09-03-2025

1001CJA101031240023 JA

PART-1 : PHYSICS

SECTION-I

1) The n-storey symmetrical tower shown in the figure was built from dominoes of length ℓ. What is
the maximum length out of the balconies of the tower if each domino is pulled out as much as

possible ?

(A) (3n – 1)ℓ/3n

(B) (2n – 1)ℓ/2n
(C) (n – 1)ℓ/n
(D) 5ℓ/8 for each balcony

2) A thin wire of length L and uniform linear mass density ρ is bent into a circular loop with centre
at O as shown. The moment of inertia of the loop about the axis XX' (lies in the plane of loop) is :-

(A)

(B)

(C)

(D)
3) Assertion : The total distance moved by any point on the periphery of a wheel of radius R along
the surface in one revolution is 2πR.
Reason : In rolling motion of a wheel, every point on its periphery comes in contact with the
surface once in one revolution.

(A) If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.
(B) If both Assertion & Reason are True but Reason is not a correct explanatilon of the Assertion.
(C) If Assertion is True but the Reason is False.
(D) If both Assertion & Reason are false.

4) A disc of mass m is rolling without slipping on a smooth horizontal surface followed by a smooth
curved track. It reaches a maximum height on the ramp and then returns on the horizontal track.

Friction force acting on the disc in part BA is :-

(A) µmg

(B)

(C)

(D) zero

5) In the figure shown, the mass of the disc as well as that of the trolley is M. The spring is ideal and
has stiffness k. The trolley can move horizontally on the floor without friction, and the disc can roll
on the trolley surface without slipping. The spring is compressed and the system released so that

oscillations begin. The :-

(A) Acceleration of center of disc = twice of that of trolley

(B) Acceleration of center of disc = thrice of that of trolley
(C) Acceleration of center of disc = half of that of trolley
(D) Acceleration of center of disc = that of trolley

6) Circuit shows eight identical bulbs (A to H) connected through a battery of emf V. If bulb H is
replaced by a wire with no resistance then rank the brightness of the bulbs, from brightest to

dimmest.

(A) A > D > E = F = G > B = C

(B) D > A > B = C > E = F = G
(C) D > A > E = F = G > B = C
(D) A < D < E = F = G < B = C

7) A potentiometer has a resistance wire of 10 m length and resistance 10Ω as shown in figure. A
circuit is setup as shown. For null deflection in galvanometer length AP is :

(A) 2m
(B) 4.5 m
(C) 6.5 m
(D) None of these

8) A 15Ω resistance is connected in the left gap and an unknown resistance less than 15Ω is
connected in the right gap of a meter bridge. When the resistances are interchanged, the balance
point is found to shift by 20 cm. The unknown resistance is

(A) 5 Ω
(B) 6 Ω
(C) 8 Ω
(D) 10 Ω

9) A small particle is placed at the pole of a concave mirror and then moved along the principal axis
to a large distance. During the motion, the distance between the pole of the mirror and the image is
measured. The procedure is then repeated with a convex mirror, a concave lens and a convex lens.
The graph is plotted between image distance versus object distance. Match the curves shown in the
graph with the mirror or lens that is corresponding to it. (Curve 1 has two segments)

List - I List - II
 (P) Converging lens (1) 1

(Q) Converging Mirror (2) 2

(R) Diverging Lens (3) 3

(S) Diverging Mirror (4) 4

(A) P → 1; Q → 1; R → 2; S → 2
(B) P → 1; Q → 2; R → 3; S → 4
(C) P → 1; Q → 2; R → 2; S → 3
(D) P → 3; Q → 2; R → 1; S → 4

10) A galvanometer has coil of resistance 100Ω showing a full scale deflection 50 mA. What
resistance should be added to use it as ammeter of range 10A?

(A)

(B)

(C)

(D)

11) The length of a wire increased by 2% by stretching. Then the percentage change in its resistance
will be :-

(A) 2%
(B) 4%

(C)
%

(D)
%

12) A ring is made of a wire having a resistance R0 = 15 Ω . Find the points A and B as shown in
figure at which a current carrying conductor should be connected so that the resistance R of the sub

circuit between these point is equal to Ω.

