Solution (1) - 1
Solution (1) - 1
4602CJA105021250009 JM
PART-1 : PHYSICS
SECTION-I
1) The ratio of angular speed of minute hand and second hand of a clock is :-
(A) 60
(B) 1/60
(C) 30
(D) 1/30
(A) 4/3
(B) 3/4
(C) 5/3
(D) 3/5
4) A particle is moving in circular path in a vertical plane with the help of a string of length 4.9 m. If
the particle is projected from lowest point so that it can reach to the horizontal position then
minimum value of speed of projection is :
(D)
m/sec
5) A sphere of mass m is tied to end of a string of length l and rotated through the other end along a
horizontal circular path with speed v. The work done in full horizontal circle is :
(A) 0
(B)
(D)
6) A car is travelling with linear velocity v on a circular road of radius r. If it is increasing its speed
at the rate of a metre/sec2, then the resultant acceleration will be :-
(A)
(B)
(C)
(D)
7)
In a circular motion of a particle the tangential acceleration of the particle is given by at = 2t m/s2.
The radius of the circle described is 4m. The particle is initially at rest. Time after which total
acceleration of the particle makes 45° with radial acceleration is :-
(A) 2 sec
(B) 1 sec
(C) 3 sec
(D) 4 sec
8)
As shown in figure BEF is a fixed vertical circular tube. A block of mass m starts moving in the tube
at point B with velocity V towards E. It is just able to complete the vertical circle, then choose the
INCORRECT option :-
(A) velocity at B must be
9) A conical pendulum is moving in a circle with angular velocity ω as shown. If tension in the string
(A) T = mω2l
(B) T sinθ= mω2l
(C) T = mg cosθ
(D) T = mω2l sinθ
10) A particle is projected at an angle of 45° with the horizontal with a speed u in a uniform
gravitational field, as shown in the figure. The instantaneous angular speed of the particle w.r.t
point of projection at the moment it falls at the same horizontal level equals :-
(A)
(B)
(C)
(A) –240 J
(B) 360 J
(C) 420 J
(D) will depend upon the path
12)
Position-time graph of a particle of mass 2 kg is shown in figure. Total work done on the particle
from t = 0 to t = 4s is :-
(A) 8 J
(B) 4 J
(C) 0 J
(D) Can't be determined
13)
14) An elastic string of unstretched length ℓ and force constant k is stretched by a small length x. It
is further stretched by another small length y. The work done in the second stretching is :-
(A)
(B)
(C)
(D)
15) A bob mass m attached with string of length R and released from point A. When it reached to
(B)
(C)
(D) None
16) The kinetic energy of a particle moving along a circle of radius R depends upon the distance s as
K = as2. The force acting on the particle is :-
(A)
(B)
(C) 2 as
(D) 2 a
17) A body of mass m was slowly hauled up the hill by a force F which at each point was directed
along a tangent to the path. The work done by this force ,if the height of the hill is h, the length of its
(A)
(B)
(C)
(D) Can't determined
18) The components of a force acting on a particle are varying according to the graphs shown. To
reach at point B (8, 20, 0) from point A(0, 5, 12) the particle moves on paths parallel to x-axis then y-
19) A particle of mass m is acted upon by a constant power P. The distance travelled by the particle
when its velocity increases from v1 to v2 is :-
(A)
(B)
(C)
(D)
20) Two identical small spheres are suspended from same point O on roof with strings of different
length. Both spheres move along horizontal circles in same horizontal plane as shown. Then :-
SECTION-II
1) A force of 0.5 N is applied on the upper block as shown in figure. The coefficient of static friction
between the two blocks is 0.1 and that between the lower block and the surface is zero. The work
done by the lower block on the upper block for a displacement of 3 m of the upper block is :- (in J)
2) In the figure, a block slides along a track from one level to a higher level, by moving through an
intermediate valley. The track is frictionless untill the block reaches the higher level. There a
frictional force stops the block in a distance d. The block's initial speed v0 is 6 m/s, the height
difference h is 1.1m and the coefficient of kinetic friction µ is 0.6. The value of d is :- (in m) (if g = 10
2
m/s )
3) The potential energy of a 1 kg particle free to move along the x-axis is given by :-
The total mechanical energy of the particle is 2 J. Then the maximum speed (in m/s) is . Then N is
:-
4) A string of length 1m is fixed at one end and carries a mass of 100 g at the other end. The string
makes (2/π) revolutions per second around vertical axis through the fixed end. What is the tension
5)
A particle starts moving from rest in a non-uniform circular motion, has angular acceleration as
shown in figure. The angular velocity at the end of 4 radian is given by ω rad/s then find the value of
ω.
