Unit 1 NAS 202 Notes
Unit 1 NAS 202 Notes
Relativistic Mechanics
REFERENCE FRAME
Any moving platform or a moving coordinate system which is used by an observer to measure a physical
quantity or to observe an event is called reference frame.
The measured value of a physical quantity depends on the reference frame of the observer, e.g. the
measured value of the speed of a train would be different for the two observers, one on the ground and
other inside a moving car. Thus it is essential to quote the reference frame of the observer along with the
measured value of a physical quantity to make the measurement meaningful.
Out of the infinite number of available reference frames that frame is considered to be most suitable
from where the given motion appears to be simplest.
Reference frames are characterized in the following two categories
Inertial Reference Frames
The reference frames in which Newton’s law of inertia holds, are called as Inertial/Newtonian/Galilean
Reference Frames. These are the reference frames moving with constant velocity with respect to each other.
The observers in different inertial reference frames may obtain different numerical values for measured
physical quantities but laws of physics remain same for all observers in inertial reference frames.
Non-Inertial Reference Frames
Newton’s laws of motion do not hold well in each and every reference frame. For instances,
would not hold if mass is variable (as in case of falling raindrops, rockets and particles moving with
relativistic speeds).
The reference frames, in which Newton’s law of inertia does not hold, are known as Non-Inertial
Reference Frames. The reference frames moving with uniform acceleration with respect to each other are
non-inertial.
LUMINIFEROUS ETHER
In practice, motion is always described in a relative frame of reference. Newton insisted that there must be
a fundamental reference frame which is in absolute rest and with respect to which all the motions must be
measured.
Moreover, Maxwell proved light to be an electromagnetic wave. Since waves require a material medium
for their propagation, it was supposed that there must also be a suitable medium to carry these
electromagnetic waves which travelled even through empty space between stars and Earth. This medium
was called as LUMINIFEROUS ETHER. As light waves are transverse waves and transverse waves require
shearing forces which can occur in solids only, ETHER must be a rigid solid pervading all space, empty or
otherwise.
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Theory
A beam of light from a monochromatic source S falls on a half silvered plate P placed at an angle of 45 o
with respect to incident beam. The incident beam is partially reflected towards plane mirror M 1 and partially
transmitted towards mirror M 2 by glass plate P. After reflections at
plane mirror M1 and M2, the reflected and transmitted rays retrace
their path and enter into the telescope T. When seen through
telescope T, fringes are observed due to interference between rays
coming after reflections at mirrors M1 and M2.
In Michelson Morley experiment the interferometer is mounted on
earth such that its X - arm is parallel to the direction of motion of earth
around sun. Let the velocity of earth around sun with respect to
stationary ether is . Since apparatus is mounted on earth, it is also
moving with velocity with respect to ether.
( )
Since ,
therefore ( ) (2)
Further, when seen at absolute rest, the apparatus appears to be moving with velocity along X-direction. In
this case, the ray travelling along Y - direction will strike mirror M1 not at position B but at B’.
If light takes time in reaching B’ from P then
and .
Hence, from right angled triangle PBB’, we have
.
This gives ( )
√
i.e. ( ) (3)
Hence, the total time taken by the reflected ray in coming into the telescope after reflection at mirror M 1
( ) (4)
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( ) ( )
(5)
This gives us the path difference between the two rays moving along X and Y arms. Now, if the apparatus is
rotated by about a vertical axis then X and Y arms interchange their positions and the path difference
becomes – . Hence after a rotation of , the total path difference introduced between the two
beams is . Further, if corresponding to this path difference fringes shift in the field of view then
(7)
From the observed fringe shift , one can calculate velocity of earth with respect to stationary ether.
Result:
When the apparatus was rotated, practically no fringe shift was observed. The experiment was repeated at
difference places on earth and in different seasons but fringe shift could never be detected. Hence
Michelson - Morley experiment has a negative result.
EINSTEIN’S POSTULATES
The two basic postulates of theory of relativity are
1. Principle of Equivalence
‘All inertial reference frames are equivalent’ or ‘the laws of physics remain same in all inertial
reference frames’.
Explanation: This postulate expresses the absence of a universal frame of reference. If the laws of
physics had different forms for two observers in relative motion then from these differences it
would have been possible to determine that which of them is actually moving. But this distinction
does not exist in nature.