(A)
(B)

(C)

(D)

13) The focal lengths of objective lens and eye lens of a Galilean telescope are respectively 30 cm
and 3.0 cm. Telescope produces virtual, erect image of an object situated far away from it at least
distance of distinct vision from the eye lens. In this condition, the magnifying power of the Galilean
telescope should be :-

(A) +11.2
(B) –11.2
(C) –8.8
(D) +8.8

14) A compound microscope has a magnification of 30. The focal length of the eyepiece is 5 cm. If
the final image is formed at the least distance of vision (25 cm), the magnification produced by the
objective is

(A) 5
(B) 7.5
(C) 10
(D) 15

15) Statement-1: Voltage across a battery is always less than its emf.
Statement-2 : There is always some loss of energy due to internal resistance of the battery.

Statement–1 is True, Statement–2 is True ; Statement–2 is a correct explanation for

(A)
Statement–1.
Statement–1 is True, Statement–2 is True ; Statement–2 is not a correct explanation for
(B)
Statement–1.
(C) Statement–1 is True, Statement–2 is False.
(D) Statement–1 is False, Statement–2 is True.

16) Figures shows the graph of angle of deviation versus refractive index of the material of
constant thin angled prisms corresponding to light rays incident at a small angle of incidence. The
prism angle and slope of the line are respectively :

0
(A) 4 and 2
0
(B) 2 and 1/2
0
(C) 2 and 4
0
(D) 4 and 4

17) Four identical lenses are kept one beside the other on the same optical axis as shown in the
figure. The right surface of rightmost lens is silvered. Focal length of each lens is 20 cm and radius
of the silvered surface is 20 cm. The focal length of the combined system is

(A) 2 cm
(B) –2 cm
(C) 5 cm
(D) –5 cm

18) An erect object O is placed transverse to the axis of a converging lens at a distance equal to
twice the focal length f1 of the lens. On the other side of the lens, is placed a converging mirror of
focal length f2 at a distance d from the lens. The lens and the mirror have a common optic axis XY.
It is observed that the image of the object O seen after one refraction from lens and one reflection
from mirror is erect, real and of the same size as the object O. Then the distance d is given by :-

(A) d = f1 + f2
(B) d = 2 (f1 + f2)
(C)

(D) d = 2f2

19) The vernier of a vernier scale is divided into 10 divisions which coincide with 9 divisions of the
main scale, each main scale division being 0.5 mm. When the two jaws of the instrument are in
contact with each other, the 4th division of the vernier scale coincides with a main scale division and
the zero of the vernier lies to the right of the zero of the main scale. When a sphere is inserted
between the jaws, the zero of vernier scale lies slightly to the right of 1.8 cm and the sixth vernier
division coincides with a main division. The diameter of sphere will be

(A) 1.850 cm
(B) 1.810 cm
(C) 1.750 cm
(D) 1.710 cm

20) In the given circuit equivalent resistance between A and B is nR. Find the value of n.

(A) 6
(B) 7
(C) 8
(D) 9

SECTION-II

1) A vernier calipers has 1 mm marks on the main scale. It has 10 equal divisions on the vernier
scale which match with 8 main scale divisions. If the least count of vernier calipers is x × 10–1
mm, find x.

2) In an experiment of measuring the refractive index of a glass slab using travelling microscope in
physics lab, a student measures real thickness of the glass slab as 5.25 mm and apparent thickness
of the glass slab at 5.00 mm. Travelling microscope has 20 divisions in one cm on main scale and 50
divisions on Vernier scale is equal to 49 divisions on main scale. The estimated uncertainty in the

measurement of refractive index of the slab is , where x is _________

3)

In a Searle's experiment, the diameter of the wire as measured by a screw gauge of least count
0.001 cm is 0.050 cm. The length, measured by a scale of least count 0.1 cm, is 110.0 cm. When a
weight of 50 N is suspended from the wire, the extension is measured to be 0.125 cm by a
micrometer of least count 0.001 cm. Maximum error in the measurement of Young's modulus of the
material of the wire from these data is P × 109 N/m2, then value of P is
4) In the shown figure contains five unknown resistances and a battery. When ammeter is connected
between the terminals A and B its reading is 6A and when a resistance of connected in series
with the ammeter its reading becomes 3A. Now the ammeter and the resistance are disconnected
and an ideal voltmeter is connected between terminal A and B. What would the voltmeter reading in

volts?

