Chapter 2 (Acids, Base, Salt)
Chapter 2 (Acids, Base, Salt)
14. A drop of the liquid sample was put on the pH paper, the paper turned
blue. The liquid sample must be of
a. Lemon Juice
b. HCl
c. Sodium bicarbonate
d. Ethanoic acid
Ans: The correct answer is (c) Sodium bicarbonate
17. What effect does the concentration of H+ ions have on the nature of the
solution?
Ans: A higher concentration of H+ ions turns the solution acidic in nature.
19. Name the substance which on treatment with chlorine yields bleaching
powder.
Ans: Slaked lime (calcium hydroxide) yields bleaching powder in treatment with
chlorine.
20. Name the sodium compound which is used for softening hard water.
Ans: The compound which is used for softening hard water is Sodium carbonate.
21. A solution turns red litmus blue, its pH is likely to be
a. 11
b. 22
c. 55
d. 10
Ans: The correct answer is (d) 10
22. A solution reacts with crushed egg-shells to give a gas that turns lime-
water milky. The solution contains
a. NaCl
b. HCl
c. LiCl
d. KCl
Ans: The correct answer is (b) HCl
24. Which one of the following types of medicines is used for treating
indigestion?
a. Antibiotics
b. Analgesic
c. Antacid
d. Antiseptic
Ans: The correct answer is (c) Antacid
b. strongly alkaline?
Ans: C
c. strongly acidic?
Ans: B
d. weakly acidic?
Ans: A
e. weakly alkaline?
Ans: E
26. ‘A’ is a soluble acidic oxide and ‘B’ is a soluble base. Compared to pH
of pure water. What will be the pH of (a) solution of A (b) solution of B?
Ans: Since ‘A’ is acidic, the pH will be less than 77. On the other hand, since ‘B’
is basic, pH will be more than 7.
2 Marks Questions
1. What happens to the crystals of washing soda when exposed to air?
Ans: Upon exposure of washing soda crystals to air, the following reaction takes
place:
Na2CO3.10H2O−→airNa2CO3.H2O+9H2O
In the reaction, the white crystals of washing soda turn into washing powder
(white powder). Efflorescence occurs in the washing soda.
2. What is the chemical name of washing soda? Name three raw materials
used in making washing soda by Solvay process?
Ans: The chemical name of washing soda (Na2CO3.10H2O) is sodium
carbonate decahydrate.
Ammonia, Brine, and Limestone are used to make washing soda by the Solvay
process.
6. Why alkalis like sodium hydroxide and potassium hydroxide should not
be left exposed to air?
Ans: Alkalis are hygroscopic in nature. Upon exposure to air, they absorb
moisture from the surrounding atmosphere and get dissolved in it.
7. Dry ammonia has no action on litmus paper but a solution of ammonia in
water turns red litmus paper blue. Why is it so?
Ans: Dry ammonia has no action on the litmus paper because it contains no
hydroxyl ions in the absence of water. On dissolving in water, it forms ammonium
hydroxide (NH4OH), which is basic in nature because it dissociates to give NH4+
and OH- ions. Thus, red litmus paper turns blue.
NH3(g)+H2O→NH4OH(aq)
NH4OH(aq)→NH4+(aq)+OH-(aq)
9. Why does not an acid show any acidic behavior in the absence of water?
Ans: Water is an ionizing compound. In its presence, acids form an aqueous
solution and get ionized. This results in the release of H+ions and hence, acidic
behavior is shown.
10. Fresh milk has a pH of 6. What will be the pH value if milk changes into
a curd? Justify.
Ans: Lactose is converted to lactic acid when milk changes into a curd. Because
of the greater acidic nature, the pH value decreases.
12. How will you show that acetic acid is monobasic acid?
Ans: When acetic acid reacts with a basic solution, only one H+ ion is replaced
by the base, which shows acetic acid is a monobasic acid. For example,
CH3COOH+ NaOH→CH3COONa+H2O
13. Why should curd and sour substance not be kept in brass and copper
vessels?