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GALILEAN TRANSFORMATIONS
Let a reference frame S’ is moving along -
axis with constant velocity with respect to
another reference frame S. Suppose two
observers, one in frame S and other in S’
observe an event. The observer in frame S
notes that the event occurs at position
and at time , while the observer in
S’ observes that the event occurs at position
and at time .
If time is measured from the instant when
origins of the two frames coincide, the
distance moved by frame S’ in time along -axis is and hence
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and
i.e. (9a)
(9b)
and (9c)
where and are components of velocity in reference frames S’ and S respectively.
Equations (9) give Galilean transformations for velocity.
Further, differentiating Eq. (9) with respect to time, the components and of
acceleration in reference frames S and S’ are related as
(10a)
(10b)
and (10c)
which violates Einstein’s second postulate. Hence Galilean transformations violate both the postulates of
special theory of relativity.
LORENTZ TRANSFORMATIONS
Lorentz transformations are relativistic
analog of Galilean transformations. These
are fundamental equations of special
relativity and are derived on the basis of
its two postulates.
Suppose a reference frame S’ is moving
along -axis with a constant velocity
with respect to another reference frame
S. Let a light flash is emitted from origin
when the origin O and O’ of systems S
and S’ just coincide and the time is measured from this instant. Further, an observer at origin O in reference
frame S notes that light reaches a point P with coordinates at distance from origin O in time with
velocity , then
or (11)
Since from 2nd postulate of special relativity, the velocity of light is for both the observers, therefore
another observer at O’ records that the light reaches same point P with coordinates at distance
in time . This gives
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or (12)
Further, from 1st postulate of theory of relativity the two reference frames are equivalent, hence from Eqs.
(11) and (12) we have
Since there is no relative motion along and directions, we have and , therefore above
equation gives
(13)
Further, let the transformation equations for and are of the form
(14)
and (15)
where and are constants.
Substituting for and from Eq. (14) and (15) in Eq. (13) and equating coefficients of , and on
both sides we get three equations in constants and . Solving these equations one obtains
√
and
Hence from Eq. (14) and (15) the transformation equations for and are given by
√
and
√
Thus, Lorentz transformation equations are given by
(16a)
√
(16b)
(16c)
and (16d)
√
The inverse Lorentz transformations can be obtained by interchanging coordinates and
and replacing by – as below
(17a)
√
(17b)
(17c)
(17d)
√
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For non-relativistic speeds and , therefore Lorentz transformations as given by Eq. (16)
reduce to
and
which are Galilean transformations.
LENGTH CONTRACTION
According to theory of relativity, space is not absolute. The observed length of an object maybe different
when measured from different reference frames. The length of a moving rod is smaller than that of same rod
at rest.
Let us consider two systems S and S’
moving with respect to each other with a
constant relative velocity in the positive -
direction. Suppose a rod AB of length is
placed parallel to -axis in reference frame S’.
The observers in system S and S’ respectively
observe the -coordinate of the ends of the
rod as and , then
(18)
and (19)
where L is the length of rod as measured in system S. For the observer in system S’, the rod is at rest while
the observer in system S observes that the rod is moving along x-axis with velocity v . From Lorentz
transformations we have
and
√
substituting these values in Eq. (18) we get
√ √
This gives length of a moving rod as
√ (20)
Discussion
1. From Eq. (20) it is clear that . Thus length of a rod contracts during motion parallel to its
length.
2. At low velocities when Eq. (20) gives , which is consistent with our daily experience.
3. For , Eq. (20) gives , i.e. whatever be the length of the rod it will reduce to a point when it
moves with velocity of light.
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TIME DILATION
According to theory of relativity, time is not absolute. The time interval between two events as measured
from different reference frames may be different.
Let us consider two systems S and S’ moving
with respect to each other with a constant
relative velocity along -axis. Suppose a gun is
fixed at position P having coordinates in
system S’ and it fires two shots at time and
and as measured in S’. Hence the time
interval between the two shots in system S’
(21)
Since the gun is fixed in S’ it has a velocity
along -axis with respect to system S. let the
time interval between the shots as measured by
an observer in system S is
(22)
From inverse Lorentz transformation we have
and
√
Substituting these values in Eq. (22) we have
i.e. (23)
√
Discussion
1. From Eq. (23) it is clear that . Thus the time interval between two events taking place at a
given point in a moving frame S’ appears to be longer to an observer in the stationary frame S. This is
called time dilation.