5) The refractive indices of flint glass for red and violet light are 1.613 and 1.632 respectively. Find
the value of (1000) × (θ) (in degree), where θ is angular dispersion produced by a thin prism of flint
glass having refracting angle 5 degree.

PART-2 : CHEMISTRY

SECTION-I

1) Assertion : Nucleophilic substitution reaction on an optically active halide gives a mixture of

enantiomers.
Reason : The reaction should be in accordance with SN1 mechanism.

(A) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(B) Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
(C) Assertion is true but Reason is false.
(D) Both Assertion and Reason are false.

2)

(A) R–OH + SOCl2 (I) Swarts reaction

R–X+NaI in acetone
(B) (II) Darzen process
(X=Cl, Br)

(C) R–Br + AgF (III) Wurtz fittig

(D) (IV) Finkelstein reaction

Correctly matched option is :

(A) (A) → (IV)
(B) (B) → (II)
(C) (D) → (III)
(D) (C) → (I)
3) The major product [R] in the following sequence of reactions is :-

(A)

(B)

(C)

(D)

4) A and B can be :

(A) Both are n-Hexane

(B) Both are D-sorbitol
(C) A is n-Hexane B is D-sorbitol
(D) A is D-sorbitol and B is n-Hexane

5) Find out the major products from the following reactions.

(A)
(B)

(C)

(D)

6) Which of the following gives 2° alcohol as major product :

(A)

(B)

(C)

(D)

7) products
Which of the following statements is correct?

(A) Tertiary butyl chloride is formed as major product

(B) This reaction is example of nucleophilic substitution (SN1)
(C) Primary alkyl chloride is formed as major product
(D) More than two alkyl chloride formed as final products

8)

Which of the following has been arranged in order of decreasing freezing point :-
(Assume α = 1 and molarity = molality)

(A) 0.05 M KNO3 > 0.04 M BaCl2 > 0.140 M sucrose > 0.075 M CuSO4
(B) 0.04 M BaCl2 > 0.140 M sucrose > 0.075 M CuSO4 > 0.05 M KNO3
(C) 0.075 M CuSO4 > 0.140 M sucrose > 0.04 M BaCl2 > 0.05 M KNO3
(D) 0.075 M CuSO4 > 0.05 M KNO3 > 0.140 M sucrose > 0.04 M BaCl2

9) Assertion : Equilibrium constant for endothermic reaction increase with increase in temperature.
Reason : Rate constant increases with increase in temperature.

(A) Both assertion and reason are true and the reason is a correct explanation of assertion.
(B) Both assertion and reason are true but reason is not a correct explanation of assertion.
(C) Assertion is true but the reason is false.
(D) Assertion is false but the reason is true.

10) In the system, LaCl3(s) +H2O(g) + heat LaClO(s) + 2HCl(g), equilibrium is established. More
water vapour is added to disturb the equilibrium. If the pressure of water vapour at new equilibrium
is double of that at initial equilibrium, the factor by which pressure of HCl is changed is:

(A) 2 times
(B) times

(C)
times
(D) 4 times

11) A solution contains [Cl–] = [Br–] = [I–] = 10–2 M (initially). Now to this solution, [AgNO3] is added
gradually.
Calculate concentration of Ag+ ion when first salt starts to precipitate out of solution ?
Given:
(Ksp of [Agl] = 10–17, KSP of [AgBr] = 10–13,
KSP of [AgCl] = 10–10)

(A) 10–8
(B) 10–10
(C) 10–15
(D) 10–7

12) If first dissociation of X(OH)3 is 100% whereas second dissociation is 50% and third dissociation
–3
is negligible then the pH of 4 × 10 M X(OH)3 is :
(log2 = 0.30, log3 = 0.48)

(A) 11.78
(B) 10.78
(C) 2.5
(D) 2.22

13) Consider two liquids A and B having pure vapour pressure forming an ideal solution.

The plot of (Y-axis) vs (X-axis) (where XA and YA are the mole fraction of liquid A in liquid and

vapour phase respectively) is linear with slope and intercept respectively.

