)
ΔE = 2500 J
Q = 2700 J
ΔH = [2500 + 200 R] ≠ 4000

28) 2X + 3Y → P
t=0 2 3
t = 50 1 1.5

t1/2(x) = 50 sec. = Kx =
Kx = 2K, K = rate constant of reaction
K = 6.93 × 10–3

= Kx[X] = 6.93 × 10–3 × 2 = 13.86 × 10–3

= Ky[X] = 3 × 6.93 × 10–3 × = 10.395 × 10–3

29) Hx ⇌ H+ + x–
i = [1 + (2 – 1) 0.2] = 1.2
ΔTb = iKbm

0.52 = 1.2 × 0.52

GMM = 72 g/mol

30)

The correct answer is option (D)

31) Theory

32)

VSEPR Thoery
33)

34)

Ion-dipole ; E ∝

35)

⇒ Dipole moment :- II > I

⇒ BP :- II > I

⇒ MP : - I > II
⇒ Stability : I > II

36) (A)

(B)
(C)

(D)

37) CIP-Rule
Atomic no. → Atomic mass → next nearest atoms
Statements-I
–CH = CH2 < –C ≡ C – H < – C ≡ N

< ⇒ correct order

Statements : incorrect

38)

The correct answer option is (D)

39) (I)

(II)
(I) and (III) are mirror image of each other, so they represents pair of enantiomers.
(C) is correct.

40) The correct answer option is (A)

41) The correct answer option is (C)

42) Bent's rule

43) In KCl only ionic bond is available

44) Theory based

45) Theory based

46)

(a) 2NH3 → N2 + 3H2

a=9

(b) =2
(c) 33.15
33.15 = 17x + 34 – 34x
17x = 34 – 33.15
x = 0.05
c=5
(d) 2KClO3 → 2KCl + 3O2

%yield = × 100 = =5

47) Energy available for muscular work consuming 90 g glucose

Max distance =

48)

49)

Solution/Explanation/Calculation :-
compound having only 1 (Chiral C shows optical isomess → (ii), (v), (vii).
(iii) is assymetric compound without pos & cos, so it shoes optIcal isomerism.

(vi) is spiro compound with even rings and terminal groups different, so it shoes optical
isomerism.
Total molecules = 5

Answer = 5

50) x = 3 & y = 4
PART-3 : MATHEMATICS

51) g(x) = ƒ(ƒ2(x))

g'(x) = ƒ '(ƒ2(x)). (2ƒ(x). ƒ '(x))
g'(0) = ƒ '(ƒ2(0)). (2ƒ(0).ƒ '(0))
= ƒ '(1).(2(–1).(1))
= (–1)(–2) = 2

52)

⇒ y=1+x

53) Assertion:

x2 – bx + c =
Difference of roots = 1

⇒ b2 – 4C = 1
Reason:
D = (b2 – 4ac)2 + 4b2
D>0

54) g(ƒ(x)) = x

Put x = 1

⇒N=5

55) Let

and
Put x = cosθ ⇒ θ = cos–1x ∈ [0, π]

y = cosθ &
56) Let degree of ƒ(x) be n
n–1=n–2+n–3
n=4
Let ƒ(x) be = ax4 + bx3 + cx2 + dx + e
(32ax3 + 12bx2 ......)
= (108ax2 + 18bx + 2c).(24ax + 6b)
coefficient of x3
32a = 108a.24a(a ≠ 0)

57) Because it is homogeneous equation of degree 5

58)

ƒ'(x) = 0

59) (A) y = acost ∴

x = a(t – sint) ∴

= –1

(B)
put x = tanθ
ƒ(tanθ) = tan–1(tan3θ)
ƒ(tanθ) = 3θ or 3θ + k
∴ ƒ'(tanθ) sec2θ = 3
ƒ'(0) = 3

(C) ƒ'(x) = ·
ƒ'(0) = 2

(D)

y''(1) = 0
60) a = –2; b = –2; c = 2
(use expansion of sinx, cosx, ex)

61) m – 2 = 9 ⇒ m = 11

62) a = b = c = 1, ƒ(x) is continuous

63)
number of points of non-differentiability = 5

64) ƒ(x) = sgn(sinx)

Number of points of discontinuity = 5

65)

Statement-1 :
4a2 + 9b2 + 16c2 – 2(3ab + 6bc + 4ca) = 0
⇒ (2a)2 + (3b)2 + (4c)2 – (2a)(3b) – (3b) (4c) – (2a) (4c) = 0

⇒
⇒ 2a – 3b = 0 and 3b – 4c = 0 and 4c – 2a = 0

⇒ and and and and

Then a,b,c are of the form , which are in H.P.

So, statement-1 is false
Statement-2 : If
(a1 – a2)2 + (a2 – a3)2 + (a3 – a1)2 = 0
⇒ a1 – a2 = 0 and a2 – a3 = 0 and a3 – a1 = 0
⇒ a1 = a2 = a3, ∀ a1,a2,a3 ∈ R
So, statement-2 is true
66)
ƒ(1–) = 1, ƒ(1+) = 1 & ƒ(1) = 1

67)
discontinuous at 2 points

68) ℓ = 1 + 4 + 3 = 8

69)

Let

70)
b = 2a ...(1)
now

...(2)

71)

∴ range of ƒ(x) = (cot–11, cot–10] =

∴ a = 0, b =

72) Both are decreasing function

∴ ymax = cos–1(–1) + cot–1(–1) =

⇒ range =
∴ a + b = 2π

73) Put x = 3 and x = 7 in given equation

to get ƒ(3) = 11 & ƒ(7) = –1
2ƒ(3) + 4ƒ(7) = 18
ƒ(7) + 2ƒ(3) = 21

74)

75)