2. At low velocities , hence , showing Galilean absoluteness of time.
3. At , .
4. Twin Paradox: if one of the two identical twin brothers goes on a long space journey in a rocket
moving with a velocity comparable to velocity of light leaving his brother on earth then the clock in
the moving rocket will appear to go slow according to time dilation formula. As a result when he
returns to earth he will find himself younger than his brother who stayed on earth.
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However, µ-Mesons can be observed at sea level even though classically they can travel only 600 m distance
in their life time. Further, if length contraction and time dilation phenomena are real then 10 km distance as
seen by µ-Mesons will be given by √ √
Similarly with respect to mesons the lifetime of µ-Mesons will be given by
√ √
and distance travelled by µ-Mesons in this time interval
Proof:
Let us consider two systems S and S’ and an object O
moving in space along -axis. Suppose velocity of
system S’ with respect to S is . The velocity of object O
as measured from system S and S’ are respectively
and . Let at an instant the position of the object O as measured from two systems are and then
(24)
and (25)
where and represent proper time in system S and S’ respectively.
Further, from Lorentz transformations
and
√
Differentiating above equations we have
(26)
√
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and (27)
√
Dividing Eq. (26) by Eq. (27)
or
i.e. (28)
This is required formula for addition of velocities. If system S’ is moving in opposite direction then should
be replaced by – and so we get
i.e. (29)
Eq. (28) gives us relative velocity between two bodies moving with speeds and in same direction and Eq.
(29) gives the same for opposite direction.
Discussion:
1. At low velocities and hence
and from Eqs. (28) and (29) we have which is old classical formula.
2. When one of the velocities is , say then
Thus the relative velocity between two objects one of which is moving with velocity of light is equal
to velocity of light itself. This is in agreement with 2nd postulate of special relativity.
3. From Eq. (29), the relative velocity between two photons moving towards each other may be
obtained by substituting as
RELATIVITY OF SIMULTANEITY
Two events occurring at same time are called simultaneous events and this phenomenon is called
simultaneity. It can be shown by theory of relativity that two events occurring at same time in a physical
system may appear to be occurring at different times from other systems.
Proof
Consider two reference frames S and S’ moving with a relative velocity along -axis. Suppose an observer
in system S observes two events E1 and E2 occurring at positions and and at time and respectively.
For another observer in system S’, these events appear to be occurring at positions and and at time
and respectively.
From time transformation equation of Lorentz
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(30)
√
and (31)
√
Subtracting Eq. (30) from Eq. (31) we get the time interval between the two events as observed from system
S’ as
and (32)
√ √
Discussion:
1. If these two events are simultaneous in system S i.e. then
(33)
√
It is clear that i.e. the two events are not simultaneous in system S’ until . Further, for
we have from Eq. (33). Thus, from system S’, the event occurring at a farther position
will appear to be occurring first.
2. Space time equivalence
From Eq. (33) we have
√
This equation gives a relation between time interval and space interval . It shows relativity of
simultaneity as well as the equivalence of time and space. It indicates that space and time are inter-
convertible and hence they are equivalent.
3. From Eq. (33), one has when . Hence two simultaneous events in system S are
simultaneous in system S’ also if they are
occurring at same place.
RELATIVITY OF MASS
According to theory of relativity mass of a
body increases with its velocity i.e. mass of a
moving body is greater than its mass when it
is at rest.
Proof:
Consider two systems S and S’ moving
with respect to each other with a constant
relative velocity in the positive -direction.
Suppose there are two identical balls A and B of mass in system S’ approaching each other at equal speeds
and – . Let the balls collide and after collision they coalesce (Vdjkdj tqM+ tkuk) to form a combined mass. In
this case, applying law of conservation of momentum in system S’, we have
Therefore, after collision the combined mass must be at rest in system S’.
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Further, let us consider the same collision from system S. Let the velocities of the balls A and B as observed
from system S are and and there masses are and , then from law of addition of velocities
(34)
and (35)
Since after collision the combined mass comes to rest in system S’, the velocity of combined mass as
observed from system S will be .
Now, applying law of conservation of momentum in system S, we have
(36)
Substituting for and from Eq. (34) and (35), we get
which gives
( ) ( )
Simplifying we get ( ) ( )
i.e. (37)
( )
( ) ( )
i.e.