PART-2 : CHEMISTRY
SECTION-I
1) Calculate the standard enthalpy of formation of CH3OH(ℓ) from the following data :-
2) The enthalpy of neutralization of acetic acid and sodium hydroxide is –55.4 KJ. What is the
enthalpy of ionization of acetic acid ?
(A) –1.9 KJ
(B) +1.9 KJ
(C) + 5.54 KJ
(D) –5.54 KJ
3) Calculate the enthalpy for the following reaction using the given bond energies (kJ/mol) :
(C—H = 414; H—O = 463; H—Cl = 431,
C—Cl = 326 ; C—O = 335)
CH3—OH(g) + HCl(g) → CH3—Cl(g) + H2O(g)
(A) – 23 kJ/mol
(B) – 42 kJ/mol
(C) – 59 kJ/mol
(D) – 511 kJ/mol
4) The bond enthalpies of H2 , X2 and HX are in the ratio of 2 : 1 : 2. If the enthalpy for formation of
HX is –50 KJ mol–1, the bond enthalpy of H2 is :-
(A) 200 KJ mol–1
(B) 400 KJ mol–1
(C) 100 KJ mol–1
(D) 300 KJ mol–1
(A) 5.73 kJ
(B) 57.3 J
(C) 57.3 kJ
(D) 573 J
7) A gas expands by 0.5 L against a constant pressure of 1 atm. Calculate the work done in calorie :-
8) The work done by a system is 8 J when 40 J heat is supplied to it. The change in internal energy of
the system during the process :-
(A) 32 J
(B) 40 J
(C) 48 J
(D) –32 J
(A)
(B)
(C)
(D) P1V1 = P2V2
10)
(A) ΔH = ΔE
(B) ΔH = ½ ΔE
(C) ΔH < ΔE
(D) ΔH > ΔE
12) One mole of an ideal gas is expanded isothermally and reversibly to half its initial pressure. ΔS
for the process in JK–1 mol–1 is : [ln 2 = .693 and R = 8.314 J/mol.K]
(A) 10.76
(B) 6.76
(C) 8.03
(D) 5.76
14) The correct thermodynamic conditions for the spontaneous reaction at all temperatures is :-
15) For a reaction N2 + 3H2 2NH3, the value of KC does not depends upon :-
(a) Initial concentration of the reactants
(b) Pressure
(c) Temperature
(d) Catalyst
(A) Only a
(B) a, b, c
(C) a, b, d
(D) a, b, c, d
16) For PCl5 ⇌ PCl3 + Cl2. If α is the degrees of dissociation of PCl5 and the total equilibrium
pressure is P then :-
(A)
(B)
(C)
(D)
17) In reaction A + 2B ⇌ 2C + D, initial concentration of B was 1.5 times of [A], but at equilibrium
the concentrations of A and B became equal. The equilibrium constant for the reaction is :
(A) 4
(B) 6
(C) 12
(D) 8
(A)
(B) 1
(C) –1
(D)
19) Which of the following lines correctly show the temperature dependence of equilibrium constant,
(A) B and C
(B) C and D
(C) A and D
(D) A and B
(A) 10181
(B) 10154
(C) 1025
(D) 1077
SECTION-II
2)
Two moles of PCl5 were heated in a closed vessel of 2L. At equilibrium 40% of PCl5 is dissociated into
PCl3 and Cl2. The value of equilibrium constant is :-
5) The enthalpy of vaporisation of water is 373 kJ. Find the entropy of it at boiling point in kJ/K.