(A)

(B)

(C)

(D)

14) Select the CORRECT reactant for brown ring test of NO3– ion

(A) Aqueous solution of salt + ferrous sulphate solution + dil. H2SO4

(B) Aqueous solution of salt + ferric sulphate solution + conc. H2SO4
(C) Aqueous solution of salt + ferrous sulphate solution + conc. H2SO4
(D) Aqueous solution of salt + ferric sulphate solution + dil. H2SO4

15) Which halide does NOT produce halogen when heated with MnO2 in dil. H2SO4 :-

(A) F–
(B) Cl–
(C) Br–
(D) I–

16) Anion in Aq. solution anion in Aqueous solution is -

2–
(A) CO3
2–
(B) SO3
(C) Cl–
2–
(D) S2O3

17) Na2CO3 and NaHCO3 salts are not distinguished by :-

(A) MgCl2
(B) Hph
(C) HgCl2(aq.)
(D) HCl

18) Which of the following cation does not produce red shaded flame colour in the flame test?

(A) Li+
(B) Cu2+
(C) Ca2+
(D) Sr2+

19) In an alkaline solution, sodium nitroprusside gives a violet colour with :

(A)
(B) S2–
(C)
(D)

20)

List-I List-II

(P) Zn[Fe(CN)5(NOS)] (1) Gives brown colour ppt with NH3

(Q) K2[HgI4] + KOH (2) Gives pungent odour with Devarda Alloy in presence of alkaline medium

(R) NaHC4H4O6 (3) Gives unknown compound of red colour with SO2

(S) NO3– (4) Gives white ppt. with K

+

(A) P → 3 ; Q → 2 ; R → 4 ; S → 1
(B) P → 2 ; Q → 1 ; R → 3 ; S → 4
(C) P → 3 ; Q → 1 ; R → 2 ; S → 4
(D) P → 3 ; Q → 1 ; R → 4 ; S → 2

SECTION-II

1) How many total dichloro products of following structure on chlorination (including

stereoisomerism).
2) A gaseous mixture of vapours of A and B, under a total pressure of 0.8 atm is in equilibrium with
an ideal liquid solution of A(ℓ) and B(ℓ) . The mole fraction of A is 0.5 in the vapour phase and 0.2 in
the liquid phase. The vapour pressure of pure liquid A is (in atm) _______ . (Nearest integer)
(Assume vapours behave ideally)

3) The equilibrium constant Kc at 298 K for the reaction A + B ⇌ C + D is 100. Starting with an
equimolar solution with concentrations of A, B, C and D all equal to 1M, the equilibrium
concentration of D is_____ × 10–2 M. (Nearest integer)

4) Two salts A2X and MX have the same value of solubility product of 4.0 × 10–12. The ratio of their

molar solubilities i.e. = _______. (Round off to the Nearest Integer).

5) How many of the following precipitates are black in colour ?

PbS, CuS, Bi2S3, Fe(OH)3, CoS, NiS, Sb2S5, Cr(OH)3, MnS, BaCO3, SrCO3

PART-3 : MATHEMATICS

SECTION-I

1) Consider parallelogram constructed on the vectors and . If ,

, ^ , then length of smallest diagonal of the parallelogram is

(A)
(B) 13
(C)
(D) 15

2) Let ƒ(x) = (|x| – 1)sgn(x–1), then ƒ(x) is

(A) discontinuous at x = 0 but continuous at x = 1

(B) continuous at x = 0 but discontinuous at x = 1
(C) continuous at x = 0,1
(D) discontinuous at x = 0,1

3) Consider the function ƒ(x) such that ƒ(x –1) + ƒ(x + 3) = ƒ(x + 1) and ƒ (5) = 1.
Assertion (A) : .
Reason (R): ƒ(x) is a periodic function with period 12.

(A) A is correct but R is not correct.

(B) A is not correct but R is correct.
(C) Both A and R are correct but R is NOT the correct explanation of A.
(D) Both A and R are correct and R is the correct explanation of A.

4) The vector is perpendicular to the vectors and and satisfies the

condition , then is equal to

(A) 1
(B) 0
(C) –1
(D) 9

5) If n(U) = 600, n(A) = 100, n(B) = 200 and n(A ∩ B) = 50, then is -
(U is universal set and A and B are subsets of U)

(A) 300
(B) 350
(C) 250
(D) 200

6) Let be three unit vectors such that . If is any vector such that
and then

(A)
(B)
(C)
(D)

7) Let P1 = x + y + z + 1 = 0, P2 = x – y + 2z + 1 = 0, P3 = 3x + y + 4z + 7 = 0 be three planes. Find

the distance of line of intersection of planes P1 = 0 and P2 = 0 from the plane P3 = 0.