( ) ( )
( )( )
or (38)
( ) ( )
( )( )
(39)
( )
(40)
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or √ √ (41)
Since both sides of above equation are independent of each other, therefore above result can be true only if
each side of the above equation is a constant (say ). Hence,
√ √
(42)
√
Discussion:
1. When , we have . This shows Galilean absoluteness of mass at low velocities.
2. At , Eq. (42) gives i.e. an object having a finite rest mass and moving with velocity of light
will have infinite mass.
3. From Eq. (42)
√
which indicates that if then i.e. the particles having zero rest mass (like photons, neutrino
etc) always move with velocity of light.
Proof:
We know that the force acting on a particle is defined as the rate of change of linear momentum i.e.
Since according to theory of relativity mass varies with velocity of the particle therefore
(43)
Let the force displaces the body of mass through a distance then increase in kinetic energy of
the body
( )
i.e. (44)
Further, from mass transformation formula
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√
Squaring both sides and simplifying we get
or
Differentiating above equation we get
or (45)
from Eq. (44) and Eq. (45)
(46)
which shows that a change in kinetic energy of the particle is directly related to a change in mass. Moreover,
when body is at rest we have , and kinetic energy and when body is moving its mass
is and kinetic energy is . Integrating Eq. (46) within these limits we get
∫ ∫
or (47)
This is relativistic formula for kinetic energy. When the body is at rest the energy stored in the body is
which is called rest mass energy. The total energy of the body is the sum of rest mass energy and kinetic
energy. Hence
or (48)
Discussion:
1. Eq. (48) indicates that mass and energy are equivalent and they are inter-convertible.
2. The formula for kinetic energy reduces to the classical formula for as follows
( )
√
or {( ) }
Expanding right hand side by binomial theorem and neglecting higher terms as , we get
( )
3. Eq. (48) forms the basis of all nuclear reactions like fission and fusion.
RELATIVISTIC MOMENTUM
From Einstein’s mass energy relation, the energy equivalent to mass is given by
where √ .
Therefore (49)
√
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i.e. ( )
or
i.e.
or
or (50)
Above equation gives relation between total energy, rest mass energy and linear momentum. It shows that
for a mass at rest when then . Further a particle with no rest mass i.e. can still have
linear momentum given by
or
i.e.
or √
This gives relativistic formula for linear momentum in terms of kinetic energy of the particle. The first term in
right hand side is identical with the classical formula for momentum ( √ ). The second term may
be called relativistic correction term which reduces to zero at low velocities.
EXERCISE
Short Answer Questions
1. Is earth inertial frame of reference? Explain.
2. What do you understand by inertial and non-inertial frames? (UPTU 14 CO).
3. What are inertial and non-inertial reference frames? (UPTU 14)
4. What do you understand by time dilation? (UPTU 13)
5. What are mass-less particles? (UPTU 13, 12)
6. What is length contraction? (UPTU: 12 II)
7. What do you understand by variant and invariant under Galilean transformations? (UPTU 11)
8. Show that Galilean transformations violate the postulates of special relativity.
9. Show that a mass-less particle has energy and momentum and moves with the speed of light.
10. State Einstein’s postulates of special theory of relativity.
11. What was the objective and outcome of Michelson-Morley experiment?
12. How the negative result of MM Expt interpreted? (UPTU 15)
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13. Establish the relation , where symbols have their usual meaning.
14. Find relativistic relation between energy and momentum. (UPTU 15)
Numerical Problems
1. Calculate the length of one meter rod moving parallel to its length when its mass is 1.5 times its rest
mass. (UPTU 13)
2. What is the length of a meter stick moving parallel to its length when its mass is 3/2 times its rest
mass?
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3. Calculate the length and orientation of a rod of length 5 m in a frame of reference moving with a
velocity of 0.6c in the direction making an angle 30 degrees with the rod. (UPTU 15, 10) Hint:
√ [4.272 m, 35.8o]
4. Calculate percentage contraction of a rod moving with a velocity of 0.8c in a direction inclined at 60
deg to its own length. (UPTU 14 CO, 08) Hint: √ [8.3%]
5. How fast would a rocket have to go relative to an observer for its length to be contracted to 99% of
its length? (UPTU 07-08) Hint: √ [0.141 c]
6. A rod 1 m long is moving along its length with a velocity 0.6c. Calculate its length as it appears to an
observer (a) on the earth (b) moving with the rod itself.