PART-3 : MATHEMATICS
SECTION-I
1) Number of integral values of x satisfying the inequality (x2 – 10|x| + 25).(x2 – 7|x| + 12) < 0 is
equal to
(A) 2
(B) 1
(C) 0
(D) 3
(A) non-negative
(B) zero
(C) non-positive
(D) positive
4) If α, β are the roots of ax2 + bx + c = 0, then the roots of equation ax2 – bx(x – 1) + c(x – 1)2 = 0
are
(A)
(B)
(C)
(D) α, β
(A) 8, –1
(B) –9, 2
(C) –8, –2
(D) 9, 1
(A)
(B)
(C)
(D)
7) Maximum value of is
(A) 3
(B) 4
(C)
(D)
(A) 0
(B) 5
(C) 1/6
(D) 6
(A) x2 + 4x + 1 = 0
(B) x2 – 4x – 1 = 0
(C) x2 – 4x + 4 = 0
(D) None of these
then is
(A) 0
(B)
(C)
(D) None
12) If the median AD of a ΔABC makes an angle θ with the side AB, then sin(A–θ) is equal to
then is equal to
(A)
(B)
(C) 999
(D) 1999
14) The smallest single digit non-negative integral value of k, for which both the roots of the
equation x2 – 8kx + 16(k2 – k + 1) = 0 are real, distinct and have value atleast 4, is
(A) 1
(B) 2
(C) 0
(D) 3
(B) 2A
(C) 3A
(D) none of these
16)
(A) G.P.
(B) A.P.
(C) H.P.
(D) None
17)
then value of is
(A)
(B)
(C)
(D)
(A) 1
(B) 2
(C) 0
(D) infinite
(A)
(B)
(C) 0
(D) 1
(A) k < 0
(B) k > 6
(C) 0 < k < 4
(D) k > 4
SECTION-II
1) If the roots of the cubic, are three consecutive positive integers. Then the
2) If the median of a triangle ABC through A is perpendicular to AB then has the value
equal to
PART-1 : PHYSICS
SECTION-I
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B D A B A B A D A B B C B C A B B C D A
SECTION-II
Q. 21 22 23 24 25
A. -1.00 1.17 3.00 1.6 6.00
PART-2 : CHEMISTRY
SECTION-I
Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B A A C D A A A D A D A C C D A D D C
SECTION-II
Q. 46 47 48 49 50
A. 15.00 0.26 5.00 -28.60 1.00
PART-3 : MATHEMATICS
SECTION-I
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A A B D B A B C C C C A B B B C C A C
SECTION-II
Q. 71 72 73 74 75
A. 3.00 2.00 4.00 2.00 21.00
SOLUTIONS
PART-1 : PHYSICS
1)
3) t = 1s,
5) Work done by centripetal force in uniform circular motion is always equal to zero.
6) ar =
at = a
anet =
7)
at = 2t
v = t2
For 45°
t3 = 8
t = 2 sec
8)
vE must be
So by COME, , , ,
9) Tcosθ = mg ⇒ T = mg/cosθ
Tsinθ = mω2r
⇒ Tsinθ = mω2lsinθ
⇒ T = mω2l
10) ω = = =
11)
12)
a=0
f=0
W=0
13)
x = 1, x = 2, x = 3
neat ral.
14)
mg = mv2
V2 =
= +
=R– + =R–
But
⇒ Wext =
18) From the given graphs
, ;
19) P = F v = mav
20)
ℓ cosθ is same for two particle
21)
0.5 = 3a ⇒ a = 5/30
f= 2a = 2(5/30)= 1/3N
fmax = 0.1 × 10 = 10N
∴ f = 1/3 N will act
work done by lower block
= –f(s)
= –1/3(3) = –1 Joule
22) WET
23)
Potential energy U =
For maximum kinetic energy, potential energy of a particle should be minimum.
Umin = –
TE = KEmax + PEmin
⇒ KEmax = TE – PEmin
vmax =
24)
Tsinθ = mω2r
since r = ℓsinθ
Tsinθ = mω2ℓsinv
⇒ T = mω2ℓ
= 0.1 × ×1
= 1.6 N
25)
PART-2 : CHEMISTRY
28)
Δ0H[(3 × 414) + (335) + (463) + (431)]
– [3 × 414) + (326) + 2 × (463)] = – 23 kJ/mol
29)
Bond energy of H2 = 2X
= 2 × 100 = 200 kJ/mol
30)
The standard heat of combustion is defined as the heat evolved on burning one mole of the
compound in presence of O2 to give CO2 and water. Since the amount of the substance is
specified, it becomes an intensive property.
31) = 10 m eq H2SO4
150 × = 15 m eq NaOH
Δheat = = 573 J
32) pH = pKa +
50% ionise ⇒ [Salt] = [Acid]
pH = 4.5 ⇒ pOH = 9.5
33) ΔE = q + w
= 40 – 8 = 32 J
34)
35)
Question Explanation
The given reaction is the decomposition of silver oxide:
We are asked to compare the enthalpy change for this
reaction.