Ans: Brass is an alloy of copper and zinc metals. These metals react with acids
present in curd and sour substances to form poisonous soluble salts. Hence,
storing curd and sour substances in brass or copper vessels makes them unfit for
consumption.
14. Which gas is usually liberated when an acid reacts with a metal?
Illustrate with an example. How will you test for the presence of this gas?
Ans: When an acid reacts with a metal, hydrogen gas is liberated. For example,
Zn + Cl2→ZnCl2 + H2
We bring a burning splinter near the liberated gas. If the gas is hydrogen, it burns
with a pop sound.
16. Why does dry HCl gas not change the color of the dry litmus paper?
Ans: When litmus paper comes in contact with H+ ions, the color of the paper
changes. These ions are produced only upon dissolution of HCl gas in water.
Therefore, dry HCl does not change the color of dry litmus paper.
17. While diluting an acid, why is it recommended that the acid should be
added to water and not water to the acid?
Ans: The addition of water to acid leads to a highly exothermic reaction. The
intensity of the heat produced can break the glass container or cause severe
burns to the person adding it. On the other hand, adding acid to water with
constant stirring aids the absorption of the heat produced by water, and any
harm/damage is avoided.
18. How is the concentration of hydroxide ions (OH−) affected when excess
base is dissolved in a solution of sodium hydroxide?
Ans: The dissolution of excess base in a solution of sodium hydroxide will
release more hydroxide (OH-) ions. Therefore, it will lead to an increase in the
concentration of hydroxide ions.
19. Do basic solutions also have H+ ions? If yes, then why are these basic?
Ans: The H+ ions are present in both acidic and basic solutions. A solution is
acidic if the concentration of H+H+ ions is more than OH- ions. On the other hand,
a solution is basic if the concentration of OH- ions concentration is more than the
H+ ions.
20. Do basic solutions also have H+ ions? If yes, then why are these basic?
Ans: Acidic and basic solutions both have H+ ions. The difference is that in acids
H+ ions concentration is more than OH- ions concentration while in basic solution
OH-OH- ions concentration is more than H+ ions concentration.
21. You have two solutions ‘A’ and ‘B’. The pH of solution ‘A’ is 6 and pH of
solution ‘B’ is 8. Which solution has more hydrogen ions concentration?
Which is acidic and which one is basic?
Ans: On a pH scale, any solution having pH value less than 7 is considered
acidic and that with a pH value of more than 7 is basic. Hence, according to the
given pH values, solution ‘A’ is acidic in nature, while solution ‘B’ is basic. Also,
since ‘A’ is acidic, it has a greater concentration of hydrogen ions.
23. Write an equation to show the reaction between plaster of Paris and
water.
Ans: The reaction is as follows:
CaSO4.1\2H2O + 3\2H2O→CaSO4.2H2O
24. Why does distilled water not conduct electricity, whereas rainwater
does?
Ans: The presence of small amounts of acid in rainwater aids the conduction of
electricity. Distilled water is pure water and lacks ions. Therefore, it cannot
conduct electricity.
25. Why do acids not show acidic behavior in the absence of water?
Ans: Acids produce hydrogen ions or hydronium ions only in presence of water.
Therefore, it shows acidic behavior only in the presence of water.
26. Equal lengths of magnesium ribbons are taken in test tubes A and B.
Hydrochloric acid is added to test tube A, while acetic acid is added to test
B. In which test tube will the fizzing occur more vigorously and why?
Ans: The concentration of H+ ions in test tube A will be more than that in test
tube B because hydrochloric acid is stronger than acetic acid. Therefore, the
faster reaction in test tube A will lead to vigorous fizzing.
27. Fresh milk has a pH of 6. How do you think the pH will change as it
turns into curd? Explain your answer.
Ans: Bacterial action on fresh milk turns it into curd. Hence, the lactose in the
fresh milk is turned into lactic acid. Because of the formation of more acid, the pH
will be lower than 6.
30. A first aid manual suggests that vinegar should be used to treat wasp
sting and baking soda for bee stings.
i. What does this information tell you about the chemical nature of the
wasp stings?