7. A train, whose length is 150 meter when at rest, has to pass through a tunnel of length 125 m. The
train is moving with uniform speed of 2.4 ×10 8 m/s towards the tunnel. Find the length of the train
and that of the tunnel as observed by an observer (i) at the tunnel (ii) at the train.
8. A clock in a spaceship emits signals at intervals of 1 second as observed by an astronaut in the space
ship. If the spaceship travels with a speed of m/s. What is the interval between successive
signals as seen by an observer at the control center on the ground?
9. A particle with a proper lifetime of 1 µs moves through the laboratory at m/s, (a) what is
its lifetime as measured by the observer in the laboratory? (b) What will be the distance traversed by
it before disintegrating?
10. A man leaves the earth in a rocket that makes a round trip to the nearest star which is 4 light years
away at a velocity of 0.8c. How much younger will he be on his return than his twin brother who
preferred to stay behind?
11. Compute the lifetime of π + mesons traveling with velocity 0.8c if their proper mean life time is
s. What will be the distance traveled in one mean lifetime with a velocity 0.8c? What will
be this distance if the relativistic effect is not considerable?
12. A clock measures the proper time. With what velocity it should move relative to an observer so that
it appears to go slow by 30 s in 24 hrs.Hint: √ ,[ ]
13. A wrist watch keeping correct time on the earth is worn by the pilot of a spaceship. How much will it
appear to go slow per day with respect to an observer on the earth when spaceship leaves the earth
with velocity of 107 m/sec.
14. At what speed should a clock be moved so that it may appear to lose 1 minute in each hour? (UPTU
09) Hint: √ , [ ]
15. The proper life of mesons is sec. If a beam of these mesons of velocity 0.8c is
produced, calculate the distance the beam can travel before the flux of the meson beam is reduced
to 1/e2 times the initial flux.
16. An experimenter observes a radioactive atom moving with a velocity of . The atom then emits
a particle which has a velocity of relative to the atom in the direction of its motion. What is
the velocity of the particle as observed by the experimenter? Hint: ( ),
[ ]
17. An electron is moving with a speed of in a direction opposite to that of a moving photon.
Calculate the relative velocity of the photon with respect to the electron. Hint:
( ), [ ]
18. A particle has a velocity ̂ ̂ ̂ m/s in a coordinate system moving with velocity 0.8c
relative to laboratory along +ve direction of x-axis. Find in laboratory frame.
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19. A spaceship moving away from the earth with velocity 0.5 c fires a rocket whose velocity relative to
the space is 0.5 c. Calculate the velocity of the rocket as observed from the earth in following two
cases: (i) away from the earth (ii) towards the earth.
20. In an inertial frame S, a red light and blue light are separated by a distance = 2.45 km. The red light is
flashed after 5.35 second when the blue light flashes. Another system S’ is moving along X axis with
velocity u=0.855 c. What is the distance between the two flashes and the time between them as
measured in S’.
21. At what speed is a particle moving if the mass is equal to three times its rest mass? Hint:
√ ,[ ]
22. Find the speed that a proton must be given if its mass is to be twice its rest mass of kg.
What energy must be given to the proton to achieve this speed?
23. How fast must an electron move in order to have its mass equal to the rest mass of the proton?
24. What is the length of a meter stick moving parallel to its length when its mass is 3/2 times its rest
mass?
25. At what velocity will the mass of a body be 2.25 times its rest mass?
26. Calculate the velocity of a particle if the kinetic energy of particle is three times the rest mass
energy. (UPTU 12-II) Hint: , mass transformation formula, [ ]
27. The total energy of a moving meson is exactly twice its rest energy. Find the speed of the meson.
(UPTU 12) Hint: √ ,[ √ ]
28. The mass of a moving electron is 11 times its rest mass. Find its kinetic energy and momentum.
(UPTU 11, 09) Hint: , ,[ √ ]
29. How much does a proton gain in mass when accelerated to a kinetic energy of 500 MeV. (UPTU: 07)
Hint: ,[ kg]
30. If 4 kg of a substance is fully converted into energy, how much energy is produced?
31. Calculate the rest energy of an electron in joules and in electron volts.
32. Calculate the kinetic energy of an electron moving with a velocity in the laboratory system.
33. If the Kinetic energy of a body is double its rest mass energy, calculate its velocity. (UPTU 15)
34. Calculate the amount of work to be done to increase the speed of electron from 0.6 c to 0.8c, given
rest energy of electron = 0.5 Mev?
