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Experiment 7

The document outlines Experiment 7 for determining the mixture of Sodium Carbonate (Na2CO3) and Sodium Bicarbonate (NaHCO3) using Hydrochloric acid (HCl). It includes the chemical equations involved, detailed procedures for titration using two different indicators, and calculations for normality and strength of the compounds. The experiment aims to identify the concentrations of the two sodium compounds in a mixture.

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102 views5 pages

Experiment 7

The document outlines Experiment 7 for determining the mixture of Sodium Carbonate (Na2CO3) and Sodium Bicarbonate (NaHCO3) using Hydrochloric acid (HCl). It includes the chemical equations involved, detailed procedures for titration using two different indicators, and calculations for normality and strength of the compounds. The experiment aims to identify the concentrations of the two sodium compounds in a mixture.

Uploaded by

abdoseyam60
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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High Institute of Engineering & Technology

Basic Science Department

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Experiment 7

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Dr.
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Dr. Dalia Rashad Emam


Experiment 7
Determination of a mixture of Sodium Carbonate (Na2CO3) and
Sodium bicarbonate (NaHCO3) by Hydrochloric acid (HCl) (0.1 N)

Equation:

HCl + Na 2CO 3 NaHCO3 + NaCl

HCl + NaHCO3 NaCl + CO 2 + H 2O

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2HCl + Na2CO 3 2NaCl + CO 2 + H 2O

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HCl + NaHCO3 NaCl + CO2 + H 2O
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Procedure:
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1- In case of Ph.Ph.
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1- Fill the burette with HCl until zero mark.


2- Transfer 10 ml of mixture using pipette to the conical flask.
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3- Add 2 drops of Ph. Ph and swirl to mix well. A pink color will appear.
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4- Titrate against HCl taken in burette drop by drop; shake well until the color
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changed from pink to colorless. Record the burette volume.


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V1
HCl

End point: pink to colorless

10 ml mixture + 2 drops Ph. Ph.

1
V1 of HCl ≡ -------- ml

V1 = The volume of HCl ≡ ½ Na2CO3 → 1

HCl + Na2CO3 NaHCO3 + NaCl

2- In case of M.O.
1- Fill the burette with HCl until zero mark.

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2- Transfer 10 ml of mixture using pipette to the conical flask.

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3- Add 2 drops of M.O. and swirl to mix well. A yellow color will appear.
4- Titrate against HCl taken in burette drop by drop; shake well until the color
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changed from yellow to orange. Record the burette volume.
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End point: yellow to orange


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HCl V2
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10 ml mixture + 2 drops M.O.

V2 of HCl ≡ --------- ml

V2 = The volume of HCl ≡ all NaHCO3 + all Na2CO3 → 2

2
HCl + Na2CO3 NaHCO3 + NaCl

HCl + NaHCO3 NaCl + CO2 + H2O

HCl + NaHCO3 NaCl + CO2 + H 2O

2 V1 ≡ Na2CO3

V2 – 2 V1 ≡ NaHCO3

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Calculation:
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Normality and strength for Na2CO3
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(N x V) HCl = (N x V) Na2CO3
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0.1 x 2V1 = (N x 10) Na2CO3


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N= -------- gm. eqwt / L


D
r.

S = N x Eq. wt.
D

Mass number
Na = 23, C = 12, O = 16

3
S = N x 53 = ---------- gm / L

Normality and strength for NaHCO3

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(N x V) HCl = (N x V) NaHCO3

Im
0.1 x V2 – 2 V1 = (N x 10) NaHCO3

d
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N= -------- gm. eqwt / L
as

S = N x Eq. wt.
R
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D

Mass number
r.

Na = 23, H = 1, C = 12, O = 16
D

S = N x 84 = ---------- gm / L

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