(A)

(B)

(C)

(D)
8) Let be a unit vector which follows the equation, Also, and then

(A)

(B)

(C)

(D)

9) Given ƒ(x) = sgn(x2 – 4|x| + λ) (where sgn(x) denotes signum fuction of x, λ ∈ R)

In the List-I there are values of λ and in the List-II there are number of points where ƒ(x) is non-
differentiable.
Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(A) λ=0 (I) 0

(B) λ=4 (II) 3

(C) λ=5 (III) 4

(D) λ=2 (IV) 2

(A) (A)-II, (B)-IV, (C)-I, (D)-III
(B) (A)-II, (B)-I, (C)-III, (D)-IV
(C) (A)-I, (B)-II, (C)-III, (D)-IV
(D) (A)-IV, (B)-II, (C)-I, (D)-III

10) Complete solution set of equation [cos–1x] + 2[sin–1x] = 0 is (where [.] is greatest integer
function)

(A) (cos1,sin1)
(B) [–sin1,0) ∪ (cos1,sin1)
(C) [0,1]
(D) [–sin1,cos2] ∪ (cos1,sin1)

11) Let f(x) =

If f(x) is continuous at x = 0, then the value of k is

(A) 1

(B)

(C)
(D)

12) The volume of the tetrahedron formed by the planes whose equations are y + z = 0, z + x = 0, x
+ y = 0 and x + y + z = 2 is

(A)

(B)

(C)

(D) 32

13) The length of projection of the line segment joining the point (1, 0, –1) and (–1, 2, 2) to the plane
x + 3y – 5z = 6, is equal to

(A) 2

(B)

(C)

(D)

14) The shaded region in venn-diagram can be represented by which of the following?

(A)

(B)

(C)

(D)

15) Statement-I: cos–1x = 3cos–1a has a solution for all a ∈ [–1, 1]

and
Statement-II: cos–1a is defined when a ∈ [–1, 1]

(A) Statement-I is true but Statement-II is false.

(B) Both Statement-I and Statement-II are false.
(C) Both Statement-I and Statement-II are true.
(D) Statement-I is false but Statement-II is true.

16) Let R be a relation from A = {2,3,4,5} to B = {3,6,7,10} defined by R = {(a,b) | a divides b, a ∈

A, b ∈ B}, then number of elements in R–1 will be

(A) 0
(B) 3
(C) 4
(D) 5

17) Let , then unit digit of ƒ(10) is (where [.] is greatest integer function)

(A) 2
(B) 4
(C) 3
(D) 1

18) The value of is -

(A) – 46
(B) – 23
(C) – 30
(D) 46

19) Let ƒ(n) = (2)(4)(6)......(2n), n ∈ N and g(n) = (1) (3) (5).......(2n–1), n ∈ N, then the divisor of
ƒ(100) – g(100) is-

(A) 101
(B) 151
(C) 191
(D) 201

20) Let g(x) = ƒ(x)sinx where ƒ(x) is twice differentiable function on R such that ƒ'(–π) = 1, then value
of g"(–π) is equal to -

(A) 1
(B) 2
(C) – 2
(D) 0

SECTION-II
1) If value of is L, then the value of is

2) Given are 3 vectors such that and are unit like parallel vectors and . If
, then the sum of all possible value(s) of λ is

3) Let ƒ(x) = x + 1, g–1(x) = x3 + x + 1 and h(x) = g(ƒ(x)), then is equal to

4) Number of point(s) where g(x) = |x(2x + 1)(2x – 1)|cos(πx) is not differentiable is

5) Absolute value of a for which the lines and

intersect, is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A D A A B B D D A A B A D A D D B B B A

SECTION-II

Q. 21 22 23 24 25
A. 2 41 11 27 95

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A D B D A D C A B B C A B C A D D B B D

SECTION-II

Q. 46 47 48 49 50
A. 5 2 182 50 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C B A B D B C A D C C D C D D C C D C