(UPTU 14)
35. Find the speed of 0.1 MeV electrons according to classical and relativistic mechanics.
36. What will be the fringe shift according to the ether theory in the Michelson Morley experiment, if
the effective path length of each path is 7 m and light has 7000 Å wavelength? The velocity of earth
is 3x104 m/s. [0.2] Hint:
37. In Michelson Morley experiment the length of the paths of the two beams is 11 m each. The
wavelength of the light used is 6000 Å. If the expected fringe shift is 0.4 fringes, calculate the
velocity of the earth relative to ether. Hint: , [31.3 km/s]
38. Calculate the expected fringe shift in a Michelson Morley experiment if the distance of each path is
11 m and the wavelength of light is 5.6x10 -7 m. The experimental set up was now rotated through
90o. The linear velocity of earth may be taken as 30 km/s. (0.196) Hint:
39. The position of a point in the frame S’ moving relative to S with a constant velocity of 10 cm/s along
the X-axis is given by (11, 9, 8). Calculate its position with respect to the frame S, if the two frames
were in coincidence only 0.5 second before. (16,9,8) Hint:
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40. If at the time , the origin of systems S and S’ just coincide and a spherical pulse of light is
produced at the common origin, show that the speed of propagation of spherical wavefront is the
same in both systems, where system S’ is moving relative to stationary system S.
41. Show that the circle in frame S appears to be an ellipse in frame S’ which is moving
with velocity relative to S.
42. A circular lamina moves with its plane parallel to the -plane of a reference frame S at rest.
Assuming its motion to be along the axis of , calculate the velocity at which its surface area
would appear to be reduced to half to an observer in frame S. (UPTU 13)
43. Obtain the volume of a cube, the proper length of each edge of which is , when it is moving with a
velocity along one of its edge?
44. Show that space time interval is invariant under Lorentz transformation.
45. Prove that magnitude of momentum of a particle of rest mass and the kinetic energy T is given
by
( )
46. Establish the relation , where is the linear momentum, is the total energy of
the particle.
47. If frame S' is moving with velocity with respect to frame S, and the components of velocity in
frame S' are and then prove that for the frame S, .
48. Show that the relativistic form of Newton’s second law, when F is parallel to u is
( )
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Wave Mechanics
WAVE PARICLE DUALITY; DE-BROGLIE HYPOTHESIS
Radiation sometimes behaves as particle and some other times it behaves as wave. The phenomena such
as Photoelectric effect, Compton effect, Zeeman effect etc are explained by particle nature of radiation while
Interference, Diffraction, Polarization are explained by its wave nature.
If and are moving mass and frequency of radiation respectively, then from Einstein’s mass energy
relation and Plank’s hypothesis
where is Plank’s constant, is velocity of light, and is wavelength of radiation. Hence the wavelength
associated with a photon is given by
(1)
de-Broglie proposed that like radiation, matter should also have wave - particle dual nature and the
wavelength associated with a material particle of mass moving with velocity should be given by
(2)
i.e.
The de-Broglie wavelength
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phase velocity
This gives
This indicates that wave velocity is always greater than velocity of light because particle velocity is always
lesser than .
Show that the de-Broglie wave group associated with a particle moves with velocity of the particle itself.
Moving mass of a body is related with its rest mass by the equation
√
where is velocity of the particle.
Further, the group velocity of the wave packet is given by , where is angular frequency and
is the propagation constant.
Moreover, from Einstein’s mass energy relation and Plank’s formula we have or ,
hence angular frequency
Therefore, (9)
Hence, (10)
and (12)
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( ) (13)
i.e. (14)
This gives √
i.e. de-Broglie Wavelength
(15a)
√
Suppose a particle having charge is accelerated by an electric potential then kinetic energy gained by
the charged particle is equal to the work done by the electric field. i.e.
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The curves show that with increase in accelerating potential the electrons are scattered nearly
homogeneously up to 40 volts, but with further increase in accelerating voltage a bump appears on the
curve. The size of the bump goes on increasing with increase in voltage up to 54 volts and after that it starts
reducing and it disappears at 68 volt accelerating voltage. The size of the bump is greatest at 54 volt for 50 o
angle of colatitudes.
Interpretation of the result
The existence of the bump on polar curves indicates that electrons are being scattered along a particular
direction more than any other direction. This cannot be explained by considering electrons as particles.
