EXAM 1

1- From the following diagram which of the following is correct ?

CH3 CH3
I I
V2O5 CH3Cl V2O5
B A
O2 AlCl3 O2
I
CH3
(a) Sodium salt of compound (A) has pOH greater than 7
(b) dry distillation of both (A), (B) gives toluene
(c) compound (B) is used in the manufacture of replacement fibers for damaged
arteries
(d) A reacts with ethanol gives vinyl ethanoate
2- from the following reaction :
X+2H+→X+2 +H2 E=0.49V
X+Y+2→X+2 +Y E=0.83V
H2+Z →Z+2H
+2 +
E=0.8V
Which of the following is correct for the cell :Y0/Y+2//Z+2/Z0
a) galvanic cell and e.m.f =0.46V b) electrolytic cell and e.m.f =-0.46V
c) galvanic cell and e.m.f = 1.14V d) electrolytic cell and e.m.f = -1.14V
3- From the following diagram
NaOH Dry
Citric acid A B
distillation
(a) compound B is primary alcohol
(b) Compound A effect by oxidizing agents
(c) compound B oxidized to propanone
(d) compound B react with HCl gives tertiary alkyl halide
4- From the following diagram : which of the following choices is correct about X ,
Y?
terephthalic Excess of CH3OH X Excess
Y
with dry HCl of NH3
(a) X reacts with NaOH gives salt used in manufacture / Y is diamide compound
(b) X analyses in acidic medium and gives an aliphatic alcohol / Y is mono amide
compound
(c) X reacts with NaOH gives dibasic aromatic alcohol / Y is diamide compound
(d) X analyses in acidic medium and gives aromatic acid / Y is mono amide
compound
5- in the following reaction :
SO3 ⇌ SO2 + ½ O2
Kc increase by increasing the temperature, for increasing the speed of reversible
reaction by ……..
(a) increasing pressure and cooling
(b) decreasing pressure and increasing the temperature
(c) increasing pressure and adding catalyst
(d) increasing temperature and adding more SO2
6- Study the following shape :

And if you have known that Ecell of the cell A / A+2 //2H+ / H2 equal 0.76 volt so which
of the following is correct ?
(a) a solution containing B2+ ions can be stored in containers of element C
(b) The e.m.f of the cell produced by C,A lower than the e.m.f of A,B cell
(c) the mass of C electrode decreases by time
(d) the mass of A electrode increases by time

7-if an weak monoprotic acid its ionization degree increased to double so it will
…………………
(a) Ionization constant increase to double
(b) its concentration increase to double
(c) its concentration decreases into half
(d) its concentration decreases into quarter
8-if Ni+3/Ni+2 =0.9V ,Cd+2/Cd0 =-0.4V
When making a cell from Ni and Cd , the following reaction is happened
Cd+2Ni+3→Cd+2+2Ni+2
Which of the following choice is correct ?
a)e.m.f for the cell =1.3V during charging
b)the reaction is non-spontenous
c)e.m.f for the cell =1.3V during discharging
d)the mass of Cd during discharge
9-if you know:
X/X+2=0.49V
Z+2/Z0 =0.8V
X+Y+2→X+2+Y E=0.83V
When making a cell from Y and Z , which of the following choice is correct?
a)the cell is galvanic and e.m.f=0.46V
b)Z is anode and its mass decrease
c)the cell is electrolytic and e.m.f=-0.46V
d)Y is cathode and its mass increase
10- A solution its pH equal 5.5 so, its (OH)- concentration equal ……………..
(a) 3.16x10-9 (b) 3.1x10-6
(c) 8.5 (d) 3.2x10-5
11- Which of the following diagrams represents the relation between pH with time
while charging lead acid cell battery ? pH
pH pH pH

Time Time Time

(a) Time (b) (c) (d)

12-Solution of acetic acid its pH value 5.5 , which of the following choice is correct ?
a)the concentration of OH- equal 3.16x10-9
b)the concentration of H+ is less than the concentration of OH-
c)the concentration of H+ equal 3.16x10-9
d)its pH value decrease by dilution
13-when adding drops of HCl to HCN acidic solution so,
a)the ionization constant of HCN increase and the concentration of CN- decrease
b)the ionization constant of HCN stay constant and the concentration of CN-
increase
c)the ionization degree constant of HCN increase and the concentration of CN-
decrease
d)the ionization constant constant of HCN stay constant and the concentration of
CN- decrease
14- What is the mass of silver deposit after passing 3.01x1022 electron ? [Ag=108]
(a) 8.1g (b) 5.4g
(c) 2.7g (d) 10.29g
 15- from the following diagram which of the is correct ?
Hydroxyl NH3 NaOH
Simplest alcohol A B C
aromatic acid