SECTION-II

Q. 71 72 73 74 75
A. 2 8 4 1 3
 SOLUTIONS

PART-1 : PHYSICS

1)

For kth domino

Applying rotational equilibrium at A :-

Now,

we can see maximum length of balcony is given by k = n

2)

Mass = . L

4)
Upon return journey the disc rolls with forward slipping. Hence kinetic friction µmg will act on
the disc.
5)
kx – fs = ma1 ......(1)
fsR = ......(2)
fs = ma2 ......(3)
a1 – αr = a2 ......(4)
from (2) & (3)

ma2R =

a2 =
from equation (4)
a1 – 2a2 = a2 ⇒ a1 = 3a2

6) More i, more brightness because resistance of each bulb is same and i can be found using
series & parallel concepts.

7) As secondary battery have P.D. more than potential diffrence across wire AB. Therefore
balance point will not be achieved on wire AB.

8)

15 x x 15
ℓ 100 – ℓ ℓ – 20 120 – ℓ

9)

(P) For converging lens (convex lens)

at x = 0 y=0
For x = 0 to x = d, y = – ve
so, if x ↑ y ↓ and |y| ↑
At x = d, y = ∞
when x > d, y + ve, and
at x = ∞ , y = d
taking magnitude of y, distance graph is shown.

(Q) For converging mirror (concave mirror )

u = – x, f = – , v=y

At x = 0 , y=0

for 0 < x < , y = +ve

and as x increases decrease so y ↑ upto x =

At x = , y = ∞
So, graph is (1)

when x > y (–ve)

and as x ↑, 1/y ↓, y ↑ so, |y| ↓

At x = ∞ , y = –
graph breaks so graph is (1)

(R) For diverging Lens (concave lens )

u = – x, f=–d v= y

⇒ y is always –ve
At x = 0, y = 0
As x ↑, y ↓ so, |y| ↑
At x = d,
or x = ∞, y = – d
graph is (2)

(S) For diverging Mirror (convex mirror )

u = – x, , v=y

⇒ ⇒ y = +ve
At x = 0 , y=0

x ↑, y↑

At x = , y = , At x = ∞, y =
taking magnitude of y distance graph is

graph is (2)

10)
(I – Ig)R = IgRg

R=

11) As R ∝ ℓ2 (for stretching)

12)

As and R1 + R2 = 15
then R1R2 = 50

Now

Hence ⇒ R2 = 10Ω and R1 = 5Ω

13) Given, focal length of objective, f0 = 30 cm

Focal length of eye lens, fe = 3.0 cm
Magnifying power, M = ?
Magnifying power of the Galilean telescope,

MD =

= 10 × = 8.8 cm [∵ D = 25 cm]

14) Net magnification of compound microscope

m = m0·me
me → magnification due to eye piece
m0 → magnification due to objective
When final image is at least vision

m = m0·me

m0 = 5

0
16) For small angled prism from graph A = 4 , slope = A =4

17)

18) The image formed first by refraction in the convex lens is real and inverted and of the
same size as the object and is obtained at the distance 2f1 from the lens. This real image is
then reflected once in the converging mirror. The object distance for this reflection is given by
u = (d – 2f1). Now this reflection should yield a real and inverted image which again should
have the same size as the object.
Obviously, the object must be at the centre of curvature of this converging mirror. Hence we
must have u = radius of curvature of concave mirror i.e., u = d – 2f1 = 2f2 ⇒ d = 2f1 + 2f2 = 2(f1
+ f2)
19)

M.S. reading 35 mm
X + 4V = nM

X = nM –
X < 1 mm for n = 3 only

So,
∴ reading = 35 + 0.5 mm
= 3.55 cm

20)
⇒ x = 6R

21) 10 VSD = 8 MSD

L.C. = 1 MSD – 1 VSD = 0.2 mm

22)

Least count =

ln u = ln h – ln h′

23)

Diameter D = 0.050 cm, ΔD = 0.001 cm

Length L = 110.0 cm
ΔL = 0.1 cm
Weight W = 50 N
Extension ℓ = 0.125 cm = Δℓ = 0.001 cm

