CHEMISTRY
46. The volume of a gas in discharge tube is 58. Elements A and B form two compounds B2A3
–7
1.12 × 10 mL at STP. Then the number of and B2A. 0.05 moles of B2A3 weigh 9.0 g and
molecule of gas in the tube is - 0.10 mole of B2A weigh 10 g. Atomic weight of
4 15
(1) 3.01 × 10 (2) 3.01 × 10
12 16 A and B are-
(3) 3.01 × 10 (4) 3.01 × 10
(1) 20 and 30 (2) 30 and 40
47. Vapour density of gas is 11.2, volume occupied (3) 40 and 30 (4) 30 and 20
by 2.4 g of this at STP will be -
(1) 11.2 L (2) 2.24 L 59. If 3.01 × 1020 molecules are removed from
(3) 22.4 L (4) 2.4 L 98 mg of H2SO4, then the number of moles of
48. Which of the following contains the least number H2SO4 left are :–
(1) 0.1 × 10 (2) 0.5 × 10
–3 –3
of molecules ?
(3) 1.66 × 10 (4) 9.95 × 10
–3 –2
(1) 4.4 g CO2 (2) 3.4 g NH3
(3) 1.6 g CH4 (4) 3.2 g SO2
60. Which of the following has the highest mass ?
49. The number of molecule in 4.25 g of NH3 is - (1) 1 g atom of C
23 23
(1) 1.505 × 10 (2) 3.01 × 10 (2) 1/2 mole of CH4
23
(3) 6.02 × 10 (4) None of these (3) 10 mL of water
23
50. Vapour density of ammonia is 8.5, then 85 g of (4) 3.011 × 10 atoms of oxygen
NH3 at NTP will occupy. 61. An oxide of metal M has 40% by mass of
(1) 22.4 L (2) 112 L oxygen. Metal M has atomic mass of 24. The
(3) 224 L (4) 1120 L empirical formula of the oxide is
51. Which of the following contains the highest (1) M2O (2) M2O3 (3) MO (4) M3O4
number of molecules - 62. A compound contains 38.8% C, 16.0% H and
(1) 2.8 g of CO (2) 3.2 g of CH4
45.2% N. The formula of the compound would be
(3) 1.7 g of NH3 (4) 3.2 g of SO2
(1) CH3NH2 (2) CH3CN
52. 5.6 L of oxygen at NTP is equivalent to – (3) C2H5CN (4) CH2(NH)2
(1) 1 mole (2) 1/2 mole 63.
. 10 mL of gaseous hydrocarbon on combustion
(3) 1/4 mole (4) 1/8 mole
give 40 mL of CO2(g) and 50 mL of H2O (vap.).
53. A gas is found to have the formula (CO)x. It's VD The hydrocarbon is -
is 70 the value of x must be:- (1) C4H5 (2) C8H10
(1) 7 (2) 4 (3) 5 (4) 6 (3) C4H8 (4) C4H10
54.
23
If 32 g of O2 contains 6.022 × 10 molecules at 64. 500 mL of a gaseous hydrocarbon when burnt in
NTP then 32 g of S, under the same conditions, excess of O2 gave 2.5 L of CO2 and 3.0 L of
will contain:- water vapours under same conditions. Molecular
23 21
(1) 6.022 × 10 S (2) 3.011 × 10 S formula of the hydrocarbon is -
23 23
(3) 1 × 10 S (4) 12.044 × 10 S (1) C4H8 (2) C4H10
55. 4.4 g of an unknown gas occupies 2.24 L of (3) C5H10 (4) C5H12
volume at STP. The gas may be :- 65. 1 L of a hydrocarbon weighs as much as one
(1) N2O (2) CO
litre of CO2 Under similar conditions. Then the
(3) CO2 (4) 1 & 3 both
molecular formula of the hydrocarbon is -
56. Which contains least no. of molecules :– (1) C3H8 (2) C2H6
(1) 1 g CO2 (2) 1 g N2 (3) C2H4 (4) C3H6
(3) 1 g O2 (4) 1 g H2
66. 0.01 mole of iodoform (CHI3) reacts with Ag to
57. Air contains nearly 20% oxygen by volume. The produce a gas whose volume at NTP is
volume of air needed for complete combustion of 2CHI3 + 6Ag → C2H2 + 6Ag I(s)
100 mL of acetylene will be :
(1) 224 mL (2) 112 mL
(1) 500 mL (2) 100 mL
(3) 250 mL (4) 1250 mL (3) 336 mL (4) None of these
67. CaCO3 is 90% pure. Volume of CO2 collected at 76. On analysis, a certain compound was found to
STP when 10 g of CaCO3 is decomposed is - contain iodine and oxygen in the ratio of
(1) 2.016 litres (2) 1.008 litres 254:80. The formula of the compound is :
(3) 10.08 litres (4) 20.16 litres (At mass I = 127, O = 16)
68. How many mole of magnesium phosphate, (1) IO (2) I2O
Mg3(PO4)2 will contain 0.25 mole of oxygen atoms? (3) I5O2 (4) I2O5
–2
(1) 2.5 × 10 77. Suppose the elements X and Y combine to form
(2) 0.02 two compounds XY2 and X3Y2. When 0.1 mole
(3) 3.125 × 10
–2 of XY2 weighs 10 g and 0.05 mole of X3Y2
–2 weighs 9 g, the atomic weights of X and Y are
(4) 1.25 × 10
(1) 20,30 (2) 30,20 (3) 40,30 (4) 60,40
69. Perecentage composition of an organic compound
78. A mixture of 2.3 g formic acid and 4.5 g oxalic acid
is as follows :
is treated with conc. H2SO4. The evolved gaseous
C=10.06, H=0.84 , Cl=89.10
mixture is passed through KOH pellets. Weight
Which of the following corresponds to its
(in g) of the remaining product at STP will be
molecular formula if the vapour density is 60.0
(i) HCOOH
H 2SO 4
→ CO + H2O
(1) CH2 Cl2 (2) CHCl3
Formic acid (H2O absorbed by H2SO4)
(3) CH3Cl (4) None
(ii) H2C2O4 → CO + CO2 + H2O
H 2SO 4
70. The ratio of masses of oxygen and nitrogen in a
Oxalic acid (H2O absorbed by H2SO4)
particular gaseous mixture is 1 : 4. The ratio of
(iii) CO2 is absorbed by KOH
number of their molecule is
(1) 1.4 (2) 3.0 (3) 2.8 (4) 4.4
(1) 1 : 8 (2) 3 : 16
(3) 1 : 4 (4) 7 : 32
79. In which case the number of molecules of water is
71. 23 g sodium metal reacts with water. Calculate the maximum?