A B C
(a) Marookh oil COONa
COOH
O
O NH2
NH2
(b) Aspirin COOH COONa

O O
NH2 NH2

(c) Marookh oil CONH2 CONH2

OH ONa

(d) Aspirin CONH2 CONH2

OH O
Na

16- In Daniel’s cell , it was operated for an hour and half, and the current intensity
was 0.2A and the mass of anode = the mass of cathode =10g calculate mass of each of
them after 3hours ? [Cu 63.5 , Zn = 65]
(a) Zn = 8.55g , Cu = 8.58g
(b) Zn = 1.45g , Cu = 1.42g
(c) Zn = 11.45g , Cu = 11.42g
(d) Zn = 9.272g , Cu = 10.71g
17-ZnS solution its volume equal 5L and Ksp=10-6 at 60°𝑪 and Ksp=10-8 at 20°𝑪
calculate tha mass deposit …..
[Zn=65,S=32]
a)0.44g b)1.5X10-7
c)4.95g d)4.5X10-3
18-in the following reaction:
A2(g)+3B2(g) ⇌ 2AB3(g) ∆H<0
The reaction is moved forward when……….
a) increase the volume of vessel
b) adding catalyst
c) increase the temperature
d) add the vessel in cold medium
19- 2 mol of weak acid RCOOH has been dissolved in one liter of water and in the
equilibrium state the number of moles of the acid equal 1.5
Calculate Ka
(a) 1.66 (b) 0.25
(c) 0.5 (d) 0.166
20- mixture of magnesium chloride and sodium chloride have the same number of
moles dissolved in water then adding a silver nitrate solution into it so 12g of silver
chloride precipitated , which of the following is correct about mass of magnesium
chloride and sodium chloride respectively ?
[Ag=108 , Mg=24, Na=23 , Cl=35.5]
(a) 2.64g , 1.63g (b) 8g , 4g
(c) 2.4g , 1.2g (d) 9.1g , 5.8g
21- In mercury cell when replacing zinc with nickel so ………………
(a) there is no generation of electric current
(b) e.m.f of the cell doesn’t change
(c) e.m.f of the cell decreases
(d) e.m.f of the cell increases

22- which of the following choices is correct, if the reduction potential of nickel equal
= (-0.23V) so when replacing zinc with nickel in the mercury cell?
(a) the e.m.f of the cell increase
(b) gives an e.m.f equal = 0.82v
(c) doesn’t give an electric current
(d) convert into secondary cell
23-mercury cell is differs from the fuel cell in ……
a)the pH value of both electrolyte is more than 7
b)both of them store energy
c)both are galvanic cell and generate electric current
d)both of them electrolytic cell
24- if the difference in the activation energy between the reversible and irreversible
reactions equal -90kJ so that ………………….
(a) endothermic irreversible reaction , ∆H = -90kJ
(b) Kc increase by cooling
(c) exothermic reversible reaction , ∆H = -90kJ
(d) Kc decrease by heating
25-the electronic configuration of the positive ion in the oxide of the transition
element which is used in the preparation of an acid by contact method is ………..
a)[Ar18],3d7
b)[Ar18],3d8
c)[Ar18],4s2
d)[Ar18]
26-when roasting siderite in air, which of the following is correct ?
a)oxidation number of iron doesn’t change
b)the percentage of iron decrease in the final product
c)the mass of ore decrease then increase
d)the process of reduction then oxidation of the iron ion occurs
27-which of the following choice is hard to occur ?
a)Mn+2→Mn+3 b)Sc0→Sc+3
c)Fe+2→Fe+3 d)Ti+3→Ti+4
28-Metal (X) reacts with metal (Y) sulphate solution, as follows :
X(s) +YSO4(aq) →XSO4(aq) + Y(s)
However, metal (X) cannot react with metal (Z) sulphate solution. of these metals in
terms of their oxidation potentials ?
a)(X)<(Y)<(Z) b)(Y) < (X) <(Z)
c)(Z) < (Y) < (X) d)(Z) < (X) < (Y)
29- X is ester used in treatment of cold and headache , Y is ester used in production of
a substance for replacement of damaged arteries , so which of the following choice is
correct ?
(a) X is a product from reaction of aliphatic acid with aromatic acid
(b) Y is a product from dihydroxyl alcohol with aliphatic dicarboxylic acid
(c) X is a product from reaction of methanol with salicylic acid
(d) Y produced from polymerization by addition
30-which of the following statements is correct ?
X Y Z
C3H8O3 C2H6O2 C3H8O
a)X is tertiary alcohol
b)when oxidation the element Z , it gives acid or ketone and its boiling point is the
least
c)Y can obtain it by Alcoholic fermentation
d)the boiling point X is more than Y,Z
31-which of the following is more active ?
a)propene b)butane
c)3-methyl-1-butyene d)2-methyl-1-butene
32- formula C3H8O2 represent ……………..
(a) 1,2 di hydroxyl propane
(b) methyl ethanoate ester
(c) propanoic acid
(d) ethyl ethanoate ester