⇒ Y = 0.02241 × 1013 N/m2

Y = 2.241 × 1011 N/m2
 ⇒

⇒
⇒ ΔY = Y × 0.04891
⇒ ΔY = 2.241 × 1011 × 0.04891
⇒ ΔY = 0.1096 × 1011 N/m2
⇒ ΔY = 1.096 × 1010 N/m2
Least significant digit in this operation is two
ΔY = 1.1 × 1010 N/m2 = 11 × 109 N/m2

24)

25) Deviation of the red light is δr = (µr – 1) A and deviation of the violet light is δv = (µv – 1)A.
he dispersion θ = δv – δr = (µv – µr)A
= (1.632 – 1.613) × 5°
θ = 0.095° Hence Answer is 1000 θ = 95 degree

PART-2 : CHEMISTRY

26) Fact based.

28) Now :- (i) HgSO4/dil.H2SO4

(ii) NaBH4
is convert triple bond into ketone and formed ketone is reduced by NaBH4 and convert into
Alcohol.
30)

32)

33)

KNO3 BaCl2 Sucrose CuSO4

C = 0.05M 0.04M 0.140M 0.075M
i= 2 3 1 2
Cnet = (i × C)
Cnet 0.1 0.12 0.14 0.15
ΔTf ∝ Cnet
If Cnet increases, ΔTf also increases but freezing point decreases.

34) K = Ae–ΔH/RT

35)

LaCl3(s) + H2O(g) LaClO(s) + 2HCl(g) - heat already at equilibrium, more water vapour is
added without altering T or V of the system. When equilibrium re-established, the pressure of
water vapour is doubled. The pressure of HCl present in the system increases by a factor of
21/2.
The equilibrium constant expression is

Before addition of water vapour,

....(1)
After addition of water vapour,
 .....(2)
But (1) = (2)

.....(3)
When equilibrium re-established, the pressure of water vapour is doubled.
[H2O]f = 2[H2O]i .....(4)
Substitute (4) in (3)

[HCl]i = [HCl]f ×

36) [Ag+][I–]= KSP[Agl]

37) First dissociation :

Second dissociation :
Total [OH–] = 4 × 10–3 + 2 × 10–3 = 6 × 10–3
pOH = 3 – log 6 = 2.22
pH = 11.78

38)

39) NO3– ion + FeSO4 + Conc. H2SO4 → Brown ring complex

40) "MnO2" has less oxidising action F2. Hence F– can't be oxidised by MnO2.
41)

46)

47)

YA = 0.5 ⇒ YB = 0.5
PA = PB = 0.4 atm

atm

48)

A + B ⇌ C + D : Keq = 100
1M 1M 1M 1M
First check direction of reversible reaction.

Since QC = ⇒ reaction will move in forward direction to attain equilibrium

state.
⇒ A + B ⇌ C + D : Keq = 100
to 1 1 1 1
teq. 1–x 1–x 1+x 1+x
 Now : Keq = 100 =

(i)
⇒ 10 – 10x = 1+x
⇒ 11 x = 9

(ii)
⇒ –10 + 10x = 1 + x
⇒ –9x = –11

→ 'x' cannot be more than one, therefore not valid.

therefore equation concretion of (D) = 1 + x

= 1.8181 = 181.81 × 10–2

= 182 × 10–2

49) A2X ; Ksp = 4s3 ⇒ S =

MX; Ksp = s2, s =

S(MX) = = 2 × 10–6 M

50) PbS, CuS Bi2S3, CoS, NiS → Black

Fe(OH)3 → Brown
Sb2S5 → Orange
Cr(OH)3 → Green
MnS, → Pink
BaCO3, SrCO3 → White

PART-3 : MATHEMATICS

51) Diagonals are and

Lengths are

and
∴ length of smallest diagonal is 15

52) ƒ(1) = 0

ƒ(1 – h) = 0
at x = 0 both (|x| – 1) & sgn(x – 1) are continuous and their product is also continuous.

53)

ƒ(x – 1) + ƒ(x + 3) = ƒ(x + 1) ......(i)

Replacing x by x + 2
ƒ(x + 1) + ƒ(x + 5) = ƒ(x + 3) ......(ii)
from (i) and (ii)
ƒ(x – 1) + ƒ(x + 5) = 0
Replacing x by x + 1
⇒ ƒ(x) + ƒ(x + 6) = 0
⇒ ƒ(x) = – ƒ(x + 6) ......(v)
Replacing x by x + 6
ƒ(x + 6) = – ƒ(x + 12)
⇒ ƒ(x) = ƒ(x + 12)
hence ƒ(x) is periodic function with period 12

Now = 91
hence A is not correct but R is correct.