(a) volume of H2 liberated at NTP (b) moles of H2 (1) 18 mL of water
liberated (c) weight of H2 liberated. (2) 0.18 g of water
2Na + 2H2O → 2NaOH + H2 (3) 0.00224 L of water vapours at 1 atm and
(1) 22.4 L, 1 mol, 2g 273 K
–3
(2) 11.2 L, 1/2 mol, 1g (4) 10 mol of water
(3) 44.8 L, 2 mol, 4g
80. The number of moles of hydrogen molecules
(4) None of the above required to produce 20 moles of ammonia
72. Which of the following is a compound through Haber's process is :-
(1) graphite (2) steel (1) 10 (2) 20 (3) 30 (4) 40
(3) cement (4) marble
81. The volume occupied by 1.8 g of water vapour
73. Calculate the number of atoms of chlorine in at 374 °C and 1 bar pressure will be :-
2.08 gm of BaCl2.(Atomic weight of Ba = 137, –1
[Use R = 0.083 bar L K mol ]
–1
Cl = 35.5) (1) 96.66 L (2) 55.87 L
–1
(1) 2 × 10 NA (2) 2 NA (3) 3.10 L (4) 5.37 L
–2 –3
(3) 2 × 10 NA (4) 2 × 10 NA
82. Which one of the following has maximum number
74. A container of volume V, contains 0.28 g of N2 of atoms?
gas. If same volume of an unknown gas under (1) 1g of Li(s) [Atomic mass of Li = 7]
similar condition of temperature and pressure (2) 1g of Ag(s) [Atomic mass of Ag = 108]
weighs, 0.44 g, the molecular mass of the gas is (3) 1g of Mg(s) [Atomic mass of Mg = 24]
(1) 22 (2) 44 (4) 1g of O2(g) [Atomic mass of O = 16]
(3) 66 (4) 88 83. One mole of carbon atom weighs 12 g, the
75. 2.2 g of a compound of phosphorous and sulphur number of atoms in it is equal to, (Mass of
–23
has 1.24 g of 'P' in it. Its empirical formula is - carbon – 12 is 1.9926 × 10 g)
23 22
(1) P2S3 (2) P3S2 (1) 1.2 × 10 (2) 6.022 × 10
22 23
(3) 12 × 10 (4) 6.022 × 10
(3) P3S4 (4) P4S3
84. An organic comopound contains 78% (by wt.) 88. In one molal solution that contains 0.5 mole
carbon and remaining percentage of hydrogen. of a solute, there is
The right option for the empirical formula of this (1) 500 g of solvent
compound is [Atomic wt. of C is 12, H is 1] (2) 100 mL of solvent
(1) CH (2) CH2 (3) 1000 g of solvent
(3) CH3 (4) CH4 (4) 500 mL of solvent
85. An organic compound on analysis gave C = 54.5%, 89. What mass of 95% pure CaCO3 will be
H = 9.1% by mass. Its empirical formula is required to neutralise 50 mL of 0.5 M HCl
(1) CHO2 (2) CH2O solution according to the following reaction ?
(3) C2H4O (4) C3H4O CaCO3(s)+2HCl(aq) → CaCl2(aq)+CO2(g)+2H2O(l)
86. If 1 mL of water contains 20 drops then number [Calculate upto second place of decimal
of molecules in a drop of water is point]
(1) 6.023 × 1023 (2) 1.673 × 1021 (1) 1.32 g (2) 3.65 g
(3) 1.344 × 1018 (4) 4.346 × 1020 (3) 9.50 g (4) 1.25 g
87. A sample of phosphorous trichloride (PCl3) 90. What is the mole fraction of the solute in a
contains 1.4 moles of the substance. How many 1.00 m aqueous solution?
atoms are there in the sample? (1) 0.0354 (2) 0.0177 (3) 0.177 (4) 1.770
(1) 4 (2) 5.6
(3) 8.431 × 10 23 (4) 3.372 × 1024