However, if electrons are considered as waves then bump on polar curves can be explained as a
consequence of diffraction of electron waves by the crystal just like X-ray diffraction. The crystal may be
supposed to act as grating whose grating element is equal to the inter-planer spacing d . Hence successive
positions of maxima will be given by
Substituting d 2.15 Å, 50o and n 1, we can calculate wavelength of electron waves from above
equation as
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√
Substituting V 54 volt, one can obtain .
Since de-Broglie wavelength of electrons is same as the wavelength of electrons determined experimentally,
this verifies de-Broglie concept of matter waves.
where p, x , E , t , and j are respectively the uncertainties in measuring momentum, position,
energy, time, angular position and angular momentum.
However, from wave mechanics, the uncertainty principle can be proved to be
,
or ,
where .
Illustration
1. According to de-Broglie a particle may be represented as a wave packet of finite length . As the
particle can be found at any point within the wave packet, there is an uncertainty in measuring
position of the particle. The uncertainty in measuring position can be minimized by considering a
smaller wave packet, but then uncertainty in measuring wavelength associated with the particle will
increase and this will, in turn, increase the uncertainty in measuring momentum of the particle.
2. Suppose we wish to measure the position and momentum of an electron at a given instant. For this we
will have to illuminate the electron with light or we will have to do some other similar act. When light
falls on the electron, both position and momentum of electron will change and we will always be
measuring changed position and changed momentum of the electron.
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The limit of resolution which is the reciprocal of the resolving power of microscope is given by .
Since microscope cannot distinguish between two objects placed at a separation less than limit of resolution
therefore uncertainty in measuring position of electron
(17)
Further, the momentum of electron scattered along directions OB and OA will be respectively
and , where is the momentum of incident photon and is Plank’s constant. Since photon
should enter into the microscope between directions OA and OB therefore uncertainty in measuring
momentum
( ) (18)
,
With this substitution in Eq. (15)
(20)
For minimum energy
i.e. { }
or ( )
( ) ( ) √
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i.e.
Hence momentum of nuclear electrons will be at least of the order . The energy of electrons
with such a large momentum will be given by
i.e.
Hence if electrons exist in the nucleus, they should have an energy of the order of while the
electrons emitted from nucleus as -particles have an energy only of the order of . This indicates that
electrons are not the constituent part of the nucleus.
(21)
i.e. (22)
For above value of one can determine which comes out to be positive. Hence as
given by Eq. (22) corresponds to minimum energy of electron i.e. first Bohr orbit. Hence the radius of first
Bohr orbit
(23)
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∫ | | ∫
where integral is evaluated over the whole volume . If particle is definitely present in the given volume
then
∫ | | ∫ (24)
∫ (25)
If the wave function is not normalized, the value of the integral on the left hand side of the above
equation will not be unity and
∫ ( if is not normalized)
In such cases the wave function should be divided by √ to normalize it i.e. √ will be the normalized
wave function. Here is called as the norm of the wave function and √ is known as normalization
constant.
ORTHOGONALITY
We know that two vectors having their dot product zero are said to be orthogonal. In a similar manner two
wave functions and are said to be orthogonal in the interval if
where is complex conjugate of . For a set of wave functions above orthogonality condition may be
written as
∫ (26)
SCHRODINGER EQUATION
A plane wave propagating along positive x -axis is represented by the equation
where and , being de-Broglie wavelength associated with the particle. Further energy
and momentum , hence from above equation
(27)
or ( )
Further,
or (29)
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or (30)
i.e.
or (31)
Eq. (31) gives the time independent form of Schrodinger wave equation in one dimension. In 3D it is given by
(32)
Further, substituting for and from Eqs. (28) and (29) in Eq. (30) we get
(33)
which is time dependent form of Schrodinger wave equation in one dimension. In three dimensions this may
be written as
(34)
or [ ] (35)
In the above equation the operator inside the square bracket on the left hand side is total energy operator
(kinetic energy + potential energy). It is called as Hamiltonian operator ̂ i.e.