54) Let

given

∴
⇒ =5–4=1

55)
= n(u) – n(A ∪ B)
= 600 – (n(A) + n(B) – n(A ∩ B))
= 600 – 100 – 200 + 50
= 350
56) Given that

Let ......(1)
Take dot product in equation (1) both sides with , and we get x = 1, y = 2, z
= 3.

57) Let direction ratios of line are a, b, c

Now a + b + c = 0
a – b + 2c = 0

So direction ratios of line are (3, –1, –2)

x+y+z+1=0 ......(1)
x – y + 2z + 1 = 0 ......(2)
Put z = 0, we get x = 1, y = 0
Equation of line of intersection of P1 = 0, P2 = 0 is parallel to the plane P3 = 0.

So distance of point (–1, 0, 0) from P3 = 0 is

58)

59)

For λ = 0, ƒ(x) = sgn(x2 – |x|)

ƒ(x) is non diff. at x = 0,4,–4
for λ = 4, ƒ(x) = sgn(((x)–2)2)
∴ Non diff at x = 12

for λ = 5, ƒ(x) = sgn

∴ differentiable ∀ x ∈ R
2
for λ = 2, ƒ(x) = sgn(x – 4|x| + 2)
∴ Non diff. at 4 points.

60) [cos–1x] + 2[sin–1x] = 0

only if [cos–1x] = [sin–1x] = 0
or [cos–1x] = 2, [sin–1x] = –1
Case-I : [cos–1x] = 0 ⇒ x ∈ (cos1, 1] ....(1)
–1
[sin x] = 0 ⇒ x ∈ [0, sin1) ....(2)
⇒ (1) ∩ (2), x ∈ (cos1, sin1) ....(3)
–1
Case-II : [cos x] = 2 ⇒ x ∈ (cos3,cos2] ....(4)
[sin–1x] = –1 ⇒ x ∈ [–sin1, 0) ....(5)
(3) ∪ (5) ⇒ [–sin1, cos2] ∪ (cos1,sin1)

61)

62) The planes are

y + z = 0 ...(1)
z + x = 0 ...(2)
x + y = 0 ...(3)
x + y + z = 2 ...(4)
on solving, vertices are (0, 0, 0), (2, 2, – 2), (2, – 2, 2) and (–2, 2, 2).

Required volume =

63) Equation of line

Let P(1, 0, –1), Q (–1, 2, 2)

angle between line & plane

Projection

64) Obviously option (3) is correct.

65) 0 ≤ 3cos–1a ≤ π

66) R = {(2,6), (2,10), (3,3), (3,6),(5,10)}

∴ 5 elements in R–1

67) ƒ(10) ; let 10100 = t

⇒ ⇒ unit digit is 3.
∴ x i.e. 201 is a divisor

68)

⇒ L = – 30

69) ƒ(100) – g(100)

= (2)(4)(6) ...... (200) – (1)(3)(5)......(199)
Let x = 201
= (x – 1)(x – 2)....(x – 199) – (1)(3) ...... (199)
as constant term cancelled

70) g(x) = ƒ(x) sinx

g'(x) = ƒ(x)cosx + ƒ'(x) sinx
g"(x) = ƒ'(x)cosx – sinxƒ(x) + ƒ'(x) cosx + sinxƒ"(x)
g"(–π) = 2ƒ'(–π)cosπ = –2

71)

72)

⇒
 9 = 16 + λ2 – 8λ
⇒ λ2 – 8λ + 7 = 0
Sum of all possible values of λ = 8

73) Required limit is

∵ ƒ–1(x) = x – 1; g–1(x) = x3 + x + 1
Also h(x) = g(ƒ(x))
⇒ h–1(x) = ƒ–1(g–1(x)) = x3 + x

74) g(x) is not differentiable at x = 0 only

75)
⇒ x = 2 + λ, y = 2λ + 9, z = 3λ + 13
This lies on L2

∴
by q and r : λ = –3
put in q and solve p and q, a = –3