33- The following graph illustrates the relation between

the atomic number of three successive transition Atomic number
elements (X,Y,Z) and their oxidation numbers Y
7
- the possible groups they are found in are ……….
X Y Z 6 X
(a) VIB VIIB VIII
(b) IB IIB IIIB 3 Z
(c) IVB VB VIB
(d) IIIB VIB VB Oxidation state
34- 4g of impure sodium chloride dissolved in water and excess of silver nitrate
solution is added to it , 3,52g of silver chloride precipitated , so the mass percentage
of chloride ion = ………… [ Ag = 108 , Cl = 35.5 , Na = 23]
(a) 20.8% (b) 21.77% (c) 19.77% (d) 22.8%
35- Which of the following reactions is considered as a complete reaction ? ……
(a) AgNO3(aq) + NaBr(aq) = AgBr(s) + NaNO3(aq)
(b) 2NO(g) + O2(g) = 2NO2(g) (closed vessel)
(c) CH3COOH(l) + C2H5OH(l) = CH3COOC2H5(aq) + H2O(l)
(d) N2(g) + 3H2(g) = 2NH3(g) (closed vessel)
36-the scheme below shows some processes occurring at the required condition :

Violet fumes (2) water (2) Yellow ppt

X(s) X(aq)

Water

Colorled Colorless
(3)
solution solution

which of the following is correct ?

a)(1)AgNO3 , (2)HBr , (3)Na2SO3
b)(1)Na3PO4 , (2)HBr , (3)Na2S2O3
c)(1) AgNO3 , (2) H2SO4 , (3) Na2S2O3
d)(1)Na3PO4 , (2) H2SO4 , (3) Na2S2O3
37- What are the processes which occur (in the mentioned order) to obtain iron (III)
chloride from siderite?
(a) Roasting – Reduction at 800oC – Oxidation by chlorine
(b) Oxidation by chlorine – Reduction at 800oC – Roasting
(c) Heating – Reduction at 300oC – Oxidation by chlorine
(d) Reduction at 300oC – Oxidation by chlorine – Heating at 800oC
38-Which of the following compounds decolorizes potassium permanganate solution in
an alkaline medium?
a)CH3CH3 b)CH3CHCHCH2CH3
c) d)CH(CH3)3
39-Upon the hydration of the shown alkyne then rearrangement (tautomerization) ,
each of the following is formed , except X-C≡C-Y
Choice The product when
(X) is (Y) is
a) Aldehyde Hydrogen Hydrogen
b) Ketone Hydrogen Alkyl
c) Aldehyde Alkyl Hydrogen
d) Ketone Alkyl Alkyl
40-in the terms compound :
(A) (B) (C) (D)

CH3 O H
I II I
CH3 -C-OH H-C-H CH3OCH3 CH3-O-CH2-C-CH3
I I
CH3
OH
Which of the following is correct?
a)(A) is an isomer of propanol, (C) is an ether.
b)(B) is used in preparing Bakelite, (D) is an unsaturated aliphatic compound.
c)(B) is an alcohol, (D) contains 2 functional groups.
d)(C) is an isomer of ethanol, (A) is prepared through the hydration of 2-methyl-1-
propene
41-The ester which is an isomer of HCOOCH2CH3 can be prepared through the
reaction of………………
(a) Formic acid with ethyl alcohol
(b) Acetic acid with methyl alcohol
(c) Formic acid with methyl alcohol
(d) Acetic acid with ethyl alcohol
42- When compound (x) undergoes thermal catalytic cracking, the unsaturated
compound (Y) is formed with another saturated compound its proportion in the gas
cylinders used in the cold countries is the higher, if the number of carbon atoms in
compound (Y) is higher than in the other product by 4
What is the physical state of compound (X)? What is the formula of (Y)?
(a) (X) is liquid / (Y): C7H14
(b) (X) is liquid / (Y): C6H12
(c) (X) is solid / (Y): C7H14
(d) (X) is solid / (Y): C6H12
43-What are the products of the oxidation carbinol groups (1),(2)and(3) in glycerol?
(a) 1): Ketone , 2): Acid , 3): Aldehyde
(b) 1): Acid , 2): Ketone , 3): Acid
(c) 1): Aldehyde , 2): Acid , 3): Ketone
(d) 1): Acid , 2): Acid , 3): Ketone
44-in the terms of these
(A) (B) (C) (D)
Al(NO3)3(aq) FeSO4 NH4OH(aq) HCl(aq)
The compound ……
a)(A) is used to detect the anions of both C and D
b)(B)is used to detect the cation of C and the anion of D
c)(C) is used to detect the cations both A and B
d)(D) is used to detect the cations both A and B
45-X , Y , Z , W Four transition elements lies in 1st series so,
X has highest density
Y has highest atomic radius
Z all of its compounds which contain Z+3 ion have green color
W is diamagnetic in the state of oxidation +4
Mention one use for all of the following W , X , Z ,Y
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………
46-Write the formula for X,Y,Z,W :

C2H4 Catalytic X CH3COOH Y

hydration

H2SO4 X Z NaOH
+
180
Dry distillation

W
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
………………………………………………………………………………………………
……………….