̂ (36)
OPERATOR EQUIVALENCE
Eqs. (28) and (29) respectively indicate that the square of the momentum i.e. corresponds to operator
and energy corresponds to the operator . Hence the operators and
are respectively defined as energy and momentum operator in quantum mechanics. When an
operator corresponding to a physical variable is applied to wave function , one obtains the numerical value
of that physical variable times . Few examples of such operators in wave mechanics are
Energy Operator
Momentum operator ( )
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EXPECTATION VALUE
When measurement of a physical quantity is made for a particle, we may get different values in different
trials. This is according to Heisenberg’s uncertainty principle. Out of these measured values of physical
variable there will be one value which will be most expected. This is called as the expectation value of
dynamical variable and it is expressed as 〈 〉. The expectation value of the dynamical variable is given by
∫ ̂
〈 〉 (37)
∫
where ̂ is the operator associated with physical quantity , is the complex conjugate of the wave
function associated with the particle and integral is evaluated over the volume in which the particle is
present.
If the wave function is normalized then
Superposition Principle
According to this principle if and are two wave functions which represent two possible states of a
particle then the combination represents another possible state. Here and are
arbitrary complex numbers.
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Inside the box , therefore in region II above equation takes the form
or (39)
where (40)
Eq. (39) is a second order differential equation with general solution of the form
(41)
where and are arbitrary constants.
At and at we have , hence Eq. (41) gives following two conditions for constants and
i.e.
and
This gives
or (42)
where is a positive integer.
Eigen Values
Substituting for from Eq. (42) in Eq. (40) we obtain
( )
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As can take only integral values, the above equation suggests that inside the box particle can move with
only certain permitted energies while the energy corresponding to state is given by the above equation.
st nd rd
Further, energies corresponding to 1 , 2 , 3 etc energy levels are
and so on.
Eigen functions
Substituting for from Eq. (42) and in Eq. (41) we get wave functions corresponding to energy
state of the particle
(44)
The value of constant can be determined by applying normalization condition. As the particle is definitely
present inside the box
i.e. ∫| |
or | | ∫ ( )
i.e. | | √
Hence from Eq. (44)
√
It is clear that, two wave functions corresponding to positive and negative sign are associated with each
energy state . Figure shows some lower energy Eigen functions.
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EXERCISE
Short Answer Questions
1. Write the characteristics of wave function. (UPTU 15)
2. Why wave nature of matter is not observed in our daily life? (UPTU 14 CO)
3. What is meant by wave particle duality?
4. Compare the wavelength of a photon and an electron if the two have same momentum. (UPTU: 12, 11)
5. Can a photon and an electron of the same momentum have the same wave length?
6. Define group velocity and phase velocity.
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Numerical Problems
1. Calculate de-Broglie wavelength of an alpha particle accelerated through a potential difference of 200
V. (UPTU 14 CO)
2. A proton is moving with a speed of . Find the wavelength of the matter wave associated
with it. (UPTU 12)
3. Calculate the wavelength of an electron that has been accelerated in a particle accelerator through a
potential difference of 100 V. (UPTU 10)
4. Calculate de-Broglie wavelength of neutron of energy 12.8 MeV. (UPTU 09)
5. Calculate the kinetic energy of an electron if its de-Broglie wavelength equals the wavelength of the
yellow line of sodium (5796 Å). (UPTU 08-SCO)
6. The kinetic energy of an electron is J. Calculate velocity, momentum and wavelength of
electron. (UPTU 08)
7. If uncertainty in the position of a particle is equal to de Broglie wavelength, what will be uncertainty in
the measurement of velocity? (UPTU 15)
8. The speed of an electron is measured to be to an accuracy of . Find the
uncertainty in determining the position of this electron (mass of electron is and Plank’s
constant is ). (UPTU 13)
9. Calculate the kinetic energy needed by an electron to be confined in hydrogen atom of radius 0.5 Å.
(UPTU 11)
10. A nucleon is confined to a nucleus of diameter m. Calculate minimum uncertainty in the
momentum of the nucleon. Also calculate the minimum kinetic energy of the nucleon. (UPTU 09)
11. An electron is confined to a box of length 1.1 Å. Calculate the minimum uncertainty in its velocity.
[1.06X106 m/s] (UPTU 08)
12. Calculate the uncertainty in the position of a dust particle with mass equal to 1 mg if uncertainty in its
velocity is m/s. (UPTU 08)
13. A particle is in motion along a line between and with zero potential energy. At points for
which and , the potential energy is infinite. The wave function for the particle in state is
given by
Find the expression for the normalized wave functions. (UPTU: 09)
14. An electron is bound in one dimensional potential box which has width . Assuming the
height of the box to be infinite, calculate the lowest two permitted energy values of the electron. (UPTU
14)
15. Calculate the energy difference between the ground state and the first excited state for an electron in a
one dimensional potential rigid box of length .
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