Concept
Solution:
In the reaction:
Ag2O (s) → 2Ag(s) + 1/2 O2(g)
Change in gaseous moles:
Δn = 0.5 – 0 = + 0.5
Since gas is produced (Δn > 0).
ΔH = ΔE + positive value ⇒ ΔH > ΔE
Hence,
Correct option: (4) ΔH > ΔE
36) Explanation:
Find (ΔS)f
Given Data:
ΔHfusion = 2930 J/mol, T = 27°C
Concept:
T = 273 + 27 = 300 K
39) A. Question: The correct thermodynamic conditions for the spontaneous reaction at all
temperatures is:
B. Given Data: N/A
C. Concept: For a reaction to be spontaneous, the Gibbs free energy change (ΔG) must be
negative. ΔG = ΔH - TΔS
D. Mathematical Calculation: To ensure that ΔG is always negative, regardless of the
temperature:
41) Explanation:
To determine 'Kp'.
Given Data:
Degrees of dissociation of PCl5 = α
Total equilibrium pressure is = P
Calculation:
PCl5(g) ⇌ PCl3(g) + Cl2(g)
t=0 1 - -
t = teq. 1–α α α
Total moles = 1 – α + α + α
=1+α
Final Answer:
Option (4)
42)
43)
Δng =
So
x = –12
44)
A and B
Slop for given group for exothermic slope of group will be positive.
45)
So,
= 1025
46)
47)
48) Br2(ℓ); C(graphite); F2(g); N2(g) : Cℓ2(g) are exist in most stable form so, it’s standard heat
of formation is zero.
49) i
The question asks us to calculate the entropy change during the phase transition of water from
liquid to vapor at its boiling point. We are given the enthalpy of vaporization and need to apply
the relationship between enthalpy, entropy, and temperature during a phase change.
2. Given Data:
3. Concept:
During a phase change at constant temperature and pressure, the change in entropy (ΔS) is
related to the change in enthalpy (ΔH) and the absolute temperature (T) by the following
equation:
A. ΔS = ΔH / T
4. Mathematical Calculation:
5. Final Answer:
PART-3 : MATHEMATICS
51)
52)
x=
55) 8 + 2 = –a ⇒ a = –10
3⋅3 = b ⇒ b = 9
Now x2 + ax + b = x2 – 10x + 9 = 0
i.e. x = 9, 1
56)
ƒ(1) < 0
3m + 4 < 0 ∴
57)
...(1)
x + 4x + 5 = (x + 2)2 + 1
2
⇒ x2 + 4x + 5 ∈ [1, ∞)
⇒ ∴
58) a = c i.e. K = 5
60) α2 – 3α + 5 = 0 ; β2 – 3β + 5 = 0
∴ α2 – 3α = –5 ; β2 – 3β = –5
∴ Roots = –5 + 7, –5 + 7
= 2, 2
Reqd. equation is x2 – 4x + 4 = 0
61)
α2 = 5α – 3 & β2 = 5β – 3
∴ x2 – 5x + 3 = 0 has roots α & β
∴ α + β = 5, αβ = 3
Regd. = =
62)
In ΔABC
...(1)
In ΔACD
...(2)
∵ BD = CD
63)
= =
64)
65) cosC =
cosA =
cos2A = 2cos2A – 1 = 2 × –1=
So, cosC = cos2A ⇒ C = 2A
66)
Given ,
Also, a, b, c in G.P.
67)
If we apply Sine-Rule in we get
69) Put :
70) ∵ (a + b + c) (b + c – a) = kbc
⇒ (b + c)2 – a2 = kbc
b2 + c2 – a2 = (k – 2) bc
⇒ = = cos A
∵ In a ∆ABC –1 < cos A < 1
∴ –1 < <1
0 < k < 4.
71) n, n + 1, n + 2
sum
=b+1
⇒ = –2 ]
73)
α + β = 1 & αβ = – 1
So, α3 + β3 = (α + β) (α2 + β2 – αβ)
= (α+β) [(α+β)2 – 3αβ] = 4
74)
α2 – 6 α – 2 = 0
α10 – 6 α9 – 2 α8 = 0
Similarly, β10 – 6 β9 – 2 β8 = 0
(α10 –β10) – 6 (α9–β9) – 2 (α8 –β8) = 0
75)
so α2 + β2 + γ2 = (Σα)2 – 2Σαβ = 25 – 4 = 21