Ans: Vinegar (acetic acid) is acidic in nature and it is to be used to heal or
neutralize the effect of wasp stings, it implies that the chemical present in the
stings is basic.
ii. If there were no baking soda in the house, what other household
substance could you use to treat bee stings?
Ans: Ammonium Hydroxide (NH4OH) can be used to treat bee stings
3 Marks Questions
1. (a) Name the raw materials used in the manufacture of sodium carbonate
by the Solvay process?
Ans: The raw materials used are- sodium hydroxide, limestone, and ammonia.
5. A first aid manual suggests that vinegar should be used to treat wasp
sting and baking soda for bee stings.
a. What does this information tell you about the chemical name of the
wasp sting?
Ans: Vinegar (acetic acid) is acidic in nature and if it is to be used to heal or
neutralize the effect of wasp stings, it implies that the chemical present in the
stings is basic.
CH(OH)COOH CH(OH)COONa
Tartaric acid Disod. Tartarate
If this reaction does not occur, the Na2CO3 will impart a bitter taste to the cake.
7. Explain why?
a. Common salt becomes sticky during the rainy season.
Ans: On exposure to moist air, common salt becomes sticky because it contains
impurities of magnesium chloride, which has a tendency to become liquid.
9. Explain why-
i. Anhydrous calcium chloride is used in desiccators
Ans: The hygroscopic nature of anhydrous calcium chloride makes it readily
absorb moisture and therefore, it is used as a desiccator.
12. State the chemical property in each case on which the following uses
of baking soda are based
i. As an antacid
Ans: The weakly alkaline nature of baking soda neutralizes the hydrochloric acid
formed in the stomach.
NaHCO3 + HCl→NaCl + H2O + CO2NaHCO3 + HCl→NaCl + H2O + CO2
ii. As a constituent of baking powder. Give the chemical for baking soda
Ans: Using baking soda while baking makes the cake porous and fluffy. It is
because carbon dioxide gas is evolved in the form of bubbles when baking.
2NaHCO3−→−heatNa2CO3 + H2O + CO22NaHCO3→heatNa2CO3 + H2O + CO2
The chemical formula of baking soda is NaHCO3NaHCO3.
13. Metal compound ‘A’ reacts with dilute hydrochloric acid to produce
effervescence. The gas evolved extinguishes a burning candle. Write a
balanced chemical equation for the reaction, if one of the compounds
formed is calcium chloride.
Ans: We can say that ‘A’ is a salt of calcium because one of the products is
calcium chloride.
The burning candle is extinguished, indicating the formation of carbon dioxide by
the reaction of ‘A’ with hydrochloric acid.
Upon reaction with hydrochloric acid, calcium carbonate produces calcium
chloride and carbon dioxide. Hence, ‘A’ is calcium carbonate.
The chemical equation can be given as:
CaCO3 + HCl→CaCl2 + CO2 + H2OCaCO3 + HCl→CaCl2 + CO2 + H2O
14. Why do HCl,HNO3HCl,HNO3 etc. show acidic characters in aqueous
solution while solutions of compounds like alcohol and glucose do not
show acidic character?
Ans: In their aqueous form, compounds like hydrochloric acid and nitric acid,
release hydrogen ions, which signals acidic character.
On the other hand, compounds like alcohol and glucose cannot release hydrogen
ions. Therefore, they show no acidic properties.
15. You have two solutions ‘A’ and ‘B’. The pH of solution ‘A’ is 66 and pH
of solution ‘B’ is 88. Which solution has more hydrogen ions
concentration? Which is acidic and which one is basic?
Ans: On a pH scale, any solution having pH value less than 77 is considered
acidic and that with a pH value of more than 77 is basic. Hence, according to the
given pH values, solution ‘A’ is acidic in nature, while solution ‘B’ is basic. Also,
since ‘A’ is acidic, it has a greater concentration of hydrogen ions.
16. Under what soil condition do you think a farmer would treat the soil of
his field with quicklime (calcium oxide) or slaked lime (calcium hydroxide)
or chalk (calcium carbonate).
