D and F Block Elements - Detailed Notes
D-Block Elements
D-BLOCK ELEMENTS (Transition Elements)
Position: Groups 3 to 12 in the periodic table.
General electronic configuration: (n-1)d1-10 ns0-2
Characteristics:
- Variable oxidation states (e.g., Fe2+, Fe3+)
- Colored ions (due to d-d transitions)
- Catalytic properties (e.g., Fe in Haber process)
- Magnetic properties (paramagnetic if unpaired electrons)
- Complex formation due to high charge/small size
- High melting/boiling points, good conductors
Trends:
- Atomic radius: decreases across a period
- Ionization energy: increases slightly across a period
- Density: high
D and F Block Elements - Detailed Notes
F-Block Elements
F-BLOCK ELEMENTS (Inner Transition Elements)
Position: Below the main periodic table.
Includes: Lanthanides (4f) and Actinides (5f)
General configuration: (n-2)f1-14 (n-1)d0-1 ns2
Lanthanides:
- Common oxidation state: +3
- Lanthanide contraction (decreasing radius)
- Colored ions, paramagnetism, limited complex formation
- Uses: polishing agents, magnets, alloys
Actinides:
- Variable oxidation states (+3 to +6)
- All radioactive, form complexes, show color and magnetism
- Uses: nuclear energy (U, Th, Pu)
Comparison with D-block:
- F-block fills f-orbitals; D-block fills d-orbitals
- F-block has more radioactive elements
- D-block forms more stable complexes