Ans: Quicklime (calcium oxide), slaked lime (calcium hydroxide), and chalk
(calcium carbonate) are basic in nature. Hence, a farmer would use them to
neutralize the effect of acidic soil conditions.
17. A milkman adds a very small amount of baking soda to fresh milk.
a. Why does he shift the pH of the milk from 66 to slightly alkaline?
Ans: Sodium hydrogen carbonate (baking soda) is a base. Hence, in addition to
milk, the solution would become slightly alkaline. This implies that the pH value
would become greater than 66 (slightly alkaline) on the addition of a very small
amount of baking soda.
19. Give two important uses of washing soda and baking soda.
Ans: The uses of washing soda are as follows:
i. Cleansing agent.
ii. Permanently removing the hardness of the water.
iii. Used in paper, glass, and soap industries.
The uses of baking soda are as follows:
i. Production of baking powder.
ii. As an antacid.
21. The oxide of a metal M was water-soluble when a blue litmus strip was
dipped in this solution, it did not go any change in color. Predict the nature
of oxide.
Ans: The nature of the metal oxide is basic in nature. On dissolution in water, it
forms a metal hydroxide. This hydroxide is basic in nature, as the blue litmus did
not undergo any change in color.
MO + H2O→M(OH)2MO + H2O→M(OH)2
22. A road tanker carrying acid was involved in an accident and its
contents spilled on the road, iron drain covers began melting and fizzing as
the acid ran over them. A specialist was called to see if the acid actually
leaked into the nearby river.
a. Explain how the specialist could carry out a simple test to see if the
river water contains some acid or not.
Ans: The expert can use a simple litmus paper test to determine if the river water
contains acid or not. If the expert dips a strip of blue litmus paper into the sample
of river water and the color changes to red, it implies that the river water has
been affected by the acid spill.
b. The word melting is incorrectly used in the report. Suggest a better name
that should have been used.
Ans: The word melting can be replaced with corrosion.
c. Explain why drain covers began fizzing as the acid rain over them.
Ans: Hydrogen gas is evolved when iron reacts with an acid.
23. A compound ‘A’ on heating at 370K370� gives ‘B’ used as plaster for
supporting defractured bones in the right position. ‘B’ on mixing with water
changes to ‘A’. Identify ‘A’ and ‘B’ and write the chemical reaction.
Ans: The reaction can be given by:
CaSO412H2O+112H2O→CaSO42H2O����412�2�+112�2�→����42�2�
Plaster of Paris Gypsum
‘B’ ‘A’
24. A student heated a few crystals of copper sulphate in a dry boiling tube.
a. What will be the color of the copper sulphate after heating?
Ans: Copper Sulphate becomes white in color after heating.
5 Marks Questions
1. (a) The pH of rainwater collected from two cities A and B was found to be
66 and 55 respectively. The water of which city is more acidic? Find out
the ratio of hydrogen ion concentration in the two samples of rainwater?
Ans: Lower pH value is an indication of greater acidic nature. Hence, the rain
water of city B is more acidic.
We know that,
pH=-log[H+]pH=-log[H+]
=log[1H+]=log[1H+]
For city A,
log[1H+]=6log[1H+]=6
[1H+]=anti log6[1H+]=anti log6
=106=106
[H+]=10-6[H+]=10-6
For city B,
log[1H+]=5log[1H+]=5
[1H+]=anti log5=105[1H+]=anti log5=105
[H+]=10-5[H+]=10-5
Hence, the ratio is,
cityAcityB=10-610-5cityAcityB=10-610-5
=110=110
c. Explain why the drain covers began fizzing as the acid ran over them.
Ans: Hydrogen gas is evolved when iron reacts with an acid (like sulphuric acid
or hydrochloric acid). The release of hydrogen is accompanied by effervescence
and hence, the fizzing on the covers was observed.
4. Write word equations and then balanced equations for the reaction
taking place when:
a. Dilute Sulphuric acid reacts with zinc granules.
Ans: Zinc + Sulphuric acid →→ Zinc sulphate + Hydrogen
Zn+H2SO4→ZnSO4+H2��+�2��4→����4+�2